• Title/Summary/Keyword: P-delta effects

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Effect of Different Coagulants on Quality of Tofu Incorporated with Persimmon Fruit Powder (응고제 종류가 감 분말 첨가 두부의 품질과 저장성에 미치는 영향)

  • Lee, Yun-Rae;Chung, Hun-Sik;Seong, Jong-Hwan;Moon, Kwang-Deog
    • Food Science and Preservation
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    • v.18 no.5
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    • pp.678-683
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    • 2011
  • The effects of coagulant types (magnesium chloride, calcium chloride, calcium sulfate, glucono-${\delta}$-lactone) on yield, quality properties and storability of astringent persimmon powder added tofu were investigated. Yield, hardness, chewness, crispness, and overall acceptability of tofu coagulated by glucono-${\delta}$-lactone were higher than those coagulated by the others. L value, a value, pH, soaking-solution turbidity, and total aerobic bacteria of glucono-${\delta}$-lactone coagulated tofu were lower than those coagulated by the others. Calcium sulfate and calcium chloride coagulated tofu showed relatively high L and b values. Magnesium chloride coagulated tofu had higher sensory score for firmness, taste, overall acceptability than calcium chloride and calcium sulfate coagulated tofu, but there was no significant difference between magnesium chloride and glucono-${\delta}$-lactone. The results suggested that glucono-${\delta}$-lactone and magnesium chloride were found to be the suitable coagulants for processing of the persimmon powder added tofu.

The Effect of Acupuncture at PC7(Daereung) on EEG in Normal Human Subject (대릉(大陵)(PC7) 침자가 뇌파에 미치는 영향)

  • Park, Cheol-Jin;Lee, Sang-Ryong
    • Korean Journal of Acupuncture
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    • v.27 no.2
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    • pp.141-157
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    • 2010
  • Objectives : The aim of this study is to examine the effects of acupuncture at PC7(Daereung) on normal human EEG using power spectral analysis. Methods : EEG power spectrum exhibits site-specific and state-related differences in specific frequency bands. In this study, power spectrum was used as a measure of complexity. 30 subjects (16 males and 14 females; averaged age = 23.4 years) were engaged with thirty channel EEG study. Results : In $\alpha$(alpha) band, the power values at Fp1, Fp2, F7, F8 channels(p<0.05) during PC7 treatment were significantly decreased. But, the power values at Fz channel(p<0.05) during non-acupoint treatment was significantly decreased. In $\beta$(beta) band, the power values at Fp1, Fp2 channels(p<0.05) during PC7 treatment were significantly decreased. But, the power values at Fz channel(p<0.05) during non-acupoint treatment was significantly decreased and at F8, TCP2 channels(p<0.05) during non-acupoint treatment were increased. In $\theta$(theta) band, the power values at Fp1, Fp2, F7, F8 channels(p<0.05) during PC7 treatment were significantly decreased. But, the power values at Fz channel(p<0.05) during non-acupoint treatment was significantly decreased. In $\delta$(delta) band, the power values at Fp1, Fp2, F7, Fz, F8 channels (p<0.05) during PC7 treatment were significantly decreased. But, the power values at Fz channel (p<0.05) during non-acupoint treatment was significantly decreased. $\alpha/\beta$ values during PC7 treatment were decreased. $\beta/\theta$ values during PC7 treatment were decreased. Conclusion : These results suggest that acupuncture at PC7 induce the change on $\alpha$(alpha), $\beta$(beta), $\theta$ (theta), $\delta$(delta) wave values being decreased and and bothe $\alpha/\beta$ and $\beta/\theta$ values being decreased respectively. This is considered that acupuncture at PC7 affects the activity of cerebral cortex and endocrine system.

