• Journal of the Korean Society of Clothing and Textiles
• /
• v.29 no.7 s.144
• /
• pp.987-996
• /
• 2005

For cationization, if chitosan, which has the affinity for a human body and reacts easily without inducing any pollution, is used, cationization of Tencel blended fabrics can be expected and further expansion of its use as a new susceptible material can be expected. Therefore, in this study, in order to compare a Tencel/cotton and a Tencel/Cotton/PET as Tencel blended fabrics with a Tencel single fabric, the fabric samples were used and processed with chitosan after NaOH pretreatment and enzyme treatment thereof, and then its adherent efficiency was enhanced by using a crosslinking agent, and then it was got to be finished with a softener. The fibril of Tencel fabric was controlled by enzyme treatment so that the surface of the Tencel blended fabrics got to be smooth. Chitosan adhered to the surface of the Tencel blended fabrics in the form of particles through its processing with chitosan. Chitosan treatment caused little change in the crystal structure thereof and the thermal stability of the Tencel/Cotton/PET fabric was slightly improved. The total hand value(THV) calculated on the basis of the change due to chitosan treatment was increased in all samples.

• Fibers and Polymers
• /
• v.3 no.1
• /
• pp.18-23
• /
• 2002

The structure development and dynamic properties of fibers produced by high-speed spinning of P(EN-ET) random copolymers were investigated. The as-spun fibers were found to remain amorphous up to the spinning speed of 1500 m/min, and subsequent increases in speed resulted in the crystalline domains containing primarily $\alpha$ crystalline modification of PEN. The f modification was not found up to spinning speeds of 4500 m/min. On the other hand, annealing of constrained fibers spun at the 2100 m/min at 180,200, and 240^{\circ}C$ exhibited $\beta$-form crystalline structure, while the annealed fibers spun in 600-1500 m/min range exhibited dominantly $\alpha$-form. However $\beta$-form crystals disappeared above the spinning speed of 3000 m/min. With increasing spinning speeds from 600 to 4500 m/min, the storage modulus of as-spun fibers increased continuously and reached a value of about 10.4 spa at room temperature. The tan $\delta$curves showed the $\alpha$-relaxation peak at about 155-165^{\circ}C$, which is considered to correspond to the glass transition. The $\alpha$-relaxation peaks became smaller and broader, and shift to higher temperatures as the spinning speed increases, meaning that molecular mobility in the amorphous region is restricted by increased crystalline domain.

• Fibers and Polymers
• /
• v.1 no.1
• /
• pp.37-44
• /
• 2000

A finite element method is employed fer a flow analysis of the melt spinning process of a non-circular fiber, a PET(polyethylene terephthalate) filament. The flow field is divided into two regions of die channel and spin-line. A two dimensional analysis is used for the flow within the die channel and a three dimensional analysis fur the flow along the spin-line. The Newtonian fluid is assumed for the PET melt and material properties are considered to be constant except for the viscosity. Effects of gravitation, air drag force, and surface tension are neglected. Although the spin-line length is 4.5 m only five millimeters from the spinneret are evaluated as the domain of the analysis. Isothermal and non-isothermal cases are studied fer the flow within the die channel. The relationship between the mass flow rate and the pressure gradient is presented for the two cases. Three dimensional flow along the spin-line is obtained by assuming isothermal conditions. It is shown that changes in velocity and cross-sectional shape occur mostly in the region of 1mm from the die exit.

• Textile Coloration and Finishing
• /
• v.21 no.1
• /
• pp.30-37
• /
• 2009

Studies on plants such as lotus leaf suggested that dual-scale structure could contribute to super-hydrophobicity. We introduced super-hydrophobicity onto poly(ethylene terephthalate)(PET) fabric with dual-scale structure by assembling $TiO_2$ nano sol. PET fabric was treated with $TiO_2$ sol, water-repellent agent using various parameters such as particle size, concentration. Morphological changes by particle size were observed using field emmission scanning electron microscopy(FE-SEM) and AFM measurement, contact angle measurement equipment. The contact angle of water was about 138.5$^{\circ}$, 125.8$^{\circ}$, 125.5$^{\circ}$ and 108.9$^{\circ}$ for PET fabric coated with 60.2nm, 120.1nm, 200nm and 410.5nm $TiO_2$ particles, compared with about 111.5$^{\circ}$ for PET fabric coated with water repellent. When we mixed particle sizes of 60.2nm and 120.1nm by 7:3 volume ratio, the contact angle of water was about 132.5$^{\circ}$. And we mixed particle sizes of 60.2nm and 200nm by 7:3 volume ratio, the contact angle of water was about 141.8$^{\circ}$. Also we mixed particle sizes of 60.2nm and 410.5nm by 7:3 volume ratio, the best super-hydrophobicity was obtained. In this paper, we fabricated various surface structures to the water-repellent surfaces by using four types of $TiO_2$ nano-particles, and we found that the nanoscale structure was very important for the super-hydrophobicity.

