• Title/Summary/Keyword: POLYCARBONATE

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Excimer Laser Ablation of Polymer for Electroformed Mold (전주금형 제작을 위한 폴리머의 엑시머 레이저 어블레이션)

  • Lee Jae Hoon;Shin Dong Sig;Suh Jeong;Kim To Hoon
    • Journal of the Korean Society for Precision Engineering
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    • v.21 no.12
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    • pp.13-20
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    • 2004
  • Manufacturing process for the microfluidic device can include such sequential steps as master fabrication, electroforming, and injection molding. The laser ablation using masks has been applied to the fabrication of channels in microfluidic devices. In this study, manufacturing of polymer master and mold insert for micro injection molding was investigated. Ablation of PET (polyethylene terephthalate) by the excimer laser radiation could be used successfully to make three dimensional master fur nickel mold insert. The mechanism fur ablative decomposition of PET with KrF excimer laser $({\lambda}: 248 nm, pulse duration: 5 ns)$ was explained by photochemical process, while ablation mechanism of PMMA (polymethyl methacrylate) is dominated by photothermal process, the .eaction between PC (polycarbonate) and KrF excimer laser beam generate too much su.face debris. Thus, PET was adopted in polymer master for nickel mold insert. Nickel electroforming using laser ablated PET master was preferable for replication method. Finally, it was shown that excimer laser ablation can substitute for X-ray lithography of LIGA process in microstructuring.

The Thermal Degradation Mechanism of Polymethyl Methacrylate Blend (Polymethyl Methacrylate Blend의 열화에 따른 분해기구 해석에 관한 연구)

  • Kim, Dong-Keun;Moon, Myeong-Ho;Seul, Soo-Duk;Sohn, Jin-Eon
    • Elastomers and Composites
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    • v.23 no.2
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    • pp.125-133
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    • 1988
  • The thermal degradation of polymethyl methacrylate(PMMA) blend namely polymethyl methacrylate-polycarbonate(PMMA-PC) blend and polymethyl methacrylate-polystyrene(PMMA-PS) blend were carried out by isothermal method under air at several heating temperature from 220 to $270^{\circ}C$. Molecular weight changes during the thermal decomposition were monitored by means of the viscosity average molecular weight($\bar{M}v$). The viscosity average molecular weight was determined by Gel Permeation Chromatography(GPC). The dominant process in the degradation of PMMA-PC and PMMA-PS blend were main chain scission randomly due to weak links that may be distributed along the polymer backbone and the initial rate which the bonds are broken is not sustained. The infra-red spectra of degraded PMMA-PS blend show that the presence of aromatic ketone band at $1685cm^{-1}$. However, the infra-red spectra of degraded PMMA-PC blend show that the presence of hydroperoxide band at $3450cm^{-1}$. Thus indicating that the weak links are attacked by oxygen from the air and produce hydroperoxide or ketone. The activation energies of PMMA-PC blend and PMMA-PS blend were 18.2 and 17.9 Kcal/mol, respectively.

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Development of Up- and Down-flow Constructed Wetland for Advanced Wastewater Treatment in Rural Communities (소규모 오수발생지역의 고도처리시설을 위한 상.하 흐름형 인공습지 개발)

  • Kim, Hyung-Joong;Yoon, Chun-G.;Kwun, Tae-Young;Jung, Kwang-Wook
    • Journal of The Korean Society of Agricultural Engineers
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    • v.48 no.6
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    • pp.113-124
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    • 2006
  • The feasibility of the up- and down-flow constructed wetland was examined fur rural wastewater treatment in Korea. Many constructed wetland process was suffered from substrate clogging and high plant stresses because of long term operation. The up- and down-flow constructed wetland process used porous granule materials (charcoal pumice : SSR=10:20:70) for promoting intake rate of nutrient to plant, and especially flow type was designed continuously repeating from up-flow to down-flow. $BOD_5$ and SS was removed effectively by the process with the average removal rate being about 75% respectively. The wetland process was effective in treating nutrient as well as organic pollutant. Removal of TN and TP were more effective than other wetland system and mean effluent concentrations were approximately 7.5 and $0.4mg\;L^{-1}$ which satisfied the water quality standard for WWTPs. The treatment system did not experience any clogging or accumulations of pollutants and reduction of treatment efficiency during winter period because constructed polycarbonate glass structure prevented temperature drop. Considering stable performance and effective removal of pollutant in wastewater, low maintenance, and cost-effectiveness, the up- and down-flow constructed wetland was thought to be an effective and feasible alternative in rural area.

