• 제목/요약/키워드: PC 폴리머

검색결과 103건 처리시간 0.031초

EDLC용 폴리머 겔 전해질 (Polymer Gel Electrolytes for EDLCs)

  • 정세일;정현철;강안수
    • 대한안전경영과학회:학술대회논문집
    • /
    • 대한안전경영과학회 2003년도 추계학술대회
    • /
    • pp.351-357
    • /
    • 2003
  • The optimum polymer gel electrolyte composition ratio was 23 : 66 : 11 wt% of P(VdF-co-HFP) : PVP =20 : 3), (PC: EC =44 : 22) and TEABF$_4$. And the optimal thickness of polymer gel electrolyte was 50 ${\mu}{\textrm}{m}$. The electrochemical characteristics result of unit cell were 31.41 Fig of specific capacitance, and 3.21$\times$10$^{-3}$ S/cm of ion conductivity. Ion conductivity of polymer gel electrolytes decreased according to added PVP through impedance analysis, and it was higher in 7 wt%, but electrochemical characteristics of unit cell were better in 3 wt% PVP. And for excellent ion conductivity of polymer gel electrolytes, the use of a thin layer electrolyte(20 $\mu\textrm{m}$) was an effective method, but with unit cell application, the best thickness was 50 $\mu\textrm{m}$. Unit cell showed higher capacitance and more stable electrochemical performance when hot pressed between polymer gel electrolyte and electrode. This results from enhancement of the physical contact between the electrode and the polymer gel electrolyte and good accessibility of the liquid electrolyte to the electrode surface.

  • PDF

폴리머 피뢰기의 해석기법 (Electric Field Analysis Method of Polymer arrester)

  • 황명근;김광호;박남식;임인택;허창수
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1997년도 하계학술대회 논문집 A
    • /
    • pp.303-305
    • /
    • 1997
  • The advantage of application polymer instead of conventional porcelain as the housing material for arrester is that light weight, shorter section length of arrester would be possible due to the use of an insulated hanger (mold compound). also, polymer arrester has very good characteristics in design versatility as well as excellent resistance to moist ingress and pollution performance. The finite element method is widely used to calculate for electromagnetic devices. In this paper, we perform the each conditional analysis of PC with an advanced graphical user interface(GUI) using the vector fields simulator. And we try to analyze electromagnetic fields through the conventional two dimensional analysis in case of high voltage contamination on the electrode of a arrester.

  • PDF

Labview를 이용한 배전용 폴리머애자의 누설전류 측정 및 분석 프로그램 개발 (Development of data acquisition and analysis program modules for leakage current of polymeric insulators using the Labview software)

  • 조성수;한상옥
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2000년도 하계학술대회 논문집 C
    • /
    • pp.1969-1971
    • /
    • 2000
  • This paper presents a data acquisition and analysis program modules that has been developed using the Labview program. These program modules can use to acquire and analyze leakage current data of insulator under different contamination conditions. The experimental hardware made up salt fog chamber, AC/DC power supply, transducer (shunt resistor), measurement devices and PC with the GPIB (General Purpose Interface Bus). And analysis program modules can calculate pulse level count, accumulated charge, average leakage current, power spectrum, and harmonics. The result of applying these analytical program modules to polymeric insulator is available for evaluation of leakage current characteristic of outdoor insulators.

  • PDF

회전 중 원심력에 의한 광디스크의 피로 파손 (Static fatigue failure of the rotating optical disc)

  • 황효균;김남웅;단병주;김종만;김외열;이진우
    • 대한기계학회:학술대회논문집
    • /
    • 대한기계학회 2004년도 춘계학술대회
    • /
    • pp.150-155
    • /
    • 2004
  • The base material of optical disc is the amorphous polymer, polycarbonate. So crack growth on the rotating optical disc could happen by the static centrifugal force. This phenomenon is called static fatigue. Today's CD-R disc drive is being operated over 10,000 RPM. This is increasing the possibility of the disc fracture when operating. In this reason, new method to measure the static fatigue threshold quality and the way to calculate the threshold J-integral value and the safe crack length of the optical disc are studied. Finally the environmental effect to optical disc is also studied in this paper.

