• Title/Summary/Keyword: PEMFC (Proton Exchange Membrane Fuel Cell)

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Performance of the PEMFC for the mobile devices according to cathode (Cathode에 따른 휴대용 PEM 연료전지의 성능 변화)

  • Lee, Se-Won;Lee, Kang-In;Park, Min-Soo;Chu, Chong-Nam
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.550-553
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    • 2008
  • In this paper, experiments of air-breathing proton exchange membrane fuel cell (PEMFC) for mobile devices were carried out according to the cathode conditions. These conditions are defined by the cathode flow field plate type (the channel type, the open type) and the cathode surface direction. Single cell and 6-cell stack were used in this experiments. The experimental results showed that the open type cathode flow field plate gave better performance for small size PEMFCs because the open type cathode plate allowed better air convection than the channel type cathode plate. In the experiments related to the direction of the slits on the cathode flow field plate, the horizontal slit cell was better than the vertical slit cell. With respect to the cathode surface direction, when the cathode surface is placed in the direction normal to the ground, PEMFC generated more stable power in the mass transport loss region.

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Numerical Simulation of the Oscillating Flow Effect in the Channel of Polymer Electrolyte Membrane Fuel Cell (왕복 유동을 통한 확산증대 효과가 연료전지 성능에 미치는 영향에 대한 수치해석)

  • Kim, Jongmin;Kang, Kyung-Sik
    • Journal of the Korea Safety Management & Science
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    • v.20 no.4
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    • pp.7-13
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    • 2018
  • This study investigates the enhancement of the oxygen diffusion rate in the cathode channel of a proton exchange membrane fuel cell (PEMFC) by pure oscillating flow, which is the same as the mechanism of human breathe. Three-dimensional numerical simulation, which has the full model of the fuel cell including electrochemical reaction, ion and electronic conduction, mass transfer and thermal variation and so on, is performed to show the phenomena in the channel at the case of a steady state. This model could analysis the oscillating flow as a moving mesh calculation coupled with electrochemical reaction on the catalyst layer, however, it needs a lot of calculation time for each case. The two dimensional numerical simulation has carried on for the study of oscillating flow effect in the cathode channel of PEMFC in order to reduce the calculation time. This study shows the diffusion rate of the oxygen increased and the emission rate of the water vapor increased in the channel by oscillating flow without any forced flow.

Heat transport characteristics by heat generation of electrochemical reactions in proton exchange membrane fuel cell (고분자전해질 연료전지에서 전기화학반응 열생성에 의한 열전달특성)

  • Cho, Son-Ah;Lee, Pil-Hyong;Han, Sang-Seok;Hwang, Sang-Soon
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.3377-3382
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    • 2007
  • In proton exchange membrane fuel cell, the heat is generated at the catalyst layer as result of exothermic electrochemical reaction. This heat increases temperature of gas diffusion layer and membrane whose conductivity is very sensitive to humidity, function of temperature. So it is very important to analysis heat transfer through fuel cell to maintain temperature at specified range. In this paper numerical simulation was done including reversible, irreversible, ionic resistance, water formation loss to source term of energy equation. Results show that irreversible and water formation loss contributes mainly to energy source term and as current density increases, all of energy source terms become increased and Nusselt number is increased as results of more heat generation. Particularly irreversible loss is found to be predominant among the all energy source and water formation at cathode channel influences the temperature distribution of fuel cell greatly.

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Proton exchange membrane fuel cell stack modeling considering dynamic response characteristics (과도 응답 특성을 고려한 고분자 전해질 연료전지(PEMFC) 모델링)

  • Jang, Y.J.;Kim, N.Y.;Han, K.H.;Baek, S.H.
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1086_1087
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    • 2009
  • 본 논문에서는 과도 응답 특성에 따른 고분자 전해질 연료전지(PEMFC)를 모델링하였다. 연료전지에 이러한 과도특성이 일어나는 것에 원인에 대하여 분석해보고, 실제 실험을 통해 과도특성이 일어나는 것을 확인하였다. 실험결과 파형을 분석하여 Matlab & Simulink를 이용하여 PEMFC의 과도 응답 특성을 모델링하였다.

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PEMFC performance on reverse voltage by fuel starvation (연료 부족에 의한 고분자전해질형 연료전지의 역전압 성능)

  • Lee, Hung-Joo;Song, Hyun-Do;Kim, Jun-Bom
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.2
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    • pp.133-140
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    • 2006
  • The performance of proton exchange membrane fuel cell was decreased by reverse voltage using fuel starvation. Performance decrease in local area could be affected by duration and extent of reverse voltage. Hydrogen and air stoichiometic ratio was used to find the experimental condition of abrupt voltage decrease. LabVIEW was used to make control logic of automatic load off system in preset voltage. Reverse voltage experiment was done down to -1.2 V at constant current condition. When fuel cell voltage was reached to preset voltage, electronic load was disconnected to make open circuit voltage for 1 minute. Fuel cell performance was checked every 5 cycle and the degree of performance decrease and/or recovery was estimated. Ohmic resistance and charge transfer resistance were increased and platinum surface area was reduced 41% after reverse voltage experiment.