Absorption Characteristics of Sulfur Dioxide in Jet Bubbling Reactor (가스분사반응기에서의 SO2 흡수 특성)

  • Choi, Byung-Sun;Park, Seung-Soo;Kim, Yung-whan
    • Applied Chemistry for Engineering
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    • v.5 no.5
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    • pp.836-842
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    • 1994
  • The optimum design conditions of gas sparger pipe and the effects of operating variables on $SO_2$ removal efficiency have been examined in Jet Bubbling Reactor. Geometry of gas sparser pipe of Jet Bubbling Reactor is a very important factor to obtain a effective gas-liquid contact. Test results revealed that Reynolds numbers at sparger and slot have to be kept greater than 12,000 identically at a given gas velocity. $SO_2$ removal efficiency was a function of ${\Delta}P$, pH, inlet $SO_2$ concentration and particle size of limestone and was more sensitive to the change of ${\Delta}P$ than to the changes of others. The ${\Delta}P$ of at least 230mmAq must be maintained to acheive the above 90% $SO_2$ removal at pH of 4.0 which is considered as adequate operating pH. Higher $SO_2$ removal efficiency was obtained even at lower pH ranges, which resulted from the complete oxidation of the absorbed $SO_2$ to sulfates by adding air and consequently from the reduction of $SO_2$ equillibrium partial pressure in the gas-liquid interface The 99.5% of the limestone utilization was attained in pH range from 3.0 to 5.0 with regardless to the particle size of limestone employed.

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Frequency Characteristics of Anodic Oxide Films: Effects of Anodization Valtage

  • Lee, Dong-Nyung;Yoon, Young-Ku
    • Nuclear Engineering and Technology
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    • v.6 no.1
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    • pp.14-22
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    • 1974
  • Effects of anodization voltage on frequency characteristics of anodic oxide films on tantalum were analyzed based on the following impedance equatious : (equation omitted) Here $R_{f}$, $C_{f}$ and tan $\delta$$_{f}$ are equivalent series resistance in ohm, equivalent Belies capacitance in farad and dielectric loss, of anodic oxide films respectively Parameters P, $\tau$$_{ο}$, $\tau$$_{\omega}$, and Co are defined as follows: P=(d-w)/w, $\tau$$_{ο}$=$textsc{k}$$\rho$$_{ο}$, $\tau$$_{\omega}$=$textsc{k}$$\rho$$_{\omega}$, $C_{ο}$=$textsc{k}$A/d where d is the thickness of oxide film, $\omega$ is the diffusion layer thickness. $\rho$$_{ο}$ is the resistivity of oxide film at the interface of metal and the oxide, $\rho$$_{\omega}$ is the resistivity of oxide film at intrinsic region and A is the area of the film and $textsc{k}$=0.0885$\times$10$^{-12}$ $\times$dielectric constant, (in farad/cm). It was shown that dielectric loss and frequency dependence of equivalent series capacitance decrease as anodization voltage increases. This is a consequence of the fact that the thickness of diffusion layer increases a little with increasing anodization voltage whereas the total oxide thickness is proportional to the anodization voltage. The ngative deviation of measured values from tile relation, tan $\delta$$_{f}$=0.682 $\Delta$ $C_{f}$, was also discussed based on the Impedance equations given above. Here $\Delta$ $C_{f}$ is the change in capacitance between 0.1 and 1 KHZ.KHZ.Z.

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$^{19}$F NMR Studies on 8,9-Dehydro-2-adamantyl and 2,4-Dehydro-5-homoadamantyl Cations

  • Shim, Jae-Chul;Nam, Ghil-Soo;Kim, Kyong-Tae;Shin, Jung-Hyu
    • Bulletin of the Korean Chemical Society
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    • v.10 no.2
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    • pp.132-133
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    • 1989
  • To probe the geometrical effects of cyclopropyl moiety on the stabilization of an adjacent cation center, chemical shift of 2-p-fluorophenyl-8,9-dehydro-2-adamantyl cation (3) was compared with that of 5-p-fluorophenyl-2,4-dehydro-5-homoadamantyl cation (4). Difference between the chemical shift of 8,9-dehydro-2-adamantyl cation 3 and that of 2,4-dehydro-5-adamantyl cation 4 is 5.1 ppm (${\Delta}{\Delta}{\delta}$). We conclude, therefore, that ion 3 is about 3.82 kcal more stadble than ion 4 of which rigid carbon skeleton requires significant distortion of the cyclopropane ring from the ideal bisected conformation. The energy difference between these cations can be calculated by Taft-Relationship$^8$ on the basis of chemical shift.

