• Clean Technology
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• v.21 no.2
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• pp.117-123
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• 2015

This inquiry was conducted to develop DeNOx catalyst for LNT. In order to develop appropriate catalysts, four catalysts, which do not use PGM (Platinum Group Metal), were carefully selected : Al/Co/Mn, Al/Co/Ni/Mn, Al/Co/Mn/Ca, Al/Co/Ni mixed metal oxides during preliminary experiments. Also, XRD, EDS, SEM, BET and TPD tests were carried as well to evaluate both physicochemical properties of such four catalysts. As a result of the experiment, four catalysts were composed of spinel-shaped crystals and had more than enough pore volume and size to have oxidation-reduction reaction of NOx gases. Additionally, through TPD test, all four types of catalysts were proved to possibly have an oxidation-reduction acid site and NO oxidation activities similar to commercial catalysts. Based on the results above, if we have further change in the composition components and active ingredients according to the catalysts that were chosen in this investigation, then we are more welcomed to expect to have an enhanced DeNox catalyst for LNT.

• Journal of the Korean Society of Propulsion Engineers
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• v.21 no.1
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• pp.8-16
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• 2017

Structural integrity of solid rocket depends on the residual reactions between constituents of its composition(post cure, migration etc.), the oxygen(or anti-oxydent) in the free volume and humidity (desiccant) under the perfect sealed condition. Mechanical Properties of composite solid propellant arising from those factors are very complex. Moreover the propulsion are faced with thermal loads from diurnal & seasonal cycle till firing. In this study, the fast evaluation method of long term mechanical properties is suggested based on Thermo-Rheological Simplicity from curing oven to cool-down stage in view point of thermal stabilization. For this subject, endurance tester having temperature control capability are devised. From the results from incremental load and strain, non-linear characteristics are discussed.

• Korean Journal of Optics and Photonics
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• v.33 no.3
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• pp.99-105
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• 2022

We have evaluated the performance of an all-optical automatic gain-controlled (AGC) erbium-doped fiber amplifier (EDFA) to suppress the optical signal fluctuation induced by atmospheric turbulence in terrestrial free-space optical communication systems. In our measurements, the input power into the EDFA was set to be -30 dBm and -10 dBm to operate the amplifier in the small-signal and saturation regions, respectively. The fluctuations in the optical signal were emulated with an acousto-optic modulator driven with a sinusoidal voltage. From the measured results, we have found that an all-optical AGC EDFA could suppress the optical signal fluctuation effectively, as long as the EDFA operated in the small-signal region with a high feedback amplified spontaneous emission (ASE) power.

• Clean Technology
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• v.21 no.3
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• pp.184-190
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• 2015

Most of LNT catalysts use noble metals such as Pt for low temperature NO_x oxidation but there is an economic weakness. For the purpose of overcoming this, this study is to develop DeNO_x catalyst for LNT excluding PGM (platinum group metal) such as Pt, Pd, Rh, etc. To do so, Al/Co/Ni catalyst selected as a preliminary test is used to study fundamental property and NO_x’s conversion according to calcined temperature. Ultimately, that is, Al/Co/Ni mixed metal oxide which does not use PGM is selected and physicochemical characterization is performed by way of XRD, EDS, SEM, BET and ramp test and NO_x conversion is also analyzed. This study shows that all samples consist of mixed oxides of spinel structure of Co₂AlO₄ and NiAl₂O₄ and have enough pore volume and size for redox. But as a result of NH₃-TPD test, it is desired that calcined temperature needs to be maintained at 700 ℃ or lower. Also only samples which are processed under 500 ℃ satisfied NO and NO_x conversion simultaneously through ramp test. Based on this study’s results, optimum calcined temperature for Al/Co/Ni=1.0/2.5/0.3 mixed metal oxide catalyst is 500 ℃.

• Journal of the Korean Society of Propulsion Engineers
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• v.22 no.2
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• pp.96-107
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• 2018

Flow analysis using computational fluid dynamics was conducted to investigate the effect of the igniter flame caused by the gap between the igniter and the propellant grain in a solid rocket motor. Two propellant grain types were assumed; namely cylinder type (1 mm, 3 mm, and 5 mm gap) and the slot type. The slot type had two igniter hole locations. One was located at the small gap of the propellant grain, and the other one was located at the large gap. In the case of the cylinder type, the pressure in the igniter zone was higher with a thinner gap. Additionally, in the case of the cylinder type, the pressure difference between the igniter installed zone and the free volume was also higher as the gap became lower. The cylinder types were affected by the gap distance, but the slot types were not. Moreover, the results of the slot types were similar to the 5-mm gap case of the cylinder type.

• Steel and Composite Structures
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• v.25 no.6
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• pp.693-704
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• 2017

In this research, a simple hyperbolic shear deformation theory is developed and applied for the bending, vibration and buckling of powerly graded material (PGM) sandwich plate with various boundary conditions. The displacement field of the present model is selected based on a hyperbolic variation in the in-plane displacements across the plate's thickness. By splitting the deflection into the bending and shear parts, the number of unknowns and equations of motion of the present formulation is reduced and hence makes them simple to use. Equations of motion are obtained from Hamilton's principle. Numerical results for the natural frequencies, deflections and critical buckling loads of several types of powerly graded sandwich plates under various boundary conditions are presented. The accuracy of the present formulation is demonstrated by comparing the computed results with those available in the literature. As conclusion, this theory is as accurate as other theories available in the literature and so it becomes more attractive due to smaller number of unknowns.

• Applied Chemistry for Engineering
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• v.30 no.6
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• pp.652-658
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• 2019

Direct hydrazine fuel cells (DHFCs) have been considered to be one of the promising fuel cells because hydrazine as a liquid fuel possesses several advantages such as no emission of CO₂, relatively high energy density and catalytic activity over platinum group metal (PGM)-free anode catalysts. Judging from plenty of research works, however, regarding key components such as electrocatalysts as well as their physicochemical properties, it becomes quite necessary to understand better the underlying processes in DHFCs for the long term stability. Herein, we highlight recent studies of DHFCs in terms of a systematic approach for developing cost-effective and stable anode catalysts and electrode structures that incorporate mass transport characteristics of hydrazine, water and gas bubbles.