• Title/Summary/Keyword: PHOSPHORUS

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Spectroscopic Characterization of Phosphorus Doped HPHT Diamond (인이 첨가된 고온 . 고압 다이아몬드의 분광학적 특성)

  • Chung Jung In;Kim Hee-Soo
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.4
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    • pp.291-297
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    • 2004
  • Phosphorus is one of the interesting impurities in diamond, because it produces n-type semiconducting character. The character has been studied with spectroscopic methods as well as electric method, but most of the diamond used for these studies are conducted by the CVD (Chemical Vapor Deposition) diamond. In this study, we synthesized the phosphorus doped HPHT (High Pressure and High Temperature) diamond and investigated the characterization using CL spectroscopy to determine how phosphorus incorporated. As a result, the undocumented peaks of 248 and 603 nm as well as the reported peaks (239 nm, 240 ~ 270 nm) at the previous studies were observed. These luminescence peaks may be due to the complex defect of phosphorus with other impurities such as boron and nitrogen.

Improved Coagulant for High Efficiency Phosphorus Removal in Secondary Effluent of Waste Water Treatment Plant (하수처리장 2차 처리수의 고효율 인 제거를 위한 응집제 개선)

  • Choi, Jeung-seung;Lee, Byung-ha;Kim, Ki-pal;Baek, Dae-jin
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.6
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    • pp.683-690
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    • 2016
  • Modified coagulants were investigated for the removal of phosphorus from secondary effluent of wastewater treatment. The modified coagulants were prepared by mixing alkali earth metal ions such as calcium and magnesium. The basicity of a coagulant influenced on the removal of phosphorus, and coagulants with basicity of 5.9% showed a better removal of total phosphorus than that of 38.5%. Also, coagulants with alkali earth metals enhanced the performance of coagulation by 10% and resulted in 67.1% for total phosphorus removal. Moreover, the removal of suspended solids and chemical oxygen demand was improved using coagulants with low basicity and earth metal ions. Results of this study demonstrated that the use of coagulants with low basicity, and calcium and magnesium ions is recommended to improve wastewater effluent quality.

The Identification of Limiting Nutrients Using Algal Bioassay Experiments (ABEs) in Boryeong Reservoir after the Construction of Water Tunnel

  • Ku, Yeonah;Lim, Byung Jin;Yoon, Jo-Hee;Lee, Sang-Jae;An, Kwang-Guk
    • Korean Journal of Environmental Biology
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    • v.36 no.4
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    • pp.558-566
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    • 2018
  • The objective of the study was to determine nutrition regime and limitation in the Boryeng Reservoir where there's a water tunnel between Geum River and the reservoir. Evaluation was conducted through in situ algal bioassay experiments (in situ ABEs) using the cubitainer setting in the reservoirs. For in situ ABEs, we compared and analyzed variations in chlorophyll-a (CHL-a) and phosphorus concentrations in Boryeong Reservoir before and after the water tunnel construction. We then analyzed the nutrient effects on the reservoir. Analysis for nitrogen and phosphorus was done in the three locations of the reservoir and two locations of the ABEs. The in situ ABEs results showed that phosphorous and Nitrogen, the primary limiting nutrient regulating the algal biomass was not limited in the system. The treatments of phosphorus or simultaneous treatments of N+P showed greater algal growth than in the control of nitrate-treatments, indicating a phosphorus deficiency on the phytoplankton growth in the system. The water from the Geum River had 5 times higher total phosphorus (TP) than the water in the reservoir. Efficient management is required as pumping of the river water from Geum River may accelerate the eutrophication of the reservoir.

Thermodynamic of Phosphorus in FeO-MnO-CaO-SiO2-MgOsatd. Slag Systems (FeO-MnO-CaO-SiO2-MgOsatd. 슬래그에서의 P의 열역학적 거동)

  • Cho, Moon Kyung;Park, Kyung Ho;Min, Dong Joon
    • Korean Journal of Metals and Materials
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    • v.47 no.3
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    • pp.188-194
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    • 2009
  • Recently, new extraction technology for manganese nodule has been developed as alternative noble metallic resources. It is important to understand thermodynamic behaviors of phosphorus in low basic slag system from the viewpoint of the refining processing optimization. Thermodynamic behaviors of phosphorus in the $FeO-MnO-CaO-SiO_2-MgO_{satd.}$ slag system were investigated at 1723 K with various oxygen potential and slag composition of low basicity. The experimental results for dependence of phosphorus on oxygen potential and slag basicity indicated that the dissolution mechanism of phosphorus into slag of low basicity could be derived as follows; $[P]+5/4O_2+(O^{2-})=({PO_{3.5}}^{2-})$ Present experimental results implied that stability of phosphorus in slag would be depended on both of $O^{2-}$ (basicity) and content of $Ca^{2+}$ in molten slag. The thermodynamic effect of FeO, MnO and $Na_2O$ on low basicity on phosphate capacity was discussed.

