• Title/Summary/Keyword: P removal rate

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The Development of Estimation Model for Iron Compound Originated from Anaerobic Microbial Corrosion (혐기성 미생물부식에 의해 생성되는 철화합물 추정식 개발)

  • Jeon, Seok-Jun
    • Journal of Korean Society on Water Environment
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    • v.18 no.4
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    • pp.379-386
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    • 2002
  • In this study, estimation model for iron compound originated from upflow, anaerobic fixed bed reactor, which treats sewage domestic wastewater, was developed. The estimation model was formulated by a mathematical expression which was based on the mass balance. Below the HRT of 60 minute, sulfide concentration combining with iron $FeS_2$ is the highest because the maximum sulfate consumption rate $V_{maxS}$ and half-saturation constant of sulfate $K_{mS}$ exert an important effect on the estimation model as temperature was increased. But increment of $FeS_2$ concentration is weakened above the HRT of 60 minutes and represent the lowest value at the HRT of 108 minutes. It implies that liquid phase distribution ratio of sulfide ${\alpha}r$ becomes lower as temperature was increased. While phosphorus concentration combining with iron $Fe_3(PO_4)_3$ is increased as HRT and temperature are increased, which is affected by phosphorus removal rate constant $k_p$. As the result of estimating the iron concentrations of corrosion by the model, the concentration of iron corrosion is higher than any other at the HRT of 108 minute and $20^{\circ}C$. The predicted values were compared with measured ones at different HRT(13.5, 27, 54, 108 min) and temperature(20, 25, $30^{\circ}C$). The experimental data could be fitted with the simulated curves. Therefore, the mathematical expression could be applicable to design full-scale wastewater treatment plants.

A Study on Ozonation of 4-nonylphenol (4-nonylphenol의 오존산화 처리반응에 관한 연구)

  • Lee, Cheal-Gyu
    • Journal of Korean Society on Water Environment
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    • v.33 no.6
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    • pp.736-743
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    • 2017
  • In this study, 4-nonylphenol (4-NP), an endocrine disrupting chemical, was removed by ozone treatment processes under the various experimental conditions including UV irradiation, $TiO_2$ addition. The ozone flow rate and concentration were maintained at $1.0L{\cdot}min^{-1}$ and $70{\pm}5mg{\cdot}L^{-1}$. The pH, COD and TOC of the samples were obtained every 10 minutes for 60 minutes in laboratory scale batch reactor. We found that the combination of UV irradiation and $TiO_2$ addition for ozonation improves the removal efficiency of COD and TOC in 4-NP aqueous solution. In case of the $O_3/UV/TiO_2$ system, COD and TOC were greatly reduced to 85.3 ~ 94.0% and 89.2 ~ 97.2%, respectively. 4-NP degradation rate constants, $k_{COD}$ and $k_{TOC}$, were calculated based on the COD and TOC values. Significantly, $k_{COD}$ and $k_{TOC}$ were improved in the $O_3/UV/TiO_2$ treatment process compared with single $O_3$ process, because the oxidation and the mineralization of 4-NP were increased by generating of the hydroxyl radical. The $k_{COD}$ and $k_{TOC}$ were obtained to be $5.81{\times}10^{-4}{\sim}10.8{\times}10^{-4}sec^{-1}$ and $11.9{\times}10^{-4}{\sim}19.4{\times}10^{-4}sec^{-1}$ in the $O_3/UV/TiO_2$ process. Activation energy ($E_a$) of ozone oxidation reaction based on $k_{COD}$ and $k_{TOC}$ were increased in order of $O_3/UV/TiO_2$ < $O3/UV$ < $O_3/TiO_2$ < $O_3$ process. It was confirmed that the addition of $TiO_2$ and UV irradiation to the ozone oxidation reaction significantly reduced the $E_a$ value and the degradation of 4-NP.

