• 제목/요약/키워드: Ozone effect

검색결과 508건 처리시간 0.023초

HCFC-22 대체냉매의 모세관 선정 (Selection of Capillary Tubes for HCFC-22 Alternative Fluids)

  • 정동수;김종보
    • 설비공학논문집
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    • 제7권3호
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    • pp.435-449
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    • 1995
  • In this paper, pressure drop through a capillary tube is modeled to determine the length of a capillary tube for a given set of conditions. HCFC-22 and its alternatives, HFC-134a, R407B, and R410A are used as working fluids. The conditions on which the model is tested are as follows : condensing temperature; 40.0, 45.0, 50.0, $55.0^{\circ}C$, degree of subcooling;0.0, 2.5, $5.0^{\circ}C$, capillary tube exit condition;choked flow, capillary tube diameter;1.2~2.4mm, mass flow rate;5.0~50.0g/sec. The results justify the use of Stoecker's model which yields the results very close to the values in ASHRAE handbook. While McAdams' method yields much better results than Duckler's in calculating the viscosity of the fluid in 2-phase, the friction factor suggested by Stoecker seems to be the best for capillary tubes of large diameter used in residential air conditioners. For each refrigerant, 372 data with various variables are calculated by the model. The results show that capillary tube length varies very uniformly with changes in condensing temperature and degree of subcooling. Based on this fact, regression analysis is performed to determine the dependence of mass flow rate on the length and diameter of a capillary tube, condensing temperature, and degree of subcooling. Thus determined correlation yields a mean deviation of 2.36% for 1,488 data, showing an excellent agreement.

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초기 톨루엔 농도가 톨루엔- NOx-공기 혼합물의 광산화 반응에 미치는 영향 - II. 입자상 물질의 생성 및 성장 (Effect of Initial Toluene Concentration on the Photooxidation of Toluene-NOx-Air Mixture -II. Aerosol Formation and Growth)

  • 이영미;배귀남;이승복;김민철;문길주
    • 한국대기환경학회지
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    • 제21권1호
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    • pp.27-38
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    • 2005
  • An experimental investigation of the gas-phase photooxidation of toluene-NO$_{x}$-air mixtures at sub-ppm concentrations has been carried out in a 6.9 ㎥, indoor smog chamber irradiated by blacklights. Measured parameters in the toluene-NO$_{x}$ experiments included aerosol, $O_3$, NO, NO$_2$, NO$_{x}$ CO, SO$_2$ toluene, and air temperature. The initial toluene concentration ranged from 225 ppb to 991 ppb and the initial concentration ratio of toluene/NO$_{x}$ in ppbC/ppb was in the range of 5~20. It was found that the variation of aerosol number concentration with irradiation time caused by the photooxidation of toluene-NO$_{x}$-air mixtures depended on the initial toluene concentration for similar concentration ratio of toluene/NO$_{x}$. The dependency of initial toluene concentration on the photooxidation of toluene-NO$_{x}$-air mixtures for toluene/NO$_{x}$= 5~6 seemed to be opposite to that for toluene/NO$_{x}$=10~11. The maximum number concentration of aerosols formed by photooxidation and the aerosol yield depended on both initial toluene concentration and initial concentration ratio of toluene/NO$_{x}$. In this study, the aerosol yield, defined as aerosol formed per unit toluene consumed, was found to be 0.01~0.16.und to be 0.01~0.16.

이산화티탄 광촉매 졸(sol)의 실내환경 코팅에 의한 실내공기질 개선 (Improvement of Indoor Air Quality by Coating of Indoor Materials of $TiO_2$ Photocatalyst Sol)

