• Title/Summary/Keyword: PLA fiber

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The Effects of Blend Composition and Blending Time on the Ester Interchange Reaction and Tensile Properties of PLA/LPCL/HPCL Blends

  • Yoon, Cheol-Soo;Ji, Dong-Sun
    • Fibers and Polymers
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    • v.4 no.2
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    • pp.59-65
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    • 2003
  • PLA/LPCL/HPCL blends composed of poly(lactic acid) (PLA), low molecular weight poly($\varepsilon$-caprolactone) (LPCL), and high molecular weight poly($\varepsilon$-caprolactone) (HPCL) were prepared by melt blending for bioabsorbable fila-ment sutures. The effects of blend composition and blending time on the ester interchange reaction by alcoholysis in the PLA/LPCL/HPCL blends were studied. Their thermal properties and the miscibility due to the ester interchange reaction were investigated by $^1{H-NMR}$, DSC, X-ray, and UTM analyses. The hydroxyl group contents of LPCL in the blends decreafed by the ester interchange reaction due to alcoholysis. Thus, the copolymer was formed by the ester interchange reaction at $200^{\circ}C$ for 30-60 minutes. The thermal properties of PLA/LPCL/HPCL blends such as melting temperature and heat of fusion decreased with increasing ester interchange reaction levels. However, the miscibility among the three poly-mers was improved greatly by ester interchange reaction. Tensile strength and modulus of PLA/LPCL/HPCL blend fibers increased with increasing HPCL content, while the elongation at break of the blend fibers increased with increasing LPCL content.

Effect of Enzymatic Hydrolysis on Polylactic Acid Fabrics by Lipases from Different Origins

  • Lee, So-Hee;Song, Wha-Soon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.36 no.6
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    • pp.653-662
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    • 2012
  • This study measured the effect of general pre-treatment on PLA fabrics to confirm the benefits of enzymatic processing on PLA fabrics in the textile industry as well as evaluated the hydrolytic activities of three lipases. The effects of lipase hydrolysis were analyzed through moisture regain, dyeing ability, tensile strength, and surface morphology. As a result, PLA fibers were easily damaged by a low concentration of sodium hydroxide and a low treatment temperature. The optimal treatment conditions of Lipase from Candida cylindracea were pH 8.0, $40^{\circ}C$, and 1,000 U. The optimal treatment conditions for Lipase from Candida rugosa were pH 7.2, $37^{\circ}C$, and 1,000 U. The optimal treatment conditions for Lipase from Porcine pancreas were pH 8.0, $37^{\circ}C$, and 2,000 U. The moisture regain and dyeing ability of PLA fabrics increased and the tensile strength of PLA fabrics decreased. The results of surface morphology revealed that there were some cracks due to hydrolysis on the surface of the fiber.

A Study on the Shrinkage and Dimensional Characteristics of the Weft Knitted Fabrics with Polylactic acid(PLA) Yarn (Polylactic acid(PLA) 위편성물의 수축특성과 형태안정성에 관한 연구)

  • Choi, Jae-Woo;Jang, Bong-Sik;Lee, Eun-Woo
    • Journal of the Korean Society of Industry Convergence
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    • v.16 no.2
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    • pp.47-52
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    • 2013
  • Aim of this study is to investigate the dimensional and shrinkage characteristics of the weft knitted fabrics with Polylactic acid(PLA) knitted yarn. This PLA knitted yarn was made of the biodegradability fiber. The structure of weft knitted fabrics that was utilized for this study is the plain stitch, which is the most basic structure among all weft knitted fabrics. As the stitch length is shorter, the stitch density, courses density, and wales density are more increasing. The stitch density increased as pre-treatment process and dyeing process progressed. On the contrary, the heat setting process made it decreasing. The MR(Machine Relaxation) and DR(Dry Relaxation) standard area shrinkage were increasing as wet process progressed and as the stitch lengths are long.

Load carrying capacity of CFRP retrofitted broken concrete arch

  • Wang, Peng;Jiang, Meirong;Chen, Hailong;Jin, Fengnian;Zhou, Jiannan;Zheng, Qing;Fan, Hualin
    • Steel and Composite Structures
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    • v.23 no.2
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    • pp.187-194
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    • 2017
  • To reuse a broken plain concrete (PC) arch, a retrofitting method was proposed to ensure excellent structural performances, in which carbon fiber reinforced polymers (CFRPs) were applied to repair and strengthen the damaged PC arch through bonding and wrapping techniques. Experiments were carried out to reveal the deformation and the load carrying capacity of the retrofitted composite arch. Based on the experiments, repairing and strengthening effects of the CFRP retrofitted broken arch were revealed. Simplified analysing model was suggested to predict the peak load of the CFRP retrofitted broken arch. According to the research, it is confirmed that absolutely broken PC arch can be completely repaired and reinforced, and even behaves more excellent than the intact PC arch when bonded together and strengthened with CFRP sheets. Using CFRP bonding/wrapping technique a novel efficient composite PC arch structure can be constructed, the comparison between rebar reinforced concrete (RC) arch and composite PC arch reveals that CFRP reinforcements can replace the function of steel bars in concrete arch.

