• 제목/요약/키워드: P-S conversion

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온도에 따른 InZnP/ZnSe/ZnS (핵/다중껍질) 양자점의 형광 특성 변화 (The Effect of Temperature on the Photoluminescence Properties of the InZnP/ZnSe/ZnS (Core/Multishell) Quantum Dots)

  • 손민지;정현성;이윤기;구은회;방지원
    • 한국전기전자재료학회논문지
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    • 제31권7호
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    • pp.443-449
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    • 2018
  • We investigated the temperature-dependent photoluminescence spectroscopy of colloidal InZnP/ZnSe/ZnS (core/shell/shell) quantum dots with varying ZnSe and ZnS shell thickness in the 278~363 K temperature range. Temperature-dependent photoluminescence of the InZnP-based quantum dot samples reveal red-shifting of the photoluminescence peaks, thermal quenching of photoluminescence, and broadening of bandwidth with increasing temperature. The degree of band-gap shifting and line broadening as a function of temperature is affected little by shell composition and thickness. However, the thermal quenching of the photoluminescence is strongly dependent on the shell components. The irreversible photoluminescence quenching behavior is dominant for thin-shell-deposited InZnP quantum dots, whereas thick-shelled InZnP quantum dots exhibit superior thermal stability of the photoluminescence intensity.

Bioconversion of Aniline to Acetaminophen and Overproduction of Acetaminophen by Streptomyces spp.

  • Jin, Hyung-Jong;Park, Ae-Kyung;Lee, Sang-Sup
    • Archives of Pharmacal Research
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    • 제15권1호
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    • pp.41-47
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    • 1992
  • In order to obtain acetaminophen, a popular analgesic-antipyretic, though microbial p-hydroxylation and N-acetylation of aniline, various Streptomyces strains were screened. Aniline N-acetylation activity was rather ubiquitous but-hydroxylation activity was selective. Microbial conversion pathway of aniline to acetaminophen was considered to be through N-acetylation and p-hydroxylation or vice versa. However, depending on species used, o-hydroxylation and its degradation activity (S. fradiae) and acetaminophen degradation activity (S. coelicolar) were also detected. Among the screened Streptomyces strains, S fradiae NRRL 2702 showed the highest acetanilide p-hydroxylation activity (203% conversion rate). Furthermore, in S. fradiae carbon source and its concentration, phosphate ion concentration and pH of growth medium were found to play the crucial roles in p-hydroxylation activity. Through the proper combination of factors mentioned above, the ten times more activity (26-30% conversion rate) was attained.

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Degraded Paddy Soils. I. Theoretical Analysis on the Sultide Formation and the Effect of Iron Hydroxide Upon Removal of Sulfide from Solution

  • Cho, Chai-Moo
    • Applied Biological Chemistry
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    • 제2권
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    • pp.9-14
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    • 1961
  • The formation of sulfide from sulfate has been discussed from the thermodynamic principles. No mechanism of the reaction has been presented. From the stoichiometric and Nernst equations for the conversion of sulfate into sulfide, it was concluded that the formation of sulfide from sulfate can take place more readily if pH of a medium is low. The difficulty of this conversion increases with increasing pH. As pH of a medium increases, the degree of dissociation of H₂S into S= increases and this, in turn, renders the chance of precipitation of sulfide as FeS easier. Higher the pH of a soil or medium, greater is the S= concentration. The concentration of ferrous ion required to remove dissolved sulfide in a medium by forming insoluble FeS decreases with increasing pH. From the theory it was pointed out that an application of lime and iron rich foreign substances to a soil may be effective in causing the removal of dissolved sulfide from solution.

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Validation of a Model for Estimating Individual External Dose Based on Ambient Dose Equivalent and Life Patterns

  • Sato, Rina;Yoshimura, Kazuya;Sanada, Yukihisa;Sato, Tetsuro
    • Journal of Radiation Protection and Research
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    • 제47권2호
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    • pp.77-85
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    • 2022
  • Background: After the Fukushima Daiichi Nuclear Power Station (FDNPS) accident, a model was developed to estimate the external exposure doses for residents who were expected to return to their homes after evacuation orders were lifted. However, the model's accuracy and uncertainties in parameters used to estimate external doses have not been evaluated. Materials and Methods: The model estimates effective doses based on the integrated ambient dose equivalent (H*(10)) and life patterns, considering a dose reduction factor to estimate the indoor H*(10) and a conversion factor from H*(10) to the effective dose. Because personal dose equivalent (Hp(10)) has been reported to agree well with the effective dose after the FDNPS accident, this study validates the model's accuracy by comparing the estimated effective doses with Hp(10). The Hp(10) and life pattern data were collected for 36 adult participants who lived or worked near the FDNPS in 2019. Results and Discussion: The estimated effective doses correlated significantly with Hp(10); however, the estimated effective doses were lower than Hp(10) for indoor sites. A comparison with the measured indoor H*(10) showed that the estimated indoor H*(10) was not underestimated. However, the Hp(10) to H*(10) ratio indoors, which corresponds to the practical conversion factor from H*(10) to the effective dose, was significantly larger than the same ratio outdoors, meaning that the conversion factor of 0.6 is not appropriate for indoors due to the changes in irradiation geometry and gamma spectra. This could have led to a lower effective dose than Hp(10). Conclusion: The estimated effective doses correlated significantly with Hp(10), demonstrating the model's applicability for effective dose estimation. However, the lower value of the effective dose indoors could be because the conversion factor did not reflect the actual environment.