Evaluation of Phosphorus Balance in Green Manure-Rice Cropping Systems with Different Incorporation Rate of Green Manure Crops (녹비작물 환원에 따른 벼 재배지 인산수지 평가)

  • Kim, TaeYoung;Daquiado, Aileen Rose;Alam, Faridul;Kim, Pil-Joo;Lee, YongBok
    • Korean Journal of Environmental Agriculture
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    • v.31 no.4
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    • pp.378-380
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    • 2012
  • BACKGROUND: In Korea, green manure has been cultivated for reducing chemical fertilizer application, maintaining soil fertility, and feeding livestock in winter season. We evaluated the phosphate balance under green manure-rice cultivating system with different removal rates of green manure for maintaining soil fertility. METHODS AND RESULTS: The barley and hairy vetch mixture was selected as the green manure in this study. The barley and hairy vetch was sowed at a rate of 135 and 23 kg/ha, respectively, without fertilizer application. Total aboveground biomass was 12000 (barley: 5400 kg/ha, hairy vetch: 6600 kg/ha) kg/ha, and these green manure were incorporated with different input rates before rice planting. The input rates of green manure in this study were 0 (NPK+0%), 25 (NPK+25%), 50 (NPK+50%), 75 (NPK+75%) and 100 % (NPK+100) and the standard fertilization (NPK) without green manure cultivation. All treatments were applied with standard fertilizer (N-P-K: 90-19.6-48.3 kg/ha) before rice planting. The highest rice yield was observed in NPK+50% which was 20% higher compared with NPK. The phosphate balance with different incorporation rates of green manure was-104.0,-76.8,-52.9,-27.4, and 6.0 kg/ha for NPK+0%, NPK+25%, NPK+50%, NPK+75%, and NPK+100%, respectively. CONCLUSION(S): The use of green manure for livestock feeding in green manure-rice cropping systems could remove a huge amount of phosphate. This cropping system strongly requires phosphate application before green manure seeding for maintaining soil fertility.

Predictors of Acute Postoperative Urinary Retention after Transvaginal Uterosacral Suspension Surgery

  • Son, Eun-Joo;Joo, Eunwook;Hwang, Woo Yeon;Kang, Mi Hyun;Choi, Hyun Jin;Yoo, Eun-Hee
    • Journal of Menopausal Medicine
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    • v.24 no.3
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    • pp.163-168
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    • 2018
  • Objectives: To investigate the rate of postoperative urinary retention (POUR) and identify the risk factors for this complication in women who underwent transvaginal uterosacral suspension surgery. Methods: A retrospective chart review was conducted for 75 women who underwent transvaginal uterosacral suspension surgery with vaginal hysterectomy, repair of cystocele, and levator myorrhaphy with/without transobturator anti-incontinence surgery. POUR was defined as a need for continuous intermittent catheterization on the third day subsequent to removal of the urethral indwelling catheter. Results: Acute POUR was reported in 18 women (24.0%). Thirty-six of the 75 patients (48.0%) had undergone anti-incontinence surgery. Crude analysis revealed significant association between the following variables and the risk of POUR: hypertension, the lower average flow rate in the pressure-flow study (PFS), greater post-void residual (PVR) urine volume in PFS, and PVR >30% of the total bladder capacity (TBC) in PFS. In the logistic regression analysis, PVR >30% of the TBC in PFS was identified as the only significant predictor of POUR (odds ratio, 15.4; 95% confidence interval, 2.5-90.9; P = 0.003). Conclusions: The PVR >30% of the TBC in PFS was identified as the only predictive factor of acute POUR in women who underwent transvaginal uterosacral suspension surgery.

Risk Assessment of Azoxystrobin Residues in Fresh Crown Daisy from Farm to Fork (생산단계에서 소비단계 생식 쑥갓의 azoxystrobin 잔류량에 따른 위해성 평가)

