• Title/Summary/Keyword: PCB126

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ENIG 공정 Au 대체 Ni-P/Ag Electroless 공정 연구

  • Park, Suk-Hui;Hwang, Chung-Ho;Jo, Dae-Hyeong;Jeon, Jong-Tae
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2013.05a
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    • pp.126-127
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    • 2013
  • 기존 PCB의 Surface treatment 방식으로 널리 행하고 있는 ENIG 공정은 고가의 Au에 따른 원가 상승으로 인해 가격 경쟁력이 떨어지고 있는 실정이다. 이를 개선하고자, 기존의 Au 공정을 Ag 공정으로 대체하였으며, 그 결과 Ball Wettability 특성 1.8mm (0.76mm ball)과 Solder 접합강도 (19N)의 특징을 확보하였다.

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Analysis of Toxic-PCBs in Sediment by Isotope Dilution HRGC/HRMS (Isotope Dilution HRGC/HRMS 방법을 이용한 저니토중 Toxic-PCBs 분석)

  • Jang, Seong-Ki;Choi, Duk-Il;Park, Sun-Ku;Kim, Kyung-Sup
    • Analytical Science and Technology
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    • v.12 no.6
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    • pp.550-557
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    • 1999
  • This Analysis was conducted for 13 toxic-PCBs having TEF value among 209 PCBs isomers in sediment by isotope dilution HRGC/HRMS method. From the result, the recovery of surrogate standard was in the range of 71~99%. The concentration range for 13 toxic-PCBs in sediment was found to be 0.84~2.49 ng/g, among them the concentration levels of 2,2',3,3',4,4',5-HpCB(IUPAC No. 170) and 2,2',3,4,4',5,5'-HpCB(IUPAC No. 180) represented almost 50% of total concentrarion and that of 2,3,4,4,5-PeCB(IUPAC No. 114) showed over 10%. The TEQ concentration levelwas in the range of 0.38~2.63 pg-TEQ/g and 3,3',4,4',5-PeCB(IUPAC No. 126) concentration represented over 50% of total TEQ concentration.

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Residual Polychlorinated Biphenyls(PCBs) in the Sediment of the Kumho River (금호강(琴湖江) 저니토중(底泥土中) Polychlorinated Biphenyls(PCBs)의 잔류(殘留))

  • Kim, Jung-Ho;Moon, Chul-Ho
    • Korean Journal of Environmental Agriculture
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    • v.14 no.3
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    • pp.272-281
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    • 1995
  • The residual Polychlorinated biphenyls(PCBs) in the sediment of the Kumho River basin were measured because the Nakdong River was considered to be affected by the environmental quality of Kumho River. PCBs in the sediment were chlorinated and converted into Decachlorinated biphenyl(DCB) which showed the single peak in the GC-ECD chromatogram. The detectable concentrations of PCBs was 0.5ng/g in the sediment. PCBs in the 21 sediment samples was of Kumho River located at 7.5km from conjunction of Nakdong River were not detected from 100 samples. 49% of samples was showed lower than 50ng/g, and 9% did more than 400ng/g. The mean of PCBs concentrations was 131ng/g. The means of COD and organic carbon were 14.5mg/g and 3.41%, respectively. The relationship between PCBs were concentration and the distance from conjunction with Nakdong River was not significant. The concentration of PCBs were varied with the depth of the sediment down to the 250cm depth. The concentrations of PCBs in the depth 0-20cm and 50-90cm were higher than the mean concentration of PCBs. Along the cross of the stream, the concentrations of PCBs were 142ng/g at the center and 126 and 131ng/g at the river sides.

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Deposition flux of dioxin-like polychlorinated biphenyls(DLPCBs) in urban environment of Busan (도심 지역의 다이옥신류 폴리염화비페닐류의 침적 플럭스)

  • Mun, Hyo-Bang;Lee, Su-Jeong;Choe, Hui-Gu;Ok, Gon
    • Journal of Environmental Science International
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    • v.13 no.5
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    • pp.469-478
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    • 2004
  • Atmospheric bulk (wet and dry) samples were monthly collected in an urban environment (Daeyeon-dong) of Busan over a year, to assess the deposition flux and seasonality of dioxin-like polychlorinated biphenyls (DLPCBs) using stainless steel pots. Deposition fluxes of DLPCBs in bulk samples were determined using high resolution gas chromatography coupled to high resolution mass spectrometry (HRGC/HRMS). Particle deposition fluxes in the urban environment varied from 23 to 98 $mg^2$/year (mean 41 $gm^2$/year). DLPCB deposition fluxes in atmospheric bulk samples ranged from 0.09 to 0.77 ng-$TEQ/m^2$/year (mean 0.35 ng-$TEQ/m^2$/year). Seasonal atmospheric deposition fluxes of DLPCBs were high in winter and low in summer. Atmospheric deposition fluxes of particles and DLPCBs in this study were comparable to or slightly lower values than those of different locations in the world. Monthly DLPCB profiles in deposition bulk samples were similar over a year. Non-ortho PCBs were higher contributions to the total DLPCBs fluxes than mono-ortho PCBs. In particular, PCB 126 had the highest concentrartion (>75%) in all deposition samples, followed by PCB 169 and PCB 156. A highly positive correlation was found among the deposition fluxes of DLPCB species, suggesting the possibility of that the DLPCB contamination originated from one source. The deposition fluxes of DLPCBs were not significantly correlated with temperature and the amount of precipitation even though the summer season with the highest temperature and the largest amount of precipitation showed the lowest DLPCB deposition flux.

