• Journal of Korean Society of Environmental Engineers
• /
• v.22 no.10
• /
• pp.1809-1816
• /
• 2000

The catalytic combustion of methanol as a model volatile organic compound(VOC) was been investigated over metal-phthalocyanine(PC) in a fixed bed flow reactor system. The catalytic activity of Co-PC pretreated with air and methanol mixture at $450^{\circ}C$ and 60 cc/min for 1 hr was very excellent. The order of catalytic activity on methanol combustion was summarized as follows: metal free-PC < Zn-PC < Fe-PC < Cu($\alpha$)-PC < Co-PC. By TG/DTA analysis, the tendency of thermal decomposition was increased as follows: metal free-PC < Zn-PC < Cu($\alpha$)-PC < Co-PC < Fe-PC. Under this pretreatment condition, the basic structures of Co-PC, Cu($\alpha$)-PC and Fe-PC were destroyed, and the new metal oxide such as $Co_3O_4$ from Co-PC was confirmed by EA and XRD analysis. But Zn-PC and metal free-PC were retained its basic structure under this pretreatment condition. On the combustion of methanol over Co-PC, HCHO and $HCOOCH_3$ were observed as an intermediate products in the high concentration of reactant or the short contact time(W/F).

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.18 no.6
• /
• pp.131-138
• /
• 2014

The steel structure fabrication plant certification program was enacted as a part of the construction technology management act, article 24-3, to improve the quality of steel construction after the decay falling accident of Seongsu Bridge in 1994. However, the national certification program for structural precast concrete that is a prefabricated construction products produced by casting concrete in plant is not implemented yet. So, to introduce the proper certification system for precast concrete, the quality certification programs of North America, Europe and Japan are surveyed. In North America, the organizations that manage the plant certification programs are PCI, NPCA, CPCI and so on. Sales of precast concrete elements in Europe are governed by the construction products regulation 305/2011. Therefore, CE marking is mandatory from July 2013 for all construction products including precast concrete. In Japan, precast concrete products used in civil engineering are certificated by JIS mark, product certification system and plants for manufacturing precast concrete building elements are audited by Japan Prefabricated Construction Suppliers and Manufacturers Association. Based on these survey studies, in this paper is described an adaptation of precast concrete plant certification to comport with the certification system in Korea.

• Journal of the Korean Society for Advanced Composite Structures
• /
• v.5 no.3
• /
• pp.32-36
• /
• 2014

This study analyzes performance-weight ratio of polycarbonate(PC) pigpen and steel pigpen. The finite element models using the ANSYS program described in this paper is attractive not only because it shows excellent accuracy in analysis but also it shows the benefit of parameter study by using APDL. We have performed a parameter study by the width variation of PC pigpen. And we compared and analyzed the results of PC pigpen and steel pigpen. From the numerical examples, we confirmed the validity of PC pigpen.

• Journal of the Computational Structural Engineering Institute of Korea
• /
• v.13 no.2
• /
• pp.189-196
• /
• 2000

The objective of this paper is to propose an analysis technique to predict the behavior of PC wall structures subjected to cyclic load. While PC wall panel is idealized by finite elements, the joints at which PC walls are connected each other are idealized by nonlinear spring elements. Axial and shear spring elements are developed for simulating shear, compression and tension behaviors of joints. The strength and stiffness of each spring elements we presented from the previous research results and incorporated into the computer program of DRAIN-2DX. The proposed analysis technique is evaluated by analyzing specimens previously tested and comparing with those. On the strength, stiffness, energy dissipation and lateral drift, analytical results show good agreements with test results. This means the proposed technique is effective to predict the response of the PC wall structures.

• Korean Journal of Optics and Photonics
• /
• v.20 no.4
• /
• pp.211-216
• /
• 2009

Much research into two-dimensional (2-D) photonic crystal (PC) structures has been conducted for realization of ultrasmall optical integrated circuits. A 2-D silicon (Si) PC slab structure with air cladding (n=1) is one of the representative structures in 2-D PCs. While air-clad Si PC slab structures have good optical characteristics, their suspension in air can lead to mechanical weakness, making integration with some optical devices difficult. In this paper, we propose improving the mechanical robustness of PC structure by developing a 2-D Si PC structure with symmetric silica cladding (n=1.44) and comparing its optical properties to that of the air-clad structure. First, we investigate the optical properties of a 2-D Si PC slab structure with air cladding by using a 3-D finite difference time domain method. We determined that a photonic bandgap of 330 nm and a non-leaky propagating bandwidth of 100 nm in the optical communication range are possible. Next, we investigate the optical properties of 2-D Si PC slab structures with silica cladding. Even though the refractive index of the silica cladding is higher than that of air, we developed a silica-clad structure with good optical properties: a photonic band gap of approximately 230 nm and a non-leaky propagating bandwidth of 90 nm, comparable to that of the air-clad PC structures.

