• Title/Summary/Keyword: P-V value

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Study on the Morphologies and Electrical Properties in Polymer Blend Thin-Films Based on Two Poly(3-hexylthiophene) Conjugated Polymers with Different Regio-regularities (서로 다른 위치 규칙성을 가지는 두 개의 Poly(3-hexylthiophene) 공액 고분자를 기반으로 한 고분자 복합 박막의 구조와 전기적 특성에 대한 연구)

  • Ganghoon Jeong;Nann Aye Mya Mya Phu;Rae-Su Park;Jeong Woo Yun;Yeongun Ko;Mincheol Chang
    • Composites Research
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    • v.36 no.5
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    • pp.349-354
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    • 2023
  • Poly(3-hexylthiophene) (P3HT) is a conjugated polymer that is highly soluble in organic solvents and is readily available. However, its electrical properties as an active channel in electronic devices are not enough for practical applications, necessitating further improvement in the properties. In this study, we demonstrate that the blending of two P3HT polymers (i.e., regio-regular (RR) P3HT and regio-random (RRa) P3HT) with different regioregularities can significantly improve charge transport characteristics of the blend films. The morphological and electrical properties of the blend films were systematically investigated by varying the ratio between two P3HT polymers. Atomic force microscopy (AFM), X-ray diffraction (XRD), and UV-visible absorption spectroscopy (UV-vis) were employed to evaluate the morphological and optoelectronic properties of the blend films. The crystallinity of the blend films increased with increasing the content of RRa-P3HT to 20 wt% and gradually decreased as the content increased to 80%. Consistently, the highest charge carrier mobility was obtained from the blend films containing 20 wt% RRa-P3HT, which value was measured to be 0.029 cm2/V·s. The values gradually decreased to 0.0007 cm2/V·s with increasing the content of RRa-P3HT to 80 wt%.

Reaction Mechanism of Purine Nucleoside Phosphorylase and Effects of Reactive Agents for SH Group on the Enzyme in Saccharomyces cerevisiae (Saccharomyces cerevisiae에서 얻은 Purine Nucleoside Phosphorylase의 반응기작과 효소에 대한 Sulfhydryl Reagent의 영향)

  • Choi, Hye-Seon
    • Korean Journal of Microbiology
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    • v.32 no.3
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    • pp.222-231
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    • 1994
  • Kinetic analysis was done to elucidate the reaction mechanism of purine nucleoside phosphorylase (PNP) in Saccharomyces cerevisiae. The binary complexes of PNP${\cdot}$phosphate and PNP${\cdot}$ribose 1-phosphate were involved in the reaction mechanism. The initial velocity and product inhibition studies demonstrated were consistent with the predominant mechanism of the reaction being an ordered bi, bi reaction. The phosphate bound to the enzyme first, followed by nucleoside and base were the first product to leave, followed by ribose 1-phosphate. The kinetically suggested mechanism of PNP in S. cerevisiae was in agreement with the results of protection studies against the inactivation of the enzyme by sulfhydryl reagents, p-chloromercuribenzoate (PCMB) and 5,5'-dithiobisnitrobenzoate (DTNB). PNP was protected by ribose 1-phosphate and phosphate, but not by nucleoside or base, supporting the reaction order of ordered bi, bi mechanism. PCMB or DTNB-inactivated PNP was totally reactivated by dithiothreitol (DTT) and the activity was returned to the level of 77% by 2-mercaptoethanol, indicating that inactivation was reversible. The kinetic behavior of the PCMB-inactivated enzyme had been changed with higher $K_m$ value of inosine and lower $V_m$, and was restored by DTT. Inactivation of enzyme by DTNB showed similar pattern of K sub(m) value with that by PCMB, but had not changed the $V_m$ value, significantly. Negative cooperativity was not found with PCMB or DTNB treated PNP at high concentration of phosphate.

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QUALITATIVE PROPERTIES OF WEAK SOLUTIONS FOR p-LAPLACIAN EQUATIONS WITH NONLOCAL SOURCE AND GRADIENT ABSORPTION

  • Chaouai, Zakariya;El Hachimi, Abderrahmane
    • Bulletin of the Korean Mathematical Society
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    • v.57 no.4
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    • pp.1003-1031
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    • 2020
  • We consider the following Dirichlet initial boundary value problem with a gradient absorption and a nonlocal source $$\frac{{\partial}u}{{\partial}t}-div({\mid}{\nabla}u{\mid}^{p-2}{\nabla}u)={\lambda}u^k{\displaystyle\smashmargin{2}{\int\nolimits_{\Omega}}}u^sdx-{\mu}u^l{\mid}{\nabla}u{\mid}^q$$ in a bounded domain Ω ⊂ ℝN, where p > 1, the parameters k, s, l, q, λ > 0 and µ ≥ 0. Firstly, we establish local existence for weak solutions; the aim of this part is to prove a crucial priori estimate on |∇u|. Then, we give appropriate conditions in order to have existence and uniqueness or nonexistence of a global solution in time. Finally, depending on the choices of the initial data, ranges of the coefficients and exponents and measure of the domain, we show that the non-negative global weak solution, when it exists, must extinct after a finite time.

