• 제목/요약/키워드: P-base

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의치상 직접 이장레진의 색조 안정성 (THE COLOR STABILITY OF DIRECT DENTURE RELINE RESINS)

  • 강은숙;전영찬;정창모
    • 대한치과보철학회지
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    • 제41권2호
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    • pp.160-168
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    • 2003
  • Statement of problem : Direct denture reline resins tend to discolor during service in the oral environment by intrinsic and extrinsic factor. Purpose : This study was designed to evaluate the color stability of direct denture reline resins. Material and methods : Mild Rebaron(GC Corp., Japan), Meta Base M(Sun medical Co., Japan), Mild Rebaron LC(GC Corp., Japan) and as a control group, Vertex SC(Dentimex Zeist, Holland) were chosen for this study. Ten specimens of each direct denture reline resins were fabricated. Treatment methods designed for this study were the coffee staining test(7days) and the accelerated aging test(100hours). The color changes before and after treatment were measured by Tristimulous colorimeter(Yasuda seiki seisakusho, Ltd. Japan) and analyzed. Results All the direct denture reline resins subjected to the coffee staining test and the accelerated aging test showed noticible difference in color change. After coffee staining test, Meta Base M showed the highest color change followed by Vertex SC. Mild Rebaron LC and Mild Rebaron. There were no statistical differences between Meta Base M and Vertex SC and between Mild Rebaron LC and Mild Rebaron(p>0.05). After accelerated aging test. Mild Rebaron LC showed the highest color change followed by Vertex SC, Meta Base M and Mild Rebaron. There were no statistical differences only between Mild Rebaron and Mata Base M(p>0.05) but among the others, there were statistical differences(p<0.05). Conclusion : Within the limitation of this study, all the direct denture reline resins subjected to the extrinsic and intrinsic factors showed noticible difference in color change, and there were differences among manufacturers.

BBSA 유도체의 가수분해메카니즘과 반응속도론적 연구 (A Study on the Kinetics and Mechanism of the Hydrolysis of N-Benzylidenebenzenesulfonamide Derivatives)

  • 이석우;장병만;이광일;이기창
    • 대한화학회지
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    • 제36권6호
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    • pp.919-924
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    • 1992
  • N-Benzylidenebenzenesulfonamide 유도체의 가수분해 반응속도를 $25^{\circ}C$의 수용액에서 자외선 분광기를 사용하여 측정하고 넓은 pH 범위에 적용될 수 있는 반응속도식을 유도하였다. 가수분해 반응속도에 미치는 치환기 효과를 검토하기 위하여 Hammett plot를 한 결과 전자 끄는기에 의하여 반응속도가 촉진됨을 알 수 있었다. 가수분해 최종 생성물은 benzenesulfonamide와 benzaldehyde 이었으며 가부분해 반응속도 상수 측정과 반응속도식의 유도, 치환기 효과, general base 효과 및 최종생성물의 결과로부터 n-benzylidenebenzenesulfonamide 유도체의 가수분해 반응은 pH 0.2${\sim}$2.5에서는 hydronium ion에 의해서, pH 3.0${\sim}$8.0 사이에서는 중성의 물분자에 의하여 가수분해가 일어나고 pH 8.5 이상에서는 hydroxide ion에 의하여 진행됨을 알 수 있었다.

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Fe-EDTA계 액상촉매 산화법에 의한 분뇨처리장 악취제거에 관한 연구 (Studies on the Deodorization in the Nightsoil Treatment Plant with liquid Phase Catalytic Oxidation Method by Utilization of Fe-EDTA)

  • 이인화
    • 한국환경과학회지
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    • 제1권2호
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    • pp.105.1-113
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    • 1992
  • The present study was performed to develop the removal system of the offensive gases, including hydrogen sulfide of acid gas, ammonia or amice of base gas, from the nightsoil treatment plant. In order to remove the offensive gases, the Fe-EDTA system liquid phase catalytic oxidation method with the bubble lift column reactor was employed. From the results obtained, it was confirmed that the offensive gases can be deodorized simultaneously and also hydrogen sulfide of acid gas, ammonia of base gas completely removed at pH 6.45. In addition, as input gases feed rate the efficiency of acid gas did not change but the efficiency of base gases decreased to approximately 90 % at pH 6, 0. From the result of particle size analyzer, it was found that the particle sizes including sulfur and other impurites grew up to $21{\mu}m$ over 72hour reaction time.

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PROTROPIC AND PHOTOPHYSICAL PROPERTIES OF 7-HYDROXYQUINOLINE IN X AND Y ZEOLITES

  • Park, Ji-Ho;Jang, Du-Jeon
    • Journal of Photoscience
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    • 제1권1호
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    • pp.25-29
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    • 1994
  • Diffuse reflectance and emission spectra of 7-hydroxyquinoline intercalated in the supercage of X and Y zeolites are compared with the absorption and emission spectra of aqueous 7-hydroxyquinoline solutions at various pH to understand protropic and photophysical properties of 7-hydroxyquinoline in zeolite microenvironments. Predominance of zwitterionic spedes with significant existences of the other three protropic equilibrium species, normal, protonated and deprotonated species in zeolite samples indicates that the major fraction of the molecules interact with strong acid and base sites of zeolite at an adsorbed position. Observed zeolite pHs of near neutrality are established by a near balance in numbers of many strong acid and base sites rather than by'small numbers or weakness of acid and base sites. Excitations of nonzwitterionic species such as deprotonated species also give prevailing zwitterionic fluorescence, indicating that excited and ground proton transfer cycles of protropic species can be triggered by photons in organized zeolite media as well as in water.

