• Title/Summary/Keyword: Oxygen mass transfer

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Research and Optimization of Four Serpentine-Wave Flow Fields in PEMFC

  • Fayi Yan;He Lu;Jian Yao;Xuejian Pei;Xiang Fan
    • Journal of Electrochemical Science and Technology
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    • v.15 no.3
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    • pp.373-387
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    • 2024
  • The layout of the cathode flow field largely determines the net output power of the proton exchange membrane fuel cell (PEMFC). To make the normal mass transfer effect best, the longitudinal channel was waved based on four serpentine flow channels, and the effects of sag depth and longitudinal channel width on the output efficiency of the cell were explored. The results show that the wave channel design systematically enhances the forced convection between adjacent channels, which can prevent a large zone of oxygen starvation zone at the outlet of the channel. The increase of the normal velocity in the gas transmission process will inevitably induce a significant enhancement of the mass transfer effect and obtain a higher current density in the reaction zone. For the longitudinal channel width, it is found that increasing its size in the effective range can greatly reduce the channel pressure drop without reducing the output power, thereby improving the overall efficiency. When the sag depth and longitudinal channel width gradient are 0.6 mm and 0.2 mm respectively, PEMFC can obtain the best comprehensive performance.

Enhancement of Mass Transfer Using Piezoelectric Material in Fluid Flow System

  • Kim, Gi-Beum;Chong, Woo-Suk;Kwon, Tae-Kyu;Hong, Chul-Un;Kim, Nam-Gyun;Jheong, Gyeong-Rak
    • 제어로봇시스템학회:학술대회논문집
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    • 2004.08a
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    • pp.165-170
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    • 2004
  • The purpose of this work was to assess and quantify the beneficial effects of long-term gas exchange, at varying frequencies, for the development of a vibrating intravascular lung assistance device (VIVLAD), for patients suffering from acute respiratory distress syndrome (ARDS). The experimental design and procedure have been applied to the construction of a new device for assessing the effectiveness of membrane vibrations. An analytical solution has been developed for the hydrodynamics of flow through a bundle of sinusoidally vibrated hollow fibers, with the intention of gaining insight into how wall vibrations might enhance the performance of the VIVLAD. As a result, the maximum oxygen transfer rate was reached at the maximum amplitude and through the transfer of vibrations to the hollow fiber membranes. The device was excited by a frequency band of 7Hz at various water flow rates, as this frequency was the 2nd mode resonance frequency of the flexible beam. 675 hollow fiber membranes were also bundled, within the blood flow, into the device.

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Improved adsorption performance of heavy metals by surface modification of polypropylene/polyethylene media through oxygen plasma and acrylic acid

  • Hong, Jeongmin;Lee, Seungwoo;Ko, Dongah;Gwon, Eunmi;Hwang, Yuhoon
    • Membrane and Water Treatment
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    • v.11 no.3
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    • pp.231-235
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    • 2020
  • Industrialization and modern developments have led to an influx of toxic heavy metals into the aquatic environment, and the accumulation of heavy metals has serious adverse effects on humans. Among the various heavy metal treatment methods, adsorption is very useful and frequently used. Plastic materials, such as polypropylene and polyethylene, have been widely used as filter media due to their mechanical and chemical stability. However, the surface of plastic material is inert and therefore the adsorption capability of heavy metals is very limited. In this study, granular media and fiber media composed of polypropylene and polyethylene are used, and the surface modification was conducted in order to increase adsorption capability toward heavy metals. Oxygen plasma generated hydroxyl groups on the surface of the media to activate the surface, and then acrylic acid was synthesized on the surface. The grafted carboxyl group was confirmed by FT-IR and SEM. Heavy metal adsorption capability of pristine and surface modified adsorbents was also evaluated. Overall, heavy metal adsorption capability was increased by surface modification due to electrostatic interaction between the carboxyl groups and heavy metal ions. Fibrous PP/PE showed lower improvement compared to granular PP media because pore blockage occurred by the surface modification step, thereby inhibiting mass transfer.