  • Sun-Woo Ban;A-Yeon Oh;Hee-Ra Chang
    • Korean Journal of Environmental Agriculture
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    • v.42 no.2
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    • pp.131-138
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    • 2023
  • The biological half-life and dissipation rate of azoxystrobin in crown daisy were calculated to establish the pre-harvest residue limits (PHRLs). The pesticide residues were calculated after washing with five different processes to propose an effective process in the household and conducted a risk assessment to confirm dietary safety. Azoxystrobin was sprayed according to the critical good agricultural practices (cGAP) in two different field trials, and the samples were harvested 7 times. The limit of quantitation was 0.02 mg/kg, and the mean recoveries of azoxystrobin were within the range of 70~120% with below 20% coefficient variation at the concentration of 0.02 and 0.2 mg/kg . The biological half-lives were 7.4 and 4.7 days, and the dissipation rate constants were 0.0872 and 0.1217 in fields 1 and 2, respectively. The average removal rates were 58.13~78.13% by the different washing processes, and there were significant differences between the washing processes (one-way ANOVA analysis and post-hoc Duncan test, p-value<0.05). The residues of azoxystrobin in crown daisy were safe levels from farm to fork after application with the critical good agricultural practice (cGAP) registered in Korea.

Enhancement of biogas production from swine slurry using the underground anaerobic digester (돈슬러리 지하혐기소화조의 바이오가스생산효율에 관한 연구)

  • Suresh, Arumuganainar;Choi, Hong Lim;Kim, Jae Hwan;Chung, In
    • Journal of the Korea Organic Resources Recycling Association
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    • v.17 no.4
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    • pp.112-121
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    • 2009
  • To obtain basic design criteria for underground anaerobic digestion and enhance biogas production from swine slurry, a $20m^3$ underground anaerobic digester (UGAD) was constructed and operated at mesophilic ($31{\sim}37^{\circ}C$) temperature with an organic loading rate (OLR) at $23.6kgVS/m^3/day$. The average biogas and $CH_4$ production rate were observed at 8.62 and $5.78m^3/day$, respectively. The mean percentile of $CH_4$ and $CO_2$ were also observed at 67.5% and 19.6%. The relative biogas yield was explored at $733L/kg\;VS_{added}$ and $CH_4$ yield was at $495L/kg\;VS_{added}$ respectively. The removal rate of biochemical constituents and pathogens were noticed considerably at 68%, 74%, 79%, 86%, 89%, 81%, 55%, 79%, 98% and 100% on TS, VS, TSS, $BOD_5$, $TCOD_{cr}$, $SCOD_{cr}$, $NH_3-N$, available P, fecal coliforms and Salmonella, respectively. This study suggested that, the modified UGAD system is a greatly desirable for anaerobic digestion for swine slurry with regards to high methane yield and biodegradability.

Design Parameters of Sequencing Batch Reactor treating ship sewage (연속 회분식 공정(SBR)을 이용한 선박 오 ${\cdot}$ 폐수처리 설계인자 도출)

  • Park, Sang-Ho;Kim, In-Soo
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • v.29 no.1
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    • pp.293-298
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    • 2005
  • Lab scale experimental study was carried out for SBR process, to investigate the effects of influent ship sewage organic compound removal and Bacillus sp. state on design parameters. This process was able to remove nitrogen and phosphorus as well as organic matter efficiently. More than 95% of chemical oxygen demand(COD) were removed. In addition, about 97% of total nitrogen (T-N) was reduced. The total phosphorus(T-P) reduction averaged 93%. The performance load of SBR process was shown to be 0.095kg ${\cdot}$ TOC/$m^{3}$ ${\cdot}$ day. The pH was decreased from 8.1 to 7.0 within 30 min and increased to 7.3 at the end of anoxic stage, and these phenomena were explained. The sluge produced in the SBR process is characterized by low generation rate (about 0.36kg ${\cdot}$ MLSS/kg ${\cdot}$ TOC) and excellent settleability. The number of Bacillus sp. in the SBR was 24.2%, indicating that Bacillus sp. was a predominant species in the reactor.

