• 제목/요약/키워드: PL characteristics

검색결과 488건 처리시간 0.083초

Hybrid LED용 적색 유기형광체의 합성 및 특성 연구 (Synthesis and Characterization of Red Organic Phosphor for Hybrid LED)

  • 이승민;정연태
    • 한국전기전자재료학회논문지
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    • 제30권1호
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    • pp.48-53
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    • 2017
  • We report the studies on the red organic phosphor by using perylene bisimide derivatives. Even though perylene bisimide derivatives have excellent thermal stability and luminous efficiency, they have low solubility in organic solvents. In this research, modified perylene bisimide derivative, N,N'-Bis(4-bromo-2, 6-diisopropylphenyl)-1, 6, 7, 12-tetraphenoxyperylene-3, 4, 9, 10-tetracarboxyl bisimide (1C), has been prepared by the reaction of phenol with N,N'-Bis(4-bromo-2, 6-diisopropylphenyl)-1, 6, 7, 12-tetrachloroperylene-3, 4, 9, 10-tetracarboxyl bisimide (1B) in presence of DMF, at $70^{\circ}C$. The synthesized (1C) was characterized by using $^1H-NMR$, FT-IR, UV/V is spectroscopy, and TGA. The absorbtion and emission of (1C) was shown at 576 nm and 610 nm in UV/V is spectrum. In TGA thermogram, (1C) showed good thermal stability without significant weight loss to $220^{\circ}C$. And in the solubility analysis, (1C) with phenoxy group showed the good solubility in general organic solvents. The blended films of (1C) with PMMA (polymethyl methacrylate) at different weight % concentration such as 10, 5, 1 weight % have been prepared. The blended film was shown at 616 nm when monitored at 450 nm in PL emission spectra.

지글러-니콜스 제어파라미터 조정법(1),(2)의 상호 연관성에 대한 해석적 연구 (An Analytic Study On the Mutual Relation between Method(1) and (2) of ZIEGLER-NICHOLS Control Parameter Tuning)

  • 강인철;최순만;최재성
    • 한국마린엔지니어링학회:학술대회논문집
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    • 한국마린엔지니어링학회 2001년도 추계학술대회 논문집(Proceeding of the KOSME 2001 Autumn Annual Meeting)
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    • pp.112-119
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    • 2001
  • Parameter tuning methods by Ziegler-Nickels for control systems are generally classified into Z-N(1) and Z-N(2). The purpose of this paper is to describe what relations exist between methods of Z-N(1) and Z-N(2), or how Z-N(1) method can be originated from Z-N(2) method by analyzing one loop control system of P or PI controller and time delay process. The formulas of Z-N(1) consist of process parameters, L(time delay), $K_m$(gain) and $T_m$(time constant), but Z-N(2) method is based only on the ultimate gain $K_u$ and the ultimate period $T_u$ acquired normally by practical trial without any parameters of Z-N(1). In this paper, for the first step to seek mutual relations, the simple formulas of Z-N(2) are transformed into the formulas composed of the same parameters as Z-N(1) which is derived from the analysis of frequency characteristics. Then, the approximation of the actual ultimate frequency is proposed as important premise in the translation between Z-N(1) and (2). Such equalization and approximation brings a simple approximated formula which can explain how Z-N(1) is originated from the Z-N(2) in the form of formula. And a model system is adopted to compare the approximated formula to Z-N(1) and Z-N(2) methods, the results of which show the effectiveness of the proposals.

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브랜드 이미지에 영향을 미치는 어플리케이션 특성 요인에 관한 분석 : 백화점 어플리케이션을 중심으로 (Trait Factors of Smartphone Application Influencing the Formation of a Brand Image : Focusing on Department Store Applications)

