• Title/Summary/Keyword: Ozone trends

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SPATIAL TRENDS AND SPATIAL EXTREMES IN SOUTH KOREAN OZONE

  • Yun, Seok-Hoon;Richard L. Smith
    • Journal of the Korean Statistical Society
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    • v.32 no.4
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    • pp.313-335
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    • 2003
  • Hourly ozone data are available for 73 stations in South Korea from January, 1988 to August, 1998. We are interested in detecting trends in both the mean levels and the extremes of ozone, and in determining how these trends vary over the country. The latter aspect means that we also have to understand the spatial dependence of ozone. In this connection, therefore, we examine in this paper the following features: determining trends in mean ozone levels at individual stations and combination across stations; determining trends in extreme ozone levels at individual stations and combination across stations; spatial modeling of trends in mean and extreme ozone levels.

Surface Ozone in The Major Cities of Korea : Trends, Diurnal and Seasonal Variations, and Horizontal Distributions (한반도 주요 대도시지역의 지표오존 특성 : 추세, 일변화, 월변화, 수평분포)

  • 오인보;김유근
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.4
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    • pp.253-264
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    • 2002
  • Surface ozone concentrations measured at 40 monitoring sites in three major cities (Seoul, Busan, and Daegu) of Korea during 1993~2000 were analyzed to understand the characteristics of temporal and spatial distributions. Trends were analyzed for annual mean, 95th percentiles of daily 8-hour maximum and days exceeding 8-h ozone standard of 60 ppb. Three indicators exhibited increasing trends (+0.75 ppb yr$^{-1}$ , +2.20 ppb yr$_{-1}$ , and +5.35 days yr$_{-1}$ on average) throughout the study period at all cities. Diurnal and seasonal variations were the largest in Seoul followed by Daegue and Busan, due to the high photochemical production and titration of ozone (Seoul), strong wind and constant supply of background ozone from the ocean (Busan). In the urban centers and industrial areas at all cities, scavenging of ozone by NO reduces the daily 8-hour maximum ozone by 10 ppb on average. High concentrations of ozone have frequently occurred in downwind eastern (Seoul and Daegu) or northern (Busan) sides of the territory. In particular, the coastal area of Busan had relatively high ozone level due to the local sea land breeze circulation. The results indicated that the temporal and spatial variations of ozone concentration were non -uniform and were closely related to the local environments; emission levels, climates, and geographic locations.

Temporal Trends and Spatial Comparisons of Ozone Concentrations in Jinju (진주시 오존농도의 시간적 추이와 공간적 비교)

  • Park, Jeong-Ho
    • Journal of Environmental Science International
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    • v.19 no.6
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    • pp.761-769
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    • 2010
  • Temporal trends of ozone concentration in Jinju were investigated by using observation data from 3 air quality monitoring stations for the period of 2004~2008. In addition, spatial comparisons of ozone concentration at Jeoguri, upwind and downwind directions of Jinju were investigated between May and September 2009. Annual mean exhibited increasing trends +1.7ppb/yr throughout the study period. In the case of diurnal variation, the lowest ozone concentration was shown from 7 am to 8 am and the highest around 4 pm. The ozone concentrations of Jeoguri station of the south coast were higher than Jinju. In particular, the upwind direction of Jinju had relatively hight ozone concentration

Meteorologically Adjusted Ozone Trends in the Seoul and Susan Metropolitan Areas (서울과 부산지역 기상의 영향을 제거한 오존농도 추세)

  • 김유근;오인보;황미경
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.5
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    • pp.561-568
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    • 2003
  • Surface ozone concentrations are highly sensitive to meteorological variability. Therefore, in order to reveal the long-term changes in ozone due to the changes in precursor emissions, we need to remove the effects of meteorological fluctuations on the annual distribution of surface ozone. In this paper, the meteorologically adjusted trends of daily maximum surface ozone concentrations in two major Korean cities (Seoul and Busan) are investigated based on ozone data from 11 (Seoul) and 6 (Busan) sites over the period 1992 ∼ 2000. The original time series consisting of the logarithm of daily maximum ozone concentrations are splitted into long-term, seasonal and short-term component using Kolmogorov-Zurbenko (KZ) filter. Meteorological effects are removed from filtered ozone series using multiple linear regression based on meteorologcial variables. The long-term evolution of ozone forming capability due to changes in precursor emission can be obtained applying the KZ filter to the residuals of the regression. The results indicated that meteorologically adjusted long-term daily maximum ozone concentrations had a significant upward trend (Seoul: + 3.02% yr$^{-1}$ , Busan: + 3.45% yr$^{-1}$ ). These changes of meteorologically adjusted ozone concentrations represent the effects of changing background ozone concentrations as well as the more localized changes in emissions.