  • 양원호;김대원;정문호;양진섭;박기선
    • 한국환경보건학회지
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    • 제30권2호
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    • pp.92-97
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    • 2004
  • Three methods for VOCs emissions control in indoor air are reduction at the source, ventilation between indoor and outdoor, and removal. The best alternative should be to replace highly emitting sources with sources having low emissions, but the pertinent information on VOCs is not always available from manufactures. Other ways of improving indoor air quality are needed. It is to increase the outside fresh-air flow to dilute the pollutants, but this method would generally provide only a dilution effect without destruction in residence. An ideal alternative to existing technologies would be a chemical oxidation process able to treat large volumes of slightly contaminated air at normal temperature without additional oxidant such as ozone generator and ion generator. Photocatalytic oxidation(PCO) represents such a process. It is characterized by a surface reaction assisted by light radiation inducing the formation of superoxide, hydroperoxide anions, or hydroxyl radicals, which are powerful oxidants. In comparison with other VOCs removal methods, PCO offers several advantages. The purpose of this study was to explore the possibilities for photocatalytic purification of slightly contaminated indoor air by using visible light such as flurescent visible light(FVL). In this study, a PCO of relatively concentrated benzene using common FVL lamps was investigated as batch type and total volatile organic compounds(TVOCs) using a common FVL lamp and penetrated sun light over window. The results of this study shown the possibility of TiO$_2$ photocatalyst application in the area of indoor air quality control.

ISO 9000과 ISO 14000의 효율적인 통합방안에 관한 연구-건설업체 문서체계를 중심으로 (A Study on the Efficient Integration Program between ISO 9000 and ISO 14000)

  • 이재훈;강창욱
    • 산업경영시스템학회지
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    • 제20권43호
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    • pp.211-218
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    • 1997
  • Since Industrial Revolution, the sudden industrialization and population explosion have brought about a serious environmental pollution on the air of the earth, the quality of water and the soil, and the greenhouse effect by the destruction of the ozone layer and the greenhouse gas, the organism diversity decline, the desertification by the ruining of woods and the overall global environmental pollution such as the contamination of the ocean and rivers have been come to the front. So the new recognition on the environment is being spreaded in construction business and the efforts for certification acquisition of ISO 14000 being followed by ISO 9000 are progressing, Accordingly, with an example of H Company where integration system is built so that it can minimize the efforts and cost at the construction of the management system, operation and management after the fact, this paper shall suggest the practical scheme of 3 steps through a study to integrate both existing quality management system and new environmental management system. As the integration system of the quality and environment which is constructed by this method is executed, the number of the established and managed document is cut by about a third and so the disorder to encounter between these documents is prevented and unnecessary efforts is reduced in constructing a system, consequently the efficiency of the system is accomplished. Also as the dualization of quality management system and environmental management system additionally needs more men and money after certification acquisition, the non-construction of the integration system may give rise to a cause to aggravate the burden of the company and hereafter when a new system is imported, it may be very difficult to integrate the system. This system integration enables a efficient and effective system to be constructed , operated , and managed after the fact.

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UVB 1회 조사 후 시간에 따른 BALB/c마우스의 피부 항산화효소 활성도 변화 (Temporal changes of the activity of catalase, superoxide dismutase, and glutathione peroxidase in BALB/c mice skin after a single dose UVB irradiation)

  • 이정희;박경애;이희주;박명숙;전상은;박경찬;최스미
    • Journal of Korean Biological Nursing Science
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    • 제3권1호
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    • pp.53-61
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    • 2001
  • Skin is constantly exposed to air, solar radiation, ozone and other air pollutants formulating free radicals. The reactive oxygen species(ROS), formed under these conditions, are associated with skin cancers, cutaneous photoaging, and cutaneous inflammatory disorders. In this study, we sought to establish an animal model for UVB-induced skin alteration using BALB/c mice. The level of UVB irradiation used in this model was within physiological dose. BALB/c mice were exposed to a single dose of UVB ($200mJ/cm^2$ and were sacrificed at 3, 6, 24, and 48 hours following the irradiation. The effect of a single exposure to UVB irradiation on skin catalase(CAT), superoxide dismutase(SOD), and glutathione peroxidase(GPx) activities were examined. Significant decrease in the activity of all enzymes were observed at 6 hours after irradiation(p<.05). The activity of CAT decreased more sharply than those of SOD and GPx, and then remained depressed until 48 hours after UVB irradiation, whereas the activity of GPx recovered to basal level at 48 h after UVB irradiation. Our results indicate that BALB/c mouse could be an adequate animal model of UVB irradiation experiment. These results will also provide fundamental knowledge for the effective nursing strategies in reducing UV-induced skin disorders.