Effect of non-uniform magnetic field on the thermal behavior and mass transfer in magnetohydrodynamic Czochralski crystal growth of silicon (Magnetic Czochralski 실리콘 단결정 성장에서 열 및 유체유동과 질량전달에 미치는 비균일 자장의 효과)

  • 김창녕
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.4
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    • pp.555-562
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    • 1998
  • Under the influence of non-uniform magnetic field, melt flow in steady state and oxygen concentration in unsteady state are numerically investigated. The strength of the applied characteristic magnetic fields are B=0.1T, 0.2T, and 0.3T, respectively. The buoyancy effects due to the crucible wall heating and the thermocapillary effects due to the surface tention at the free surface are suppressed differentially by the non-uniform magnetic fields. As the intensity of characteristic magnetic fields is increasing, the recirculation region in the meridional plane is moving toward the growing crystal, and is diminishing. The oxygen concentration on the growing surface of crystals is decreasing and the uniformity of the oxygen concentration is increasing as the intensity of the magnetic fields is increasing.

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Effect of Pluronic F-68 and Oxygen Vectors on Cell Growth of Angelica gigas Nakai in Fed-batch Culture

  • Jeon, Su-Hwan;Lee, Sang-Yun;Jo, Ji-Suk;Min, Byeong-Hyeok;Kim, Dong-Il
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.159-162
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    • 2000
  • It has been commonly known that cell growth is inhibited by the lack of dissolved oxygen and mass transfer inhibition of nutrients at stationary phase in fed-batch culture. In this study, Pluronic F-68 and oxygen vectors were added in Angelica gigas Nakai suspension culture in order to enhance cell growth in fed-batch culture. It was observed that the addition of 6%(w/v) Pluronic F-68 promoted cell growth up to 6.1% compared to control and that the use of 4%(v/v) n-hexadecane markedly enhanced cell growth up to 11.4%.

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Development and Performance Tests of the Waste Water Diffusers using Acoustic Resonance and Oscillatory Pulsation (음향공진과 맥진동 현상을 이용한 폐수처리용 산기관 개발 및 성능시험)

  • Hong, Suk-Yoon;Moon, Jong-Duck
    • The Journal of the Acoustical Society of Korea
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    • v.15 no.6
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    • pp.52-58
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    • 1996
  • Using the acoustic resonances and oscillatory pulsations considered as the branch of wave technologies, the concept of the acoustic resonance diffusers for waste water treatment which maximize the oxygen transfer efficiency in gas-liquid two phase medium have been proposed, and studies for the principles and performance tests were accomplished. Besides, the design concepts for the low pressure Helmholtz resonator, cylinder and annular type reflection resonator and combined type resonance system have been implemented. The acoustic resonance energy which can speed up the mass transfer process increase the oxygen transfer efficiency, and periodic pulsations generated from the instability of air jet from nozzle make very small air bubbles. Then, the annular type jet resonator(AJR) applying these two principles successfully was evalulated as the most promising device and also the efficiency showing $20{\sim}30%$ better than conventional diffusers has been verified experimentally.

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Production of high dissolved O2/O3 with rotating wheel entraining gas method for environmental application

  • Li, Haitao;Xie, Bo;Hui, Mizhou
    • Advances in environmental research
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    • v.2 no.1
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    • pp.1-8
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    • 2013
  • There is a significant demand to make various dissolved gases in water. However, the conventional aeration method shows low gas mass transfer rate and gas utilization efficiency. In this study, a novel rotating wheel entraining gas method was developed for making high dissolved $O_2$ and $O_3$ in water. It produced higher concentration and higher transfer rate of dissolved $O_2$ and $O_3$ than conventional bubble aeration method, especially almost 100% of gas transfer efficiency was achieved for $O_3$ in enclosed reactor. For application of rotating wheel entraining gas method, aerobic bio-reactor and membrane bio-reactor (MBR) were successfully used for treatment of domestic and pharmaceutical wastewater, respectively; and vacuum ultraviolet $(VUV)/UV+O_3/O_2$ reactors were well used for sterilization in air/water, removal of dust particles and toxic gases in air, and degradation of pesticide residue and sterilization on fruits and vegetables.