Kinetics of the Reaction of Phenacyl Bromide with Anilines in Methanol and Dimethylformamide (Phenacyl Bromide와 置換아닐린類와의 反應에 關한 反應速度論的 硏究)

  • Soo-Dong Yoh;Doo-Jung Kim
    • Journal of the Korean Chemical Society
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    • v.25 no.6
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    • pp.376-382
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    • 1981
  • The rates and the activation parameters for the reaction of phenacyl bromide with substituted anilines in methanol and dimethylformamide were measured. The effects of substituted anilines were discussed. The rate of the reaction was increased with the electron donating power of substituent and showed larger value in DMF than in MeOH. The isokinetic relationship was shown between ${\delta}H^{\neq}$ and ${\delta}S^{\neq}$, isokinetic temperature was 539 and $400^{\circ}C$ in MeOH and DMF respectively, but p-nitro aniline was deviated from linearity in both solvents caused by solvent effects. The excellent linear relationship between log k and p$K_a$ of substituted anilines was observed by following equation. log k = 0.57p$K_a$-1.28 (r = 0.996) in MeOH at $45^{\circ}C$, log k = 0.65p$K_a$-0.88 (r = 0.970) in DMF at $45^{\circ}C$. From the Hammett plot, this reaction was a nucleophilic displacement of aniline to phenacyl bromide and the following equation was obtained at $45^{\circ}C$. log k/$k_0$ = -2.00${\sigma}$ + 0.06 (r = 0.985) in MeOH; log k/$k_0$ = -2.22${\sigma}$ + 0.08 (r = 0.995) in DMF. Large deviation of p-nitro aniline in DMF is resulted from solvent effects too. From above results, the substituent effect of this reaction can be described as $S_N2$ mechanism and bond formation more proceeds in DMF relative to MeOH.

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A reinforced concrete frame element with shear effect

  • Valipour, Hamid R.;Foster, Stephen J.
    • Structural Engineering and Mechanics
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    • v.36 no.1
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    • pp.57-78
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    • 2010
  • A novel flexibility-based 1D element that captures the material nonlinearity and second order P-$\Delta$ effects within a reinforced concrete frame member is developed. The formulation is developed for 2D planar frames in the modified fiber element framework but can readily be extended to 3D cases. The nonlinear behavior of concrete including cracking and crushing is taken into account through a modified hypo-elastic model. A parabolic and a constant shear stress distribution are used at section level to couple the normal and tangential tractions at material level. The lack of objectivity due to softening of concrete is addressed and objectivity of the response at the material level is attained by using a technique derived from the crack band approach. Finally the efficiency and accuracy of the formulation is compared with experimental results and is demonstrated by some numerical examples.

Drift Control for Multistory Moment Frames under Lateral Loading

  • Grigorian, Carl E.;Grigorian, Mark
    • International Journal of High-Rise Buildings
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    • v.2 no.4
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    • pp.355-365
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    • 2013
  • The paper reports results of recent studies on the effects of column support conditions on the lateral displacements of moment frames at incipient collapse. The article presents a number of exercises in the plastic theory of structures that lead to useful design formulae. It has been shown that Drift Shifting (DS) is caused due to differences in the stiffnesses of adjoining columns, and that changes in drift ratios are more pronounced at first level column joints in both fixed as well as pinned base frames. In well proportioned moment frames, DS in the upper levels could be minimized, even reduced to zero. It has been demonstrated that DS can be eliminated in properly designed fixed and grade beam supported (GBS) moment frames. Several examples, including symbolic P-delta effects, have been provided to demonstrate the validity and the applications of the proposed ideas to the design and drift control of moment frames. The proposed methodology is exact within the bounds of the theoretical assumptions and is well suited for preliminary design and teaching purposes.

