• The Transactions of the Korean Institute of Electrical Engineers C
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• v.48 no.3
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• pp.215-220
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• 1999

$SO_2$and CO gas removal characteristics of a wire-to-cylinder type nonthermal discharge plasma reactor in various applied voltage (-dc, ac, fast rising pulse and high frequency pulse) and a crossed dc magnetic field have been investigated. The experiment has been emphasized on the oxidizing characteristics of $SO_2$ and CO gas by $O_3$ and the applying of a crossed magnetic field, which would induce the cyclotronic and drift motions of electrons making the residual time longer in the removal airgap space. And it also would enhance the energy of electrons and the electrophysicochemical actions to remove the pollutant gases effectively. It is found thatthe corona onset voltage and the breakdown voltage were decreased with increasing the crossed magnetic field and decrease initial fed $SO_2$and CO concentration. As a result, a higher ozone generation and $SO_2$ and CO gas removal rate of 20[%] can be obtained with -dc, ac and fast rising pulse corona discharges in the crossed dc current-induced magnetic field. But high frequency pulse didn't show effect in applying of a crossed magnetic field.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.17 no.4
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• pp.74-80
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• 2003

Ionic wind is produced by a corona discharge when a DC high voltage is applied across the point-to-plane gap geometry. The corona discharge phenomena have been investigated in several beneficial application fields such as electrostatic cooling, ozone generation, electrostatic precipitation and electrostatic spraying. Recently ionic wind might be used in aerodynamic, for example, heat transfer, airflow modification, and etc. In this work, in order to analyze the control behavior of the velocity and amount of ionic wind produced by the positive DC corona discharges. The ionic wind velocity was measured as a function of the applied voltage, diameter of the punched hole on plate electrode and separation between the point-to-plate electrodes. As a results, the airflow is generated from the tip of needle to the plate electrode in the needle-to-punched-plate electrode systems. The ionic wind velocity is linearly increased with an increase in applied voltage and ranges from 1 to 3 m/sec at the locations of 100-200 mm from the punched-plate.

• Journal of Korean Society of Water and Wastewater
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• v.36 no.2
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• pp.59-79
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• 2022

Conventional wastewater treatment plants (WWTPs) do not fully remove micropollutants. Enhanced treatment of sewage effluents is being considered or implemented in some countries to minimize the discharge of problematic micropollutants from WWTPs. Representative enhanced sewage treatment technologies for micropollutant removal were reviewed, including their current status of research and development. Advanced oxidation processes (AOPs) such as ozonation and UV/H₂O₂ and adsorption processes using powdered (PAC) and granular activated carbon (GAC) were mainly discussed with focusing on process principles for the micropollutant removal, effect of process operation and water matrix factors, and technical and economic feasibility. Pilot- and full-scale studies have shown that ozonation, PAC, and GAC can achieve significant elimination of various micropollutants at economically feasible costs(0.16-0.29 €/m³). Considering the current status of domestic WWTPs, ozonation and PAC were found to be the most feasible options for the enhanced sewage effluent treatment. Although ozonation and PAC are all mature technologies, a range of technical aspects should be considered for their successful application, such as energy consumption, CO₂ emission, byproduct or waste generation, and ease of system construction/operation/maintenance. More feasibility studies considering domestic wastewater characteristics and WWTP conditions are required to apply ozonation or PAC/GAC adsorption process to enhance sewage effluent treatment in Korea.

• Journal of Environmental Health Sciences
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• v.48 no.3
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• pp.167-175
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• 2022

Background: Disinfection is essential to provide drinking water from a water source. The disinfection process mainly consists of the use of chlorine and ozone, but when chlorine is used as a disinfectant, the problem of disinfection by-products arises. In order to resolve the issue of disinfection by-products, electro-chlorination technology that produces chlorine-based disinfectants from salt water through electrochemical principles should be applied. Objectives: This study surveys the possibility of optimally producing active chlorine from synthetic NaCl solutions using an electro-chlorination system through RSM. Methods: Response surface methodology (RSM) has been used for modeling and optimizing a variety of water and wastewater treatment processes. This study surveys the possibility of optimally producing active chlorine from synthetic saline solutions using electrolysis through RSM. Various operating parameters, such as distance of electrodes, sodium chloride concentration, electrical potential, and electrolysis time were evaluated. Results: Various operating parameters, such as distance of electrodes, sodium chloride concentration, electrical potential, and electrolysis time were evaluated. A central composite design (CCD) was applied to determine the optimal experimental factors for chlorine production. Conclusions: The concentration of the synthetic NaCl solution and the distance between electrodes had the greatest influence on the generation of hypochlorite disinfectant. The closer the distance between the electrodes and the higher the concentration of the synthetic NaCl solution, the more hypochlorous acid disinfectant was produced.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.37 no.1
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• pp.68-73
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• 2024