Preparation of Composites using Carbonyl Iron with Ferromagnetic Properties for Effective Phosphorus Removal in Water (효과적인 수중의 인제거를 위해 강자성력을 가진 카보닐 철을 활용한 복합제 제조)

  • Kim, Jong Kyu
    • Journal of Korean Society of Water Science and Technology
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    • v.26 no.6
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    • pp.117-124
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    • 2018
  • For the effective removal of phosphorus in water, a novel type of composite was prepared by combining Poly Alumiun Chloride, widely used in sewage/wastewater treatment plants, and Humic Acid particles, which are known to have phosphorus removal ability, with CI. The surface of the ferromagnetic CI particles was oxidized and activated, and then PAC and HA were synthesized to finally produce CIPAC and CIHA. CIPAC and CIHA prepared by this study showed similar results to the phosphorus removal efficiencies of PAC and HA coagulants. The novel composite has a larger weight than the conventional coagulant, and the coagulated sludge precipitates rapidly. The sludge could be easily separated in a short time if the external magnetic field was given by the ferromagnetic force of CIPAC and CIHA prepared with CI as support. Therefore, it can be concluded that if phosphorus removal is carried out using CIPAC and CIHA prepared through this study with external magnetic field, the sedimentation rate will be much faster than that of conventional coagulant. Thus it is possible to obtain a high economic benefit in the sludge recovery part.

Impacts of Phosphorus on Lignification and Carbohydrate Metabolism in Relation to Drought Stress Tolerance in Kentucky Bluegrass (Poa pratensis L.)

  • Kim, Dae-Hyun;Lee, Bok-Rye;Park, Sang-Hyun;Kim, Tae-Hwan
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.42 no.2
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    • pp.120-126
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    • 2022
  • The objective of this study was to determine effects of phosphorus on lignification and carbohydrate metabolism in Kentucky bluegrass under drought stress. Drought stress was induced by reducing of water to plants in pots. Two types of phosphorus were applied as potassium phosphate (PO43-; P) or potassium phosphonate (PO33-; PA) in drought-stressed plants. Drought had significant negative effects on plant growth, as revealed by reduced biomass of shoot. Drought-induced increase of lignin content was concomitant with the increase of phenylalanine ammonia-lyase (PAL). Soluble sugar content was highly increased but fructan content was largely decreased by drought stress. However, the application of phosphorus was efficient to ameliorate the adverse effects of drought. PA application improved reduced shoot growth and relative water content, and inhibited lignification synthesis with a reduction of PAL activity. P or PA application maintained soluble sugar and fructan content at similar levels to controls under drought stress. These results indicate that phosphorus application may mitigate the drought stress by inhibiting the lignification and promoting the fructan assimilation.

Effect of Dietary Microbial Phytase on Laying Performance, Egg Quality, Phosphorus Utilization and Nutrient Metabolizability in Laying Hens (산란계에 Microbial Phytase 첨가시 산란율, 계란 품질, 인 이용율 및 영양소 대사율에 미치는 영향)

  • Jang, H.D.;Hyun, Y.;Kim, H.S.;Hwang, I.W.;Yoo, J.S.;Kim, H.J.;Shin, S.O.;Hwang, Y.;Zhou, T.X.;Chen, Y.J.;Cho, J.H.;Kim, I.H.
    • Korean Journal of Poultry Science
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    • v.35 no.2
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    • pp.115-121
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    • 2008
  • The study was conducted to evaluate the effects of dietary microbial phytase on egg productivity, egg quality, phosphorus utilization and nutrient digestibility in laying hens. The animals used in the experiment were a total of 120 Hy-Line Brown laying hens (32 weeks old). Dietary treatments included 1) CON (basal diet), 2) LP (low phosphorus diet) 3) NP (low phosphorus diet + 0.03% normal microbial phytase) and 4) CP (low phosphorus diet + 0.03% coated microbial phytase). Six laying hens were allotted to a block (pen) with five replicated. Through the whole period of experiment, egg production was significantly increased in CON and CP treatments compared to LP treatment (P<0.05). CON, CP and NP treatments significantly increased their egg shell breaking strength and egg shell thickness compared to LP treatment (P<0.05). CON, CP and NP treatments resulted higher yolk color and Haugh unit than LP treatment (P<0.05). Calcium and inorganic phosphorus contents in blood were higher in CP treatment compared to LP treatment (P<0.05). Dry matter digestibility and nitrogen digestibility were greater in CP treatment than CON, LP and NP treatments (P<0.05). Crude ash was increased in CON, CP and NP treatments compared to LP treatment (P<0.05). Calcium digestibility and phosphorus digestibility were significantly improved in CP and NP treatments than CON and LP treatments (P<0.05). Calcium retention of CON, CP and NP treatments were higher than LP treatment (P<0.05). Phosphorus retention was increased in CP and NP treatments compared to CON and LP treatments (P<0.05). LP treatment significantly increased their nitrogen, calcium excretion compared to CON, CP and NP treatments (P<0.05). Phosphorus excretion was decreased in LP, CP and NP treatments compared to CON treatment (P<0.05). In conclusion, CP treatment improved egg production, egg quality, inorganic calcium and phosphorus in blood, calcium and phosphorus retention and nutrient digestibility and decreased nitrogen and calcium excretion in laying hens.