용융방사-폴리락타이드 섬유의 구조와 물성

  • 김병철;임승순;김승규;조성무;이화섭
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.10a
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    • pp.227-231
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    • 1998
  • Poly(lactic acid)(PLA)는 인체내에서 재흡수성(resorbability), 분해물의 비독성, 성형물의 높은 기계적 강도 등과 같은 바람직한 특성을 가지는 생체 친화성 고분자로서 fracture fixation devices, drug delivery system 및 surgical suture 등과 같은 의료용 소재로의 응용에 관한 연구가 활발히 진행되고 있다[1-2]. (중략)

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Effect of Filter Parameters on a Supercontinuum-Based All-Optical Tunable Thresholder

  • Zhu, Huatao;Wang, Rong;Pu, Tao;Fang, Tao;Xiang, Peng;Zhu, Huihui
    • Journal of the Optical Society of Korea
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    • v.20 no.4
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    • pp.470-475
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    • 2016
  • In this paper, the effects of filter parameters on a supercontinuum-based all-optical thresholder are experimentally investigated. By tuning the filter parameters, the power transfer function and power transmission function are tailored. The experimental results show that a thresholder with short center wavelength has a better power function, and the slope in the middle level of the thresholder increases with increasing bandwidth. Through tuning the filter parameters, the thresholder can achieve a steplike power transfer function for optical thresholding, and a steplike power transmission function for optical self-switching. This makes the supercontinuum-based thresholder more flexible, and allows customization of performance to meet different demands in various applications.

Interfacial Adhesion of Silk/PLA Composite by Plasma Surface Treatment (플라즈마 표면처리에 의한 Silk/PLA 복합재료의 계면접착)

  • 추보영;한철희;권미연;이승구;박원호;조동환
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.189-190
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    • 2003
  • 섬유강화 복합재료의 사용이 점점 증가함에 따라 구조용 및 내장재 등으로 사용된 수명이 다한 섬유강화 복합재료의 사용후 폐기가 문제가 되고 있다. 특히, 자동차 부품, 건축자재 및 전기절연재 등으로 가장 많이 사용되는 유리섬유 복합재료의 폐기물이 급격히 증가하여 환경 오염문제가 심각해지고 있어서, 환경 친화적인 새로운 복합재료에 대한 필요성이 제기되어 왔다. 따라서 본 연구에서는 천연섬유를 이용한 천연섬유/생분해성 수지계 복합소재를 대상으로 환경적합성이 우수하고 자연환경에서 완전한 생분해성을 가지며, 유리 섬유복합재료를 대체할 물성이 우수한 새로운 Biocomposite를 개발하고자 하였다. (중략)

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Effects of Annealing and Drawing on Crystal Structure and Supermolecular Structure of Poly (L-Lactide)

  • Sawade, E.;Irie, S.;Sasaki, T.;Sakurai, K.
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.97-97
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    • 2003
  • Recently, attention has been paid to biodegradable polymers in relation to the global environment. Poly-lactide (PLA) is one of such polymers and has studied by some investigators. In this study, the changes of crystal structure, crystal orientation and supermolecular structure of Poly(L-lactide) (PLLA) during drawing or annealing have been investigated.

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Effect of hydrogen-rich water on the lactic acid level in metformin-treated diabetic rats under hypoxia

  • Zhao, Chuan;Guo, Yushu;Wang, Ruoxi;Cheng, Cheng;Chen, Xiangmei
    • The Korean Journal of Physiology and Pharmacology
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    • v.25 no.6
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    • pp.517-523
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    • 2021
  • The present study aims to investigate the impact of hydrogen-rich water on the lactic acid level in metformin-treated diabetic rats under hypoxia. Thirty Sprague-Dawley rats were randomly divided into five groups, including normal diet group, and diabetes model (DM) group, DM + metformin treatment (DMM) group, DMM + hypoxia treatment (DMMH) group and DMMH + hydrogen-rich water (DMMHR) group. We found that the levels of lactic acid, pyruvate and lactate dehydrogenase were significantly lower in the blood of DMMHR group than DMMH group. Superoxide dismutase and glutathione levels in liver and heart were significantly higher in DMMH group after hydrogen-rich water treatment, while malondialdehyde and oxidized glutathione levels were decreased in DMMHR group when compared with DMMH group, which indicates that hydrogen-rich water could reduce oxidative stress. qPCR analysis demonstrated that that pro-apoptotic genes Bax/Caspase-3 were upregulated in DM group and metformin treatment suppressed their upregulation (DMM group). However, hypoxic condition reversed the effect of metformin on apoptotic gene expression, and hydrogen-rich water showed little effect on these genes under hypoxia. HE staining showed that hydrogen-rich water prevented myocardial fiber damages under hypoxia. In summary, we conclude that hydrogen-rich water could prevent lactate accumulation and reduce oxidant stress in diabetic rat model to prevent hypoxia-induced damages. It could be served as a potential agent for diabetes patients with metformin treatment to prevent lactic acidosis and reduce myocardial damages under hypoxic conditions.