• 공업화학
• /
• 제23권5호
• /
• pp.490-495
• /
• 2012

오존/활성탄 공정을 이용하여 페놀을 처리 할 경우, 활성탄에 의해 나타나는 촉매효과에 관한 연구를 수행하였다. 오존 단독공정에 활성탄을 추가할 경우, 활성탄 투입량이 증가할수록 용존 오존 및 페놀의 분해효율이 증가하는 것으로 나타났다. 이는 활성탄에 의해서 용존 오존이 분해되어 생성된 수산화 라디칼이 페놀 제거에 영향을 미쳤으며, 본 연구에서는 활성탄의 촉매효과([$\Delta$phenol] / $[{\Delta}O_{3}]_{AC}$)로 나타내었다. 활성탄 10~40 g/L 투입 시, 모든 활성탄의 최대 촉매효과 값은 $2.0\;{\pm}\;0.1$로 나타났지만, 10 g/L와 20 g/L를 투입한 경우, 40 min 경과 후 최대 촉매효과에 근접한 반면, 활성탄 30 g/L와 40 g/L를 투입한 경우, 반응 20 min 경과 후 최대 촉매효과에 도달하였다. 또한 Total Organic Carbon (TOC, 총유기탄소)의 제거율은 오존 단독공정에서 0.23으로 나타났으며, 오존/활성탄 공정에서는 0.63으로 나타났다.

• 대한환경공학회지
• /
• 제32권4호
• /
• pp.325-332
• /
• 2010

본 연구에서는 오존을 이용한 잉여슬러지의 가용화 실험을 실시하였다. 오존의 접촉효율을 높이기 위해 마이크로버블화된 오존(이하 마이크로버블 오존이라 함)을 이용하였으며, 생성된 마이크로버블 오존의 사이즈는 평균 직경 30 ${\mu}m$ 정도였고, 40 ${\mu}m$ 이하가 전체의 약 90% 정도를 나타내었다. 마이크로버블 오존을 이용한 슬러지 처리에 있어서는 슬러지 농도에 상관없이 오존주입율을 0.34 g $O_3/g$ SS 이하로 주입할 경우, 폐오존의 발생 없이 오존소모율이 100%인 것으로 조사되었다. 각 농도별 슬러지 처리에 있어서 슬러지의 초기 SS 농도를 6,447 mg/L, 5,557 mg/L, 3,180 mg/L, 1,092 mg/L 및 515mg/L로 하였을 경우, 동일한 오존주입율에 있어서 초기 SS의 농도가 증가할수록 제거되는 SS량이 증가하는 경향을 나타내어, 오존의 산화효율을 높이기 위해서는 초기 SS의 농도가 높은 슬러지를 처리하는 것이 효과적이었다. 한편, 슬러지의 복합 처리로서 산과 알칼리 그리고 오존처리를 검토한 결과, 오존의 전처리로서 산처리를 이용하는 것이 알칼리처리에 비해 효과적이었으며, 슬러지에 주입하는 황산의 농도를 0.01 N로 하고, 오존주입율 0.05 g $O_3/g$ SS로 처리한 경우, 제거된 SS의 양은 153.9 g으로 오존단독처리시 81.2 g에 비해 1.9배의 많은 양이 제거되었다.

• 한국대기환경학회지
• /
• 제15권5호
• /
• pp.545-554
• /
• 1999

We would like to develop a short-term model to predict the time-related concentration of ozone whose reaction mechanism is complex. The paper targets Seoul where an ozone alert system has recently been employed. In order to develop a short-term prediction model for ozone, we suggested the Ozone Peak Indicator(OPI), an equivalent of the potential daily maximum ozone concentration, with precursors being the only limiting factor, and we calculated the Ozone Peak Indicarot as OPI={$rac{(O_3)_{max}cdot(H_{eH})_{max}(Rad)_{max}$ to preclude the influence of mixing height and solar radiation on the daily maximum ozone concentration. The OPI on the day of the prediction is to be calcultated by using the relation between OPI and the initial value of precursors. The basic prediction formula for time-related ozone concentration was established as $O_3(1)={(OPI)cdot Rad(t-2)H_{eH}}$, using the OPI, solar radiation two hours before prediction and mixing height. We developed, along with the basic formula for predicting photochemical oxidants, "SEOM"(Seoul Empirical Oxidants Model), a Fortran program that helps predict solar radiation and mixing height needed in the prediction of ozone pollution. When this model was applied to Seoul and an analysis of the correlation between the observed and the predicted ozone concentrations was made through SEOM, there appeared a very high correlation, with a coefficient of 0.815. SEOM can be described as a short-term prediction model for ozone concentration in large cities that takes into account the initial values of precursors, and changes in solar radiation and mixing height. SEOM can reflect the local characteristics of a particular and region can yield relatively good prediction results by a simple data input process.t process.

