• 제목/요약/키워드: P polarity

검색결과 150건 처리시간 0.025초

고농축에멀션중합방법을 이용한 분리막제조와 선택적 흡수성 연구 (Preparation of Hydrophilic-Hydrophobic Composites by A Concentrated Emulsion Polymerization Method and Their Permselectivity to Mixture of Water-Ethanol)

  • 박준서
    • 공업화학
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    • 제8권1호
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    • pp.29-38
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    • 1997
  • 고농축에멀션중합방법을 이용하여 친수성-친유성 고분자복합소재를 합성하였다. w/o 형태의 고농축에멀션의 연속상은 styrene이며, 분산상은 수용성 acrylamide용액으로 분산상의 부피분율이 0.74 이상이다. 중합온도에서 에멀션의 안정성에 미치는 주요 요인들로는 친유성액체와 친수성액체의 물리화학적 특성인 극성, pH, 이온세기 및 계면활성제의 종류와 농도가 있다. 친유성액체와 친수성액체 사이의 계면장력이나 친수성액체와 계면활성제 수용액사이의 계면장력에 있어 계면장력의 값이 큰 경우는 높은 에멀션의 안정성을 나타낸다. 계면활성제의 HLB가 3.0~9.0 경우와 계면활성제의 농도가 CMC가 이상에서 에멀션이 높은 안정성을 나타낸다. 전자현미경을 이용한 조사에 의하며 복합재료는 분산상의 Poly acrylamide입자가 망상구조의 얇은 polystyrene필림에 의해 분리된 구조로 이루어져 있음을 보여주고 있다. 고농축에멀션에서부터합성된 고분자복합재료막은 물-에탄온 혼합물에서 물에 대해서 높은 선택성을 나타내었으며, 또 에탄올의 농도가 증가할수록 막의 선택도는 증가하였으나 투과속도는 감소함을 나타내었다.

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남한 중부지역에서 발생한 미소지진의 단층면해와 응력장 해석 (Analysis of Fault Plane Solution and Stress Field Using the Micro-ewarthquakes in the Central Region of South Korea)

  • 정태웅;이재구;이덕기;이은아;경재복
    • 한국지구과학회지
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    • 제22권4호
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    • pp.292-300
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    • 2001
  • 1997년 12월 이후 남한 중부지역에서 방생한 지진 중 13개 지진에 대하여, 지역에 따라 5개 그룹으로 구분하여 P 파 극성을 이용하여 구한 복합단층면해와 P, S파 극성 및 진폭비(SV/P, SH/P, SV/SH)를 이용하여 구한 결과를 비교 해석하였다. 지진원에서의 단층운동은 NNE-SSW와 WNW-ESE 방향의 단층면을 나타내며 주향이동 혹은 역단층성 주향이동운동이 우세하게 나타났다. 단층운동에 작용한 주압축응력방향은 ENE-WSW 방향, 혹은 NE-SW 방향을 나타내며, 이는 남한지역에 발생하는 주요 지진에 대하여 구해진 주압축 응력장 방향과 거의 일치한다.

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Overexpression of ginseng patatin-related phospholipase pPLAIIIβ alters the polarity of cell growth and decreases lignin content in Arabidopsis

  • Jang, Jin Hoon;Lee, Ok Ran
    • Journal of Ginseng Research
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    • 제44권2호
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    • pp.321-331
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    • 2020
  • Background: The patatin-related phospholipase AIII family (pPLAIIIs) genes alter cell elongation and cell wall composition in Arabidopsis and rice plant, suggesting diverse commercial purposes of the economically important medicinal ginseng plant. Herein, we show the functional characterization of a ginseng pPLAIII gene for the first time and discuss its potential applications. Methods: pPLAIIIs were identified from ginseng expressed sequence tag clones and further confirmed by search against ginseng database and polymerase chain reaction. A clone showing the highest homology with pPLAIIIβ was shown to be overexpressed in Arabidopsis using Agrobacterium. Quantitative polymerase chain reaction was performed to analyze ginseng pPLAIIIβ expression. Phenotypes were observed using a low-vacuum scanning electron microscope. Lignin was stained using phloroglucinol and quantified using acetyl bromide. Results: The PgpPLAIIIβ transcripts were observed in all organs of 2-year-old ginseng. Overexpression of ginseng pPLAIIIβ (PgpPLAIIIβ-OE) in Arabidopsis resulted in small and stunted plants. It shortened the trichomes and decreased trichome number, indicating defects in cell polarity. Furthermore, OE lines exhibited enlarged seeds with less number per silique. The YUCCA9 gene was downregulated in the OE lines, which is reported to be associated with lignification. Accordingly, lignin was stained less in the OE lines, and the expression of two transcription factors related to lignin biosynthesis was also decreased significantly. Conclusion: Overexpression of pPLAIIIβ retarded cell elongation in all the tested organs except seeds, which were longer and thicker than those of the controls. Shorter root length is related to auxinresponsive genes, and its stunted phenotype showed decreased lignin content.

