• Title/Summary/Keyword: Oxygen transfer model

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Design of Cooling Channels of Preburners for Small Liquid Rocket Engines with Computational Flow and Heat Transfer Analysis

  • Moon, In-Sang;Lee, Seon-Mi;Moon, Il-Yoon;Yoo, Jae-Han;Lee, Soo-Yong
    • Journal of Astronomy and Space Sciences
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    • v.28 no.3
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    • pp.233-239
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    • 2011
  • A series of computational analyses was performed to predict the cooling process by the cooling channel of preburners used for kerosene-liquid oxygen staged combustion cycle rocket engines. As an oxygen-rich combustion occurs in the kerosene fueled preburner, it is of great importance to control the wall temperature so that it does not exceed the critical temperature. However, since the heat transfer is proportional to the speed of fluid running inside the channel, the high heat transfer leads to a trade-off of pressure loss. For this reason, it is necessary to establish a certain criteria between the pressure loss and the heat transfer or the wall surface temperature. The design factors of the cooling channel were determined by the computational research, and a test model was manufactured. The test model was used for the hot fire tests to prove the function of the cooling mechanism, among other purposes.

Decarbonization Kinetics of Molten Iron by Ar+O2 Gas Bubbling (Ar+O2 혼합가스 취입에 의한 용철의 탈탄 반응속도)

  • Sohn, Ho-Sang;Jung, Kwang-Hyun
    • Korean Journal of Metals and Materials
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    • v.47 no.2
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    • pp.107-113
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    • 2009
  • Molten iron with 2 mass % carbon content was decarbonized at 1823 K~1923 K by bubbling $Ar+O_2$ gas through a submerged nozzle. The reaction rate was significantly influenced by the oxygen partial pressure and the gas flow rate. Little evolution of CO gas was observed in the initial 5 seconds of the oxidation; however, this was followed by a period of high evolution rate of CO gas. The partial pressure of CO gas decreased with further progress of the decarbonization. The overall reaction is decomposed to two elementary reactions: the decarbonization and the dissolution rate of oxygen. The assumptions were made that these reactions are at equilibrium and that the reaction rates are controlled by mass transfer rates within and around the gas bubble. The time variations of carbon and oxygen contents in the melt and the CO partial pressure in the off-gas under various bubbling conditions were well explained by the mathematical model. Based on the present model, it was explained that the decarbonization rate of molten iron was controlled by gas-phase mass transfer at the first stage of reaction, but the rate controlling step was transferred to liquid-phase mass transfer from one third of reaction time.

Relationships between Biodegradation and Sorption of Phenanthrene in Slurry Bioremediation

  • ;;Bruce E. Rittmann
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.11a
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    • pp.171-176
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    • 2000
  • Bioremediation of hazardous hydrophobic organic compounds, such as polycyclic aromatic hydrocarbons (PAHs), is a major environmental concern due to their toxic and carcinogenic properties. Due to their hydrophobicity, the hydrophobic organic compounds are mainly associated with the soil organic matter or nonaqueous-phase liquids. A major question concerns the relationships between biodegradation and sorption. This work develops and utilizes a non- steady state model for evaluating the interactions between sorption and biodegradation of phenanthrene, a 3-ring PAH compound, in soil-slurry systems. The model includes sorption/desorption of a target compound, its utilization by microorganisms as a primary substrate existing in the dissolved phase and/or the sorbed phase in biomass and soil, oxygen transfer, and oxygen utilization as an electron acceptor. Biodegradation tests with phenanthrene were conducted in liquid and soil-slurry systems. The soil-slurry tests were performed with very different mass transfer rate: fast mass transfer in a flask test at 150 rpm, and slow mass transfer in a roller-bottle test at 2 rpm. In the slurry tests, phenanthrene was degraded more rapidly than in liquid tests, but with a similar rate in both slurry systems. Modeling analyses with several hypotheses indicate that a model without biodegradation of compound sorbed to the soil was not able to account for the rapid degradation of phenanthrene, particularly in the roller bottle slurry test. Reduced mass-transfer resistance to bacteria attached to the soil is the most likely phenomenon accounting for rapid sorbed-phase biodegradation.

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Simulation of oxygen mass transfer in fuel assemblies under flowing lead-bismuth eutectic

  • Feng, Wenpei;Zhang, Xue;Chen, Hongli
    • Nuclear Engineering and Technology
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    • v.52 no.5
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    • pp.908-917
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    • 2020
  • Corrosion of structural materials presents a critical challenge in the use of lead-bismuth eutectic (LBE) as a nuclear coolant in an accelerator-driven system. By forming a protective layer on the steel surfaces, corrosion of steels in LBE cooled reactors can be mitigated. The amount of oxygen concentration required to create a continuous and stable oxide layer on steel surfaces is related to the oxidation process. So far, there is no oxidation experiment in fuel assemblies (FA), let alone specific oxidation detail information. This information can be, however, obtained by numerical simulation. In the present study, a new coupling method is developed to implement a coupling between the oxygen mass transfer model and the commercial computational fluid dynamics (CFD) software ANSYS-CFX. The coupling approach is verified. Using the coupling tool, we study the oxidation process of the FA and investigate the effects of different inlet parameters, such as temperature, flow rate on the mass transfer process.