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음용수 소독 미량 유기오염물질 생성에 대한 생물활성탄(Biological Activated Carbon)의 흡착제거 특성 (The Adsorption Removal Characteristics of Trace Organic By-Products in Disinfection of Drinking Water by Biological Activated Carbon(BAC))

  • 옥치상;김정아;배기철
    • 한국환경과학회지
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    • 제1권1호
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    • pp.53-68
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    • 1992
  • In order to research the adsorption removal characteristics of trace organic by-products in disinfection of drinking water by biological activated carbon(BAC), water samples disinfect- ted with $Cl_2$, $O_3$ and $ClO_2$ after treatment by fluidized-bed system with water added with humic acid(10mg/L) were investigated the formation and the removal of trihalomethanes (THMs), and the trace organic by-products by gas chromatography(GC) II gas chromatography/mass selective detector(GC/MSD). Control was used by activated carbon(AC) and water added with humic acid(HA). The results were summarized as follow : The THMs removal effect of BAC by chlorination was in lower 90 % than that of control(HA), the sorts of oxidants formed by $Cl_2$ , $O_3$ and $ClO_2$ were that $O_3$ was very fewer than $Cl_2$ or $ClO_2$, and that $ClO_2$ was fewer than $Cl_2$. The trace organic by-products were esters and phthalates etc. Based on results above, it is concluded that BAC was appeared the more desirable adsorbtion-degradation removal characteristics than that of AC.

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오존수와 오존수를 이용한 세척방법이 식중독 세균 제어에 미치는 영향 (Influence of Ozonated Water and Washing Method Using Ozonated Water for Controlling Food-borne Disease Bacteria)

  • 박정미;신한승
    • 산업식품공학
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    • 제14권4호
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    • pp.316-321
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    • 2010
  • 본 연구는 식중독을 일으키는 병원성 미생물들은 식품시료와 교차오염 원인의 지표가 될 수 있는 도마에 접종한 후 오존수와 일반 수돗물을 이용하여 세척한 후 미생물의 변화와 세척방법에 따른미생물의 변화를 각각 비교 관찰하였다. 실험결과 일반 수돗물보다 오존수가 살균효과가 더 높았고, 같은 세척수로 세척 시에도 접종 방법, 실험시료 및 시료의 표면, 균질화에 따라 살균효과가 다르게 나타나는 것을 확인할 수 있었다. 세척방법으로는 침수보다 주수 에서 살균효과가 더 컸으며 오존수의 농도는 0.2 ppm에서 유의적인 살균효과를 나타내었으며 오존수 농도가 0.4, 0.6, 1.0 ppm으로 증가함에 따라 농도 의존적으로 살균효과 또한 증가하였다. 위의 결과들을 통해 0.2 ppm 이상의 오존수가 부패 미생물 제어에 미치는 영향이 크고 식품의 제조 가공 시 여러 안전성 면에 있어서 오존수를 이용한 세척이 효과적이라고 생각된다.

자동차 배출가스 중 BTEX의 비율과 C2-benzenes의 상관성 연구 (A Study on the BTEX Ratio and Correlation of C2-benzenes in Vehicle Exhaust)

  • 문선희;정택호;정성운;김선문;서석준;이승환;김정화;홍유덕;홍희경
    • 한국분무공학회지
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    • 제23권4호
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    • pp.185-191
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    • 2018
  • Benzene, toluene, ethylbenzene and xylene (BTEX) were well known as ozone precursors from photochemical reactions and contribute to the formation of photochemical smog which pose health hazards. Also, some of these compounds directly affect the human health due to their toxicity such as benzene. In this study, BTEX ratios and correlation of $C_2$-benzenes (xylenes, ethylbenzene) in vehicle exhaust from recreational vehicle (RV) and multi-purpose vehicle (MPV) were characterized using a chassis dynamometer. VOCs were collected by tedlar bag and a GC/MS system was used for their quantification. Among all of the BTEX, toluene has the highest concentration(more than 30% in composition of BTEX). The average ratio of toluene to benzene emissions (T/B ratio=2.2) was found in vehicle exhaust. The average m,p-xylene/ethylbenzene and m,p-xylene/o-xylene ratios were 1.0 and 3.0 respectively. As a result, it showed a good correlation between the $C_2$-benzenes ($R^2=0.98{\sim}0.99$). In the future, it can be used as a marker for effect evaluation to atmospheric environment by vehicle exhaust.

