• Title/Summary/Keyword: Ozonation process

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A Study of Advanced Oxidation Process for Reuse of Industrial Wastewater (산업폐수 재이용을 위한 고급산화공정 시스템 연구)

  • Kim, Sung-Joon;Jin, Ming-Ji;Won, Chan-Hee;Hwang, Jeong-Seok;Lee, Gil-Yong
    • Journal of Korean Society on Water Environment
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    • v.26 no.4
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    • pp.580-584
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    • 2010
  • As water becomes more scarce around the world the reuse of treated wastewater is being recenlty considered as indispensible trend we need to follow. Especially, industrial area consuming large amount of water has been encouraged to reuse the treated wastewater to secure sufficient water for the production of merchandise. In this study, a study of advanced oxidation process for treatment of industrial wastewater. The treatment performance of UV and ozoznation and five types advanced oxidation processes such as UV/AC, UV/Catalyst, $O_3$/Catalyst, UV/$O_3$/Catalyst was experimentally investigated for reuse of industrial wastewater. The removal efficiency of $COD_{Cr}$, color were relatively evaluated in each treatment unit simulated outflow water of wastewater treatment area. UV/$O_3$/Catalyst process showed the highest $COD_{Cr}$ remaval and color remaval among proposed oxidation process.

Removal of NOM Using Biological Rope Media Sedimentation Tank (로프형 미생물 담체 침전조를 이용한 상수원수중의 NOM 제거)

  • 심상준;강연석;김우식;박대원
    • KSBB Journal
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    • v.16 no.4
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    • pp.332-336
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    • 2001
  • This paper is intended as an application of the biological rope media sedimentation tank using biodegradability of BAC(Biological activated carbon) to the drinking water treatment system for the removal of NOM. The removal of DOC(Dissolved organic carbon), UV absorbance(UV$\_$254/), and turbidity were evaluated under various operation condition of a biological rope media sedimentation tank such as raw water-media process (Media 1), ozonation-media process (Media 2), and ozonation-coagulation/sedimentation-media process (Media 3). The raw water had DOC concentration of 1.3∼3.4 mg/L, UV$\_$254/ of 0.027∼0.039 cm$\^$-1/, and turbidity of 0.3∼4.5 NTU, respectively. The average DOC concentration were 2.2 mg/L in media 1, 1.8 mg/L in media 2, and 1.3 mg/l in media 3 from raw water, respectively. On the other hand, the DOC concentration in conventional sedimentation tank was 1.5 mg/l. Higher removal of the DOC was noted in media 3 than media 1 and media 2. The UV$\_$254/ of the treated water were 0.037 cm$\^$-1/ in media 1, 0.027 cm$\^$-1/ in media 2, and 0.014 cm$\^$-1/ in media 3 from raw water, respectively The UV$\_$254/ in conventional sedimentation tank was 0.014 cm$\^$-1/ which is similar to that of media 3. Average turbidity of the treated water was 1.1 NTU in media 1, 0.9 NTU in media 2, and 0.5 NTU in media 3, respectively. It is expected that the biological rope media sedimentation tank is a good alternative over the conventional sedimentation process from these results.

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Combination of Sequential Batch Reactor (SBR) and Dissolved Ozone Flotation-Pressurized Ozone Oxidation (DOF-PO2) Processes for Treatment of Pigment Processing Wastewater

  • Kim, Jeong-Hyun;Kim, Hyung-Suk;Lee, Byoung-Ho
    • Environmental Engineering Research
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    • v.16 no.2
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    • pp.97-102
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    • 2011
  • This study investigates the treatment of pigment wastewater using a sequential batch reactor (SBR) followed by dissolved ozone flotation-pressurized ozone oxidation treatement (DOF-$PO_2$). The process efficiency has been evaluated at the lab scale on the basis of water quality parameters. In addition, the effect of pure oxygen and air was investigated on the removal of COD, BOD, and TN in the SBR process. It was observed that under comparable conditions the removal efficiencies of these water quality parameters using pure oxygen and air were similar. The effect of the recycle rate was also investigated for its impact on the water quality parameters using different ozone dissolving pressures in a DOF process in order to optimise conditions. The results conclude that the use of an SBR and ozone contact by DOF-$PO_2$ is a highly effective treatment for pigment wastewater and aids in the achievement of effluent discharge criteria.