The design of an ejector type microbubble generator for aeration tanks

  • Lim, Ji-Young;Kim, Hyun-Sik;Park, Soo-Young;Kim, Jin-Han
    • Membrane and Water Treatment
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    • v.10 no.4
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    • pp.307-311
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    • 2019
  • The ejector type microbubble generator, which is the method to supply air to water by using cavitation in the nozzle, does not require any air supplier so it is an effective and economical. Also, the distribution of the size of bubbles is diverse. Especially, the size of bubbles is smaller than the bubbles from a conventional air diffuser and bigger than the bubbles from a pressurized dissolution type microbubble generator so it could be applied to the aeration tank for wastewater treatment. However, the performance of the ejector type microbubble generator was affected by hydraulic pressure and MLSS(Mixed Liquor Suspended Solid) concentration so many factors should be considered to apply the generator to aeration tank. Therefore, this study was performed to verify effects of hydraulic pressure and MLSS concentration on oxygen transfer of the ejector type microbubble generator. In the tests, the quantity of sucked air in the nozzle, dissolved oxygen(DO) concentration, oxygen uptake rate(OUR), oxygen transfer coefficient were measured and calculated by using experimental results. In case of the MLSS, the experiments were performed in the condition of MLSS concentration of 0, 2,000, 4,000, 8,000 mg/L. The hydraulic pressure was considered up to $2.0mH_2O$. In the results of experiments, oxygen transfer coefficient was decreased with the increase of MLSS concentration and hydraulic pressure due to the increased viscosity and density of wastewater and decreased air flow rate. Also, by using statistical analysis, when the ejector type microbubble generator was used to supply air to wasterwater, the model equation of DO concentration was suggested to predict DO concentration in wastewater.

ASPHERICAL DUST ENVELOPES AROUND OXYGEN-RICH AGB STARS

  • Suh, Kyung-Won
    • Journal of Astronomy and Space Sciences
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    • v.23 no.4
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    • pp.303-310
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    • 2006
  • We model the aspherical dust envelopes around O-rich AGB stars. We perform the radiative transfer model calculations for axisymmetric dust distributions. We simulate what could be observed from the aspherical dust envelopes around O-rich AGB stars by presenting the model spectral energy distributions and images at various wave-lengths for different optical depths and viewing angles. The model results are very different from the ones with spherically symmetric geometry.

Photosensitized oxidative damage of human serum albumin by water-soluble dichlorophosphorus(V) tetraphenylporphyrin

  • Ouyang, Dongyan;Hirakawa, Kazutaka
    • Rapid Communication in Photoscience
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    • v.4 no.2
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    • pp.41-44
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    • 2015
  • Biomolecular photo-damaging activity of a water-soluble cationic porphyrin was examined using human serum albumin (HSA), a water-soluble protein as a target biomolecule model by a fluorometry. Dichlorophosphorus(V) tetraphenylporphyrin ($Cl_2P(V)TPP$), was synthesized and used as a photosensitizer. This porphyrin could bind to HSA and cause the photosensitized oxidation of HSA through the singlet oxygen generation and the oxidative photo-induced electron transfer (ET). Near infrared emission spectroscopy demonstrated the photosensitized singlet oxygen generation by this porphyrin. Decrement of the fluorescence lifetime of $Cl_2P(V)TPP$ by HSA supported the ET mechanism. Furthermore, the estimated Gibb's energy indicated that the ET mechanism is possible in the terms of energy. Because oxygen concentration in cancer cell is relatively low, ET mechanism is considered to be advantageous for photosensitizer of photodynamic therapy.

Effects of Energy Input and Air Flow Rate on Oxygen Transfer Rate at Different MLVSS in a Jet Loop Reactor (JLR) (MLVSS에 따른 Jet Loop Reactor (JLR)에서 동력량과 공기량이 산소전달률에 미치는 영향)

  • Yoon, Ae-Hwa;Bae, Jong-Hun;Lim, Hyun-Woo;Jun, Hang-Bae;Huh, Tae-Young
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.12
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    • pp.868-873
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    • 2011
  • Oxygen transfer rate generally determines the performance of an aerobic wastewater treatment process that treats high strength wastewater such as food wastewater, animal wastewater and landfill leachate. In this paper, OUR and $K_L{\cdot}a$ were evaluated by using Jet Loop Reactor (JLR) according to the concentration of a mixed liquor volatile suspended solid (MLVSS), oxygen (air) flow rate and energy input as the variable of the operating conditions. Also, a nonlinear regression model was proposed by the statistical methods with the calculated $K_L{\cdot}a$. As a results, in case of applying the high strength wastewater which has to maintain high MLVSS, the energy input and the air flow rate are major parameters oxygen transfer rate in JLR. Finally, the final nonlinear regression model had been developed as a function of E/V, $Q_g$, and ${\mu}_c$.

Transport Phenomena in Solid State Fermentation: Oxygen Transport in Static Tray Fermentors

  • Muniswaran, P.K.A.;Moorthy, S.Sundara;Charyulu, N.C.L.N.
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.7 no.6
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    • pp.362-366
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    • 2002
  • A mathematical model has been developed for describing the oxygen concentration during the exponential growth of microorganisms, in a static solid substrate bed supported on a tray fermentor. The model equations comprise of one partial differential equation for mass transfer and an ordinary differential equation of growth. After nondimensionlisation, analytical solution tn the model has been obtained by the method of Laplace transforms. An expression for critical thickness of bed is deduced from the model equation. The significance of the model in the design of tray fermentors is discussed. The validity of the discussion is verified by taking an illustration from the literature.

DUST SHELL MODELS FOR LOW MASS-LOSS RATE OXYGEN-RICH AGB STARS

  • SUH KYUNG-WON
    • Journal of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.267-270
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    • 2005
  • We investigate the spectral energy distributions (SEDs) of low mass-loss rate O-rich asymptotic giant branch (AGB) stars using the infrared observational data including the Infrared Space Observatory (ISO) data. Comparing the results of detailed radiative transfer model calculations with observations, we find that the dust formation temperature is much lower than 1000 K for standard dust shell models. We find that the superwind model with a density-enhanced region can be a possible alternative dust shell model for LMOA stars.