Effects of Polychlorinated Biphenyls and Phenols on the Biosynthesis of 6-Methoxymellein, a Phytoalexin (당근 Phytoalexin 6-Methoxymellein 생합성에 미치는 Polychlorinated Biphenyls 및 Phenol의 영향)

  • Lim, Do-Hyung;Lim, Da-Som;Keum, Young-Soo
    • Korean Journal of Environmental Agriculture
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    • v.35 no.3
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    • pp.216-222
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    • 2016
  • BACKGROUND: Polychlorinated biphenyls (PCBs) are one of the most common environmental contaminants. Because of their recalcitrant properties and long-term toxicity, numerous studies have been performed. The toxicological concerns are focused on endocrinological effects of animal. Several different metabolites have been reported, including hydroxy PCBs, PCB quinones, and methylsulfonyl PCBs from animal tissues. However, details in plants have never been studied. It is well-known that plants can produce phytoalexin in response to chemical, physical, or pathological stress.METHODS AND RESULTS: In this study, the several PCBs and hydroxy derivatives were prepared by chemical syntheses. Their effects on secondary metabolite biosynthesis were determined in carrot roots. The levels of 6-methoxymellein were determined in several different treatments, using gas chromatography-mass spectrometry. In general, the concentration of 6-methoxymellein reached a maximum at 2 days and gradually decreased to trace level at 5 days in control experiments. However, the effects of PCBs or hydroxy derivatives were highly dependent on compounds. For example, the maximum concentrations of 6-methoxymellein were observed at 3 days for 2-hydroxy/4-hydroxybiphenyl, while 3,3',4,4',5-pentachlorobiphenyl and 3,5-dichloro-2-hydroxybiphenyl showed a rapid accumulation within 1 day, followed by rapid dissipation to undetectable levels.CONCLUSION: Biphenyl derivatives were effective elicitor of 6-methoxymellein accumulation. In general, hydroxybiphenyls (phenols) more efficiently induced phytoalexin biosynthesis than those without hydroxy groups. It can be concluded that PCBs or their possible metabolites could change the plant secondary metabolism.

Residual Consistency and Interrelationship Estimation of PCDDs, PCDFs, Dioxin-like PCBs in Colostrum of Primipara and Multipara (초산부, 경산부 초유 중 PCDDs, PCDFs, dioxin-like PCBs의 축적수준 및 상관성 평가)

  • We, Sung-Ug;Kim, Ki-Ho;Cho, Yu-Jin;Cho, Bong-Hui;Park, Sang-Ah;Baek, In-Cheon;Kang, Seong-Hoon;Yoon, Cho-Hee;Min, Byung-Yoon
    • Journal of Life Science
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    • v.20 no.7
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    • pp.1078-1085
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    • 2010
  • Polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and dioxin-like polychlorinated biphenyls (dl-PCBs) are bioaccumulative chemicals that are considered to be toxic contaminants based on several epidemiological studies. These chemicals in colostrum were investigated and estimated for their residual consistencies by maternal characteristics like parity and maternal ages. Test subjects were healthy primipara and multipara mothers with a mean age of 31.5 (S.D=3.6) in 2007. Seven isomers of PCDDs, 10 of PCDFs, 4 of non-orthopolychlorinated biphenyls(non-ortho PCBs) and 8 of mono-orthochlorinated polychlorinated biphenyls (mono-ortho PCBs) were analyzed by HRGC/HRMS. From the analyzed data, the mean level of total WHO-TEQs was 9.41 pg TEQ/g lipid, which is significantly lower than the level found in individuals from other countries. The main contributors to the total WHO-TEQs with increasing percentages were 2,3,4,7,8-PeCDF, 1,2,3,7,8-PeCDD and 3,3',4,4',5-PCB (#126), and they accounted for more than 60% of the total WHO-TEQs. PCDFs concentrations and total WHO-TEQs were negatively associated with parity (p<0.05), and maternal age was positively associated with total WHO-TEQs (p<0.01). However, the associations with body mass index (BMI) and fish intake during pregnancy were not significant. These results were suggested that parity and maternal age are an important factor affecting the concentrations of PCDD/DFs and dl-PCBs in these specimens.

