• 한국농공학회논문집
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• 제46권6호
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• pp.21-28
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• 2004

This study aims to investigate the effects of partially distributed loads on the dynamic behaviour of steel parabolic arches by using the elasto-plastic finite element model based on the Von Mises yield criteria and the Prandtl-Reuss How rule. For this purpose, the vertical and the radial load conditions were considered as a distributed loading and the loading range is varied from 40% to 100% of arch span. Normal arch and arch with initial deflection were studied. The initial deflection of arch was assumed by the sinusoidal motile of ${\omega}_i\;=\;{\\omega}_O$ sin ($n{\pi}x/L$). Several numerical examples were tested considering symmetric initial deflection when the maximum initial deflection at the apex is fixed as L/1000. The analysis resluts showed that the maximum deflection at the apex of arch was occurred when 70% of arch span was loaded. The maximum deflection at the quarter point of arch span was occurred when 50% of arch span was loaded. It is known that the optimal rise to span ratio between 0.2 and 0.3 when the vertical or radial distributed load is applied. It is verified that the influence of initial deflection of radial load case is more serious than that of vertical load case.

• Bulletin of the Korean Chemical Society
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• 제24권3호
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• pp.325-333
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• 2003

An analysis of the electronic structure and bonding in the ternary silicide YNiSi₃is made, using extended Huckel tight-binding calculations. The YNiSi₃structure consists of Ni-capped Si₂dimer layers and Si zigzag chains. Significant bonding interactions are present between the silicon atoms in the structure. The oxidation state formalism of $(Y^{3+})(Ni^0)(Si^3)^{3-}$ for YNiSi₃constitutes a good starting point to describe its electronic structure. Si atoms receive electrons from the most electropositive Y in YNiSi₃, and Ni 3d and Si 3p states dominate below the Fermi level. There is an interesting electron balance between the two Si and Ni sublattices. Since the ${\pi}^*$ orbitals in the Si chain and the Ni d and s block levels are almost completely occupied, the charge balance for YNiSi₃can be rewritten as $(Y^{3+})(Ni^{2-})(Si^{2-})(Si-Si)^+$, making the Si₂layers oxidized. These results suggest that the Si zigzag chain contains single bonds and the Si₂double layer possesses single bonds within a dimer with a partial double bond character. Strong Si-Si and Ni-Si bonding interactions are important for giving stability to the structure, while essentially no metal-metal bonding exists at all. The 2D metallic behavior of this compound is due to the Si-Si interaction leading to dispersion of the several Si₂π bands crossing the Fermi level in the plane perpendicular to the crystallographic b axis.

• 한국응용과학기술학회지
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• 제24권1호
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• pp.61-66
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• 2007

X-ray diffraction studies have been made to investigate the effects of binding of ADP, ADP+Vi, ADP+AIF4, $ADP+BeF_3$ on the structure of glycerinated rabbit skeletal muscle in the rigor state. Although these phosphate analogs are known to bind actively cycling myosin heads, it is not clear whether they can bind to the attached heads in the rigor muscle. We have found that these analogs can bind to the myosin heads attached to actin filaments in the rigor state. The present results indicate that (1) bound myosin heads altered their conformation in the proximal end toward the plane perpendicular to the fiber axis when MgADP bound to them, and (2) myosin heads were dissociated substantially (up to 50%) from actin filaments but still remained in the vicinity of actin filaments when MgADP and metallofluorides (AIF4 and BeF3) or vanadate bound to them. We detected new conformations of myosin heads attached to actin filaments when they had MgADP or ADP.Pi analogs. We report here these findings on the effects of MgADP and MgADP+phosphate analogs to the rigor crossbridges.

• 산업기술연구
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• 제20권B호
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• pp.155-162
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• 2000

Although Fuzzy Logic Controller(FLC) adopted three terms as input gives better performance, FLC is in general composed of two-term control because of the difficulty in the construction of fuzzy rule base. In this paper, a three-term FLC which is similar to PID control but acts as a nonlinear controller is proposed. To reduce the complexity of the rule base design and to increase efficiency. a simplified fuzzy PID control is induced from a hybrid velocity/position type PID algorithm by sharing a common rule base for both fuzzy PI and fuzzy PD parts. It is simple in structure, easy in implementation, and fast in calculation. The phase plane technique is applied to obtain the rule base for fuzzy two-term control and the resultant rule base is Macvicar-Whelan type. And the membership function is a Gaussian function. The frequency response information is used in tuning of the membership functions. Also a tuning strategy for the scaling factors is proposed based on the relationship between PID gain and the scaling factors. Simulation results show better performance and the effectiveness of the proposed method.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2000년도 International Symposium on Magnetics The 2000 Fall Conference
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• pp.251-265
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• 2000

