• Journal of Korea Technical Association of The Pulp and Paper Industry
• /
• v.36 no.4 s.107
• /
• pp.60-66
• /
• 2004

In this paper, oyster shell, diatomaceous earth, and active carbon were used as filter media for treating wastewater produced in paper mills. After filtering, the changes of COD and turbidity were investigated. As the results of estimating the efficiency of wasterwater treatment, porous oyster shell having higher specific surface area in powder was more effective than the others in removal of contaminants in waterwater, especially turbidity.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
• /
• v.27 no.1
• /
• pp.41-48
• /
• 2021

In this study, ethylene vinyl acetate (EVA) and low density polyethylene (LDPE) composite films (EVA/LDPE-OSP) containing calcined oyster shell powder (OSP) were prepared using twin-screw extruder as an antimicrobial packaging material. The OSP composite was initially prepared and then incorporated into an EVA/LDPE blend at different ratios (0, 1, 3 and 5%) to develop the EVA/LDPE-OSP composite films. The as-prepared EVA/LDPE-OSP composites films were evaluated using FT-IR, DSC, TGA, OTR, WVTR, SEM and UTM as well as antimicrobial activity was examined using JIS Z 2801:2000 standard. OPS endowed the antimicrobial potency to the composite films against Gram-positive (Staphylococcus aureus) and Gram-negative (Escherichia coli) bacteria. In addition, the incorporation of OSP remarkably enhanced the thermal stability. OSP as a natural biocidal agent can be used as a multifunctional additive in packaging industry such as improving the thermomechanical properties and preventing the microbial contamination of packaged products.

• Food Science of Animal Resources
• /
• v.38 no.6
• /
• pp.1246-1252
• /
• 2018

This study was conducted to investigate the effects of the addition levels of a phosphate replacer blend in ground pork sausages. The phosphate replacer consisted of 0.2% oyster shell calcium powder, 0.3% egg shell calcium powder, and 0.25% whey protein concentrate. Depending on the presence or absence of synthetic phosphate and the addition level of phosphate replacer, the following products were processed: control (+) (0.3% phosphate), control (-) (non-phosphate), 20AL (20% replacer), 40AL (40% replacer), 60AL (60% replacer), 80AL (80% replacer), and 100AL (100% replacer). The pH values of pork sausages increased (p<0.05) with increasing addition level of the phosphate replacer. When more than 40% of the phosphate replacer was added to pork samples (40AL, 60AL, 80AL, and 100AL), cooking loss was significantly reduced compared to both the control (+) and control (-). However, no significant differences were observed in the moisture content and CIE $L^*$ values between the controls and the treatments with a phosphate replacer. The control (+) and 100AL treatment had the highest (p<0.05) hardness, but the samples with the phosphate replacer were not significantly different in cohesiveness and springiness from the control (+). As addition level increased, the gumminess and chewiness of the products with the phosphate replacer increased, which were lower than those of the control (+). Therefore, more than 40% of a phosphate replacer may possibly substitute synthetic phosphate to improve product yields in ground pork sausages, although further studies may be needed for improving the textural properties of the final products.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2020.06a
• /
• pp.75-76
• /
• 2020

Use fire resistant construction methods, of which fire resistant boards are used to protect buildings and structures from fire. However, in the case of fire resistant boards, the unit price of the main raw material is high and the cost efficiency is low. There have been studies to apply oyster shells to fire resistant boards to solve these problems. On the other hand, egg shells are also considered to be applicable to fire-resistant boards with components like oyster shells, but there is no case of using egg shells as building materials. Therefore, in this study, we confirmed the physical properties of egg shell powers used as mortar filler and compared them with the fire resistant board flexural strength standard. As a result, it was judged that the powder of egg shells could be used as a building material, because the standards for the flexural strength of fire resistant boards were satisfied except for a part.

• Journal of Microbiology and Biotechnology
• /
• v.22 no.8
• /
• pp.1155-1160
• /
• 2012

Sulfur-utilizing autotrophic denitrification relies on an inorganic carbon source to reduce the nitrate by producing sulfuric acid as an end product and can be used for the treatment of wastewaters containing high levels of nitrates. In this study, sulfur-denitrifying bacteria were used in anoxic batch tests with sulfur as the electron donor and nitrate as the electron acceptor. Various medium components were tested under different conditions. Sulfur denitrification can drop the medium pH by producing acid, thus stopping the process half way. To control this mechanism, a 2:1 ratio of sulfur to oyster shell powder was used. Oyster shell powder addition to a sulfur-denitrifying reactor completely removed the nitrate. Using 50, 100, and 200 g of sulfur particles, reaction rate constants of 5.33, 6.29, and $7.96mg^{1/2}/l^{1/2}{\cdot}h$ were obtained, respectively; and using 200 g of sulfur particles showed the highest nitrate removal rates. For different sulfur particle sizes ranging from small (0.85-2.0 mm), medium (2.0-4.0 mm), and large (4.0-4.75 mm), reaction rate constants of 31.56, 10.88, and $6.23mg^{1/2}/l^{1/2}{\cdot}h$ were calculated. The fastest nitrate removal rate was observed for the smallest particle size. Addition of chemical oxygen demand (COD), methanol as the external carbon source, with the autotrophic denitrification in sufficiently alkaline conditions, created a balance between heterotrophic denitrification (which raises the pH) and sulfur-utilizing autotrophic denitrification, which lowers the pH.