• 한국환경과학회지
• /
• 제14권8호
• /
• pp.749-760
• /
• 2005

This study examines the local ozone photochemistry in the urban air. The photochemical formation and destruction of ozone was modeled using a photochemical box model. For the model prediction of ozone budget, measurements were carried out from an urban monitoring station in Seoul ($37.6^{\circ}N,\;127^{\circ}E$), Korea for intensive sampling time period (Jun. $1\~15$, 2003). Photochemical process is likely to play significant role in higher ozone concentrations during the sampling period. The results of model simulation indicated that photochemical ozone production pathway was the reaction of NO with $HO_2$ while ozone destruction was mainly controlled by a photochemical destruction pathway, a reaction of $H_2O$ with $O(^1D).$ The contribution of NMHCs to formation and destruction of ozone in the urban was significant. This was entirely different from remote marine environment. The rates of net photochemical ozone production ranged from 0.1 to 1.3 ppbv $h^{-1}$ during the study period.

• 한국환경과학회지
• /
• 제25권2호
• /
• pp.191-216
• /
• 2016

Since prolonged exposure to elevated ozone ($O_3$) concentrations is known to be harmful to human health, appropriate control strategies for ozone are needed for the non-attainment area such as Seoul, Korea. The goal of this research is to assess factors linked with the 1-hour ozone exceedance through a decision tree model. Since ozone is a secondary pollutant, lag times between ozone and explanatory variables for ozone formation are taken into account in the model to improve the accuracy of the simulation. Results show that while ozone concentrations of the previous day and $NO_2$ concentrations in the morning are major drivers for ozone exceedances in the early afternoon, meteorology plays more important role for ozone exceedances in the late afternoon. Results also show that a selection of lag times between ozone and explanatory variables affect the accuracy of predicting 1-hour ozone exceedances. The result analyzed in this study can be used for developing control strategies of ozone in Seoul, Korea.

• 대한화장품학회지
• /
• 제30권1호
• /
• pp.39-51
• /
• 2004

Ozone(O$_3$), one of best-known toxic air pollutant, act as a strong oxidant. It is possible that skins exposed to the air can be easily damaged by such oxidative air pollutants. Therefore, in the present study, anti-oxidative effects of natural product. on $O_2$ㆍ and ㆍOH were investigated by EPR. Ozone caused protein damage and lipid oxidation, in HaCaT and B16F10 leading ultimately to programmed cell death. It also reduced the level of antioxidant molecules including ascorbic acid and tocopherol in stratum comeum. However, antioxidants originated from natural products could protect skin from these products could protect skin from these oxidative damages. We concluded that eight natural extracts including Rosa davurica, Ligularia sibrica, Green tea acted as strong antioxidants against ozone.

• 한국대기환경학회지
• /
• 제15권2호
• /
• pp.159-173
• /
• 1999

Based on air quality monitoring data('89~'97) operated by the Department of Environment, we provide various fundamental statistics for ground ozone. The purpose of this paper are to review the national ambient ozone standard, to study spatial distribution of ozone. Since we, in Korea, calculate average ozone level, to examine the occurrences of ozone level 3 times a day (1~8, 9~16, 17~24 hours), the method does not seem to be scientifically sound comparing to a running average method adapted by the USEPA. When we counted the number of cases with 8-h average O3 level exceeding 60ppb(8-h average standard in Korea)and 80 ppb (that in the U.S.A) and also when we calculated 8-hour average ozone level based on th US method, some regions were classified as non-attainment areas. Especially in Seoul, results of spatial distribution analysis showed that high level ozone over 80 ppb was observed at Kuui-Dong and Pangi-Dong in the eastern part and at Ssangmun-Dong in the northeastern part. Also, occurrences of ozone episode defined as number of days then ozone level exceeding 80 ppb for 3 consecutive hours were extensively reviewed in this paper.

