• Title/Summary/Keyword: P removal rate

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Composting and trickling filter for treatment of olive mill waste

  • Li, Xinhua;Lin, Ching-Chieh;Sweeney, Daniel;Earl, Jessica;Hong, Andy
    • Advances in environmental research
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    • v.2 no.2
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    • pp.131-141
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    • 2013
  • Agricultural practice and improper waste disposal in developing regions have resulted in environmental degradation in land and waters, for which low-cost, proven solutions are needed. We demonstrate in the laboratory the applications of composting and trickling filter techniques to treat olive mill wastes that can be implemented in the West Bank and other regions of the world. To a pomace waste sample from a California mill, we amended with saw dust (wood carbon source) and baking soda ($NaHCO_3$ alkalinity) at weight ratios of waste/wood/$NaHCO_3$ at 70:27:1 and composted it for periods of 11 and 48 days; the compost was used as an additive to potting soil for transplanting. The pomace sample was also blended into slurry and introduced to a water-circulating pond and trickling filter system (P/TF) to examine any inhibitive effect of the pomace on biological removal of the organic waste. The results showed the compost-amended potting soil supported plant growth without noticeable stress over 34 days and the P/TF system removed BOD and COD by >90% from the waste liquid within 2 days, with a first-order rate constant of 1.9 $d^{-1}$ in the pond. An onsite treatment design is proposed that promises implementation for agricultural waste disposal in developing regions.

Effects of Consumable on STI-CMP Process (STI-CMP 공정에서 Consumable의 영향)

  • 김상용;박성우;정소영;이우선;김창일;장의구;서용진
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.185-188
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    • 2001
  • Chemical mechanical polishing(CMP) process is widely used for global planarization of inter-metal dielectric (IMD) layer and inter-layer dielectric (ILD) for deep sub-micron technology. However, as the IMD and ILD layer gets thinner, defects such as micro-scratch lead to severe circuit failure, which affect yield. In this paper, for the improvement of CMP Process, deionized water (DIW) pressure, purified $N_2$ (P$N_2$) gas, slurry filter and high spray bar were installed. Our experimental results show that DIW pressure and P$N_2$ gas factors were not related with removal rate, but edge hot-spot of patterned wafer had a serious relation. Also, the filter installation in CMP polisher could reduce defects after CMP process, it is shown that slurry filter plays an important role in determining consumable pad lifetime. The filter lifetime is dominated by the defects. However, the slurry filter is impossible to prevent defect-causing particles perfectly. Thus, we suggest that it is necessary to install the high spray bar of de-ionized water (DIW) with high pressure, to overcome the weak-point of slurry filter. Finally, we could expect the improvements of throughput, yield and stability in the ULSI fabrication process.

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A Study on CMP Mechanism of $Bi_{3.25}La_{0.75}Ti_{3}O_{12}$ (BLT) Thin Films ($Bi_{3.25}La_{0.75}Ti_{3}O_{12}$ (BLT) 박막의 CMP 메커니즘 연구)

  • Shin, Sang-Hun;Ko, Pil-Ju;Kim, Nam-Hoon;Lee, Woo-Sun
    • Proceedings of the KIEE Conference
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    • 2006.07c
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    • pp.1450-1451
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    • 2006
  • In this paper, we first applied the chemical mechanical polishing (CMP) process to the planarization of ferroelectric film in order to obtain a good planarity of electrode/ferroelectric film interface. $Bi_{3.25}La_{0.75}Ti_{3}O_{12}$ (BLT) ferroelectric fan was fabricated by the sol-gel method. Removal rate and non-uniformity (WIWNU%) were examined by change of silica slurries pH(10.3, 11.3, 12.3). Surface roughness of BLT thin films before and after CMP process was inquired into by atomic force microscopy (AFM). Effects of silica slurries pH(10.3, 11.3, 12.3) were investigated on the CMP performance of BLT film by the surface analysis of X-ray photoelectron spectroscopy(XPS).

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Heavy Metals Immobilization in Soil with Plant-growth-promoting Rhizobacteria and Microbial Carbonate Precipitation in Support of Radish Growth

  • He, Jing;Zhang, Qiuzhuo;Achal, Varenyam
    • Microbiology and Biotechnology Letters
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    • v.48 no.2
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    • pp.223-229
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    • 2020
  • The application of plant-growth-promoting rhizobacteria (PGPR) supports the growth of plants in contaminated soil while ureolytic bacteria can immobilise heavy metals by carbonate precipitation. Thus, dual treatment with such bacteria may be beneficial for plant growth and bioremediation in contaminated soil. This study aimed to determine whether the PGPR Pseudomonas fluorescens could work in synergy with ureolytic bacteria to assist with the remediation of cadmium (Cd)- and lead (Pb)-contaminated soils. Pot experiments were conducted to grow radish plants in Cd- and Pb-contaminated soils treated with PGPR P. fluorescens and the results were compared with dual inoculation of P. fluorescens combined with ureolytic Staphylococcus epidermidis HJ2. The removal rate of the metals from the soil was more than 83% for Cd and Pb by the combined treatment compared to 17% by PGPR alone. Further, the dual treatment reduced the metal accumulation in the roots by more than 80%. The translocation factors for Cd and Pb in plant tissues in both treatments remained the same, suggesting that PGPR combined with the carbonate precipitation process does not hamper the transfer of essential metal ions into plant tissues from the soil.