Study on TSD Characteristics of LiF ( Mg , Cu , P ) Single Crystal (LiF ( Mg , Cu , P ) 단결정의 TSD 특성에 관한 연구)

  • 도시홍
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.26 no.1
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    • pp.8-13
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    • 1990
  • The microscopic relaxation parameters for the single crystal were measured by using thermally stimulated depolarization (TSD). Initial rise method, various heating rate method and total glow peak method were used for the determination of the activation energy and Debye relaxation time from TSD glow curves. Activation energy, pre-exponential factor and relaxation time for impurity-vacancy dipole reorientation were 0.55eV, 1.97$\times$10 super(-12) sec and 12.19sec in average, respectively. Dielectric dissipation factor for the crystal was calculated from the measured TSD glow curve, its value being about 3$\times$10 super(-2).

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Numerical Simulation of Ozone using UAM-V on Summer Episode in the Costal Urban Area, Busan (UAM-V를 이용한 부산지역 고농도 오존사례 수치모의)

  • 김유근;오인보;황미경
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.1
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    • pp.1-11
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    • 2003
  • Temporal and horizontal distributions of surface ozone concentrations covering the Busan metropolitan area were simulated by UAM -V (The Variable grid Urban Airshed Model) that was run with meteorological inputs taken from MM5 for ozone episode day (18 July 1999). UAM-V underestimated the daily maximum ozone con-centration about 14 ppb on average at all monitoring sites within Busan area comparing with observed value. but the correlation between observed and simulated values showed quite significant (R = 0.896, p< 0.01 on average). Higher concentrations of ozone occurred near the city center and industrial areas (western side of city) with high levels of anthropogenic source in the morning, and transport of ozone and its precursors by sea breeze developed in the afternoon contributed to elevated ozone levels in downwind rural areas. Particalarly in slightly downwind area of city center, the highest daily maximum ozone concentration ($\geq$120 ppb) was simulated by UAM-V at 1400 LST. Consequently, local environments including emission distributions and land -sea breeze circulation influenced ozone distributions in the Busan metropolitan area.

Consequence of Synthetic Bone Substitute Used for Alveolar Cleft Graft Reconstruction (Preliminary Clinical Study)

  • Rawaa Y. Al-Rawee;Bashar Abdul-Ghani Tawfeeq;Ahmed Mothafar Hamodat;Zaid Salim Tawfek
    • Archives of Plastic Surgery
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    • v.50 no.5
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    • pp.478-487
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    • 2023
  • Background The outcome of alveolar grafting with synthetic bone substitute (Osteon III) in various bone defect volumes is highlighted. Methods A prospective study was accomplished on 55 patients (6-13 years of age) with unilateral alveolar bone cleft. Osteon III, consisting of hydroxyapatite and tricalcium phosphate, is used to reconstruct the defect. Alveolus defect diameter was calculated before surgery (V1), after 3 months (V2), and finally after 6 months (V3) postsurgery. In the t-test, a significant difference and correlation between V1, V2, and V3 are stated. A p-value of 0.01 is considered a significant difference between parameters. Results The degree of cleft is divided into three categories: small (9 cases), medium (20 patients), and large (26 cases).The bone volume of the clefted site is divided into three steps: volume 1: (mean 18.1091 mm3); step 2: after 3 months, volume 2 resembles the amount of unhealed defect (mean 0.5109 mm3); and the final bone volume assessment is made after 6 months (22.5455 mm3). Both show statistically significant differences in bone volume formation. Conclusion An alloplastic bone substitute can also be used as a graft material because of its unlimited bone retrieval. Osteon III can be used to reconstruct the alveolar cleft smoothly and effectively.