S $m_{2}$F $e_{17}$ $N_{x}$ film magnets using a S $m_{2}$F $e_{17}$ target were prepared at $N_{2}$ gas atmosphere using a Nd-YAG laser ablation technique. The effect of nitrogen pressure, deposition temperature, pulsation time and film thickness on the structure and magnetic properties of S $m_{2}$F $e_{17}$ $N_{x}$ film were studied. Increasing the nitrogen pressure up to 5 atm. was confirmed to lead the formation of complete S $m_{2}$F $e_{17}$ $N_{x}$ compound. Optimized magnetic properties with the nitrogenation temperature ranging over 500-53$0^{\circ}C$ could be obtained by extending the nitrogenation time up to 4 hours. Relatively low coercivities of 400~600 Oe were exhibited from the S $m_{2}$F $e_{17}$ $N_{x}$ films having the thickness of 50~100 nm while 4$\pi$ $M_{s}$ of 10~12 kG could be achieved. In-plane anisotropic characteristic, which was the basic goal in this study, was achieved by controlling the nitrogenation parameters.ameters.ers.ameters.

• 한국수산과학회지
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• 제28권2호
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• pp.183-193
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• 1995

본 연구에서는 그물을 그것의 영역권 내로 물을 유입한 후 영역권 밖으로 투과시키는 하나의 유공성 구조물로 간주하고, 벽 면적이 S되는 그물이 유속 v에서 받는 저항 R을 $R=kSv^2$으로 취하여, 레이놀즈수를 $R_e$, 그물 입구의 단면적을 $S_m$, 흐름에 수직인 평면에 대한 그물의 총 투영면적을 $S_m$이라 할 때 저항계수 k를 $$k=c\;Re^{-m}(\frac{S_n}{S_m})n(\frac{S_n}{S})$$으로 표시한 후, 지금까지 행해진 평면 그물감에 대한 저항 실험 결과들을 이용하여 이 식의 타당성과 각계수 값을 함께 조사하였다. 조사 결과, 발의 지름이 d, 그물코의 크기가 21, 전개각이 $2\varphi$ 그물감의 $R_e$에 관한 대표치수를 그물코의 면적에 대한 발의 체적의 비 $\lambda$, 즉 $$\lambda={\frac{\pi\;d^2}{21\;sin\;2\varphi}$$로 택하였을 때, c와 m의 값은 각각 $240(kg\;\cdot\;sec^2/m^4)$ 및 0.1로 일정해졌고, n의 합은 1.2로서 1.0보다 컸기 때문에 매듭과 발에서 생기는 반류가 그물코 속으로의 물의 투과를 나쁘게 하여 저항을 증대시킨다는 것을 알 수 있었다. 반면, $R_e$가 커서 그 영향이 무시되는 경우는 $cR_e\;^{-m}$의 값이 상수가 되는데, 그 값은 흐름에 대한 그물감의 영각 $\theta$가 $ 45^{\circ}<\theta\leq90^{\circ}$의 구간에 있을 때 100$(kg\cdot sec^2/m^4)$으로 주어졌고, $ 0^{\circ}<\theta\leq45^{\circ}$의 구간에 있을 때는 후류의 영향 때문에 $100(S_m/S)^{0.6}\;(kg\cdot\;sec^2/m^4)$으로 주어 졌다. 그런데, 평면 그물감에 대 한 $S_m$ 및 $S_n$의 값은 각각 $$S_m=S\;sin\theta$$ 및 $$S_n=\frac{d}{I}\;\cdot\;\frac{\sqrt{1-cos^2\varphi cos^2\theta}} {sin\varphi\;cos\varphi} \cdot S$$로 주어지므로, 이들과 상기 c, m 및 n 값을 이용하면 평면 그물감의 저항계수 k가 구해지는데, $\theta=0^{\circ}$인 경우는 저항 특성 자체가 변하여 k가 그물감 표면의 조도에 따라 달라졌으므로 $$k=9(\frac{d}{I\;cos\varphi})^{0.8}$$으로 주어졌다. 그러나, 이상의 결과를 실제 그물에 적용할 때는 $\theta=0^{\circ}$ 때의 것은 고려하지 않아도 되고, 전기한 c 및 m 값도 불충분한 자료에 의한 것들이기 때문에 $R_e$의 영향이 무시되는 경우의 것만을 이용하면, 그물 각부의 $\theta$가 $45^{\circ}<\theta\leq90^{\circ}$의 구간 또는 $0^{\circ}<\theta\leq45^{\circ}$의 구간에 들어오는 그물의 저항계수 $k(kg\cdot sec^2/m^4)$는 $$k=100(\frac{S_n}{S_m})^{1.2}\;(\frac{S_m}{S})$$ 또는 $$k=100(\frac{S_n}{S_m})^{1.2}\;(\frac{S_m}{S})^{1.6}$$으로 주어진다는 것을 알 수 있었다.