불평등전장에서 $SF_6$ 기체의 뇌임펄스 절연파괴특성 (Characteristics of lightning impulse breakdowns in inhomogeneous $SF_6$ gas gap)

  • 이복희;최휘성;오성균;이봉
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2004년도 하계학술대회 논문집 C
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    • pp.1921-1923
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    • 2004
  • V-p characteristics and the discharge luminous characteristics in inhomogeneous $SF_6$ gas gap under the positive and negative lightning impulse voltages are presented. The test gap was composed of the plane-to-plane with a needle-shaped protrusion. The applied voltage and the predischarge current were measured by the electric field sensor and the shunt of 50 ${\Omega}$, respectively. The light emission signals were observed by a photomultiplier tube, and a high-speed camera. In a consequence, the dielectric strengths of $SF_6$ gas gap under positive lightning impulse voltages were independent of the gas pressure. In the presence of the positive polarity, the branches of discharge channel were created and the directions of the discharge paths were random. On the other hands, the discharge paths of the negative polarity were more thicker and brighter.

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Degradation of Ferroelectric Properties of Pt/PZT/Pt Capacitors in Hydrogen-containing Environment

  • Kim, Dong-Chun;Lee, Won-Jong
    • Transactions on Electrical and Electronic Materials
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    • 제6권5호
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    • pp.214-220
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    • 2005
  • The ferroelectric properties of the $Pt/PZT(Pb(Zr,Ti)O_3)/Pt$ capacitors are severely degraded when they are annealed in hydrogen-containing environment. Hydrogen atoms created by the catalytic reaction of Pt top electrode during annealing in hydrogen ambient penetrate into PZT films and generate oxygen vacancies by the reduction of the PZT films, which is likely to cause the degradation. The degree of hydrogen-induced degradation and the direction of voltage shift in P-E curves of the pre-poled PZT capacitors after annealing in hydrogen ambient is dependent on the polarity of the pre-poling voltage. This implies that oxygen vacancies causing hydrogen induced degradation are generated by hydrogen ions having a polarity. The degraded ferroelectricity of the PZT capacitors can be effectively recovered by the shift of oxygen vacancies toward the Pt top electrode interface during post-annealing in oxygen environment with applying negative unipolar stressing.

Studies on the Separation Performances of Chlorophenol Compounds from Water by Thin Film Composite Membranes

  • Yogesh, K.M. Popat;Ganguly, B.;Brahmbhatt, H.;Bhattacharya, A.
    • Macromolecular Research
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    • 제16권7호
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    • pp.590-595
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    • 2008
  • The pressure driven membrane process has been a breakthrough in the removal of pollutants from drinking water. These experiments examined the removal of chlorophenol compounds from water using low pressure membranes. The removal performance of the membranes was based primarily on size exclusion. Apart from size exclusion, the polarity and pKa of the compounds also influences the membrane performance. The molecular size and dipole moments of the respective molecules were calculated using a quantum chemical method. The rejection of pollutants also followed the same trend as salt rejection by the membranes.

샘플치 제어계의 팔스폭변조에 의한 최적제어특성 (The Optimum Control of the Sampled Data System by the Method of Pulse-Modulated Signal)

  • 양흥석;김경기
    • 전기의세계
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    • 제20권1호
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    • pp.9-18
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    • 1971
  • The characteristics of optimum control for the second order P.W.M. sampled-data system with linear plants are investigated, with the development of method for finding the cannonical represetations for the initial states, as well as the optimality of modulator output for the P.W.M. system, which contains the electro-mechanical components, by dividing the phase plane into several regions, in which the position of the system in the phase plane are converted into the pulse polarity and pulse width.