• 한국조명전기설비학회:학술대회논문집
• /
• 한국조명전기설비학회 2004년도 학술대회 논문집
• /
• pp.339-342
• /
• 2004

It is research about special quality of ozone gas concentration and dissolved ozone concentration that show according to change of flow rate when liquefied ozone gas in water. If increase flow rate of ozone gas, ozone concentration increases being proportional and amount to fixed flow rate, dissolved ozone concentration was measured low. When ozone concentration How rate 1000 [ppm], dissolved ozone concentration smelted to flow rate 1.5[Q] for 28 [min] is $0.1740{\sim}0.8020[mg/l]$. Could know that half-life is most short by 3 minutes 8 seconds in flow rate 1.5 [Q]. And ozone smelted 20 minutes later after half-life measurement became disjointing all.

• 한국재료학회지
• /
• 제15권12호
• /
• pp.760-764
• /
• 2005

The influences of the oxidant($O_2\;and\;O_3$) on the FeOOH formation were studied with fixed $FeSO_4{\cdot}7H_2O$ concentration (0.5M) and NaOH equivalent ratio(0.5). The characteristics of the synthesized powders were evaluateed by XRD, and equantitative phase analysis. $\alpha-FeOOH$ (Geothite) and/or $\gamma-FeOOH$ was promoted when $O_3$ was used as a oxidant which is stronger oxidizing agent than $O_2$.

• 대한환경공학회지
• /
• 제28권12호
• /
• pp.1274-1279
• /
• 2006

본 연구에서는 낙동강 하류 매리원수, 부산시 회동수원지 원수 및 매리원수를 정수처리하는 pilot-plant의 급속 모래여과 처리수를 이용하여 오존 투입농도별로 $BDOC_{rapid}$4와 $BDOC_{slow}$의 생성특성에 대하여 조사하였다. $BDOC_{total}$ 농도가 최대가 되는 오존 투입 농도는 매리원수, 회동원수 및 모래여과 처리수에서 각각 0.9, 1.1 및 1.4 $mgO_3/mgDOC$로 조사되어 실험에 사용된 시료수의 특성에 따라 $BDOC_{total}$이 최대로 생성되는 오존 투입농도는 다르게 나타났다. $BDOC_{rapid}$를 최대로 생성시키는 오존 투입농도는 $BDOC_{total}$을 최대로 생성시키는 오존 투입농도 보다 낮은 $0.9{\sim}1.1\;mgO_3$/mgDOC로 나타났으며, 1 $mgO_3$/mgDOC 이상의 오존 투입농도에서는 $BDOC_{rapid}$의 농도가 오하려 낮아지는 것으로 나타났다. 또한. 오존 처리에 따른 $BDOC_{slow}$의 생성특성 조사에서 $BDOC_{slow}$는 $BDOC_{total}$과 $BDOC_{rapid}$를 최대로 생성시키는 오존 투입농도 보다 더 높은 오존 투입농도에서도 지속적으로 생성되었다. Biofiltration 공정의 전처리로 사용되는 오존의 최적 투입량을 결정할 수 있는 $BDOC_{rapid}/BDOC_{total}$비를 실험에 사용된 시료수별로 조사한 결과 $0.6{\sim}1.0\;mgO_3$/mgDOC로 조사되어 $BDOC_{total}$이 최대로 생성되는 오존 투입농도 $0.9{\sim}1.4\;mgO_3$/mgDOC보다 낮은 것으로 나타났다. 따라서 최적의 오존 투입율 결정시 BDOC 분류를 통한 접근법이 경제성 측면이나 biofiltration 공정의 효율면에서도 훨씬 효율적인 것으로 조사되었다.