In this study, the praseodymium-doped yttrium phosphate (YPO₄:Pr³⁺) powder, which is well known for its high luminescent efficiency, and long life in the UV range, was synthesized with various content ratios of Pr₆O₁₁ and calcination temperature. Crystal structure and luminescent properties of various phosphor powders based on different concentrations and calcination conditions were characterized by XRD (X-Ray Diffraction) and PL (photoluminescence) spectrometers. From the XRD analysis, the structure of YPO₄:Pr³⁺ which is calcinated at 1,200℃ was stable tetragonal phase and crystal size was calculated about 25 nm by Scherrer equation. PL emission of YPO₄:Pr³⁺ with a different content ratio of Pr₆O₁₁ by excitation λ_exc=250 nm shows that 0.75 mol% phosphor powder has maximum PL intensity and PL decreases with the increase of the ratio of Pr₆O₁₁ up to 1.25 mol% which is caused by changes of crystallinity of phosphor powders. With increasing dopant ratio, photo-luminescence Emission decreases due to Concentration quenching, which is commonly observed in phosphors. Currently, 0.75 mol% is considered the optimal doping concentration. A hybrid ultraviolet-emitting device incorporating YPO₄:Pr³⁺ fluorescent material with plasma discharge was fabricated to enhance UV germicidal effects while minimizing ozone generation. UV emission from the plasma discharge device was shown at about 200 nm and 350 nm which caused additional emission of the regions of 250 nm, 315 nm, and 370 nm from the YPO₄:Pr³⁺ phosphor.

• Applied Chemistry for Engineering
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• v.19 no.1
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• pp.17-26
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• 2008

With the effectuation of Kyoto Protocol on the United Nations Framework Convention on the Climate Change, the emission reduction of greenhouse gases became an urgent issue and has been competitively secured among countries as the form of certificates through clean development mechanism (CDM) or joint implementation (JI). Nitrous oxide ($N_2O$) is one of the major greenhouse gases along with carbon dioxide ($CO_2$) and methane ($CH_4$) having warming potential 310 times that of carbon dioxide and chemically very stable in the atmosphere to give a life time of more than 120 years so that it reaches to the stratosphere to act as an ozone depleting substance. $N_2O$ hardly decomposes and thus, besides to the adoption of thermal decomposition at high temperature, selective catalytic reduction methods are usually used at temperatures over $400^{\circ}C$ in which the presence of NOx acts as a major impeding material in the decomposition process. In this article, the sources of various $N_2O$ generation, catalytic reduction processes and the status and trends of emission trade with CDM projects for greenhouse gas reduction are summarized and discussed on a condensed basis.

• Journal of Environmental Science International
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• v.20 no.10
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• pp.1273-1284
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• 2011