• Journal of Korean Association for Spatial Structures
• /
• v.21 no.4
• /
• pp.65-72
• /
• 2021

The Precast concrete(PC) modular structures are a method of assembling pre-fabricated unit modules in the construction site. The essential aim of modular structures is to introduce a connection method that can ensure splicing performance and effectively resist shear strength. This study proposed PC module using a connecting plate that can replace splice sleeves and shear keys used in the conventional PC modular structures. To evaluate the splicing performance and shear capacity of the proposed method, the shear test was conducted by fabricating one monolithic reinforced concrete(RC) beam and two PC modular beams with a shear span-to-depth ratio as variables. The experimental results showed that the shear capacity of the PC modular beam was about 89% compared to that of the RC beam, and showed a failure of the RC beam according to the shear span-to-depth ratio. Therefore, it was considered that the connecting plate effectively transferred the stress between each PC module through the joint and ensure integrity. In addition, the applicability of shear strength equation of ACI 318-19 and Zsutty's equation to PC modular beams were evaluated. Results demonstrated that the improved shear strength equations are needed to consider reduction of shear strength in PC modules.

• Applied Chemistry for Engineering
• /
• v.26 no.3
• /
• pp.336-340
• /
• 2015

Three different types of polycarbonate (PC)/graphene oxide (GO) composites using diphenyl carbonate as a monomer were fabricated by melt polymerization. Those were the PC/GO composite (PC/GO) using a twin extruder, in-situ PC/GO composite (PC/GO-cat.) using a catalyst, and in-situ PC/GO composite (PC/GO-COCl) using a GO-COCl treated by -COCl, Chemical structures of the composites were confirmed by C-H and C=O stretching peak at $3000cm^{-1}$ and $1750cm^{-1}$, respectively. The slope for the storage (G') versus loss (G") modulus plot decreased with an increase in the heterogeneous property of polymer melts. So we can check the GO dispersion of the PC/GO composites using by the slop for G'-G" plot. According to the G'- G" slopes for three different types of PC/GO composites, GO was well dispersed within PC matrix in case of PC/GO and PC/GO-cat.. It was also confirmed by atomic force microscope (AFM) photos. One of the reasons for the poor GO dispersion of PC/GO-COCl is branching and crosslinking processes occurred during polymerization, which was further confirmed by a plot for the complex modulus versus phase difference.

• Journal of the Korean Chemical Society
• /
• v.53 no.5
• /
• pp.521-529
• /
• 2009

Molecular structures of the various conformers for the 1,3-dimethoxy-p-tert-butylthiacalix[4] crown-5-ether (3) were optimized by using DFT B3LYP/6 - 31 + G(d,p) and mPW1PW91/6 - 31 + G(d,p) (hybrid HF-DF) calculation methods. We have analyzed the energy differences and structures of eight in/out orientations (cone_oo, cone_oi, pc_oo, pc_io, pc_oi, pc_ii, 13a_oo, 13a_io) of two methoxy groups in three major conformations (cone, partial-cone and 1,3-alternate). The 13a_oo (out-out orientation of the 1,3-alternate conformer) is calculated to be the most stable among eight different conformations of 3, and in accord with the experimental result. The ordering of relative stability resulted from the mPW1PW91/6 - 31 + G(d,p) calculation method is following: 13a_oo > 13a_io$\sim$pc_io$\sim$cone_oo > cone_oi$\sim$pc_oo$\sim$pc_oi > pc_ii.

• Journal of the Korea Concrete Institute
• /
• v.26 no.1
• /
• pp.35-46
• /
• 2014

Two types of cast-in-place concrete-filled hollow PC (HPC1, HPC2) columns were developed to reduce lifting load of heavy-weight PC columns and to improve the structural integrity of joints. To form the hollow PC columns, a couple of prefabricated PC panels was used for HPC1, and special hoops were used for HPC2. Lateral pressure of wet concrete on PC faces was measured while placing the concrete inside the columns. To evaluate the seismic resistance, full scale specimens of two HPC columns and a conventional RC column were tested under combined axial compression and lateral cyclic loading. The test results showed that the structural performance of the proposed HPC columns such as intial stiffness, maximum strength, and displacement ductility was comparable to that of the conventional RC column, but the energy dissipation of HPC2 slightly decreased after rebar-buckling. However, all the test specimens satisfied the energy dissipation requirement specified in ACI 374.

• Polymer(Korea)
• /
• v.35 no.4
• /
• pp.356-362
• /
• 2011

The branched polycarbonates (B-PCs) with two different branching agents were synthesized from melt polymerization. The contents of branching agent were in the range of 0.001~0.005 mol%. The chemical structure of the synthesized PC was determined by FTIR, $^1H$ NMR, and $^{13}C$ NMR, spectroscopy. The molecular weight, glass transition and degradation temperatures were determined by GPC, DSC, and TGA. The molecular weight of the phloro type B-PC had a lower value than the other one, and the glass transition temperature increased with molecular weight. Compared with linear PC, the rheological properties of the B-PC indicated an increase of complex viscosity in the low frequency region and shear thinning tendency. Power law index(n) representing shear thinning was calculated by linear regression and the values were in the range of 0.483~0.996. The rheological properties of the B-PCs were measured by a dynamic rheometer.