  • 김예리;장은지;최준호
    • 한국콘텐츠학회논문지
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    • 제11권8호
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    • pp.102-111
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    • 2011
  • 본 논문은 브랜드 이미지 향상에 영향을 미치는 어플리케이션 특성 요인들을 파악하기 위하여, 백화점 브랜드 어플리케이션을 대상으로 사용자의 만족도와 브랜드 이미지 향상에 미치는 영향을 분석하였다. 어플리케이션의 디자인, 콘텐츠, 사용용이성, 커뮤니티의 특성이 어플리케이션 사용만족도와 브랜드 이미지 향상도에 미치는 영향을 검증하기 위해 백화점 어플리케이션을 이용해본 스마트폰 사용자 114명을 대상으로 설문 조사를 시행하였고, 통계 분석은 PLS를 이용하여 확인적 요인분석, 상관분석, 모형 검증을 실시하였다. 가설 검증 결과, 어플리케이션의 디자인과 콘텐츠는 만족도와 브랜드 이미지 향상도에 영향을 미치는 것으로 나타났으나, 사용용이성은 영향 요인으로 도출되지 않았다. 또한 커뮤니티 특성은 만족도에는 영향을 미쳤으나 브랜드 이미지 향상도에는 영향을 미치지 않았다. 어플리케이션의 만족도 또한 브랜드 이미지 향상도에 크게 영향을 미치는 것으로 나타나, 브랜드 이미지 향상을 위해서는 어플리케이션 만족도를 높여야 한다는 시사점을 제시하였다.

Growth and characterization of periodically polarity-inverted ZnO structures grown on Cr-compound buffer layers

  • Park, J.S.;Goto, T.;Hong, S.K.;Chang, J.H.;Yoon, E.;Yao, T.
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2010년도 제39회 하계학술대회 초록집
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    • pp.259-259
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    • 2010
  • Periodically polarity inverted (PPI) ZnO structures on (0001) Al2O3 substrates are demonstrated by plasmas assisted molecular beam epitaxy. The patterning and re-growth methods are used to realize the PPI ZnO by employing the polarity controlling method. For the in-situ polarity controlling of ZnO films, Cr-compound buffer layers are used.[1, 2] The region with the CrN intermediate layer and the region with the Cr2O3 and Al2O3 substrate were used to grow the Zn- and O-polar ZnO films, respectively. The growth behaviors with anisotropic properties of PPI ZnO heterostructures are investigated. The periodical polarity inversion is evaluated by contrast images of piezo-response microscopy. Structural and optical interface properties of PPI ZnO are investigated by the transmission electron microcopy (TEM) and micro photoluminescence ($\mu$-PL). The inversion domain boundaries (IDBs) between the Zn and the O-polar ZnO regions were clearly observed by TEM. Moreover, the investigation of spatially resolved local photoluminescence characteristics of PPI ZnO revealed stronger excitonic emission at the interfacial region with the IDBs compared to the Zn-polar or the O-polar ZnO region. The possible mechanisms will be discussed with the consideration of the atomic configuration, carrier life time, and geometrical effects. The successful realization of PPI structures with nanometer scale period indicates the possibility for the application to the photonic band-gap structures or waveguide fabrication. The details of application and results will be discussed.

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1.3 μm 광통신용 소자를 위한 InAs 양자점 성장 및 파장조절기술 개발 (Development of the Growth and Wavelength Control Technique of In As Quantum Dots for 1.3 μm Optical Communication Devices)

  • 박호진;김도엽;김군식;김종호;류혁현;전민현;임재영
    • 한국재료학회지
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    • 제17권7호
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    • pp.390-395
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    • 2007
  • We systematically investigated the effects of InAs coverage variation, two-step annealing and an asymmetric InGaAs quantum well (QW) on the structural and optical characteristics of InAs quantum dots (QDs) by using atomic force microscopy (AFM), transmission electron microscopy (TEM) and photoluminescence (PL) measurement. The transition of size distribution of InAs QDs from bimodal to multi-modal was noticeably observed with increasing InAs coverage. By means of two-step annealing, it is found that significant narrowing of the luminescence linewidth (from 132 to 31 meV) from the InAs QDs occurs together with about 150 meV blueshift, compared to as-grown InAs QDs. Finally, the InAs QDs emitting at longer wavelength of $1.3\;{\mu}m$ with narrow linewidth were grown by an asymmetric InGaAs QW. The excited-state transition for the InAs QDs with an asymmetric InGaAs QW was not noticeably observed due to the large energy-level spacing between the ground states and the first excited states. The InAs QDs with an asymmetric InGaAs QW will be promising for the device applications such as $1.3\;{\mu}m$ optical-fiber communication.