광원에 따른 조사거리의 증가가 복합레진의 중합도에 미치는 영향 (INFLUENCE OF TIP DISTANCE ON DEGREE OF CONVERSION OF COMPOSITE RESIN IN CURING WITH VARIOUS LIGHT SOURCES)

  • 김상배;박호원
    • 대한소아치과학회지
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    • 제31권2호
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    • pp.273-279
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    • 2004
  • 최근에 소개된 single high-intensity LED 중합기는 이전의 LED 중합기에 비해 높은 광도를 가지며 짧은 중합시간에 적절한 물성을 가질 수 있다고 한다. 본 연구는 single high-intensity LED 중합기의 중합성능을 평가하기 위하여 거리에 따른 중합도를 조사하였다. Mylar strip사이에 복합레진(Filtek Z250)을 넣고 압접시켜 만든 얇은 필름형 시편을 LED 중합기(Elipar Freelight 2, 10초), 플라스마 중합기(Flipo, 6초)와 할로겐 중합기 (XL3000, 20초)를 사용해 0mm, 2mm, 4mm, 6mm에서 광도를 측정하고 중합시켰다. 중합된 시편을 Fourier Transform Infrared Spectrometer(FTIR)를 이용해 중합도를 측정한 후 다음과 같은 결론을 얻었다. 1. 모든 중합기에서 거리가 증가할수록 유의하게 광도가 감소하였으며 LED중합기의 경우 6mm에서 다른 중합기에 비해 가장 많은 광도 감소율을 보였다(p<0.05). 2. 모든 중합기에서 거리가 증가함에 따라 4mm까지는 중합도가 감소하였지만 유의한 차이는 보이지 않았다(p>0.05). 하지만 4mm와 6mm사이에서는 모든 중합기에서 유의하게 감소하였다(p<0.05). 3. 각 거리에 따른 중합기간의 중합도 차이는 0mm, 2mm, 4 mm에서 LED중합기가 다른 중합기보다 유의하게 높은 중합도를 보였으며 (p<0.05) 플라스마 중합기와 할로겐 중합기 사이에서는 유의한 차이가 없었다. 하지만 6 mm에서는 모든 중합기 사이에 유의한 차이를 보이지 않았다(p>0.05).

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SOA 집적 XPM형 파장변환기 모듈 제작 및 특성 (Fabrication and characterization of XPM based wavelength converter module with monolithically integrated SOA's)

  • 김종회;김현수;심은덕;백용순;김강호;권오기;엄용성;윤호경;오광룡
    • 한국광학회지
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    • 제14권5호
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    • pp.509-514
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    • 2003
  • SOA(Semiconductor Optical Amplifier)를 단일 기판에 집적한 Mach-Zehnder 간섭계 구조의 파장변환기를 제작하여 40 nm 지역폭에 대한 10 Gb/s 파장변환 특성을 조사하였다. 제작된 파장변환기는 BRS(Buried Ridge Structure)형 SOA와 수동 도파로를 butt-joint결합하여 단일 집적한 구조이다. 집적화 과정에서 높은 도파 손실을 발생시키는 p+ InP덮개층을 제거하고 무첨가 InP로 도파로 덮개층 및 전류 차단층을 동시에 형성시키는 새로운 방법을 이용하였고, 모듈 제작에서 경사진 도파로와 광섬유를 효율적으로 광 접속하기 위하여 경사진 광섬유 배열을 제작하여 사용하였다. 이와 같이 제작된 파장변환기 모듈을 이용하여 1535-1575 nm의 40 nm 대역폭에서 1 ㏈ 이하의 power penalty를 갖는 10 Gb/s 파장변환을 구현하였고, 특히 negative penalty를 갖는 파장변환을 성공적으로 구현함으로써 2R(re-amplification, re-shaping) 기능을 제공할 수 있음을 보였다.