Immunopathological studies in mice exposed to bisphenol A (마우스에서 bisphenol A 노출로 인한 면역병리학적 연구)

  • 변정아;표명운
    • Environmental Mutagens and Carcinogens
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    • v.22 no.4
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    • pp.324-330
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    • 2002
  • Bisphenol A (BPA) is a monomer widely used in the manufacturing polycarbonate plastics or epoxy resin, and xenobiotics recently known as endocrine disrupting chemical. In this paper, to assess the effects of bisphenol A on immunopathological parameters (body weight, organ weight, hematological parameters, cellularity and surface marker) in mice, ICR female mice were orally exposed to BPA dissolved in olive oil as concentrations of 100, 500, 1000 ㎎/㎏/day b.w. 5 days a week for 30 days (subacute exposure). Liver - and kidney weight was significantly increased as dose-dependent manner, but body- , spleen- and thymus- weight didn't changed. In hematological parameters, WBC and MCHC were lowered but HCT and MCV were siginificantly enhanced. There was no significant differences in peritoneal macrophages number of the mice exposed to BPA. However, number of splenocytes of spleen, CD3/sup +/ and CD4/sup +/ cell in splenocytes, CD4/sup +/ and CD8/sup +/ cell in thymocytes were decreased at the mice subacutely exposed to BPA. In addition, BPA decreased expression of B7-1 and B7-2 on macrophages. Therefore, these results showed BPA may affect hematological parameters, cellularity and surface marker of immunocytes.

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Fabrication of a Silicon Nanostructure Array Embedded in a Polymer Film by using a Transfer Method (전사방법을 이용한 폴리머 필름에 내재된 실리콘 나노구조물 어레이 제작)

  • Shin, Hocheol;Lee, Dong-Ki;Cho, Younghak
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.25 no.1
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    • pp.62-67
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    • 2016
  • This paper presents a silicon nanostructure array embedded in a polymer film. The silicon nanostructure array was fabricated by using basic microelectromechanical systems (MEMS) processes such as photolithography, reactive ion etching, and anisotropic KOH wet etching. The fabricated silicon nanostructure array was transferred into polymer substrates such as polymethyl methacrylate (PMMA), polyethylene terephthalate (PET), and polycarbonate (PC) through the hot-embossing process. In order to determine the transfer conditions under which the silicon nanostructures do not fracture, hot-embossing experiments were performed at various temperatures, pressures, and pressing times. Transfer was successfully achieved with a pressure of 1 MPa and a temperature higher than the transition temperature for the three types of polymer substrates. The transferred silicon nanostructure array was electrically evaluated through measurements with a semiconductor parameter analyzer (SPA).

Evaluation on Mechanical Properties of PC and ABS Plastic Materials by Repetitive Impact (PC와 ABS 플라스틱재료의 반복적인 충격하중에 의한 기계적 특성 평가)

  • Lee, Jin-Kyung
    • Journal of the Korean Society of Industry Convergence
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    • v.23 no.3
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    • pp.375-380
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    • 2020
  • In this study, we tried to evaluate the mechanical properties of Polycarbonate(PC) and acrylonitrile-butadiene-styrene(ABS) plastic materials, which are frequently used as parts of home appliances and machinery, when repeated impacts were applied. A repeating impact tester for this research was designed and manufactured to apply repetitive impacts. Two types of plastic were repeatedly impacted under a constant load, and a tensile test was performed on the plastic material that was impacted. The tensile strength of PC plastic materials that received impact more than 2000 times was reduced by about 45 % and elongation was reduced by about 10 % when compared to impact free specimens. On the other hand, in ABS plastic, a reduction of tensile strength of about 20 % was observed at about 2,000 impacted specimen, but at about 20,000 repetitive impacted specimen, a tensile strength decrease of about 65 % was observed. And the elongation was reduced by 10 % due to the cyclic harding behavior of the material.