• Proceedings of the Korean Geotechical Society Conference
• /
• 2000.03b
• /
• pp.496-503
• /
• 2000

The friction between soils and the geosynthetics varies depending upon the types and characteristics of the involved materials. Many engineers have studied the frictional characteristics between the two materials in may way but the results obtained so far is not satisfactory. In this study the frictional characteristics between the soil and the geogrid were examined through laboratory direct shear test and pull-out test. Tests were conducted on two different types of geogrid: Polyester grids(PET) which are currently used and newly developed fiber-glass grids(FG). Result showed that FG grid yielded smaller displacements and uniform displacement distribution mainly due to much higher stiffness. Therefore, it is expected that more efficientbfl support and displacement control can be achieved by the FG grid.

• Transactions of the Korean Society for Noise and Vibration Engineering
• /
• v.21 no.9
• /
• pp.850-857
• /
• 2011

Generally, sound-absorbing materials in vehicles are used for giving the comfort to passengers by reducing noise while driving. Materials of which targets are light weight, high performance, eco friendliness and recycling have been developed recently. In this study, sound-absorbing materials using PET(polyethylene terephthalate) hollow fibers to achieve the light weight and the high sound absorption performance are developed, and then evaluated to meet a requirement for the automotive components. The test results show that the acoustic performances of developed products having new fiber structure are better than those of the conventional product.

• Textile Coloration and Finishing
• /
• v.8 no.2
• /
• pp.56-63
• /
• 1996

Low-temperature plasma treatment or sputter etching is of interest as one of the techniques to modify polymer surface. In this study, poly(ethylene terephthalate)(PET), nylon 6 and cotton fabrics dyed three black dyes were subjected to low-temperature argon plasma and also sputter etching. In relation to bathochromic effect, the surface characteristics of the treated fabrics and films were investigated by means of critical surface tension, SEM and ESCA measurement. The depth of shade of fabrics more increased by the sputter etching technique than argon plasma treatment. Many microcraters on the fiber surface formed by the sputter etching resulted in increase of surface area of the fiber and wettability, but the hydrophobic group was increased by the results of ESCA analysis. In particular the change in reflective index of the fibers was much more effective than the chemical composition of the fiber surface on increasing of the depth of shade.

• Journal of Fashion Business
• /
• v.9 no.3
• /
• pp.114-124
• /
• 2005

Based on the previous study, three types at synthetic fibers comprising nylon, PET, and acrylic fibers were investigated in this study. The effect at mordanting on the air-permeability and dyeing properties at fabrics was investigated. The effect at rinsing process on the air-permeability and color was quantitatively investigated by rinsing the mordanted fabric specimens 1$\sim$3 times after mordanting. The air-permeability changed peculiarly according to the characteristics of the tiber materials after mordanting. The air-permeability values of nylon and acrylic fabric specimens dropped significantly after mordanting. On the other hand, those of PET fabric specimens hardly changed after mordanting. The metal ions absorbed on the fibers of nylon and acrylic fabrics did not show the mordanting effect. Regardless of mordanting, cochineal dyestuff made direct links with the molecular chains in nylon fabrics exhibiting dark colors. After dyeing acrylic fabrics, the color did not develop at all, even though partial components of the cochineal dyestuff were absorbed apparently.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.9
• /
• pp.2637-2643
• /
• 2010

In order to develop a new line injection system for spin draw yarn (FD SDY) fibers, the effect of various parameters in extrusion and melt line conditions on the dispersion and distribution of $TiO_2$ particles within FD PET fibers was investigated. As a result, the dispersibility of $TiO_2$ particles in a PET matrix is found to depend on the particle size and its surface characteristics. Surface modification of $TiO_2$ by dimethyl polysiloxane resulted in the improved dispersibility and affinity of $TiO_2$ particles in the PET matrix. Especially, residence time, mixing temperature, and mixing shear rate in the new line injection system under the SDY spinning process were very important parameters to minimize the agglomeration of $TiO_2$ particles. The FD SDY prepared by the new line injection system was superior to those using the polymerization process and the conventional masterbatch chip dosing process in the color-L and color-b values of the fibers.

• Fashion & Textile Research Journal
• /
• v.19 no.4
• /
• pp.493-503
• /
• 2017

This study investigated water vapor permeability of the 73 breathable fabrics for sports-wear according to the materials, finishing methods and fabric structural parameters. The water vapor permeability by KS K 0594 method of PET breathable fabric was superior than that of nylon one, in addition, water vapor permeability of coated or laminated breathable fabrics were higher than those of hot melt or dot laminated fabrics. The water vapor permeability of breathable fabric was dependent on the thickness, weight and density, which was consistent with measuring method. However, water vapor permeability according to materials and finishing method showed different results according to measuring method. The correlation coefficient of WVP of PET breathable fabrics between ISO and KS K measuring methods was -0.83 and the correlation coefficient of WVP of coated breathable fabrics was -0.72 and -0.71 for KS K and ASTM and -0.72 for KS K and ISO in hot melt laminated breathable fabrics. According to regression analysis, WVP of PET breathable fabric by both KSK and ISO measuring methods was highly dependent upon on the density and weight. In addition, WVP of hot melt laminated breathable fabric was highly dependent upon thickness, weight and density. Therefore, relevant measuring method for WVP of breathable fabrics has to be adopted to measure precise breathability.