• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.46 no.3
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• pp.1-10
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• 2014

Offset paper printing is a promising roll-to-roll technique for color printed materials. Although it is no doubt that understanding ink transfer mechanism in offset printing process is necessary to achieve high printing quality, investing the relationship between inks and substrates at the nip is difficult experimentally due to high printing speed. In this paper, rheological behavior and splitting point of the ink at the nip is studied using package software Ployflow and Flow 3D based on Navier-Stokes equation. Polydimethylsiloxane (PDMS) ink and IGT printability tester were used for an model ink and experiment to compare with that of simulation data, respectively. As a result, higher viscosity at state flow and pressure increased ink transfer due to higher possibility of presence of cavitation at the nip and increase in covering area ratio. These results have shown good agreements with experimental data compared by measuring density of print through.

• Applied Chemistry for Engineering
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• v.25 no.2
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• pp.157-160
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• 2014

We examined and compared the feasibility of vegetable oils with synthetic thermal conductive oils to recover highly purified copper metal from waste jelly-filled communication cables. While polydimethylsiloxane shows relatively poor separation efficiency under entire operating conditions, dibenzyltoluene and waste vegetable oil show the high separation efficiency if the appropriate operating temperature and time were given. By running 50 kg-class equipment with waste vegetable oils, we obtained 100% copper metal recovery with 99.2% purity at $300^{\circ}C$ for 60 min.

• Journal of Sensor Science and Technology
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• v.15 no.1
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• pp.53-57
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• 2006

This paper describes a novel processing technique for fabrication of polymer-derived SiCN (silicone carbonitride) microstructures for super-temperature MEMS applications. PDMS (polydimethylsiloxane) mold is fabricated on SU-8 photoresist using standard UV photolithographic process. Liquid precursor is injected into the PDMS mold. Finally, solid polymer structure is cross-linked using HIP (hot isostatic pressure) at $400^{\circ}C$, 205 bar. Optimum pyrolysis and annealing conditions are determined to form a ceramic microstructure capable of withstanding over $1400^{\circ}C$. The fabricated SiCN ceramic microstructure has excellent characteristics, such as shear strength (15.2 N), insulation resistance ($2.163{\times}10^{14}{\Omega}$) and BDV (min. 1.2 kV) under optimum process condition. These fabricated SiCN ceramic microstructures have greater electric and physical characteristics than bulk Si wafer. The fabricated SiCN microstructures would be applied for supertemperature MEMS applications such as heat exchanger and combustion chamber.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2018.06a
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• pp.43.1-43.1
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• 2018

Spatial distribution of binding state in depth direction is investigated in a hard skin layer on soft polydimethylsiloxane (PDMS) fabricated by Ar ion beam irradiations. The hard skin layer known as a silica-like homogenous layer was composed of two layers. Impinging Ar ions transfer energy to PDMS as a function of collisional energy transfer rate, which is the maximum at surface and decreases gradually as an ion penetrates. This formed the heterogeneous hard skin layer that consists of a top-most layer and an intermediate layer. XPS depth profiling showed the existence of the top-most layer and intermediate layer. In the top-most layer, scission and cross-linking were occurred simultaneously and Si-O bond showed dissociated status, SiOx (x = 1.25 - 1.5). Under the top-most layer, there was the intermediate layer in which cross-linking is mainly occurred and Si-O bond showed silica-like binding status, SiOx (x = 1.75 - 2). And theoretical analysis which calculates the collisional energy transfer and a displacement per atom explained the thickness variation of top-most layer according to Ar ion energy from 360 eV to 840 eV.

• Transactions on Electrical and Electronic Materials
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• v.3 no.4
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• pp.10-15
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• 2002

Surface states of polydimethylsiloxane (PDMS) treated by plasma were investigated by the analysis by x-ray photoelectron spectroscopy (XPS) and surface voltage decay. Plasma treatment causes the silica-like(SiO$\_$x/, x=3∼4) oxidative layer, which is confirmed with XPS, and lowers surface resistivity from 1.78$\times$1014 Ω/square to 1.09$\times$10$\^$13/ Ω/square with increasing the plasma treatment time. By measuring the decay time constant of surface voltage, the calculated surface resistivity was compared with the value directly measured by a voltage-current method, so good agreement between two methods was obtained. It was observed that the plasma treatment led to decrease of the thermal activation energy of the surface conduction from 31.0 kJ/mol of untreated specimen to 21.8 kJ/mol. It is found that our results allow the examination of effects of plasma on electrical properties of PDMS.

• Membrane Journal
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• v.4 no.1
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• pp.57-62
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• 1994

This study uses pervaporation process to separate small amount of organic trichloroethylene, chloroform and perchloroethylene from contaminated water, since chlorinated hydrocarbones are known to be cancer suspecting compounds. For the separation of small amount of halogenated organic compound dissolved in wastewater, pervaporation membranes should be polymers that possess affinity with orgnic compounds and hydrophobicity. We used polyisobutylene, polyetheramide and polydimethylsiloxane membranes. The degree of affinity between organics and polymers were measured by contact angle method. We had good separation results that separation factor ranged from 34 to 19100 and permeate flux was$19.7~140g/m^2hr$.

