• Journal of the Korean Ceramic Society
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• v.40 no.11
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• pp.1102-1105
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• 2003

The fiber drawing process induced defects in silica fiber have been investigated. This study has focused on the Oxygen Deficient Centers (ODCs) and E' centers induced by the fiberization process in low-OH silica fibers. To investigate those defects induced by the fiberization process, the optical absorption spectrum and Electron Spin Resonance (ESR) have both been employed. The concentration of Oxygen Deficient Centers (ODCs) and E' centers are increased by the fiber drawing process. The population of defects in the neck-down region has also been investigated. The most significant generation of defects during fiber drawing process has been shown to occur in this region of silica preform. The population of defects is higher on the edge region than in the center of neck-down region.

• Environmental Analysis Health and Toxicology
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• v.24 no.3
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• pp.181-191
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• 2009

As an effort to prevent serious accidents involving oxygen deficiency and suffocation in confined spaces and to identify the causes of such accidents, the present study investigated relevant accidents and systems in Korea and other countries. This study also conducted a number of experiments at lethal concentration levels of oxygen deficiency using SD rats and observed the changes of experimental animals with humidity, organic gas (toluene), hydrogen sulfide, carbon monoxide and so on at the oxygen deficient environment. The results of the study are as follows. 1. The results from the experiment conducted using SD rats at lethal concentration levels of oxygen showed that there were no casualties at the 7% oxygen concentration level, but the mortality increase to 20% at 6% oxygen, it was jumped to 90% at 5% oxygen, and it was also dramatically reached 100% at 4% oxygen concentration. Therefore, 5.5% was calculated as the $LC_{50}$ (rat, 4hr) from these dose-response experiments with oxygen deficiency. 2. When we changed the level of toluene, $H_2S$, CO, humidity, and so on, in an oxygen deficient environment, it was observed that the small concentrations of $H_2S$ and CO make the highest effect on animals. In case of 350 ppm $H_2S$, it resulted in 30% mortality, and the 100% mortality was shown in 1,200 ppm CO concentration. The mortality increased as an oxygen deficient condition. However in the case of toluene up to 1,000 ppm, it were not affected with oxygen deficiency, and it did not indicate any significant differences in mortality as 20%, 90% humidities.

• Journal of the Korean Society for Marine Environment & Energy
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• v.9 no.4
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• pp.216-224
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• 2006

To clarify the formation process and characteristics of oxygen deficient water mass in Gamak Bay, oxygen deficiency was weekly observed from 17 June to 12 September 2005. Surface water temperature was significantly lower in the outer bay than in the inner bay, whereas the bottom water temperature was higher in the central area of bay than in the outer and inner bay. The vertical stratification of water mass was strongly formed during the period, and thermocline was observed between 3 and 5m deep. The oxygen deficiency in the bottom layer began to appear at early July in the inner bay and gradually spread to the center area of the bay in early August. The mean transparency and light attenuation coefficient($K_d$) in water mass was 4.0m and 0.47, respectively. Average concentrations of nutrient and chlorophyll ${\alpha}$ in the bottom layer were significantly higher than those in surface, and those concentrations were significantly higher in the inner bay than in the outer bay. During the formation of oxygen deficiency in the bottom layer, oxygen penetration depth in the bottom sediment were extremely shallow, and oxygen consumption rate in the bottom sediment were lower than that in the area where oxygen deficient water mass disappeared. Dissolved oxygen concentrations in the bottom layer are negatively correlated with nutrient concentrations, whereas those in the surface layer did not show a significant relationship with nutrient concentrations. Elevated loss of oxygen in the bottom water mass was attributed to the increase of the oxygen consumption rates in sediments and the decomposition of organic matter by microorganism.

• Journal of Hydrogen and New Energy
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• v.15 no.1
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• pp.32-38
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• 2004

Thermal behaviors of $(Cu_{0.5}Mn_{0.5})Fe_2O_4$, prepared by a solid method, were investigated for $H_2$ production by a thermochemical cycle. The thermal reduction of $(Cu_{0.5}Mn_{0.5})Fe_2O_4$ started from $300^\circ{C}$ and the weight loss was 1.3 wt% up to 1200. XRD shows the prepared ferrite has the spinel structure with a lattice constant of $8.414{\AA}$ and changed to the oxygen deficient structure by thermal reduction. Oxygen and hydrogen can be separately produced by the cycles of thermal reduction and water oxidation of the oxygen deficient ferrite.

• Journal of the Korean Vacuum Society
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• v.12 no.4
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• pp.269-274
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• 2003

The electrical, optical and structural properties of ZnNiO thin _ films deposited on Si substrates using rf-magnetron sputtering method have been investigated before and after the thermal annealing processes. The crystallinity of the ZnNiO thin film become degraded with increasing the Ni contents. This is mainly because the lattice of the thin film was expanded due to the oxygen-deficient conditions. Concerning the electrical properties of the thin film, the carrier concentration increases ($6.81\times10^{14}\textrm{cm}^{-2}$) and Hall mobility decreases (36.3 $\textrm{cm}^2$/Vㆍs) with higher doping concentration of Ni. However, the carrier concentration and Hall mobility became low ($1.10\times10^{14}\textrm{cm}^2$ and high (209.6 $\textrm{cm}^2$/Vㆍs), respectively, after the thermal annealing process at $1000 ^{\circ}C$. We also observed a strong luminescene center peaking at 546 nm in photoluminescence spectra, which was caused by a deep level center in the ZnO band gap with oxygen deficient ZnNiO structure.