Performance of Backwashing Process in Biological Activated Carbon Column (생물활성탄접촉조에서 역세척 공정의 성능)

  • Lee, Gangchoon;Yoon, Taekyung;Moon, Byunghyun;Noh, ByeongIl
    • Journal of Korean Society on Water Environment
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    • v.22 no.6
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    • pp.1082-1087
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    • 2006
  • BAC backwashing process in ozone-BAC advanced water treatment process was experimentally studied. The operation and performance of backwashing were evaluated by measuring the effects of water temperature and water input rate on the backwashing interval and duration, and also the change of the amounts of biofilm and HPC in treated water before and after backwashing. The experiments were carried out with the pilot scale test module built in a existing water treatment plant, and the following results were obtained. Longer backwashing time than that of design operating condition was needed for satisfying the suitable turbidity of washing water effluent. Depending on water temperature, 7 days of backwashing cycle was recommended for the period lower than $15^{\circ}C$, and 10 days for the period higher than $15^{\circ}C$. After backwashing, the amounts of biofilm and HPC decreased to 1/10 and 80%, respectively.

Detection and Distribution of Bacterial Pathogens in Raw Water and During Water Treatment Process by Polymerase Chain Reaction (유전자 검색법을 이용한 상수원수와 정수처리 공정중의 병원성 미생물 검출 및 분포특성)

  • Park, Hong-Ki;Jung, Eun-Young;Jung, Jong-Moon;Yu, Pyung-Jong
    • Journal of Life Science
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    • v.17 no.10
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    • pp.1374-1380
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    • 2007
  • The development of polymerase chain reaction (PCR) technology has the potential to solve for isolating pathogenic microorganisms from environmental samples than traditional plate counting methods. We have been detected pathogenic bacteria from raw water and water treatment process in Busan metropolitan city by PCR method. According to the result of survey from July 2004 to October 2005, 80 out of 92(87.0%) were positive for bacterial pathogens in raw water samples and positive rate of Shigella spp., Yersinia spp., Salmonella spp. and Legionella spp. were 46.2%, 40.7%, 17.6% and 9.9%, respectively. Pathogenic bacteria in raw water was mainly distributed through the lately Autumn to the winter and more highly detected Maeri than Mulgum region. During the period of survey in water treatment process, Shigella spp. was highly detected but all of bacterial pathogens were entirely removed after in post-ozonation step. These suggest that waters supplied in Busan metropolitan city may be safe against the pathogenic bacteria.

The Effects of Preozonation on Organic Removal in Biological Activated Carbon Fluidized Bed (생물활성탄 유동상에서 전오존처리가 유기물 제거에 미치는 영향)

  • 우달식;곽필재;남상호
    • Journal of environmental and Sanitary engineering
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    • v.13 no.1
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    • pp.166-173
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    • 1998
  • This study was to investigate the effects of preozonation on the waterborne organic removal by the biologically active GAC fluidized bed on a laboratory scale. The raw water to be treated comes from midstream of Han river. As the ozone dose was increased in the range of $1~3{;\}mgO_{3}/mgDOC$, it produced BDOC from 1.82 to 2.65 times. And BDOC formation can be expressed as [BDOC] = 0.74 + 0.21[DOC] ($R^{2}{\;}={\;}0.8399$). The effects of combination of ozonation followed by BACFB (Biological Activated Carbon Fluidized Bed) process were analyzed. At the ozone doze of $1~3{\;}mgO_{3}/mgDOC$, the large fraction of BDOC was removed by BACFB, but parameter revealed only around 10% reduction.

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The Trend and Prospect of Advanced Water Treatment Process using Ozonizer (오존발생기를 이용한 고도정수처리기술 동향 및 전망)

  • 조국희;김영배;서길수;이형호;이광식;송현직;이상근
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 1998.11a
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    • pp.242-244
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    • 1998
  • Over the years manufactures have become increasingly aware of the importance of water purity and its effect on the quality of the final product. One of the largest problems that confronts pure water system operators is bacterial recontamination shortly after the water purification equipment. There are several recommended methods of either preventing or recommended methods of either preventing or removing such contamination but most have inherent disadvantages. Drinking water has required new treatment techniques such as ozonation and granular activated carbon(GAC) filtration. Ozone is known to be a powerful oxidant and disinfectant. Therefore it has been found to be necessary for the treatment of taste, odor and color as an oxidant of inorganic and organic compounds.