Electrokinetic Remediation of Cobalt Contaminated Soil Using Ethanoic Buffer

  • Kim, Gye-Nam;Won, Hui-Jun;Oh, Won-Zin;Shim, Jun-Bo
    • Nuclear Engineering and Technology
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    • v.34 no.1
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    • pp.1-8
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    • 2002
  • After kaolin clay was artificially contaminated with Co$^{2+}$ ion, the remediation characteristics were analyzed by the electrokinetic method. Ethanoic buffer was injected in the soil column and $CH_3$COOH was continuously inputted to the cathode reservoir to restrain the pH increase. Since the pH of the cathode side of the soil column was 4.0 initially and increased to only 6.5 after remediation for 43.6 hours, precipitate, Co(OH)$_2$, was not formed in the column. The effluent rate increased with the passage of time and Co$^{2+}$ removal in the column at the initial time were mainly controlled by ion migration. 13.1% of the total amount of Co$^{2+}$ in the soil column was removed in 10 hours, 46.8% of the total Co$^{2+}$ in 20.8 hours, 71.7% of the total Co$^{2+}$ in 30.1 hours, and 94.6% of the total Co$^{2+}$ in 43.6 hours. Meanwhile, residual concentrations in the column calculated by the developed model were similar to those by experiment. experiment.

Membrane Degassing Process of Sweep Gas-vacuum Combination Type for Ammonia Removal (스윕 가스-진공 혼합식 탈기막 시스템을 활용한 암모니아 제거)

  • Yoon, Hongsik;Min, Taijin;Lee, Gunhee;Kim, Hyoung-Tak;Shin, Wanho
    • Journal of the Korean Society of Industry Convergence
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    • v.25 no.5
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    • pp.835-842
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    • 2022
  • In this study, the membrane degassing process of the sweep gas - vacuum combination type was proposed for ammonia wastewater treatment. The effect of pH, initial ammonia concentration and scale-up on ammonia degassing performance was investigated. As a result, as the pH and the initial ammonia concentration increased, the degassing permeate flux was improved. On the other hand, the ammonia mass transfer coefficient increased as the initial ammonia reduced, which seems to be due to the driving force of the sweep gas-vacuum combination type membrane degassing system proposed in this study. In addition, 80 mg NH3/min of the ammonia degassing rate was achieved using a 6×28 inch size module. Better degassing performance is expected if consideration for maintaining vacuum pressure is involved in the scale-up design.

Study on dispersion stability according to AMP content of CMP ceria slurry for semiconductor (반도체 CMP 용 세리아 슬러리의 AMP 함량에 따른 분산안정성에 관한 연구)

  • Sohee Hwang;JinA Lim;Woonjung Kim
    • Transactions on Semiconductor Engineering
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    • v.2 no.2
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    • pp.1-9
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    • 2024
  • CMP (Chemical Mechanical Polishing) processes have become essential for creating multilayered component structures in semiconductor manufacturing. Typically, the slurry composition in CMP processes involves a balance of three components such as ceria, dispersant, and deionized water. In this study, we conducted research on the stability of ceria slurries using an amphoteric surfactant with controlled concentrations of AMP (2-Amino-2-methyl-1-propanol). The results indicated pH stabilization influenced by carboxylic (-COOH) groups depending on the AMP concentration. Additionally, there was no occurrence of aggregation in the ceria slurry, confirming the absence of dispersion stability issues.

Determination of Optimum Operating Parameters for Enhanced Alkaline Hydrolysis of Soils Contaminated with TNT (TNT 오염토의 염기성 가수분해 효율 향상을 위한 최적 운전인자 도출)