Distributions and Budgets of Nitrogen and Phosphorus in Hiroshima Bay (Hiroshima만에서의 질소, 인의 분포 및 수지)

  • Kim Do-Hee
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.2 no.1
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    • pp.74-89
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    • 1999
  • Distributions and budgets of nitrogen and phosphorus in inner and central areas of Hiroshima bay were investigated for three years from January 1991 to December 1993. The mean loadings of nitrogen and phosphorus Stowed into the entire bay were 870 tonN/month and 129 tonP/month, respectively. About 79 % of nitrogen and 84 % of phosphorus loadings were flowed into the inner area. The TN:TP and DIN:DIP atomic ratios of the discharged freshwater were about 15 and 21, respectively. The PON:POP and DIN:DIP atomic ratios of seawater in the bay varied from 8 to 14 with a mean value of 11, and from 8 to 18 with a mean value of 12, respectively. Estimated fluxes of nitrogen and phosphorus based on the exchange of seawater were 585 tonN/month and 106 tonP/month, respectively, from the inner area to the central area, whereas those fluxes were 62 tonN/month and 107 tonP/month, respectively, from the central area to Akinada. When the remainders of nitrogen and phosphorus substracted outflows from inflows should be sunk, sink fluxes of nitrogen and phosphorus per surface area of the entire bay would be about 9.83 gN/m²ㆍyr and 0.27 gP/m²ㆍyr, respectively. In the central area, the remainders of nitrogen and phosphorus were greater than those in inner area. The residence times of nitrogen and phosphorus were estimated to be about 112 days, respectively, in the entire of Hiroshima Bay.

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Phosphorus Removal Characteristic of the Aluminum (III)-loess Composite (알루미늄-황토 복합체의 인 제거 특성)

  • Shin, Gwan-Woo;Kim, Jin-Sik;Kim, Keum-Yong;Lee, Sang-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.7
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    • pp.530-535
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    • 2011
  • In this work, the adsorption characteristic of the composites by adding loess with aluminum ("Al-loess") and Loess with lanthanum ("La-loess") which have been developed to effectively remove phosphorus, the substance which causes the eutrophic lake has been evaluated. According to the result of the work, as the amount of aluminum or lanthanum put in 1g of loess increases, the combined amount also increases accordingly. When the loess with no aluminum or lanthanum attached was used, the rate of removing phosphorus was different in comparison with the case of using the composites of 0.5, 1 and 2 mg of aluminum and 0.5, 1 and 3 mg of lanthanum in each gram of loess. It was observed the amount required to remove 1 mg $PO_4^{3-}$-P/L of phosphorus completely is approximately 2 to 10 times less for the composite of Al-loess than loess alone. Also, in case of the composite of La-loess, the amount was decreased by about 1.5 to 10 times. In order to observe the rate of adsorption phosphorus with Al-loess and La-loess, the composites were used for the observation up to three times by water washing. As a result, the water washing of the composite did not affect phosphorus removal. According to the effect of pH, there is a high rate of removing phosphorus in the pH range of 5~8. It seems that the developed composite will effectively remove phosphorus when it is spread in the natural water system. Also, since Al-loess and La-loess composites are rapidly precipitated within 30 minutes, it is stabilized quickly at the bottom of the eutrophic lake and becomes responsible for the removal of phosphorus in water and eluted from the water and the sedimentary layer.

Laboratory Study of Phosphorus Fractionation in the Sediments of Yeongsan River (영산강 퇴적물 인의 존재형태에 대한 실험실 연구)

  • Oh, Hae Seong;Huh, In Ae;Choi, Jung Hyun
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.9
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    • pp.519-526
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    • 2017
  • This study investigated the effect of phosphorus fractionation on the phosphorus release from the sediments of Juksan reservoir in Yeongsan River. The field sediments were collected, incubated, and analyzed with respect to phosphorus fractionation of sediments and total phosphorus (TP) of overlying water after 7 days. The total amount of inorganic phosphorus of YS2 site was higher than YS1 site. Al-P and Fe-P were major constituents of inorganic phosphorus. During the incubation, Al-P, Fe-P and Ca-P were increased and Red-P was decreased at both sites. YS1 site showed increased TP concentration of overlying water, however, YS2 had opposite trend during the incubation. Counting on the particle size distribution of YS1 and YS2, particle size distribution is major factor to control the TP concentration of overlying water. There were positive relationship between Fe-P and TP and negative relationship between Red-P. From the results, it is essential to continuously monitor the sediment phosphorus fraction in order to control the TP concentration of the water.