Probabilistic Assessment of life Time for Gas Pipe Lines (통계적 방법을 통한 가스배관의 잔여수명 예측)

  • Choe, B.H.;Lee, S.H.;Kim, Y.P.;Kim, W.S.;Ko, Y.T.
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.234-239
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    • 2004
  • A study on the probabilistic methodology for the estimation of the remaining life of Pressurized pipelines containing active corrosion defects is presented. This reliability assessment is earned out using extream value distribution of the corroded defects instead of already published failure perssure moded like NG18 or ASME B31G. The failure probability of pipelines depends on the number of corroded defects. and it could be calculated directly as the area exceeded a defined L V(Limited Value of corrosion depth). The remaining life of pressurized pipelines can also be estimated by the PDF of extream value distribution as calculating the exceeded area with a defined failure probability.

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Characteristics of Wine Fermented from Mulberry Juice (오디 착즙액을 이용한 와인발효 특성)

  • Kim, Kang-Il;Kim, Mi-Lim
    • Food Science and Preservation
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    • v.17 no.4
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    • pp.563-570
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    • 2010
  • We sought to ferment wine from mulberry (Morus alba) juice. The soluble solid content was $9.5{\sim}14.5^{\circ}brix$ on day 6 of fermentation, and gradually fell later; sugar was not further consumed when $3^{\circ}brix$ was attained. Alcohol content rose dramatically on day 6 of fermentation, being 4.5% (v/v) at fermentation temperatures of 16C and 18C, 6.5% (v/v) at 20C, and 8.0% (v/v) at 25C, rising further to 10.5~11.5% (v/v) on day 48, at higher culture temperatures. Citric acid, malic acid, and oxalic acid were present in mulberries. The levels of both citric and oxalic acid fell after fermentation, whereas malic acid concentration increased. All of fructose, glucose, maltose, and sucrose were fermented. Electron-donating ability (EDA) was elevated to over 90% of the control value in mulberry juice diluted to 40% (v/v). SOD-like activities in juice and wine were 80.1% and 72.1% of the control value. Nitrite-scavenging abilities (NSAs) were 86.2% and 85.2% of control in undiluted juice and wine, respectively. Mulberry juice had an activation level higher than that of mulberry wine, but functionality neither rose nor fell after fermentation. Insensory evaluation, the overall wine score was better than average, at 5.00, demonstrating the commercial potential of mulberry wine.

Novel $Ca^{2+}$-ATPase Found in the Human Milk Membrane Fraction

  • Cho, Jin-Kook;Kanno, Choemon
    • 한국유가공학회:학술대회논문집
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    • 1997.05a
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    • pp.23-34
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    • 1997
  • Calcium-stimulated ATPase ($Ca^{2+}$-ATPase) which has optimal pH value at 7.0 was found in the membrane fraction of human milk, and its enzymatic properties were studied. The purified $Ca^{2+}$-ATPase required 0.45 mM Ca ion for maximal activity. Among the nucleosides, $Ca^{2+}$-ATPase showed a higher substrate specificity to ATP and UTP than to CTP and GTP. $Ca^{2+}$-ATPase had apparent Km value of 0.065, and V max of 7.63 mol ATP hydrolyzed/mg pro-tein per min, respectively. $Ca^{2+}$-ATPase was potently inhibited by lanthanide, vanadate, and p-chloromercuribenzoate, and inactivated by EDTA, and CDTA and EGTA, but were unaffected by N-ethylmaleimide, $NaN_3$, ouabain, or oligomycin, and was completely inactivated by heating at $60^{\circ}C$ for 10 min. This enzyme activity was concentrated in the membrane fraction of the cream and skim milk membrane, but not founded in bovine milk.

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Effect of scoparone on the hepatic sulfatransferase activity in mice

  • Huh, Keun;Park, Jong-Min;Shin, Uk-Seob;Lee, Sang-Il
    • Archives of Pharmacal Research
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    • v.13 no.1
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    • pp.51-54
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    • 1990
  • Effect of scoparone (6, 7-dimethoxycoumarin) on the hepatic cytosolic sulfotransferase activity was investigated. After treatment with scoparone, hepatic cytosolic sulfotransferase activity was increased with odse and time-dependent manner as compared to control. The $V_{max}$ value (control = 1.33 n moles/mg protein/min, scoparone = 2.39n moles/mg protein/min) without affecting the $K_m$ value for p-nitrophenol was increased by the scoparone treatment. Whereas, the hepatic cytosolic sulfotransferase was not changed by the addition of scoparone in vitro, and was strongly inhibited by the addition of metabolites of scoparone. The results obtained suggest that the characteristics of increase in the enzyme activity may include induction of enzyme proteins, and may be due to the metaboltes of scoparone.

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