Durability Evaluation of Air-Cooled Proton Exchange Membrane Fuel Cells Stacks by Repeated Start-Up/Shut-Down (시동/정지반복에 의한 공랭식 고분자연료전지 스택 내구성 평가)

  • YOO, DONGGEUN;KIM, HYEONSUCK;OH, SOHYEONG;PARK, KWON-PIL
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.5
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    • pp.315-323
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    • 2021
  • The air-cooled proton exchange membrane fuel cells (PEMFC) stacks, which is widely used in small-sized PEMFC, have a problem in that durability is weaker than that of the water-cooled type. Because the cathode is open to the atmosphere and the structural problem of the air-cooled stack, which is difficult to maintain airtightness, is highly likely to form a hydrogen/air boundary during start-up/shut-down (SU/SD). Through the accelerated durability evaluation of the 20 W air-cooled PEMFC stack, the purpose of this study was to find out the cause of the degradation of the stack and to contribute to the improvement of the durability of the air-cooled PEMFC stack. In this study, it was possible to evaluate durability in a relatively short time by reducing 20-30% of initial performance by repeating SU/SD 1,000 to 1,200 times on an air-cooled PEMFC stack. After disassembling the stack, each cell was divided into two and the performance analysis showed that the electrode degradation was more severe in the anode outlet membrane electrode assembly (MEA), which facilitates air inflow as a whole, than in the inlet MEA. It was shown that the cathode Pt was dissolved/precipitated to deteriorate the polymer ionomer inside the membrane.

PSCAD/EMTDC Model of PEMFC for Power System Analysis (전력계통 해석을 위한 PEMFC의 PSCAD/EMTDC 모델)

  • Lee, Jong-Su;Kim, Hak-Man;Lee, Byoung-Kuk;Shin, Myong-Chul
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.58 no.1
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    • pp.9-14
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    • 2009
  • The modelling of PEMFC(Proton Exchange Membrane Fuel Cell) has been studied in many kinds of methods. But there are some limitations in application of the developed models to analyze transient phenomena of power systems. The PSCAD/EMTDC is very popular simulation tool in power system areas. To analyze power systems interconnected to PEMFCs, the PSCAD/EMTDC model of the PEMFCs is needed. In this paper, we developed a PSCAD/EMTDC model of PEMFC based on electro-chemical characteristic equations of PEMFC. Also, we performed simulations using the developed model in the PSCAD/EMTDC program and tested appropriateness of the proposed models. The simulations showed good results.

Cost Policy Effects of Economic Feasibility of 1kw household PEMFC System (요금 정책이 PEMFC 시스템 경제성에 미치는 영향)

  • Kim, Ki-Young;Hwang, Nam-Sun;Kong, Min-Seok;Kim, Hee-Su;Oh, Si-Doek
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.31-34
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    • 2007
  • Fuel cell with high electric efficiency has many probabilities of commercial use. Especially, polymer electrolyte or proton exchange membrane fuel cell (PEMFC) which is a low operating temperature and has less influence on $CO_2$ concentration is considered the power generation system of small building and household. We calculated the optimal operational plans of 1 kW household PEMFC power system based on daily electric and heat demand patterns of various size of apartments. Calculated results show that the economic feasibility of PEMFC power system is very sensitive to the cost policy of electricity and natural gas.

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A Study on the Performance Analysis of Mobile Fuel Cell (모바일용 연료전지의 성능해석에 관한 연구)

  • Kim, Kwang-Soo;Choi, Jong-Pil;Jeong, Chang-Ryeol;Jang, Jae-Hyeok;Jeon, Byeong-Hee;Kim, Byeong-Hee
    • Journal of the Korean Society for Precision Engineering
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    • v.25 no.1
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    • pp.115-121
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    • 2008
  • In this paper, a three-dimensional computational fluid dynamic model of a proton exchange membrane fuel cell(PEMFC) with serpentine flow channel is presented. A steady state, single phase and isothermal numerical model has been established to investigate the influence of the GDL (Gas Diffusion Layer) parameters. The GDL is made of a porous material such as carbon cloth, carbon paper or metal wire mesh. For the simplicity, the GDL is modeled as a block of material having numerous pathways through which gaseous reactants and liquid water can pass. The porosity, permeability and thickness of the GDL, which are employed in the model parameters significantly affect the PEMFC performance at the high current region.

Methods for Diagnosis and Minimum PT-Loading of PEM Fuel Cell Stack (자동차 연료전지 진단 및 백금 촉매제 최소화에 대한 연구)

  • Yoo, Seoug Yeol;Lee, Young-Hyun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.62 no.1
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    • pp.105-108
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    • 2013
  • To resolve global environmental problems, many automobile companies are making a great deal of effort to develop so-called green-cars. One of the solutions is an electric vehicle equipped with the PEMFC (Proton Exchange Membrane Fuel Cell) stack. However, the cost of the stack, at the moment, is still too high. This obstacle must be resolved for commercialized fuel cell cars. One of the reasons for high cost is a relatively large amount of Pt (platinum) in the membrane. In this paper, a method for reducing the Pt-loading is introduced. Furthermore, the durability of the stack will be important for a company to stay competitive in world markets (in the future). For this, the diagnosis of the stack must be conducted on-line. Some diagnosis methods as key technology are also introduced in this paper.