  • Lee, Hwan;Choi, Jae-Heon;Lee, Cheol-Hyo;Kim, Ju-Yup
    • Journal of Soil and Groundwater Environment
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    • v.20 no.6
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    • pp.103-110
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    • 2015
  • Nitro-aromatic Compounds (NACs) of explosives are structurally non-degradable materials that have an adverse effect to humans and ecosystems in case of emissions in natural due to the strong toxicity. In this study, batch test in the laboratory-scale has been conducted to find some process parameters of alkaline hydrolysis by considering the characteristics of NACs which are unstable in a base status and field application evaluation have been performed on the batch test results. Based on the experimental results of both laboratory and pilot-scale test, the optimum conditions of parameters for the alkaline hydrolysis of soils contaminated with explosives were pH 12.5, above the solid-liquid ratio 1 : 3, above the room temperature and 30 minute reaction time. In these four process parameters, the most important influencing factor was pH, and the condition of above pH 12.0 was necessary for high contaminated soils (more than 60 mg/kg). In the case of above pH 12.5, the efficiency of alkaline hydrolysis was very high regardless of the concentrations of contaminated soils. At pH 11.5, the removal efficiency of TNT was increased from 76.5% to 97.5% when the temperature in reactor was elevated from room temperature to 80℃. This result shows that it is possible to operate the alkaline hydrolysis at even pH 11.5 due to increased reaction rate depending on temperature adjustment. The results found in above experiments will be able to be used in alkaline hydrolysis for process improvement considering the economy.

Fundamental Studies on the Wood Decay(II) - Physiological and Physicochemical Characteristics of the White Rot Fungi in Korea - (목재부후(木材腐朽)의 기초적(基礎的) 연구(硏究)(II) - 주요(主要) 백색부후균(白色腐朽菌)의 부후(腐朽) 생리(生理) 및 물리(物理)·화학적특성(化學的特性) -)

  • Lee, Dong-Heub;Choi, Don-Ha;Yoon, Seung-Lak;Sohn, Seung-Hyun
    • Journal of the Korean Wood Science and Technology
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    • v.20 no.4
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    • pp.49-56
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    • 1992
  • Seven white rot fungi (Irpex lactenis, Coriolus hirsutus, Lopharia mirabilis, Schizopora paradoxa, Ganoderma lucidum, Pleurotus ostreatus and Pycnoporus coccineus) native to Korea and two famous exotic lignin degradable white rot fungi (Coriolus versicolor and Phanerochaete chrysosporium) were investigated to clarify their physiological and physicochemical characteristics on white-rotted wood blocks. G. lucidum degraded wood blocks more seriously than those by exotic lignin-degrading fungi, C. versicolor and P. chrysosporium, but only slightly decreasecl the strength of wood which was compared to the weight loss, persumably on the account of its small use of cellulose when attacking wood. It is quite interesting to note that the holocellulose degradation rate of G. lucidum was also higher than any of the other tested fungi. The order of fungi, according to the lignin-decomposing rates, was G. lucidum>P. coccineus>C. versicolor>S. paradoxa>P. chrysosporium>L. mirabilis>P. ostreatus>C. hirsutus>I. lactenis. The lignin degradation of G. lucidum and P. coccineus which were collected in Korea was greater than that of C. versicolor and P. chrysosporium. If holocellulose degradation is not considered. G. lcidum has the merit of actual application in biomass conversion due to linin removal.

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Optimum Configuration Method and Livestock Wastewater Loding for Treating Livestock Wastewater in Constructed Wetlands by Natural Purification Method (자연정화공법에 의한 인공습지 축산폐수처리 시스템의 최적 조합방법 및 부하량)

  • Park, Jong-Hwan;Seo, Dong-Cheol;Kim, Ah-Reum;Kim, Sung-Hun;Lee, Seong-Tae;Jeong, Tae-Uk;Choi, Jeong-Ho;Kim, Hyun-Ook;Cho, Ju-Sik;Heo, Jong-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.2
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    • pp.278-284
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    • 2011
  • To obtain optimum configuration method and livestock wastewater loading in small-scale livestock wastewater apparatus by natural purification method for treating livestock wastewater, the small-scale livestock wastewater apparatuses were constructed with 9 kinds of combined systems such as aerobic bed (ae)-anaerobic bed (an), ae-ae, ae-anoxic bed (ox), an-an, an-ae, an-ox, ox-ae, ox-an and ox-ox livestock wastewater treatment apparatuses. Under different configuration methods, the removal rate of COD in Ae-Ae and Ae-An livestock wastewater treatment apparatus was higher than that in other configuration methods. The removal rate of T-N in Ae-An livestock wastewater treatment apparatus was higher than that in other configuration methods. Removal rates of SS and T-P were not different regardless of configureation methods in small-scale livestock wastewater treatment apparatus. Under different livestock wastewater loading, the removal rates of pollutants were higher in the order of $50L\;m^{-2}\;day^{-1}{\fallingdotseq}100L\;m^{-2}\;day^{-1}\;>\;200L\;m^{-2}\;day^{-1}$. Therefore, optimum configuration method was Ae-An livestock wastewater treatment apparatus, and optimum livestock wastewater loding was $100L\;m^{-2}\;day^{-1}$ in small-scale livestock wastewater treatment apparatus.