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Effect of Nitrite and Nitrate as the Source of OH Radical in the O3/UV Process with or without Benzene

  • Son, Hyun-Seok;Ahammad, A.J. Saleh;Rahman, Md. Mahbubur;Noh, Kwang-Mo;Lee, Jae-Joon
    • Bulletin of the Korean Chemical Society
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    • v.32 no.spc8
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    • pp.3039-3044
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    • 2011
  • This study suggests the prediction model for the concentration variation of $NO_2{^-}$ and $NO_3{^-}$ along with the rate constants of all reactions during ozonation under UV radiation ($O_3$/UV process). While $NO_2{^-}$ was completely converted into $NO_3{^-}$ during the $O_3$-only process, the production of $NO_2$ radical or $N_2O_4$ was expected in the $O_3$/UV process. In addition, the quenching of OH radicals, by $NO_2$ radical in the $O_3$/UV process, resulted in regeneration of $NO_2{^-}$. However, the regeneration of $NO_2{^-}$ was not observed in the $O_3$/UV process in the presence of $C_6H_6$ where the concentrations of $NO_2{^-}$ and $NO_3{^-}$ were significantly reduced compared to in the process without $C_6H_6$. The pseudo-first order rate constants of all species were calculated with and without the presence of $C_6H_6$ to predict the variation of concentrations of all species during the $O_3$/UV process. It was suggested that $NO_2{^-}$ and $NO_3{^-}$ in the $O_3$/UV process can be more effectively removed from an aqueous system with an OH radical scavenger such as $C_6H_6$.

Evaluation of Water Treament System for Phenol Removal in the Nakdong River Basin (낙동강 수계 페놀처리를 위한 정수처리시스템 평가)

  • Kang, Byung-Jae;Chae, Seon-Ha;Lee, Kyung-Hyuk;Jeon, Hang-Bae
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.5
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    • pp.609-618
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    • 2009
  • Repeated phenol spill in the Nakdong River has been a big issue in Korea since 1991. In this study, treatment of phenol in each water treatment process and total water treatment system is evaluated. Phenol was highly volatile, easily oxidized by ozone, and readily absorbed onto GAC. When there was phenol of 0.3mg/L in water, by ozonation of 1mg/L or by GAC adsorption with EBCT of 10minutes or longer, it could be treated to lower than 0.005mg/L, the national drinking water standard of phenol. Even when a sufficient contact time(70minutes) was allowed, only 35 to 40% of phenol could be removed by powdered activated carbon(PAC). Based on the test results, it can be concluded that 1.0mg/L or less concentration of phenol can be treated at the plants adopting the combination process of ozone and GAC down to the safe level. In this study, removal characteristics for phenol were evaluated with the existing pilot plant and demo plant in different advanced water treatment processes(AWTPs). In the future, studies on changes in oxidation and adsorption characteristics caused by competitive matters such as DOC and removal characteristics by other various AWTPs including ozone/filter adsorber need to be performed.

DBPs Variation by Chlorination and Preozonation in Drinking Water (염소 및 오존소독시 정수처리공정별 소독부산물 발생 변화)

  • Kim, Junsung;Choi, Yongwook;Chung, Yong
    • Journal of Korean Society on Water Environment
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    • v.21 no.6
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    • pp.676-681
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    • 2005
  • This study was researched for disinfection by-products (DBPs) by preozonation, prechlorination and/or postchlorination. DBPs including trihalomethanes (THMs), haloacetic acids (HAAs), halonitriles, and aldehydes were analyzed by the treatment steps of prechlorination, preozonation, sedimentation, filtration, and postchlorination comparatively. THMs were detected as $52.20{\mu}g/L$ after prechlorination and decreased during sedimentation and filtration process. The HAAs and aldehydes increased more during preozonaiton than prechlorination. However, chlorinated DBPs and aldehydes increased more by postchlorination. Chlorinated DBPs formed by preozonation increased 26% more than the chlorination process. If aldehydes were included in the total DBPs, DBPs increased up to 39% by preozonation. Preozonation could increase the removal efficiency of organic carbon during the coagulation and sedimentation processes. Ozonation might produce aldehydes that are not permitted for drinking water regulations. Also, DBPs were produced by preozonation than by chlorination. These results would bring a need for alternative disinfection studies to decrease DBPs.