  • PDF

리튬 폴리머전지용 PAN/PVDF계 고분자 전해질의 리튬 이온 거동 (Behavior of $Li^{+}$ in PAN/PVDF based Polymer Electrolyte for Lithium Polymer Battery)

  • 이재안;김상기;김종욱;구할본;박계춘
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
    • /
    • pp.540-543
    • /
    • 2000
  • The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li polymer battery. The temperature dependence of conductivity, impedance spectroscopy and electrochemical properties of PAN/PVDF electrolytes as a function of a mixed ratio were reported for PAN/PVDF based polymer electrolyte films, which were prepared by thermal gellification method of preweighed PAN/PVDF, plasticizer and Li salt. The conductivity of PAN/PVDF electrolytes was $10^{-3}$S/cm. $PAN_{10}$$PVDF_{10}$$LiClO_4$$PC_{5}$$EC_{5}$ electrolyte has the better conductivity compared to others. The interfacial resistance behavior between the lithium electrode and PAN/PVDF based polymer electrolyte has also been investigated and compare with that between the lithium electrode and the PAN/PVDF based polymer electrolyte.

  • PDF

리튬 폴리머전지용 Graphene Composite의 전기화학적 특성 (Electrochemical Properties of Graphene Composite for Lithium Polymer Battery)

  • 김종욱;구할본
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2000년도 추계학술대회 논문집
    • /
    • pp.359-362
    • /
    • 2000
  • The purpose of this study is to research and develop graphene composite for lithium polymer battery. VO(graphene) composite is one of the promising material as a electrode active material for lithium polymer battery(LPB). We investigated AC impedance response and charge/discharge cycling of VO(graphene)/SPE/Li cells. The first discharge capacity of VO(graphene) cathode with 50wt.% V$_2$O$\sub$5/ was 150mAh/g, while that of VO(graphene) cathode with 85wt.% V$_2$O$\sub$5/ was 248mAh/g. The Ah efficiency was above 98% after the 2nd cycle. The discharge capacity of VO(graphene) anode with 3wt.% V$_2$O$\sub$5/ was 718 and 266mAh/g at cycle 1 and 10 at room temperature, respectively. The VO(graphene) anode with 3wt.% V$_2$O$\sub$5/ in PVDF-PAN-PC-EC-LiC1O$_4$ electrolyte showed good capacity with cycling.

  • PDF

리튬 이온 폴리머 전지용 Tin oxide-flyash Composite 전극의 전기화학적 특성 (Electrochemical Properties of Tin oxide-flyash Composite for Lithium Ion Polymer Battery)

  • 김종욱;구할본
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2003년도 춘계학술대회 논문집 센서 박막재료 반도체 세라믹
    • /
    • pp.88-90
    • /
    • 2003
  • The purpose of this study is to research and develop tin oxide-flash composite for lithium Ion polymer battery. Tin oxide is one of the promising material as a electrode active material for lithium Ion polymer battery (LIPB). Tin-based oxides have theoretical volumetric and gravimetric capacities that are four and two times that of carbon, respectively. We investigated cyclic voltammetry and charge/discharge cycling of SnO-flyash/SPE/Li cells. The first discharge capacity of SnO-flyash composite anode was 720 mAh/g. The discharge capacity of SnO-flyash composite anode 412 and 314 mAh/g at cycle 2 and 10 at room temperature, respectively. The SnO-flyash composite anode with PVDF-PMMA-PC-EC-$LiClO_4$ electrolyte showed good capacity with cycling.

  • PDF

초임계추출법을 이용한 브롬계 난연제 화합물 환경성 평가 추출효율 분석 연구 (Quantitative Extraction Analysis of Brominated Flame Retardant Substances Using Supercritical-Fluid Method for Environmental Assessment)