• BMB Reports
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• v.41 no.2
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• pp.164-169
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• 2008

The tumor suppressor gene p53 regulates apoptotic cell death and the cell cycle. In this study, we investigated the role of p53 in nitric oxide (NO)-induced apoptosis in vascular smooth muscle cells (VSMCs). We found that the NO donor S-nitroso-N-acetyl-penicillamine (SNAP) increased apoptotic cell death in p53-deficient VSMCs compared with wild-type cells. The heme oxygen-ase (HO) inhibitor tin protoporphyrin IX reduced the resistance of wild-type VSMCs to SNAP-induced cell death. SNAP promoted HO-1 expression in both cell types. HO-2 protein was increased only in wild-type VSMCs following SNAP treatment; however, similar levels of HO-2 mRNA were detected in both cell types. SNAP significantly increased the levels of non-heme-iron and dinitrosyl iron-sulfur clusters in wild-type VSMCs compared with p53-deficient VSMCs. Moreover, pretreatment with FeSO4 and the carbon monoxide donor CORM-2, but not biliverdin, significantly protected p53-deficient cells from SNAP-induced cell death compared with normal cells. These results suggest that wild-type VSMCs are more resistant to NO-mediated apoptosis than p53-deficient VSMCs through p53-dependent up-regulation of HO-2.

• Journal of Ocean Engineering and Technology
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• v.22 no.5
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• pp.75-82
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• 2008

As a basic study for establishing a countermeasure for an oxygen deficient water mass (ODW), we investigated the variation of ODW volume according to the enforced total pollution load management in Jinhae Bay. This study estimated the inflowing pollutant loads into Jinhae Bay and predicted the reduction in ODW by using a sediment-water ecological model (SWEM). The result obtained in this study are summarized as follows: 1) The daily average pollutant loads of COD, SS, TN, TP, DIN, and DIP inflowing into Jinhae bay in 2005 were estimated to be about 12,218 kg-COD/day, 91,884 kg-SS/day, 5,292 kg-TN/day, 182 kg-TP/day, 4,236 kg-DIN/day, and 130 kg-DIP/day. 2) The calculated results of the tidal current by the hydrodynamic model showed good agreement with the observed currents. Also, an ecological model well reproduced the spatial distribution of the water quality in the bay. 3) This study defined the ODWDI (ODW decreasing index) in order to estimate the ODW decreasing volume caused by a reduction in the inflowing pollutant loads. As a result, the ODWDI was predicted to be about 0.91 (COD 30% reduction), 0.87 (COD 50% reduction), 0.79 (COD 70% reduction), 0.85 (ALL 30% reduction), 0.66 (ALL 50% reduction), and 0.45 (ALL 70% reduction). The ODW volume was decreased 1.5 $\sim$ 2.6 times with a reduction in the COD, TN, and TP inflowing pollutant loads compared to a reduction in just the COD inflowing pollutant load. Therefore, it is necessary to enforce total pollution load management, not only for COD, but also fm TN and TP.

• The Korean Journal of Ceramics
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• v.4 no.2
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• pp.128-135
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• 1998

The paper gives a brief introduction to protonic defects and their chemistry, thermodynamics and transport in oxides. The temperature dependence of the equilibrium concentration of protons is illustrated and compared for different acceptor-doped oxides. The difficulties of saturating as well as emptying the oxides of protons are discussed. In order to illustrate the possibility of lattice relaxation of defects, a conceptual study is made of a case where the enthalpy of dissolution of protons(water) at the cost of oxygen vacancies is assumed dependent on the concentration of vacancies. It is shown how this changes the behavior of hydration curves vs temperature and water vapour pressure. finally, a discussion is given on the water uptake in heavily oxygen deficient oxides; how water uptake may affect order-disorder in the oxygen sublattice and eventually lead to defective, disordered or ordered oxyhydroxides or hydroxides of potential interest as intermediate temperature proton conductions.

• Journal of Hydrogen and New Energy
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• v.14 no.4
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• pp.298-304
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• 2003

The thermal behavior of $NiFe_2O_4$ prepared by a solid-state reaction was investigated for $H_2$ generation by the thermochemical cycle. The reduction of $NiFe_2O_4$ started from $800^{\circ}C$, and the weight loss was 0.2-0.3 wt% up to $1000^{\circ}C$. In the $H_2O$ decomposition reaction, $H_2$ was generated by oxidation of reduced $NiFe_2O_4$. The crystal structure of $NiFe_2O_4$ maintained during the redox reaction of 5 cycles. From this observation, the lattice oxygen in $NiFe_2O_4$ is released without the structural change during the thermal reduction and oxygen deficient $NiFe_2O_4$ can be restored to the spinel structure of $NiFe_2O_4$.

• Journal of the Korean Society of Marine Environment & Safety
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• v.24 no.6
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• pp.726-734
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• 2018

The total number of Sea Area Utilization Consultation in the environment management sea areas reviewed from 2015 to 2017 were 60. The number of development projects in the environment conservation sea areas decreased steadily, but special management sea areas increased. Development types in environment management sea areas showed that artificial structure installation was the highest ratio, followed by fishery port development and construction of habor and coastal maintenance and sea water intake and draining. By comparing the trend of water quality changes using marine environment information system (MEIS) data in the environment management areas from 2006 to 2017, COD showed no significant changes but the environment conservation sea areas increased slightly, and the concentration of TN and TP decreased. Gwangyang and Masan bays in the special management sea areas and Gamak bay in the environment conservation sea areas displayed oxygen deficient mass in the summer. As the use of development projects of the environment management sea areas are performed continuously, an analysis of the status of sufficient water quality changes is necessary for environmental impact assessment (Sea Area Utilization Consultation) in the marine environment and should be evaluated mainly for management of contamination by diagnosing thoroughly water quality effects and the pollution of sediment. Especially, the water quality goal for the purpose of designation in each of the environment management sea areas is set clearly, connection with pollution source control and the total pollution load management system (TPLMS) should be proposed and measured to reduce the amount of contaminated water.