• Bulletin of the Korean Chemical Society
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• 제33권2호
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• pp.443-448
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• 2012

Ferrocenyl chalcones (Fc-C(O)CH=CH-Ar: Fc-Ar) with mono- and di-1-naphthalenyl moieties (Fc-1Naph and Fc-d1Naph) were prepared and spectroscopically characterized. The enone bridge was in the s-cis conformation and the $\pi$-electrons on the C=C bond were further delocalized on the bridge. The naphthalenyl moiety deviates greatly from the enone-Cp plane by $26.9(1)^{\circ}$. Cyclic voltammetry measurements for Fc-1Naph exhibit one reversible cycle for the redox of the ferrocenyl moiety at a lower potential, and one irreversible oxidation peak at the higher potential region. For Fc-d1Naph, the cyclic voltammogram is more featureless. Fluorescence properties for both compounds are active in polar solvents with $\lambda_{em}$ = 500 nm (EtOH) and $\lambda_{em}$ = 512 nm (MeOH) for Fc-1Naph and $\lambda_{em}$ = 496 nm (EtOH) and $\lambda_{em}$ = 508 nm (MeOH) for Fc-d1Naph. The intensity of Fc-d1Naph is more than twice than that of Fc-1Naph. The fluorescence properties for both compounds are inactive in the less polar solvents such as $CH_3CN$, $CH_2Cl_2$ and $CHCl_3$.

• 한국광학회지
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• 제10권1호
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• pp.10-14
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• 1999

일차적인 비균일 위상변조가 광학계의 MTF에 미치는 연향을 연구하였다. 시험평가 렌즈는 국산 유효경 37.5mm, 초점거리 128.04 mm인 이중렌즈를 택하였다. 시험렌즈의 수차특성은 축상과 시계각 $1^{\circ}$와 $2^{\circ}$인 비축에 대해 각각 ray-fan과 파면수차를 계산하여 그림으로 도시하였다. 위상변조는 실험렌즈 앞에 근접하여 위상변조판을 위치함으로 이루어 진다. 위상 변조판은 계단식으로 하나의 계단이 $\lambda$/2씩 위상 차이가 되도록 제작하였고 선형 위상변조판은 연속적으로 위상이 변하도록 제작하였다. 위상변조를 실시한 경우와 변조하지 않은 경우에 각각 축상과 시계각 $1^{\circ}$ 및 $2^{\circ}$인 비축에 대해 MTF를 측정해서 그 값을 서로 비교하였다. 대체로 계단식으로 위상변조한 경우에는 전반적으로 MTF의 증진현상을 나타내었으며 선형으로 위상변조한 경우에 축상에서는 감소하고 축외에서는 tangenjtial MTF의 증진효과가 크게 나타났다.

• Bulletin of the Korean Chemical Society
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• 제35권3호
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• pp.875-880
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• 2014

Adsorption of 4,4'-bis(mercaptomethyl)biphenyl (44BMBP) on silver nanoparticles has been investigated by surface-enhanced Raman scattering (SERS) spectroscopy. In addition, the Raman spectra of 44BMBP in solid state and in basic condition have been obtained for comparative study to elicit the characteristics of adsorption. The observed Raman and SERS spectra were analyzed comparing with the normal modes and vibrational frequencies from density functional theory (DFT) calculations performed for the feasible structures of 44BMBP molecule. On the basis of excellent agreement between the calculated and the experimental results, the molecule is found to have both the cis- and trans-forms for the mercaptomethyl groups in the solid state as well as in the basic condition. In contrast, the molecule is found to be chemisorbed on the silver surface by forming two Ag-S linkages only in the cis-form but not in the trans-form due to the steric interruption, which indicates the parallel orientation of molecules on the surface. Particularly, the spectral features in the SERS spectra such as the absence of the C-H stretching band and enhancement for the out-of-plane skeletal modes are confirmatory for the parallel geometry through ${\pi}$ interaction between the phenyl rings and the metal surface, based on the electromagnetic surface selection rule.

• 플랜트 저널
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• 제17권3호
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• pp.42-46
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• 2021

드릴 스트링의 진동 문제는 수년간 드릴링 성능 저하의 주요 원인 중 하나로 인식되어 왔으며, 굴착 작업 시 발생하는 과도한 진동은 드릴링의 효율성, 파이프 피로, 비트의 수명 단축으로 인하여 고장을 초래할 수 있다. 이러한 진동의 원인은 드릴 스트링이 굴착 작업 중 궤적에 따라 파이프의 굽힘과 wellbore와의 접촉으로 인해 마찰이 발생하고 이러한 진동은 일반적으로 축 방향, 굴곡 및 비틀림 변형을 일으킨다. 본 연구에서는 Khulief와 Al-Naser가 제시한 모델을 바탕으로 드릴 스트링에 6자유도(DOF)의 구성요소를 갖는 모델을 적용하여 curved beam의 수치해석 값과 Analytical값을 비교하여 검증하고 드릴 스트링에 hookload와 WOB 경계조건을 주어 각 element 마다 동적 거동을 분석하였다. 실제 궤적을 적용하여 드릴 파이프의 굽힘이나 중력으로 인하여 Wellbore와 접촉되는 부분에 마찰을 적용하였고, 또한 마찰 작용 시 일정한 축 방향 속도를 유지하기 위한 PI제어 값을 설계하여 drillstring 전체의 각속도 변화와 실제 드릴 굴착 작업 중 발생하는 stick slip현상을 관찰하였다.