  • 오민경;윤상화;이영관;한재성;원성호;남재도
    • 폴리머
    • /
    • 제32권1호
    • /
    • pp.13-18
    • /
    • 2008
  • 전기 전자재료 중 고분자에 포함된 브롬계 난연제의 분석에 있어 용출이 어려운 4가지 재질 PC(polycar-bonate) PP(polypropylene), PET(poly(ethylene terephthalate)), PBT(poly(butylene terephthalate))에 대하여 추출방법 및 헥산/에세톤, THF, 톨루엔, THF/톨루엔에 대한 용매 특이성과 그 특성을 고찰하였다. 각 고분자에서의 deca-BDE(decabromo diphenyl ether)의 함량을 속슬렛, 초음파. 가속용매, 마이크로파, 초임계 유체 추출법을 사용하여 이들 방법의 효율을 정량분석 하였다. 초음파 추출은 낮은 고분자의 용해도 때문에 낮은 추출효율을 보여 사용한 고분자의 경우에 있어서 추출방법으로는 적합하지 않았으며, 나머지 3가지 방법에서는 톨루엔 사용시 약 80% 이상의 높은 추출효율을 보였다. 초임계 유체 추출은 고분자의 난연제 추출에 시도되지 않았던 방법이었으나, 본 실험에서 PP와 PC의 추출에서는 100%에 가까운 매우 높은 추출효율을 보였다.

폴리머 기판상의 Al-doped ZnO 박막의 두께에 따른 특성 변화 (Thickness Dependance of Al-doped ZnO Thin Film on Polymer Substrate)

  • 김봉석;김응권;강현일;이규일;이태용;송준태
    • 한국진공학회지
    • /
    • 제16권2호
    • /
    • pp.105-109
    • /
    • 2007
  • 본 논문에서는 AZO 박막 두께 변화에 따른 구조적, 전기적, 광학적 특성의 영향에 대하여 연구하기 위하여 폴리카보네이트(PC : polycarbonate) 기판 위에 DC 스퍼터링법으로 증착시간을 변화시켜 박막의 두께를 조절하였다. 박막의 두께는 100 nm에서 500 nm까지 100 nm단위로 실험하였으며, 제작된 AZO 박막의 비저항 특성은 four point probe system를 이용하여 측정하였고, 박막의 입자크기, 표면상태를 Environment Secondary Electron Microscopy (ESEM)으로 관찰하였다. 또한 AZO 박막의 결정상태를 조사하기 위하여 High Resolution X-Ray Diffractometer (HR-XRD)를 이용하였고 광학적 투과도는 UV-visible spectrophotometer를 이용하여 분석하였다. 실험 결과 모든 박막에서 90% 이상의 광투과도를 보였으며 400 nm과 500 nm 두께의 AZO 박막에서는 $4.5{\times}10^{-3}\;{\Omega}-cm$의 비저항과 3.61 eV의 광밴드갭 에너지를 보였다.

폴리머계 단일 및 이중구조 방음패널의 차음특성 비교분석 (Comparison of Sound Transmission through Single and Double-layer Polymer Panels)

  • 김일호;이주행;손진희
    • 대한환경공학회지
    • /
    • 제36권9호
    • /
    • pp.597-603
    • /
    • 2014
  • 본 연구에서는 PC, PMMA, HDPE, PP를 소재로 한 방음패널의 두께와 구조적 특성, 소재가 차음성능에 미치는 영향을 알아보았다. 각 소재로 구성된 단일 패널의 음향투과손실을 비교한 결과, PC, PMMA, HDPE, PP 순으로 음향투과손실이 높게 나타났으며, 질량법칙에 따르는 결과임을 확인하였다. 단일패널의 두께에 따른 투과손실을 비교해보면, 4 mm 단일패널에 비해 8 mm 두께의 투과손실이 약 5~6 dB(A) 크게 측정되었다. 또한 두께가 2배가 됨에 따라 일치효과 주파수가 낮아져 4,000~5,000 Hz에서 투과손실이 감소하는 영역이 발생하였으며, 4 mm 단일패널보다 투과손실이 작았다. 두 개의 4 mm 패널 사이에 공기층을 두어 이중으로 구성한 실험체를 대상으로 한 투과손실 실험 결과, 300 Hz 이하의 주파수에서는 동일한 두께인 8 mm의 단일패널과 효과가 비슷하였으며, 2,000 Hz 이상의 고주파수 대역에서 8 mm 단일패널에 비해 효과가 매우 뛰어났다. 반면 공명(resonance) 주파수와 인접한 500~630 Hz 대역에서 투과손실이 낮아지는 것을 알 수 있었다.