The Long Term Trends of Tropospheric Ozone in Major Regions in Korea

  • Shin, Hye Jung;Park, Ji Hoon;Park, Jong Sung;Song, In Ho;Park, Seung Myung;Roh, Soon A;Son, Jung Seok;Hong, You Deog
    • Asian Journal of Atmospheric Environment
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    • v.11 no.4
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    • pp.235-253
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    • 2017
  • This study was conducted for analyzing the contribution factors on ozone concentrations and its long term trends in each major city and province in Korea through several statistical methods such as simple linear regression, generalized linear model, KZ-filer, correlation matrix, Kringing method, and cluster analysis. The overall ozone levels in South Korea have been consistently increasing over the past 10 years. The ozone concentrations in Seoul, the biggest city in Korea, are the lowest in all areas with the highest increasing ratio for $95^{th}%$ ozone. It is thought that the active photochemical reaction could affect the higher ozone concentration increase. On the other hand, the ozone concentrations in Jeju are the highest in Korea with the highest increasing ratio for $5^{th}%$, $33^{th}%$, and $50^{th}%$ ozone. It is also thought that the weak $NO_x$ titration could be the reason of higher ozone concentrations in Jeju. In case of Jeju, transport related factors is the major factor affecting the ozone trend. Thus, it is assumed that the variation of ozone trend of Asian region affecting the ozone trend in Jeju, where domestic ozone photochemical reaction is less active than urban area. It is thought that the photochemical reaction plays the role of increasing of ozone concentrations in the urban area, even though the LRT affected on the increase of ozone concentrations in non-urban area.

Temporal and Spatial Variability of the TOMS Total Ozone; Global Trends and Profiles (TOMS 오존전량의 시공간 변동; 전구적인 추세 및 연직 분포)

  • Yoo Jung-Moon;Jeong Eun-Joo
    • Journal of the Korean earth science society
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    • v.26 no.3
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    • pp.199-217
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    • 2005
  • Using monthly total ozone data obtained from a Total Ozone Mapping Spectrometer (TOMS) onboard the Nimbus-7 and Earth Probe satellite, this study examined the trend in the total amount of global ozone during two periods: from 1979-1992 [Early period] and 1997-2002 [Latter period]. The Annual average of total ozone during the Early period was globally reduced by about 10 DU compared to the amount during the Latter, except in some areas between the equator and 20 N. Global trends of total ozone showed a decrease of -6.30 DU/decade during 1979-1992, and an increase of 0.12 DU/decade during 1997-2002. Its enhancement during the Latter period was especially noticeable in tropical areas. The EOF analyses of total ozone from this period indicated signs of temporal/spatial variability, associated with the phenomena of Quasi-Biennial Oscillation (QBO), Quasi-Triennial Oscillation (QTO), El Nino Southern Oscillation (ENSO), and volcanic eruption. Seasonal profiles of tropospheric ozone in the tropics obtained from ozonesondes, showed the spatial pattern of zonal wavenumber one. Overall, this study may be useful in analyzing possible causes in the variations of statospheric and tropospheric ozone.

Trend Analysis for Stratospheric Ozone Concentration in the Middle Latitude Northern Hemisphere Using HALOE Data (HALOE 자료를 이용한 중위도 지역의 오존농도 추이분석)

  • Ka, Soo-Hyun;Kwon, Mi-Ra;Oh, Jung-Jin
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.4
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    • pp.413-422
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    • 2005
  • The ozone concentration measured by HALOE (Ver 19) from Oct. 1991 to Dec. 2003 is used for analyzing the variation of ozone concentration. The HALOE loaded in UARS is observing several gases in the atmosphere, from 10km to 80km. Fourier analysis of these data in the middle latitude northern hemisphere is reported in this paper. To detect any possible long term trends, the fourier transformed time series was back transformed after removing signals with time periods of less than 6 months. Although the results clearly show the strong annual cycle, it is difficult to show any long term trends from the fourier series. We also compared the ozone volume mixing ratio's from HALOE with that from the ground-based radiometry to evaluate the accuracy of microwave observation at Sookmyung Women's University.

The Variations of Stratospheric Ozone over the Korean Peninsula 1985~2009 (한반도 상공의 오존층 변화 1985~2009)