Statistical comparison analysis based on Monte Carlo simulation between PSD random analysis and it's equivalent static analysis for avionics equipment (Monte Carlo모의에 의한 항공전자장비의 PSD랜덤진동해석과 등가정적해석의 통계적 비교분석)

  • Park, Hee-Beom;Lee, Seok-Kyu;Yang, Sung-Cheol;Kim, Jin-Cheon
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2008.04a
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    • pp.119-126
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    • 2008
  • 방위산업분야의 항공기용 전자장비는 신뢰성 설계를 위하여 MIL규격이나 실측된 PSD데이터를 이용하여 보수적으로 설계하는 것이 일반적이다. 하나의 프로젝트에서 개발되는 PCB는 수십 종에 이르고 그 장착위치나 설계변경이 병행되므로 PSD랜덤 진동해석의 대안으로 등가정적해석을 수행하게 된다. 등가정적해석결과의 보수성을 확인하기 위하여 PSD랜덤진동해석으로부터 추출된 정규분포를 갖는 각 방향 응력에 대해 Monte Carlo모의를 수행하여 결과를 비교분석하였다. 결론적으로 PSD랜덤진동 해석의 대안으로 등가정적해석결과의 유용성과 보수성을 통계적으로 비교하였고 실험을 통하여 결과의 타당성을 보였다.

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Electromagnetic Susceptibility Analysis of I/O Buffers Using the Bulk Current Injection Method

  • Kwak, SangKeun;Nah, Wansoo;Kim, SoYoung
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.13 no.2
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    • pp.114-126
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    • 2013
  • In this paper, we present a set of methodologies to model the electromagnetic susceptibility (EMS) testing of I/O buffers for mobile system memory based on the bulk current injection (BCI) method. An efficient equivalent circuit model is developed for the current injection probe, line impedance stabilization network (LISN), printed circuit board (PCB), and package. The simulation results show good correlation with the measurements and thus, the work presented here will enable electromagnetic susceptibility analysis at the integrated circuit (IC) design stage.

몇 가지 PBTs (Persistent, Bioaccumulative, Toxic Chemicals)가 생태계 곤충에 미치는 영향

  • Lee Seun Yeong;Kim Yong Gyun
    • Proceedings of the Korea Society of Environmental Biology Conference
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    • 2002.11a
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    • pp.123-126
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    • 2002
  • Pollutants that are persistent, bioaccurnulative, and toxic have been linked to numerous adverse effects in human and animals, PBTs include heavy metals, polychlorinated biphenyls (PCBs), dioxins, polycyclic aromatic compounds (PACs) in addition to pesticides. This study focuses on toxic effects of the PBTs except pesticides on insects. Eight PBTs were selected from subgroups: three heavy metals (Pb, Hg, and Cd), two PCB mixtures (Aroclor mixtures 1 and 2), 2,3,7,8-tetrachlorodibenzo-p-dioxin, two monophenols (4-octylphenol and 4-nonylphenol), and tetrabutyltin, Beet armyworm, Spodoptera exigua, was used as test target insect species. Three physiological markers (metamorphosis, immune reaction, and follicle patency) were assessed in each exposure to different doses of the PCBs. Heat-shock proteins as molecular markers were also analyzed in response to the PCBs. All tested PBTs were toxic to metamorphosis from larvae to pupae when they were applied with diet. Two PCB mixtures were the most toxic compounds in this assay by giving significant toxicity at 0.005 ppm, while others had from 10 to 1000 ppm. Dioxin (0.1 ppb), tetrabutyltin (0.1 ppb), Pb (10 ppb), and Hg (0,01 ppb) were potent to inhibit immune reactions analyzed by inducing phenoloxidase activity and blocked phospholipase $A_2$ enzyme, Tetrabutyltin and dioxin significantly induced follicle cell patency, but their effects were lower than that of endogenous juvenile hormone, Dioxin, Pb, Hg, and Cd could induce the expression of heat shock proteins that were detected by immunoblotting against human HSP70 monoclonal antibody. HSP78 and HSP80 were upregulated in response to the PBTs. This expression was detected from the fat body and epidermis at as fast as 4h after injection. All these results clearly suggest that PBTs give significant ecotoxicity to insects that are valuable organisms in our environment.

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Implementation and Effectiveness of Smart Equipment Engineering System (스마트 설비관리시스템 구축 및 효과분석)

  • Sim, Hyun-Sik
    • Journal of the Semiconductor & Display Technology
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    • v.16 no.3
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    • pp.121-126
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    • 2017
  • EES System support to maximize equipment efficiency by providing real-time information of main equipment which has a significant effect on product quality and productivity, and to prevent equipment failure by detecting equipment abnormality in advance. Smart Equipment Engineering System(S-EES) integrates the activities performed at equipment that are the core of production activities and manages them by system so as to maximize the efficiency of equipment and raise the quality level of products to one level. In other words, when the product is put into the equipment, the recipe is downloaded through the RMS, the recipe is set to the optimal condition through R2R(process control), and the system detects and controls the abnormality of the equipment during operation through the FDC function in real time it means. In this way, we are working with the suitable recipe that matches the lot of product, detecting the abnormality of the equipment during operation, preventing the product from being defective, and establishing a system to maximize the efficiency through real-time equipment management. In this study, we review the present status and problems of equipment management in actual production lines, collect the requirements of the manufacturing line for the PCB line, design and develop the system, The measurement model was studied.

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