IRAS 09425-6040: A Silicate Carbon Star with Crystalline Dust

  • Suh, Kyung-Won;Kwon, Young-Joo
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.2
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    • pp.140.2-140.2
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    • 2012
  • The silicate carbon star IRAS 09425-6040 shows very conspicuous crystalline silicate dust features and excessive emission at far infrared. To investigate properties of dusty envelopes around the object, we use radiative transfer models for axisymmetric and sphericallly symmetric dust distributions. We perform model calculations for various possible combinations of dust shells and disks with various dust species. We compare the model results with the observed spectral energy distributions (SEDs) including the IRAS, ISO, AKARI, MSX and 2MASS data. We find that a model with multiple disks of amorphous and crystalline silicate and multiple spherical shells of carbon dust can reproduce the observed SED fairly well. This supports the scenario for the origin of silicate carbon stars that oxygen-rich material was shed by mass loss when the primary star was an M giant and the O-rich material is stored in a circumbinary disk. Highly (about 75 %) crystallized forsterite dust in the disk can reproduce the conspicuous crystalline features of the ISO observational data. This object looks to have a detached silicate and H2O ice shell with a much higher mass-loss rate. It could be a remnant of the chemical transition phase. The last phase of stellar winds of O-rich materials looks to be a superwind.

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Membrane Diffuser Coupled Bioreactor for Methanotrophic Denitrification under Non-aerated Condition: Suggestion as a Post-denitrification Option

  • Lee, Kwanhyoung;Choi, Oh Kyung;Song, Ji Hyun;Lee, Jae Woo
    • Environmental Engineering Research
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    • v.19 no.1
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    • pp.75-81
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    • 2014
  • Methanotrophic denitrification under a non-aerated condition (without external supply of oxygen or air) was investigated in a bioreactor coupled with a membrane diffuser. Batch experiment demonstrated that both methane consumption and nitrogen production rates were not high in the absence of oxygen, but most of the nitrate was reduced into $N_2$ with 88% recovery efficiency. The methane utilized for nitrate reduction was determined at 1.63 mmol $CH_4$/mmol $NO_3{^-}$-N, which was 2.6 times higher than the theoretical value. In spite of no oxygen supply, methanotrophic denitrification was well performed in the bioreactor, due to enhanced mass transfer of the methane by the membrane diffuser and utilization of oxygen remaining in the influent. The denitrification efficiency and specific denitrification rate were 47% and 1.69 mg $NO_3{^-}-N/g\;VSS{\cdot}hr$, respectively, which were slightly lower than for methanotrophic denitrification under an aerobic condition. The average concentration of total organic carbon in the effluent was as low as 2.45 mg/L, which indicates that it can be applicable as a post-denitrification method for the reclamation of secondary wastewater effluent. The dominant fatty acid methyl ester of mixed culture in the bioreactor was $C_{16:1{\omega}7c}$ and $C_{18:1{\omega}7c}$, which was predominantly found in type I and II methanotrophs, respectively. This study presents the potential of methanotrophic denitrification without externally excess oxygen supply as a post-denitrification option for various water treatment or reclamation.

Characteristics of (Ba,Sr)RuO$_3$Bottom Electrodes by Liquid Delivery Metalorganic Chemical Vapor Deposition (액체 운반 유기 금속 화학 기상 증착법에 의한 $(Ba,Sr)RuO_3$ 하부전극의 특성)

  • Choe, Eun-Seok;Yun, Sun-Gil
    • Korean Journal of Materials Research
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    • v.11 no.11
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    • pp.997-1000
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    • 2001
  • Conducting perovskite oxide, $(Ba,Sr)RuO_3(BSR)$, which has many advantages for $(Ba,Sr)TiO_3(BST)$ due to their similarity in crystal structure, lattice constant and chemical composition, was prepared on n-type Si (100) by liquid delivery metalorganic chemical vapor deposition(LDMOCVD). The deposition characteristics of BSR were controlled by gas-phase mass-transfer in the experiment. The BSR films deposited at 50$0^{\circ}C$ and oxygen flow rate of 100 sccm(standard cc/min) showed an average roughness of 22 $\AA$and resistivity of 810 $\mu$$\Omega$-cm. The roughness of BSR films with oxygen flow rate showed a close relationship with the resistivity of films. BSR (110) peak shifted toward lower Bragg angle with increase of x in the$(Ba_x,Sr_{1-x})TiO_3$. The resistivity of BSR films increased from 810 to 924 $\mu$$\Omega$-cm with increase of Ba content(x).

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