Ag/ZnO-rGO 하이브리드 나노구조 기반 C2H2 가스센서의 제작과 그 특성 (Fabrication of C2H2 Gas Sensors Based on Ag/ZnO-rGO Hybrid Nanostructures and Their Characteristics)

  • 이관우;정귀상
    • 센서학회지
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    • 제24권1호
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    • pp.41-46
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    • 2015
  • In this work, pure hierarchical ZnO structure was prepared using a simple hydrothermal method, and Ag nanoparticles doped hierarchical ZnO structure was synthesized uniformly through photochemical route. The reduced graphene oxide (rGO) has been synthesized by typical Hummer's method and reduced by hydrazine. Prepared Ag/ZnO nanostructures are uniformly dispersed on the surface of rGO sheets using ultrasonication process. The synthesized samples were characterized by SEM, TEM, EDS, XRD and PL spectra. The average size of prepared ZnO microspheres was around $2{\sim}3{\mu}m$ and showed highly uniform. The average size of doped-Ag nanoparticles was 50 nm and decorated into ZnO/rGO network. The $C_2H_2$ gas sensing properties of as-prepared products were investigated using resistivity-type gas sensor. Ag/ZnO-rGO based sensors exhibited good performances for $C_2H_2$ gas in comparison with the Ag/ZnO. The $C_2H_2$ sensor based on Ag/ZnO-rGO had linear response property from 3~1000 ppm of $C_2H_2$ concentration at working temperature of $200^{\circ}C$. The response values with 100 ppm $C_2H_2$ at $200^{\circ}C$ were 22% and 78% for Ag/ZnO and Ag/ZnO-rGO, respectively. In additions, the sensor still shows high sensitivity and quick response/recovery to $C_2H_2$ under high relative humidity conditions. Moreover, the device shows excellent selectivity towards to $C_2H_2$ gas at optimal working temperature of $200^{\circ}C$.

II-VI족 화합물 반도체의 결정성장 및 센서 개발에 관한 연구 (Crystal Growth Sensor Development of II-VI Compound Semiconductor : CdS)

  • D.I. Yang;Y.J. Shin;S.Y. Lim;Y.D. Choi
    • 한국진공학회지
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    • 제1권1호
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    • pp.126-133
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    • 1992
  • E-Beam 기법을 이용하여 증착시킨 Ag doped CdS 박막은 육방정계이고 공기, Ar 분위기에서 $^550{\circ}C$로 열처리한 결과 grain size가 1$mu extrm{m}$ 정도로 성장되었고, Van Der Pauw 방법으로 구한 Hall data로부터 CdS crystal은 n형 반도체이고 상온에서의 carrier 농 도는 2.7 $\times$ 1011cm-3이고 Hall mobility는 5.8 $\times$ 102cm2V-1sec-1정도임을 알 수 있었다. CdS : Ag 박막의 PL spectra는 Gaussian curve를 보여주었고, spectra peak는 파장이 520nm 근처에 위치하고 있으며, CdS : Ag 박막에서의 광전류(pc)와 암전류(dc)의 ratio(pc/dc)는 공기 중에서 열처리한 시료의 값이 크다는 것을 알 수 있었다.

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자외선 여기용 청색 및 황색 형광체의 발광특성 (Luminescence Characteristics of Blue and Yellow Phosphor for Near-Ultraviolet)