• Proceedings of the Materials Research Society of Korea Conference
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• 2012.05a
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• pp.77.2-77.2
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• 2012

급속한 첨단기술의 발전으로 인해 차세대 정보산업의 핵심 기술은 사용자의 편의를 바탕으로 필요에 따라 형태가 변환되어 휴대 또는 착용이 가능하고 다양한 기능이 융합된 전자소자의 기술을 개발 하는 것이다. 현재까지는 이를 구현하기 위해 저분자, 고분자 반도체 및 박막형 무기 반도체를 이용하여 신축 가능한 소자를 구현 하였으나 기존 소재들의 제한적인 물성으로 인해 그 연구가 한계를 다다르고 있다. 이에 반해 신소재 그래핀은 우수한 기계적, 전기적 및 광학적 특징을 동시에 가지고 있는 물질로써 유연 소자분야에 적합한 재료로 각광받고 있다. 하지만 뛰어난 그래핀의 특성에도 불구하고 소자를 구성하는 다른 요소인 기판, 유전막 등의 물성적 한계로 인하여 신축 가능한 소자제작을 위해서는 아직도 많은 과제가 남아있다. 본 연구에서는 Polydimethylsiloxane (PDMS) 고무기판 위에 전해질 유전막을 도입하여 신축 가능하고 투명한 그래핀 트렌지스터를 구현하였다. 에어로졸 프린팅 방법으로 상온에서 형성 된 전해질 유전막은 높은 정전용량으로 인해 3V이하의 낮은 전압에서도 소자가 구동하는 것을 확인할 수 있었으며, 1100 과 420 $cm^2/Vs$의 높은 정공과 전자의 이동도를 나타내었다. 뿐만 아니라 이러한 전기적 특성은 외부에 가해지는 5%의 응력 및 1000회의 피로도 테스트 후에도 안정적인 거동을 보이는 매우 우수한 탄성특성을 보였다.

• Bulletin of the Korean Chemical Society
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• v.28 no.4
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• pp.553-556
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• 2007

We previously reported a 27.12 MHz inductively coupled plasma source at atmospheric pressure for atomic emission spectrometry based on polymer microchip plasma technology. For the PDMS polymer microchip plasma, molecular emission was observed, but no metallic detection was done. In this experiment, a lab-made electrothermal vaporizer (ETV) with tantalum coil was connected to the microchip plasma for aqueous sample introduction to detect metal ions. The electrode geometry of this microchip plasma was redesigned for better stability and easy monitoring of emission. The plasma was operated at an rf power of 30-70 W using argon gas at 300 mL/min. Gas kinetic temperatures between 800-3200 K were obtained by measuring OH emission band. Limits of detection of about 20 ng/mL, 96.1 ng/mL, and 1.01 μ g/mL were obtained for alkali metals, Zn, and Pb, respectively, when 10 μ L samples in 0.1% nitric acid were injected into the ETV.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.30 no.10 s.253
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• pp.1261-1268
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• 2006

This paper reports low-cost microreactor $(10{\mu}{\ell})$ biochip for the DNA PCR (polymerase chain reaction). The microbiochip $(20mm{\times}28mm)$ is a hybrid type which is composed of PDMS (polydimethylsiloxane) layer with serpentine micochannel $(360{\mu}m{\times}100{\mu}m)$ chamber and glass substrate integrated with microheater and thermal microsensor. Undesirable bubble is usually created during sample loading to PMDS-based microchip because of hydrophobic chip surface. Created bubbles interrupt stable biochemical reaction. We designed improved microreactor chamber using microfluidic simulation. The designed reactor has a coner-rounded serpentine channel architecture, which enables stable injection into hydrophobic surface using micropipette only. Reactor temperature needed to PCR reaction is controlled within ${\pm}0.5^{\circ}C$ by PID controller of LabVIEW software. It is experimentally confirmed that SRY gene PCR by the fabricated microreactor chip is performed for less than 54 min.

• Membrane Journal
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• v.9 no.2
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• pp.107-113
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• 1999

Alcohol concentration via pervaporation process was performed by using commercial PDMS(polydimethylsiloxane) composite membrane and plasma treated PP(polypropylene) membranes. Effects of operating parameters of pcrvaporation process were examined. With the increase of butanol concentration in the feed, flux and selectivity increased due to the greater affinity of butanol with PDMS than that of water. As the operating temperature increased, free volume as well as the solubilities and diffusivities of alcohol and water increased to result in the greater flux and less selectivity of the membrane. As solubility parameter difference between alcohol and PDMS membrane decreased, high flux and good selectivity were obtained. When PP membrane was plasma treated with methanol, it has 6 times greater flux than PDMS membrane with equivalent separation factor. With the increase of plasma treatment time, flux and selectivity were enhanced. However, excess treatment time caused pore blocking to result in the flux decrease.