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Determination of Microviscosity and Location of 1,3-Di(1-pyrenyl) propane in Brain Membranes

  • Kang, Jung-Sook;Kang, In-Goo;Yun, Il
    • Archives of Pharmacal Research
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    • 제20권1호
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    • pp.1-6
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    • 1997
  • We determined the microviscosity of synaptosomal plasma membrane vesicles (SPMV) isolated from bovine cerebral cortex and liposomes of total lipids (SPMTL) and phospholipids (SPMPL) extracted from SPMV. Changes in the microviscosity induced by the range and rate of lateral diffusion were measured by the intramolecular excimerization of 1, 3-di(1-pyrenyl)propane (Py-3-Py). The microviscosity values of the direct probe environment in SPMV, SPMTL and SPMPL were 38.17, 31.11 and 27.64 cP, respectively, at$37^{\circ}C$and the activation energies $(E_a)$ of the excimer formation of Py-3-Py in SPMV, SPMTL and SPMPL were 8.236, 7.448 amd 7.025 kcal/mol, respectively. Probe location was measured by polarity and polarizability parameters of the probe Py-3-Py and probe analogues, pyrene, 1-pyrenenonanol and 1-pyrenemethyl-3${\beta}$-hydroxy-22, 23-bisnor-5-cholenate (PMC), incorporated into membranes or solubilized in reference solvents. There existed a good linear relationship between the first absorption peak of the $^1_a$ band and the polarizability parameter $(n^{2}-1)/(2n^{2}+1)$.The calculated refractive index values for SPMV, SPMTL and SPMPL were close to 1.50, which is higher than that of liquid paraffin (n=l.475). The probe location was also determined by using a polarity parameter $(f-1/2f^{I})$. Here f=$({\varepsilon}-1)/(2{\varepsilon}+1)$ is the dielectric constant function and $f^I=(n^2-1)/(2n^2+1)$ is the refractive index function. A correlation existed between the monomer fluorescence intensity ratio and the solvent polarity parameter. The probes incorporated in SPMV, SPMTL, and SPMPL report a polarity value close to that of 1-hexanol $({\varepsilon}=13.29)$. In conclusion, Py-3-Py is located completely inside the membrane, not in the very hydrophobic core, but displaced toward the polar head groups of phospholipid molecules, e.g., central methylene region of aliphatic chains of phospholipid molecules.

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SF6 압력에 따른 결함별 부분 방전 펄스의 분포 분석 (Analysis on PD Pulse Distribution by Defects Depending on SF6 Pressure)

  • 김선재;조향은;정기우;길경석;김성욱
    • 한국전기전자재료학회논문지
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    • 제28권1호
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    • pp.40-45
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    • 2015
  • Electrode systems: a protrusion on conductor (POC), a protrusion on enclosure (POE), a crack in epoxy plate and a free particle (FP) were fabricated to simulate insulation defects in a gas insulated switchgear (GIS). $SF_6$ gas was filled in the electrode systems by 3 bar and/or 5 bar, respectively. Partial discharge (PD) pulses were detected through a $50{\Omega}$ non-inductive resistor. A calibration test was carried out according to IEC 60270, and the sensitivity was 0.25 pC/mV. PD pulses were distributed in the phase of $50^{\circ}{\sim}135^{\circ}$ and over 95% of them existed in the phase of $55^{\circ}{\sim}120^{\circ}$ for the POC. PD pulses were distributed in the phase of $230^{\circ}{\sim}310^{\circ}$ and over 90% of them existed in phase of $220^{\circ}{\sim}300^{\circ}$ for the POE. PD pulses occurred in the phase of $40^{\circ}{\sim}60^{\circ}$ and $220^{\circ}{\sim}300^{\circ}$ for the crack, and pulse counts were 25% higher in negative polarity than in positive polarity. PD pulses were distributed in every phase unlike to other three electrode systems and the peak magnitude was measured at $118^{\circ}$ and $260^{\circ}$ for the FP. As described above, PD pulses were observed in positive polarity for the POC, in negative one for the POE, in both one for the crack and the FP. In conclusion, it is expected that the identification rate of defect type can be improved by considering the polarity ratio of PD pulses on the PRPDA method.