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Advanced Wastewater Treatment using Sequencing Batch Reactor on ship's sewage (연속 회분식 공정(SBR)을 이용한 선박 오·폐수의 고도처리)

  • Park Sang-Ho;Kim In-Soo
    • Journal of Navigation and Port Research
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    • v.29 no.5 s.101
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    • pp.475-480
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    • 2005
  • Lab scale experimental study was carried out for SBR process, to investigate the effects of influent ship sewage organic compound removal and Bacillus sp. state on design parameters. This process was able to remove nitrogen and phosphorus as well as organic matter efficiently. More than $92.0\%$ of chemical oxygen demand(COD) were removed. In addition, about $84.0\%$ of total nitrogen (T-N) was reduced. The total phosphorus(T-P) reduction averaged $93\%$. The performance load of SBR process was shown to be $0.095kg{\cdot}TOC/m3{\cdot}day$. The pH was decreased from 8.1 to 7.0 within 30 min and increased to 7.3 at the end of anoxic stage, and these phenomena were explained. The sludge produced in the SBR process is characterized by low generation rate (about $0.36kg{\cdot}MLSS/kg{\cdot}TOC$) and excellent settleability. The number of Bacillus sp. in the SBR was $24.2\%$, indicating that Bacillus sp. was a predominant species in the reactor.

Comparison of detergency effectiveness by the type of household washer, detergent and soil - Focused on detergency, rinsing, fabric damage and tanglement - (가정용 세탁기, 세제 및 오염의 종류별 세탁 성능 비교 - 세탁성, 헹굼성, 섬유손상도, 엉킴도를 중심으로 -)

  • Piao, Shujing;Park, Myung-Ja
    • The Research Journal of the Costume Culture
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    • v.21 no.6
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    • pp.950-960
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    • 2013
  • The purpose of this research is to provide accurate information of household washers and detergents for consumers, so that help the producers who make washing machine and detergent to get basic material and also help consumers to choose washing machine. Experiment was proceed with two type of washers to compare energy consumption, washing performance, rinsing effectiveness further, damage caused by entanglement of laundry and fabric was assessed. Detergent P and T were used to compare the performance related to differences of ingredients of detergent. Soiled fabrics of EMPA 108 set were used to evaluate performance of washing by different types of contamination. A summary of experimental results are : First, for the consumption of water, drum-type washer consumed 53% less than pulsator-type washer. On the other hand, the washing time was almost similar for both these machines, but pulsator-type washer showed shorter progress, implying that power saving was more efficient in this case. Second, the drum-type washer showed better performance for contamination with all types of detergent, but the pulsator-type washer showed better rinsing performance. Third, the drum-type washer performed less data of tangle level and fabric damage. Fourth, detergent "P" exhibited better washing performance than did detergent "T", regardless of the type of soil. And with no limit of detergent variety, water-soluble protein soil showed high removal rate, liposoluble soil especially pigment was hardly removed.

Sidestream Deammonification (반류수탈암모니아 공정)

  • Park, Younghyun;Kim, Jeongmi;Choi, Wonyoung;Yu, Jaecheul;Lee, Taeho
    • Journal of Korean Society on Water Environment
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    • v.34 no.1
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    • pp.109-120
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    • 2018
  • Sidestream in domestic wastewater treatment plants contains high concentration of ammonium, which increases nitrogen loading rate in the mainstream. The process for deammonification consisting of partial nitritation-anaerobic ammonium oxidation (ANAMMOX) and heterotrophic denitrification is an economical method of solving this problem. Currently, about 130 full-scale deammonification plants are fully operating around the world, but none is in Korea. In order to transfer the principal information about sidestream deammonification processes to researchers and operators, we summarized basic concepts, processes type, and key influence factors (e.g., concentration of nitrogen compounds, dissolved oxygen (DO), temperature, and pH). This review emphasis on the processes of single-stage sequencing batch reactor (SBR) deammonification, which are widely used as full-scale plants. Since simultaneous processes of partial nitritation, ANAMMOX and heterotrophic denitrification occur in a single reactor, the single-stage SBR deammonification requires appropriate control/monitoring strategies for several operating factors (DO and pH mostly) to achieve efficient and stable operation. In future, AB-process consisting of A-stage (energy harvesting from organics) and B-stage (ammonium removal without organics) will be applied to the wastewater treatment process. Thus, we suggest mainstream deammonification for B-stage connected with the sidestream deammonification as seeding source of ANAMMOX. We expect that many researchers will become more interested in the sidestream deammonification.