Short-term Effect of Ambient Air Pollution on Emergency Department Visits for Diabetic Coma in Seoul, Korea

  • Kim, Hyunmee;Kim, Woojin;Choi, Jee Eun;Kim, Changsoo;Sohn, Jungwoo
    • Journal of Preventive Medicine and Public Health
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    • 제51권6호
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    • pp.265-274
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    • 2018
  • Objectives: A positive association between air pollution and both the incidence and prevalence of diabetes mellitus (DM) has been reported in some epidemiologic and animal studies, but little research has evaluated the relationship between air pollution and diabetic coma. Diabetic coma is an acute complication of DM caused by diabetic ketoacidosis or hyperosmolar hyperglycemic state, which is characterized by extreme hyperglycemia accompanied by coma. We conducted a time-series study with a generalized additive model using a distributed-lag non-linear model to assess the association between ambient air pollution (particulate matter less than $10{\mu}m$ in aerodynamic diameter, nitrogen dioxide [$NO_2$], sulfur dioxide, carbon monoxide, and ozone) and emergency department (ED) visits for DM with coma in Seoul, Korea from 2005 to 2009. Methods: The ED data and medical records from the 3 years previous to each diabetic coma event were obtained from the Health Insurance Review and Assessment Service to examine the relationship with air pollutants. Results: Overall, the adjusted relative risks (RRs) for an interquartile range (IQR) increment of $NO_2$ was statistically significant at lag 1 (RR, 1.125; 95% confidence interval [CI], 1.039 to 1.219) in a single-lag model and both lag 0-1 (RR, 1.120; 95% CI, 1.028 to 1.219) and lag 0-3 (RR, 1.092; 95% CI, 1.005 to 1.186) in a cumulative-lag model. In a subgroup analysis, significant positive RRs were found for females for per-IQR increments of $NO_2$ at cumulative lag 0-3 (RR, 1.149; 95% CI, 1.022 to 1.291). Conclusions: The results of our study suggest that ambient air pollution, specifically $NO_2$, is associated with ED visits for diabetic coma.

구급차량 내 전자파 방출에 관한 조사 (Research on the emission of electromagnetic waves in ambulance)

  • 윤종근
    • 한국응급구조학회지
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    • 제23권1호
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    • pp.61-69
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    • 2019
  • Purpose: The study aims to provide basic data to enhance the health of paramedics responsible for patient transport and treatment by analyzing the exposure level of paramedics to electromagnetic waves generated by electric devices used in ambulances. Methods: The study measured electromagnetic waves in ambulances in N region from July to December 2018. ME3030B produced by German Gigahertz Solutions was used to measure these waves and the maximum value was selected by moving it slowly in various directions. Each measurement part was selected and the mean value was calculated by repeatedly measuring at 10-minute intervals three times in total: $1^{st}$, $2^{nd}$, and $3^{rd}$ phase. Results: Among the electrical devices installed in the patient room of the ambulance measured at distances of 1 cm or 30 cm, results showed a high level of electric waves at the inverter ($26.25{\pm}39V/m$) and high level of electromagnetic waves ($564.00{\pm}31.75nT$) at the ozone sterilizer. According to measurements toward the front near the driver's seat, results indicated high levels of electric waves ($3.67{\pm}1.15V/m$) and electromagnetic waves ($450.00{\pm}19.52nT$) at the black box hard drive. Conclusion: Electromagnetic waves within the ambulance were stable and not beyond the range that might impact human health. However, in the case of the black box hard drive ($3.67{\pm}1.15V/m$, $450.00{\pm}19.52nT$) located under the passenger seat, it may have a direct effect on the human body and, thus it is necessary to move it to a storage area further away from the paramedics to minimized the impact.