The aim of this research was to evaluate the performance of insoluble electrode for the purpose of degradation of Rhodamine B (RhB) and oxidants generation [N,N-Dimethyl-4-nitrosoaniline (RNO, indicator of OH radical), $O_3$, $H_2O_2$, free Cl, $ClO_2$)]. Methods: Four kinds of electrodes were used for comparison: DSA (dimensional stable anode; Pt and JP202 electrode), Pb and boron doping diamond (BDD) electrode. The effect of applied current (0.5~2.5 A), electrolyte type (NaCl, KCl and $Na_2SO_4$) and electrolyte concentration (0.5~3.5 g/L) on the RNO degradation were evaluated. Experimental results showed that the order of RhB removal efficiency lie in: JP202 > Pb > BDD ${\fallingdotseq}$ > Pt. However, when concerned the electric power on maintaining current of 1 A during electrolysis reaction, the order of RhB removal efficiency was changed: JP202 > Pt ${\fallingdotseq}$ Pb > BDD. The total generated oxidants ($H_2O_2$, $O_3$, free Cl, $ClO_2$) concentration of 4 electrodes was Pt (6.04 mg/W) > JP202 (4.81 mg/W) > Pb (3.61 mg/W) > BDD (1.54 mg/W), respectively. JP202 electrode was the best electrode among 4 electrodes from the point of view of performance and energy consumption. Regardless of the type of electrode, RNO removal of NaCl and KCl (chlorine type electrolyte) were higher than that of the $Na_2SO_4$ (sulfuric type electrolyte) RNO removal. Except BDD electrode, RhB degradation and creation tendency of oxidants such as $H_2O_2$, $O_3$, free Cl and $ClO_2$, found that do not match. RNO degradation tendency were considered a simple way to decide the method which is simple it will be able to determinate the electrode where the organic matter decomposition performance is superior. As the added NaCl concentration was increases, the of hydrogen peroxide and ozone concentration increases, and this was thought to increase the quantity of OH radical.

• Journal of Korean Society of Environmental Engineers
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• v.38 no.11
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• pp.589-595
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• 2016

This study evaluated the environmental impacts for landfill treatment of the wastewater treatment sludge (WTS) from petrochemical firms by life cycle assessment (LCA) and reviewed the impact reduction by landfill gas (LFG) utilization. The functional unit was 'landfill of 1 ton of WTS', and the system boundary included the process of input and treatment for WTS in landfill site. The impacts were high at landfill process (LP) and leachate treatment process (LTP). Global warming (GWP) and photochemical oxidants creation (POCP) were high at LP, while abiotic depletion (ADP), acidification (AP), eutrophication (EP), ozone depletion (ODP) were high at LTP. The major substances of various impact categories were crude oil (ADP), $NO_X$ (AP, EP), $CH_4$ (GWP, POCP), $Cl_2$ (ODP), respectively. The major factor of ADP, AP, EP was attributed from the generation of electricity used in LTP, and the methane within uncollected LFG was main factor of GWP and POCP. Therefore, electricity consumption reduction is identified to be an impact improvement option, and the flaring system installation or enhanced LFG recovery could be an alternative to reduce impacts. Among the various categories, GWP accounted the highest impact (${\geq}90%$) followed by ADP, POCP. In the avoidance impact resulted from the utilization of LFG, to substitute B-C oil or LNG showed the impact reduction of 32.7% and 12.0%, respectively.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.10
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• pp.1108-1113
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• 2005

Advanced oxidation process involving $O_3/H_2O_2$ was used to eliminate 1,4-dioxane and to enhance the biodegradability of dioxane-contaminated water. Oxidation process was carried out in a bubble column reactor under different pH and $H_2O_2$ concentrations. The removal efficiencies of 1,4-dioxane were investigated at hydrogen peroxide concentration between 40 and 120 mg/L. At the same pH, removal efficiencies of 1,4-dioxane increased with increasing initial $H_2O_2$ concentration. There was a linear relationship between initial concentration of $H_2O_2$ and the amount of consumed $O_3$. It was observed that the high $H_2O_2$ concentration accelerated the generation of hydroperoxy ions(${HO_2}^-$) and hydroxyl radicals($OH{\cdot}$). Hydrogen peroxide enhanced the decomposition of 1,4-dioxane and the biodegradability of the solution.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.5
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• pp.494-500
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• 2006

Life Cycle Assessment(LCA) is an environmental assessment tool for evaluating environmental burdens associated with products, processes and activities from the raw material acquisition stage to the end-of-life stage. End-of-life stage as well as other processes requires a reliant database in order to increase the confidence in the LCA results. In this study, the flow of Personal Computer(as PC) in the end-of-life stage was examined and the database of two scenarios has been established, i.e. one is part reuse and the other is no part reuse, in the end-of-life phase of PC. Also, key environmental issues were identified by carrying out LCA on a PC in the end-of-life phase for eight environmental impact categories. The 'ozone layer depletion' contributes the highest environmental impact due to generation of $Cl_2$ gas during the incineration of waste plastics. In addition, the scenario 1(part reuse) is more environmentally sound than the scenario 2(no part reuse) when comparing two scenarios.