An Overview on Performamce Control and Efficient Design of Lateral Resisting Moment Frames

  • Grigorian, Mark;Grigorian, Carl E.
    • International Journal of High-Rise Buildings
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    • v.2 no.2
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    • pp.141-152
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    • 2013
  • This paper presents a brief overview of the recently developed performance-control method of moment frame design subjected to monotonously increasing lateral loading. The final product of any elastic-plastic analysis is a nonlinear loaddisplacement diagram associated with a progressive failure mechanism, which may or may not be as desirable as expected. Analytically derived failure mechanisms may include such undesirable features as soft story failure, partial failure modes, overcollapse, etc. The problem is compounded if any kind of performance control, e.g., drift optimization, material savings or integrity assessment is also involved. However, there is no reason why the process can not be reversed by first selecting a desirable collapse mechanism, then working backwards to select members that would lead to the desired outcome. This article provides an overview of the newly developed Performance control methodology of design for lateral resisting frameworks with a view towards integrity control and prevention of premature failure due to propagation of plasticity and progressive P-delta effects.

Metabolic Activation of Marijuana Constituents, Cannabinoids, in Relation to Their Toxicity for Human and Its Oxidation Mechanism

  • Ikuo, Yamamoto
    • Proceedings of the PSK Conference
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    • 2002.10a
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    • pp.194-199
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    • 2002
  • Many oxidative metabolites of tetrahydrocannabinols (THCs), active components of marijuana, were pharmacologically active, and 11-hydroxy-THCs, 11-oxo-${\Delta}^8$-THC, 7-oxo-${\Delta}^8$-THC, 8$\beta$, 9$\beta$-epoxyhexahydrocannabinol (EHHC), 9$\alpha$, l0$\alpha$-EHHC and 3'-hydroxy-${\Delta}^9$-THC were more active than THC in pharmacological effects such as catalepsy, hypothermia and barbiturate synergism in mice. Cannabidiol (CBD), another major component, was biotransfomred to two novel metabolites, 6-hydroxymethyl-${\Delta}^9$-THC and 3-pentyl-6, 7, 7a, 8, 9, lla-hexahydro-I, 7-dihydroxy-7, 1O-dimethyldibenzo[b, d]oxepin (PHDO) through 8R, 9-epoxy-CBD and 85, 9-epoxy-CBD, respectively. Both metabolites exhibited some pharmacological effects comparable to d9 - THe. Cannabinol (CBN), the other major component, was mainly metabolized to ll-hydroxy-CBN by hepatic microsomes of animals including humans. The pharmacological effects of the metabolite were higher than those of CBN demonstrating that II-hydroxylation of CBN is metabolic activation pathway of the cannabinoid as is the case in THCs. Tolerance and reciprocal cross-tolerance developed to pharmacological effects d8 - THC and ll-hydroxy-d8-THC , and the magnitude of tolerance development produced by the metabolite was significantly higher than that by d8-THC. The results indicate that ll-hydroxy-d8-THC has an important role not only in the pharmacological effects but also its tolerance development of d8 - THe. THCs and their metabolites competed to the specific binding of CP-55, 940, an agonist of cannabinoid receptor, to synaptic membrane from bovine cerebral cortex. The Ki value of THCs and their metabolites were closely paralleled to their pharmacological effects in mice. A novel cytochrome P450 (cyp2c29) was purified and identified as a major enzyme responsible for the metabolic activation of d8-THC at the II-position in the mouse liver. cDNA of CYP2C29 was cloned from a mouse cDNA library and its sequence was determined. The oxidation mechanism of THC by cyp2c29 was proposed.

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