• Title/Summary/Keyword: POLYCARBONATE

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Hard Coatings on Polycarbonate Plate by Sol-Gel Reactions of Silicates and Melamine Derivative (폴리카보네이트 판 위에 Silicates와 Melamine 유도체의 졸-겔 반응을 이용한 하드 코팅)

  • Kim, Se-Ra;Kang, Min-Kyung;Shin, Young-Jae;Oh, Mee-Hye;Yoon, Yeo-Seong;Shin, Jae-Sup
    • Polymer(Korea)
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    • v.31 no.6
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    • pp.485-490
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    • 2007
  • Hard coating was made on a polycarbonate plate using a sol-gel process with a melamine derivative and silicates, and examined as potential substitutes for automobile glass. Methylated poly(melamine-co-formaldehyde), tetraethoxysilane, and phenyltriethoxysilane were used to form a coating solution. The coatings on the polycarbonate plate were deposited using a sol-gel process. Poly(methyl methacrylate) was coated on the surface of polycarbonate in order to improve adhesion property. The optimum conditions and formulation to obtain excellent physical properties of the coating were determined. Adding the melamine derivative to the coating solution, the pencil hardness of the coating was improved. The hardness of a 3H class pencil, excellent abrasion resistance, and surface uniformity were found in the coated polycarbonate surface.

Effect of 1,3-Dioxolane on the Structure Development in Solution Casting Polycarbonate Film (1,3-Dioxolane이 용액 가공 폴리카보네이트 필름 구조 형성에 미치는 영향)

  • Kim, Jae-Hyun;Kim, Sung-Do;Han, Joon-Hee;Kang, Ho-Jong
    • Polymer(Korea)
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    • v.32 no.5
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    • pp.478-482
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    • 2008
  • The effect of 1,3-dioxolane on the structural development in the optical polycarbonate film was studied. The 1,3-dioxolane was used as an environmental friendly solvent for manufacturing solution-cast polycarbonate film instead of methylene chloride. The evaporation rate in film drying process decreased due to the high boiling temperature of 1,3-dioxolane. This caused the crystallization in the polycarbonate film. As a result, The increase of crystallinity and roughness led to the decrease of light transmissivity. It was also found that the lowering of mechanical properties in polycarbonate film was attributed to the morphological change due to the solvent evaporation rate in film drying process.

Improvement of Polycarbonate Properties by Coating of TiO2 and SiO2 Thin Film (TiO2/SiO2 박막 코팅에 의한 폴리카보네이트 특성 개선)

  • Won, Dong So;Lee, Won Gyu
    • Applied Chemistry for Engineering
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    • v.25 no.1
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    • pp.41-46
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    • 2014
  • The property improvement of polycarbonate coated with a multilayer film composed of an inorganic $SiO_2$ film and a photocatalytic $TiO_2$ film was studied. The $SiO_2$ film as a binder had an excellent light transmission characteristic. After the treatment with atmospheric pressure plasma, the surface of $SiO_2$ film showed the hydrophilicity, which increased the film coating uniformity with a $TiO_2$-containing aqueous solution. When $TiO_2$ film was over 200 nm thick, the absorption effect of UV rays in the range of 180~400 nm suppressed the yellowing phenomena of polycarbonate substrate. The inorganic film improved the heat resistance of polycarbonate substrates. $TiO_2$ film in the outmost under the exposure of UV rays promotes the catalytic oxidation characteristics and yields the capability to the decomposition of organic contaminants, and also increases the self-cleaning properties due to the increase of hydrophilicity. Structural stability of the polycarbonate substrate coated with inorganic $TiO_2$ and $SiO_2$ film was shown. The role of $SiO_2$ film between $TiO_2$ and polycarbonate substrate suppressed the peeling of $TiO_2$ film by inhibiting the photocatalytic oxidation effect of $TiO_2$ film on the polycarbonate substrate.

A Study on Development of Bezelless Digital Signage Using Light Guide Film (광가이드 필름을 이용한 베젤리스 디지털 사이니지 구현에 관한 연구)

  • Park, Jae-Soon;Kim, Eung-Bo;Kang, Young-Hwan;Choi, Won Seok;Joung, Yeun-Ho
    • Journal of Satellite, Information and Communications
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    • v.11 no.1
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    • pp.51-54
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    • 2016
  • This paper present a method which resolves an optical discontinuity in bezel of digital signage using light guide film. On a polycarbonate film, a light guide film is bonded to produce refraction, reflection, diffraction of light. Arc shaped light guide film is assembled on the top LED light sources (red and green) to see light propagation through the film. When the two light sources (red and green) are mechanically attached at the end of the film, optical convergence brings new colors which have light wavelength between red and green. This result indicates that the light waveguide method could solve the light discontinuity on bezel of the digital signage system.

A Study on the Change of Optical and Mechanical Properties by Reprocessing for High Melt-Indexed Polycarbonate Used in Injection Molded Optical Parts (광학용 사출성형품에 사용되는 고유동성 폴리카보네이트의 재사용에 따른 광학적, 기계적 물성 변화에 대한 연구)

  • Lee, J.H.;Kang, J.J.;Yoon, K.H.;Kim, J.S.
    • Transactions of Materials Processing
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    • v.27 no.4
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    • pp.211-221
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    • 2018
  • To estimate the recycling feasibility of high melt-indexed polycarbonate, 3.5 inch LGP, tensile, flexural and impact specimens were injection-molded and the LGP was shredded into scraps. The scraps were injection-molded again and this process was repeated for 4 times. Properties of the sample, i.e., optical properties, mechanical properties and number average molecular weight were measured at each cycle. Based on the results, as the number of reprocessing increased, transmittance decreased at low wavelength and color coordinate was changed systematically to yellow. Yellow index increased more than twofold during 4 recycling processes. On the other hand, the number average molecular weight decreased during recycling processes. Flexural and impact strength showed no tendency according to the number of recycling, but tensile strength decreased sharply after the third recycling process. Based on these properties, it was concluded that the number of recycling for high melt-indexed polycarbonate allowed in this study was one.

The Plasma Modification of Polycarbonate and Polyethersulphone Substrates for Ta2O5 Thin Film Deposition (Ta2O5 박막증착에서 플라즈마 전 처리를 통한 Polycarbonate와 Polyethersulphone 기판의 표면 개질)

  • Kang, Sam-Mook;Yoon, Seok-Gyu;Jung, Won-Suk;Yoon, Dae-Ho
    • Journal of the Korean Ceramic Society
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    • v.43 no.1 s.284
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    • pp.38-41
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    • 2006
  • Surface of PC (Polycarbonate) and PES (Polyethersulphone) treated by plasma modification with rf power from 50 W to 200 W substrates in Ar (3 sccm), $O_2$ (12 sccm) atmosphere. From the results of modified substrates in XPS (X-ray Photoelectron Spectroscopy), the ratio of oxide containing bond increased with rf power. As the rf power was 200 W, the contact angle was the lowest value of 14.09 degree. And the datum from AFM (Atomic Force Microscopy), rms roughness value of PES and PC substrates increased with rf power. We could deposit $Ta_2O_5$ with good adhesion on plasma treated PES and PC substrates using by in-situ rf magnetron sputter.