  • 최경재;박정규;김경남;김창해;김호건
    • 한국세라믹학회지
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    • 제43권5호
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    • pp.304-308
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    • 2006
  • We have synthesized a $Eu^{2+}-activated\;Sr_3MgSi_2O_8$ blue phosphor and $(Sr,Ba)_2SiO_4$ yellow phosphor and prepared white LEDs by combining these phosphors with a InGaN UV LED chip. Three distinct emission bands from the InGaN-based LED and the two phosphors are clearly observed at 405 nm, 460 nm and at around 560 nm, respectively. The 405 nm emission band is due to a radiative recombination from a InGaN active layer. This blue emission was used as an optical transition of the $Sr_3MgSi_2O_8:Eu$ blue phosphor and $(Sr,Ba)_2SiO_4:Eu$ yellow phosphor. The 460 nm and 560 nm emission band is ascribed to a radiative recombination of $Eu^{2+}$ impurity ions in the $Sr_3MgSi_2O_8:Eu$ and $(Sr,Ba)_2SiO_4$ host matrix. As a consequence of a preparation of UV White LED lamp using the $Sr_3MgSi_2O_8:Eu$ blue phosphor and $(Sr,Ba)_2SiO_4:Eu$ yellow phosphor, the highest luminescence efficiency was obtained at the ration of epoxy/two phosphor (1/0.2361). At this time, the CIE chromaticity was CIE x = 0.3140, CIE y = 0.3201 and CCT (6500 K).

Fuzzy-AHP를 활용한 의류 물류창고 운영개선에 관한 연구 (A Study on the Operation and Function Improvement for apparel warehouse Using Fuzzy-AHP)

  • 권성준;차영두;여기태
    • 디지털융복합연구
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    • 제15권9호
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    • pp.23-33
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    • 2017
  • 국가 간 다양한 상품 무역에서 파생되는 물류업무를 처리하기 위해 세계 물류시장은 성장하고 있는 추세이다. 특히 의류물류는 매년 처리량이 증가하고 있으며, 세계 산업 중 손꼽히는 매출 기록을 나타내고 있다. 현재 의류품목은 고가의 제품으로 성장하였으며, 정교하고 알맞은 물류서비스가 요청되고 있다. 본 논문은 3PL 서비스를 제공하는 회사들이 앞으로 성장하고 있는 의류시장에 대한 서비스 및 오퍼레이션에 대응할 수 있도록 효과적인 운영방안을 제시하는 것에 연구목적이 있다. Fuzzy AHP방법을 사용하여 의류창고 운영에 대한 중요요인의 가중치를 산출하였다. 분석결과, 1위로는 인력교육(0.17) 2위로는 화재관리(0.169), 3위로 입출고 관리(0.142)로 나타났으며, 4위와 5위는 각각 Warehouse management system 및 바코드 시스템으로 확인되었다. 즉 '의류' 특성을 정확히 이해하고 이를 바탕으로 인력교육, 화재관리 그리고 입출고관리를 수행해야하며, 이를 통하여 의류물류 서비스의 질을 제고할 수 있다.

Chlorobium limicola f. thiosulfatophilum NCIB 8327에서 분리한 Chlorosomes의 물리화학적 특성 (Physicochemical Characterization of Chlorosome Isolated from Chlorobium limicola f. thiosulfatophilum NCIB 8327)

  • 나종욱;윤환;강사욱
    • 미생물학회지
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    • 제31권1호
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    • pp.9-16
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    • 1993
  • 녹황색 세균인 Chlorobium limicola f. thiosulfatophilum NCIB 8327 로부터 광수확기구인 chlorosome 을 초원심분리법으로 분리하여 그들의 물리화학적 특성을 조사하였다. Chlorosome 은 Percoll self gradient 에서 초원심분리하였을 때 약 1.05 g/$cm^{3}$ 의 밀도인 것으로 측정되었다. UV-visible absorption spectra 에 의한 분석결과. chlorosome 은 세균엽록소 (bacteriochlorophyll)d, chlorobactene 및 약간의 세균엽록소 a 로 구성되었음을 확인하였다. 분리된 chlorosome 은 산성조건에서보다 염기성 조건(pH>7) 에서 더 안정하고, 0.deg. C 에서 $80^{\circ}C$ 까지 온도에서는 안정하나 그이상의 온도에서는 급격하게 파괴되었으며, 빛에 의해서도 쉽게 파괴되는 것을 확인하였다. 이러한 결과를 두고 볼 때, chlorosome 에서는 색소를 안정화시켜주는 단백질이나 지질이 존재할 석으로 생각된다.

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