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InAlGaAs/InGaAs HBT의 Monte carlo 해석 (Monte carlo analysis of InAlGaAs/InGaAs HBT)

  • 황성범;김용규;송정근
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 1998년도 하계종합학술대회논문집
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    • pp.405-408
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    • 1998
  • Due to the large conduction band discontinuity between emitter base, OmGaAs HBT has an advantge to enable the hot electrons to inject into the base. In this paper, InAlGaAs/InGaAs HBT with the various emitter junction gradings and the modified collectors are simulated and analyzed by HMC(hybrid monte carlo) simulator in order to find a optimal structure for the shortest transit time. A minium base transit time (.tau.$_{b}$ ) of 0.21 ps was obtained for HBT with the grading layer, which is parabolically graded from x=1.0 to x=0.5. The minimum collector transit time (.tau.$_{c}$ ) of 0.31ps was found when the collector was modified by inserting p$^{[-10]}$ and p$^{+}$ layers. Thus HBT in combination with the emitter grading and the modified collector layer showed the cut-off frequency (f$_{T}$) of 183GHz.z.z.

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토양의 산/염기 완충능의 모델링 (Modeling of Acid/Base Buffer Capacity of soils)

  • 김건하
    • 한국토양환경학회지
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    • 제3권3호
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    • pp.3-10
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    • 1998
  • 토양의 산/염기 완충능은 토양-오염물질-공극수로 이루어진 시스템의 pH에 직접적인 영향을 미치므로 오염물질의 토양내 거동예측시에 많은 영향을 미치는 매우 중요한 토양의 성질이다. 본 연구는 이중확산층이론과 two layer electrostatic 흡착모델을 응용하여 토양의 산/염기 완충능의 이론모델을 유도하고 이 모델의 적용절차를 제시하였다. 산-염기 적정실험을 통하여 두 종류의 카올리나이트의 완충능을 실측하고 이를 본 연구에서 개발된 모델의 예측치와 비교하였다.

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TCAD Simulation을 통한 GaAs태양전지 Base Layer의 물리적 Parameter 및 에너지 효율의 최적화 연구

  • 이충학;이준신
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.449.1-449.1
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    • 2014
  • GaAs태양전지는 일반적으로 22%이상의 변환효율을 가지는 차세대 태양전지이다. GaAs태양전지의 변환효율은 태양광이 조사되었을 때, p-type emitter와 n-type base의 p-n접합으로 생기는 Voc, Isc, FF 인자들로 인하여 그 값이 결정되는데, 이때 각 layer의 물리적 parameter에 의해 그 효율이 변한다. 일반적으로는 각 parameter가 증가할 때, 더욱 많은 전자로 인하여, 저 높은 변환효율을 기대할 수 있겠으나, 전자의 재결합이나 mobility의 감소와 같은 이유로 변환효율은 감소 될 수 있다. GaAs태양전지의 base layer의 두께와 도핑농도를 simulation한 결과 두께 $2.6{\mu}m$, 도핑농도 $7{\times}E17cm^{-3}$와 두께 $2.7{\mu}m$, 도핑농도 $8{\times}E17cm^{-3}$에서 25.86%의 가장 높은 에너지 효율을 가짐을 확인 할 수 있었다.

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COCOMPACT F-BASES AND RELATION BETWEEN COVER AND COMPACTIFICATION

  • Lee, Sang-Deok;Kim, Chang-Il
    • 한국수학교육학회지시리즈B:순수및응용수학
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    • 제3권2호
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    • pp.163-171
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    • 1996
  • Observing that a locally weakly Lindel$\"{o}$f space is a quasi-F space if and only if it has an F-base, we show that every dense weakly Lindel$\"{o}$f subspace of an almost-p-space is C-embedded, every locally weakly Lindel$\"{o}$f space with a cocompact F-base is a locally compact and quasi-F space and that if Y is a dense weakly Lindel$\"{o}$f subspace of X which has a cocompact F-base, then $\beta$Y and X are homeomorphic. We also show that for any a separating nest generated intersection ring F on a space X, there is a separating nest generated intersection ring g on $\phi_{Y}^{-1}$(X) such that QF(w(X, F)) and ($\phi_{Y}^{-1}$(X),g) are homeomorphic and $\phi_{Y}_{x}$(g$^#$)=F$^#$.

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보레인 화합물을 이용한 불소 이온 검출에 관한 교육 연구 (A Educational Study on Detection of Fluoride by Borane Compounds)

  • 이강문
    • 한국교육논총
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    • 제37권1호
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    • pp.33-45
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    • 2016
  • 본 연구는 다양한 치환기를 포함하고 있는 3종의 보레인 화합물을 합성하고, UV/Vis 하에서 합성된 화합물이 내는 흡광을 이용하여 유기 용매 하에서 매우 적은 농도로 존재하는 불소 이온($F^-$)의 검출에 적용하고자 하는 것이다.

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Quinizarin-ethylenediamine의 Schiff's Base 와 금속 (Ⅱ) 이온이 만드는 Coordination polymer의 합성에 관하여 (Inorganic polymers of metal (Ⅱ) ions with Schiff's Base of quinizarin-ethylenediamine)

  • 오준석;곽원석
    • 대한화학회지
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    • 제13권1호
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    • pp.29-36
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    • 1969
  • lnorganic polymers, which are composed of metal (Ⅱ) ions and Schiff's Base of quinizarin-ethylenediamine, have been prepared. In order to find out proper conditions for the reaction, some investigations have been carried out to test the effect of pH, kind of solvent and the state of reagent. As a result, the highest yield occurred near pH 7 and it was found that there were not great difference in the kind of solvent and the state of reagent we had used. Most of the polymers are seemed not to be those we have attempted to prepare. They are found to be coordination polymers which have rather low molecular weight.

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