Evaluation of Radiolucent Considering the Compression Paddle Materials in Mammography (유방촬영장치의 압박대 재질을 고려한 투과선량 평가)

  • Hong, Dong-Hee
    • The Journal of the Korea Contents Association
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    • v.15 no.11
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    • pp.307-312
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    • 2015
  • Mammography improves image quality that is on the increase day by day and get a picture with the pressure it is essential to reduce the dose. However, because due to the thickness of the cuff itself may increase the dose scattering lines is necessary study on the cuff material. Material that is currently being used in clinical Polycarbonate is a plastic and family. If you try to reduce the exposure of patients than itgie need to consider for the better material in this study to compare against a radiolucent line for amorphous plastic material of the plastic. results radiolucent and half layer, transmitting dose Pixel values HIPS, GPPS, ABS, Tritan, PC, PMMA showed high results in the net.

Influence of Sputter Power on the Structural and Optical Properties of CdS Films for Photovoltaic Applications (태양전지용 CdS 박막의 구조적, 광학적 물성에 미치는 스퍼터 전력 효과)

  • Lee, Jae-Hyeong;Lim, Dong-Gun;Yang, Kea-Joon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.4
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    • pp.322-327
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    • 2006
  • CdS films have been prepared on polycarbonate, polyethylene terephthalate, and Coming 7059 substrates by r.f magnetron sputtering technique at room temperature. A comparison of the properties of the films deposited on polymer and glass substrates was performed. In addition, the influence of the sputter power on the structural and optical properties of these films was evaluated. The XRD measurements revealed that CdS films were polycrystalline and retained the mixed structure of hexagonal wurtzite and cubic phase, regardless of substrate types. As the sputter power was increased from 75 to 150 Watt, the structure of CdS films was converted from the mixed of hexagonal and cubic phase to hexagonal phase. The morphology of CdS films is found to be continuous and dense. Also, the grain of CdS films is larger with increasing the sputter power. The average transmittance exceeded 80 % in the visible spectrum for all films and decreases slightly with the sputter power.

Properties of ITO/Cu/ITO Multilayer Films for Application as Low Resistance Transparent Electrodes

  • Kim, Dae-Il
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.5
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    • pp.165-168
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    • 2009
  • Transparent and conducting ITO/Cu/ITO multilayered films were deposited by magnetron sputtering on unheated polycarbonate (PC) substrates. The thickness of the Cu intermediate film was varied from 5 to 20 nm. Changes in the microstructure and optoelectrical properties of ITO/Cu/ITO films were investigated with respect to the thickness of the Cu intermediated layer. The optoelectrical properties of the films were significantly influenced by the thickness of the Cu interlayer. The sandwich structure of ITO 50 nm/Cu 5 nm/ITO 45 nm films had a sheet resistance of $36{\Omega}$/Sq. and an optical transmittance of 67% (contain substrate) at a wavelength of 550 nm, while the ITO 50 nm/Cu 20 nm/ITO 30 nm films had a sheet resistance of $70{\Omega}$/Sq. and an optical transmittance of 36%. The electrical and optical properties of ITO/Cu/ITO films were determined mainly by the Cu film properties. From the figure of merit, it is concluded that the ITO/Cu/ITO films with a 5 nm Cu interlayer showed the better performance in transparent conducting electrode applications than the conventional ITO films.

Characterization of a Crystallized ZnO/CuSn/ZnO Multilayer Film Deposited with Low Temperature Magnetron Sputtering

  • Kim, Dae-Il
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.5
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    • pp.169-172
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    • 2009
  • The ZnO/CuSn/ZnO (ZCSZ) multilayer films were deposited on polycarbonate substrates using reactive RF and DC magnetron sputtering. The thickness of each layer was 50 nm/5 nm/45 nm, respectively. The ZCSZ films showed a sheet resistance of $44{\Omega}$/Sq, which was an order of magnitude lower than that indium tin oxide (ITO) films. Although the ZCSZ films had a CuSn interlayer that absorbed visible light, both films had similar optical transmittances of 74% in the visible wavelength region. The figure of merit of the ZCSZ films was $1.0{\times}10^{-3}{\Omega}^{-1}$ and was greater than the value of the ITO films, $1.6{\times}10^{-4}{\Omega}^{-1}$. From the X-ray diffraction (XRD) analysis, the ITO films did not show any diffraction peaks, whereas the ZCSZ films showed diffraction peaks for the ZnO (100) and (002) phases. The hardness of the ITO and ZCSZ films were 5.8 and 7.1 GPa, respectively, which were determined using nano-indentation. From these results, the ZCSZ films exhibited greater optoelectrical performance and hardness compared to the conventional ITO films.