• Journal of Conservation Science
• /
• v.23
• /
• pp.103-118
• /
• 2008

Hobun(Oyster shell W.) is a traditional material used as extender and white pigment from ancient times. The production method of it, however, has been discontinued. We have studied the traditional production method of Hobun through calcination of oyster shell, which is one of the traditional ways for preparing Hobun. Our work has the important meaning in that we can reproduce the manufacturing method of the discontinued traditional material and also it provides a solid background knowledge to stabilize the production and supply of Hobun for the cultural asset repairing materials. The result can be summarized as followings: The production processes of Hobun by calcination method are divided into 4 steps - calcination ${\rightarrow}$ slaking(pulverization) ${\rightarrow}$ separating fine powder by submergence in water ${\rightarrow}$ drying. In calcination step, the temperature is required to exceed $700^{\circ}$ to get pure white color of Hobun, since organic materials in the shell cause the final powder to be less white below $600^{\circ}$. And the calcination methods produce significant amount of calcium hydroxide, which is incongruent for pigment materials without additional treatments. The experimental study also demonstrated that the additional treatment process introduced in traditional paintings can be a probable process since the calcium of potassium hydroxide is observed to be promoted by this treatment. It is also concluded that, the calcination method of Hobun is appropriate for a small amount and high quality production.

• Journal of the Korean Ceramic Society
• /
• v.38 no.3
• /
• pp.231-237
• /
• 2001

NaOH 용액 처리로 제조한 개질 굴 패각 미분말은 98.7 wt%의 CaCO$_3$와 1.3 wt%의 chitosan으로 구성되어 있으며, chitosan의 탈아세틸화는 74.9%이었다. 개질화함으로서 입경은 작아지고 비표면적은 증가하였으며, 밀도는 감소하는 경향을 나타냈다. 입자 형상은 모서리가 각지고 매끄러운 형태에서 모서리가 침식되고 표면이 다공성인 환상의 형태로 변화되었다. 개질 굴 패각 미분말을 시멘트 대신 5.0 wt%까지 치환했을 때의 모르터의 압축강도는 치환량이 증가할수록 증가하였고, 흡수율은 치환량이 증가할수록 감소하는 경향을 나타냈다. 굴 패각 미분말은 대장균 및 황색포도상구균에 대해 항균력이 나타나지 않았으나, 개질 굴 패각 미분말은 5.0 wt% 첨가했을 때 99.8-99.9%의 항균력을 나타냈다. 또한 KS M 5000에 의한 항곰팡이 시험은 피막이 변색이나 변형이 전혀 없는 10등급으로 판정되었다.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2017.05a
• /
• pp.75-76
• /
• 2017

In the case of B / a 1: 3, the intensity when the substitution rate increased to 15% showed a tendency to decrease, but it turned out that the strength increased at the substitution rate of 20%. In the case of B / a 1: 4 and 1: 5, it was found that when the substitution rate at the substitution rate of 10% was the highest and the substitution rate increased further, the strength was reduced. However, since the test body does not exist at the age of 3 days and the age of 7 days at the substitution rate of 0%, there is no specimen, so blast furnace slag binder substitution for increasing strength of refractory mortar is judged to be meaningless.

• Journal of Environmental Science International
• /
• v.15 no.11
• /
• pp.1027-1034
• /
• 2006

Antimicrobial powder was made by exchanging silver ion on calcined oyster shell. On the purpose of application to water clarifier, bail-type media mixed with antimicrobial powder and $0{\sim}30%$ white kaoline were made. The sterilization effect, pore size distribution and zeta potential was tested to indicate the condition for the media of water clarifier. From these tests, it was confirmed that this media have an excellent sterilization power on $G^-\;and\;G^+$ germs. As the concentration of the exchanged silver ion increased, the surface charge density of the anions on the surface of the media also increased. The surface pore size decreased with the concentration of silver ion and 20% more white kaoline ratio. Consequently, mixing ratio of white kaoline would appear to indicate the optimun condition as media have sterilization power.

• Journal of Powder Materials
• /
• v.13 no.2 s.55
• /
• pp.102-107
• /
• 2006

Recycling industrial wastes such as fly ash from a coal burning heat power plant and shell from an oyster farming were investigated to prevent environment contamination as well as to enhance the value of recycling materials. In this study, the lightweight aggregates and the red bricks were fabricated from fly ashes with other inorganic materials and wastes. The starting materials of the lightweight aggregate were fly ash powder and water glass, and the compacts of these materials were heat treated at $1100^{\circ}C$. The fabricated lightweight aggregates had low bulk density, $0.9-1.2\;g/cm^3$, hence floated on the water and had the strength of 7.0-11.0 MPa and the modulus of 2900-3300 MPa which indicates it has enough strength as the aggregate. Another type of the light weight aggregate was prepared from fly ashes, shell powders and clays. The bulk density, porosity, and compressive strength of these aggregates were $1.19-1.34\;g/cm^3,\;18.3{\sim}56.1%$ and 5-12 MPa, respectively. The addition of a small amount of fly ash powder prevented hydration of the light weight aggregates. The red brick was also fabricated from the fly ash containing materials. It is suitable for the brick facing of a building as it has moderate strength and low water absorption rate.