치자황색소로부터 변환된 색소의 특성 (Characteristics of the Conversion Pigment from Gardenia jasminoides Yellow Pigment)

  • 정형석;박근형
    • 한국식품과학회지
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    • 제30권2호
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    • pp.319-323
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    • 1998
  • 치자의 황색소를 L. plantalium, V. vulinficus, P. aeruginosa, S. mutans, B. subtilis, S. epidermidis, S. typhimurium, S. aureus 등 8종의 균주의 배지에 첨가하고 배양하면 청녹색계 색소로 변환된다. 미생물에 의해 변환된 색소의 분광학적 성질을 경시적으로 추적하면 색소의 변환형태는 3군으로 나뉘어지며, 색차계로 측정된 ${\Delta}E$ 값의 변환형태도 그러하였다. 청녹색계색소로의 변환속도는 균주에 따라 차이를 보였는데 8종의 미생물중 S. epidermidis는 가장 빨라 배양 16시간에 색소변환이 완성되었다. 치자황색소와 변환된색소는 $H_2O-MeOH$ 용매계에 의한 Amberlite XAD-4 column chromatography에 의해 완전히 분리되었으며, 광과 열에 대한 저장안정성은 치자황색소보다 변환된 색소가 보다 안정함을 나타냈다.

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n-CdS/p-InP 태양전지에 관한 연구 (A study on the n-CdS/p-InP solar cells)

  • 송복식;최영복;한성준;문동찬;김선태
    • E2M - 전기 전자와 첨단 소재
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    • 제8권4호
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    • pp.406-412
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    • 1995
  • A n-CdS thin films were evaporated by thermal evaporation method and their structure, optical transmission spectra and electrical characteristics were investigated. The photovoltaic characteristics of solar cells which were fabricated in optimum conditions measured. The evaporated CdS thin films showed in hexagonal structure and above 80% of optical transmission spectra regardless of impurity doping. The high quality thin films could be obtained at 150.deg. C temperature of substrate, which is useful for solar cell window layer with low resistivity of 6*10$\^$-2/(.ohm.-cm) by In doping We measured the electrical and optical characteristics of the n-CdS/p-InP heterojunction solar cells. The most efficient photovoltaic characteristics of heterojunction solar cells had the open circuit voltage of 0.66V, short circuit current density of 13.85mA/cm$\^$2/, fill factor of 0.576 and conversion efficiency of 8.78% under 60mW/cm$\^$2/ illumination.

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GEOUNED: A new conversion tool from CAD to Monte Carlo geometry

  • J.P. Catalan;P. Sauvan;J. Garcia;J. Alguacil;F. Ogando;J. Sanz
    • Nuclear Engineering and Technology
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    • 제56권6호
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    • pp.2404-2411
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    • 2024
  • The GEOUNED code is specifically designed to convert CAD models, defined using the B-rep approach, into MC radiation transport models, defined using the CSG approach, and vice versa from MC to CAD. This code incorporates standard features commonly found in conversion tools, including decomposition, conversion, and automatic void generation. Additionally, it introduces innovative features, mainly in the automatic void generation part, which are described in this article. GEOUNED has demonstrated successful application in highly detailed 3D models used in fusion neutronics, which are known for their complex geometries, particularly those utilized in ITER. The article includes examples showcasing GEOUNED's performance in these challenging models, as well as custom applications that highlight its flexibility in addressing non-standard problems. The code is open-source and utilizes Open CASCADE as the geometry engine, with FreeCAD serving as the Python API.

극저온냉동기 예냉 수소액화기의 기초설계 (Basic design of hydrogen liquefier precooled by cryogenic refirgerator)

  • 김승현;장호명;강병하
    • 설비공학논문집
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    • 제9권3호
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    • pp.389-400
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    • 1997
  • A thermodynamic cycle analysis is performed for refrigerator-precooled Linde-Hampson hydrogen liquefiers, including catalysts for the ortho-to-para(o-p) conversion. three different configurations of the liquefying system, depending upon the method of the o-p conversion, are selected for the analysis. After some simple and justifiable models are introduced, a general analysis program to predict the liquid yield and the figure of merit(FOM) is developed with incorporating the commercial computer code for the hydrogen properties. The discussion is focused on the effect of the two primary design parameters-the precooling temperature and the high pressrure of hydrogen. When the precooling temperature is in the range between 45 and 60 K, the optimal high pressure for the maximal liquid yield is found to be in the range between 100 to 140 bar, regardless of the o-p conversion. However, the FOM can be maximized at slightly smaller values of high pressures. It is remarkable to observe that the lower precooling temperatures are favorable since both the liquid yield and the FOM can be obtained without compressing hygrogen to extremely high pressures.

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