Browse > Article

DBPs Variation by Chlorination and Preozonation in Drinking Water  

Kim, Junsung (Department of Civil and Environmental Engineering, University of Massachusetts)
Choi, Yongwook (Department of Environmental System Engineering, Jeonju University)
Chung, Yong (Department of Preventive Medicine and Public Health, College of Medicine Yonsei University)
Publication Information
Abstract
This study was researched for disinfection by-products (DBPs) by preozonation, prechlorination and/or postchlorination. DBPs including trihalomethanes (THMs), haloacetic acids (HAAs), halonitriles, and aldehydes were analyzed by the treatment steps of prechlorination, preozonation, sedimentation, filtration, and postchlorination comparatively. THMs were detected as $52.20{\mu}g/L$ after prechlorination and decreased during sedimentation and filtration process. The HAAs and aldehydes increased more during preozonaiton than prechlorination. However, chlorinated DBPs and aldehydes increased more by postchlorination. Chlorinated DBPs formed by preozonation increased 26% more than the chlorination process. If aldehydes were included in the total DBPs, DBPs increased up to 39% by preozonation. Preozonation could increase the removal efficiency of organic carbon during the coagulation and sedimentation processes. Ozonation might produce aldehydes that are not permitted for drinking water regulations. Also, DBPs were produced by preozonation than by chlorination. These results would bring a need for alternative disinfection studies to decrease DBPs.
Keywords
Preozonation; Chlorination; Disinfection by-products; Aldehydes; Trihalomethanes (THMs);
Citations & Related Records
연도 인용수 순위
  • Reference
1 염철민, 조순행, 윤재용, 서울시 정수장의 필요소독능 관리 현황, 상하수도학회지, 16(4), pp. 455-465 (2002)
2 Glaze, W. H., Drinking-Water Treatment with Ozone, Environ. Sci. Technol., 21(3), pp. 224-230 (1987)   DOI   ScienceOn
3 Glaze, W. H., Determining Health Risks Associated with Disinfectants and Disinfection By-Products Research needs, J. AWWA, 85(3), pp. 53-56 (1993)
4 Nieminski, E. C., Chaudhuri, S. and Lamoreaux, T., The Occurrence of DBPs in Utah Drinking Waters, J. AWWA, 85(9), pp. 98-105 (1993)
5 U.S. EPA, Determination of Carbonyl Compounds in Drinking Water by Dinirophenylhydrazine Derivatization and High Performance Liquid Chromatography, Method 554 (1992)
6 U.S. EPA, Methods for the Determination of Organic Compounds in Drinking Water Supplemen I, Method 551 (1990)
7 Weinberg, H. S., Glaze, W. H., Krasner, S. W. and Sclimenti, M. J., Formation and Removal of Aldehydes in Plants that Use Ozonation, J. AWWA, 85(9) pp. 72-85 (1993)
8 Amy, G. L., Tan, L. and Davis, M. K., The Effects of Ozonation and Activated Carbon' Adsorption on Trihalomethane Speciation, Water Res., 25(2), pp. 191-202 (1991)   DOI   ScienceOn
9 Froese, K. L., Wolanski, A. and Hrudey, S. E., Factors Governing Odorous Aldehyde Formation as Disinfection By-Products in Drinking Water, Wat. Res., 33(6), pp. 1355-1364 (1999)   DOI   ScienceOn
10 정 용, 신동천, 양지연, 박연신, 김준성, 수도수중 염소 소독 부산물로 인한 건강위해성 평가에 관한 연구, 한국환경독성학회지, 12(3), pp. 31-41 (1997)
11 Periera, W. E., Hayano, Y., Summons, R. E., Bacon, V. A. and Du'eld A. M., Chlorination studies II. The Reaction of Aqueous Hypochlorous Acid with Apha-Amino Acids and Peptides, Biochim. Biophys. Acta, 313, pp. 140-180 (1973)
12 U.S. EPA, Determination of Haloacetic Acids and Dalapon in Drinking Water by Liquid-liquid Extaction, Derivatization and GC-ECD, Method 552.2. (1995)
13 Richardson, S., Water Analysis: Emerging Contaminants and Currents Issues, Anal. Chem., 75(18), pp. 2831-2857 (2003)   DOI   ScienceOn
14 Reckhow, D. A. and Singer, P. C., The Removal of Organic Halide Precursors by Preozonation and Alum Coagulation, J. AWWA, 76(4), pp. 151-157 (1984)
15 Ivancev-tumbas, I. and Dalmacija B., Effects of Coagulation Processes on Aldehydes Formation in Groundwater Treated with Common Oxidative Agents, Wat. Res., 35(16), pp. 3950-3958 (2001)   DOI   ScienceOn
16 David, L. W., Kimberly, A. G. and Kim, S. M., Removal of Algal-derived Organic Material by Preozonation and Coagulation: Monitoring Changes in Organic Quality by Pyrolysis-GC-MS, Wat. Res., 30(11), pp. 2621-2632 (1996)   DOI   ScienceOn
17 U.S. EPA, Methods for the Determination of Organic Compounds in Drinking Water Supplement II, Method 524.2. (1992)
18 김준성, 상수 중 염소 및 오존소독부산물의 발생특성과 생성저강공정에 관한 연구, 연세대학교 대학원 박사학위논문 (2000)
19 Smith, M. E., Cowman, G. T. and Singer, P. C., The Impact of Ozonation and Coagulation on Disinfection By-Product Formation, AWWA, 1989 annual conference proceedings, LA, California, June 18-22, pp. 24-40 (1989)