  • Park, Sang Seo;Kim, Jhoon;Cho, Nayeong;Lee, Yun Gon;Cho, Hi Ku
    • Atmosphere
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    • v.21 no.4
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    • pp.349-359
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    • 2011
  • The climatology in stratospheric ozone over the Korean Peninsula, presented in previous studies (e.g., Cho et al., 2003; Kim et al., 2005), is updated by using daily and monthly data from satellite and ground-based data through December 2009. In addition, long-term satellite data [Total Ozone Mapping Spectrometer (TOMS), Ozone Monitoring Instrument (OMI), 1979~2009] have been also analyzed in order to deduce the spatial distributions and temporal variations of the global total ozone. The global average of total ozone (1979~2009) is 298 DU which shows a minimum of about 244 DU in equatorial latitudes and increases poleward in both hemispheres to a maximum of about 391 DU in Okhotsk region. The recent period, from 2006 to 2009, shows reduction in total ozone by 6% relative to the values for the pre-1980s (1979~1982). The long-term trends were estimated by using a multiple linear regression model (e.g., WMO, 1999; Cho et al., 2003) including explanatory variables for the seasonal variation, Quasi-Biennial Oscillation (QBO) and solar cycle over three different time intervals: a whole interval from 1979 to 2009, the former interval from 1979 to 1992, and the later interval from 1993 to 2009 with a turnaround point of deep minimum in 1993 is related to the effect of Mt. Pinatubo eruption. The global trend shows -0.93% $decade^{-1}$ for the whole interval, whereas the former and the later interval trends amount to -2.59% $decade^{-1}$ and +0.95% $decade^{-1}$, respectively. Therefore, the long-term total ozone variations indicate that there are positive trends showing a recovery sign of the ozone layer in both North/South hemispheres since around 1993. Annual mean total ozone (1985~2009) is distributed from 298 DU for Jeju ($33.52^{\circ}N$) to 352 DU for Unggi ($42.32^{\circ}N$) in almost zonally symmetric pattern over the Korean Peninsula, with the latitudinal gradient of 6 DU $degree^{-1}$. It is apparent that seasonal variability of total ozone increases from Jeju toward Unggi. The annual mean total ozone for Seoul shows 323 DU, with the maximum of 359 DU in March and the minimum of 291 DU in October. It is found that the day to day variability in total ozone exhibits annual mean of 5.7% in increase and -5.2% in decrease. The variability as large as 38.4% in increase and 30.3% in decrease has been observed, respectively. The long-term trend analysis (e.g., WMO, 1999) of monthly total ozone data (1985~2009) merged by satellite and ground-based measurements over the Korean Peninsula shows increase of 1.27% $decade^{-1}$ to 0.80% $decade^{-1}$ from Jeju to Unggi, respectively, showing systematic decrease of the trend magnitude with latitude. This study also presents a new analysis of ozone density and trends in the vertical distribution of ozone for Seoul with data up to the end of 2009. The mean vertical distributions of ozone show that the maximum value of the ozone density is 16.5 DU $km^{-1}$ in the middle stratospheric layer between 24 km and 28 km. About 90.0% and 71.5% of total ozone are found in the troposphere and in the stratosphere between 15 and 33 km, respectively. The trend analysis reconfirms the previous results of significant positive ozone trend, of up to 5% $decade^{-1}$, in the troposphere and the lower stratosphere (0~24 km), with negative trend, of up to -5% $decade^{-1}$, in the stratosphere (24~38 km). In addition, the Umkehr data show a positive trend of about 3% $decade^{-1}$ in the upper stratosphere (38~48 km).

A Simulation of High Ozone Episode in Downwind Area of Seoul Metropolitan Using CMAQ Model (CMAQ을 이용한 수도권 풍하지역의 고농도 오존 현상 모사)

  • Lee, Chong Bum;Song, Eun Young
    • Journal of Environmental Impact Assessment
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    • v.15 no.3
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    • pp.193-206
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    • 2006
  • Recently, high ozone episode occurred frequently in Korea. Moreover ozone episode occurred not only in the city but also in background area where local anthropogenic sources are not important. It analyzed frequency exceeding 100ppb ozone at air quality monitoring stations in Seoul and rural area during 1995-2004. This paper reports on the use of the Community Multiscale Air Quality (CMAQ) modelling system to predict hourly ozone levels. Domain resolutions of 30km, 10km, 3.333km (innermost) have been employed for this study. Summer periods in June 2004 have been simulated and the predicted results have been compared to data for metropolitan and rural air quality monitoring stations. The model performance has been evaluated with measured data through a range of statistical measures. Although, the CMAQ model reproduces the ozone temporal spatial trends it was not able to simulate the peak magnitudes consistently.

Characterization of Ozone Distributions in Pohang: Measurement Data during 2002~2006 (포항지역 오존농도의 분포 특성: 2002~2006년 측정자료)

  • Lim, Ho-Jin;Lee, Yong-Jik
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.1
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    • pp.50-62
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    • 2011
  • Temporal trends and spatial distributions of ozone concentrations in Pohang were investigated using data measured at 4 air quality monitoring stations (i.e., Daedo, Jukdo, Jangheung, and Desong) during 2002-2006. The monthly mean ozone concentrations were highest during April and June and decreased during July and August, which follows the typical trend in the Northeast Asia region. The high springtime ozone concentration might have been strongly influenced by the enhanced photochemical ozone production of accumulated precursors during the winter under increased solar radiations. In July and August, ozone levels were decreased by frequent and severe precipitation that caused lower mean monthly solar radiation and efficient wash-out of ozone precursors. This suggests that precipitation is extremely beneficial in the aspect of ozone pollution control. High ozone concentrations exceeding 80ppb dominantly occurred in May and June during the late afternoon between 16:00~17:00. Ozone concentrations were higher in Jangheung and Daesong relative to Daedo and Jukdo, whereas total oxidants $(O_3+NO_2)$ were higher in Jangheung and Daedo. In the suburban area of Daesong, ozone concentrations seem to be considerably higher than those in urban sites of Daedo and Jukdo due to lower ozone loss by NO titration with lower local NO level.