• Title/Summary/Keyword: Oxygen atmosphere

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Influence of the tempering and magnetic annealing on soft magnetic properties for the KM35F alloy (템퍼링 및 자장열처리가 KM35F 합금의 연자성 특성에 미치는 영향)

  • Park, Byung-Ki;Jeon, Yong-Sik;Kim, Dong-Soo
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.1240-1243
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    • 2008
  • The tempering and magnetic annealing are used to improve the soft magnetic properties such as initial permeability coercivity and core loss of the KM35F alloy. The first heat treatmentis performed at the temperature less than the curie temperature of the KM35F alloy to remove the thermal stress for few hours in nitrogen atmosphere. The second stage heat treatment is performed the magnetic annealing at $500{\sim}800^{\circ}C$ for few hours in nitrogen atmosphere, and then quenching to room temperature in absence of oxygen. Finally, magnetic properties of the thermally treated KM35F alloy are investigated for application as a soft magnetic material of the ISO solenoid valve core and plunger.

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Respiration rate of the Fuji apple according to the ULO storage conditions (ULO 저장에서의 사과 Fuji의 호흡속도)

  • Gang, Jun-Su;Lee, Ho-Jae;Choe, Jong-Uk
    • Food Science and Preservation
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    • v.1 no.2
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    • pp.87-92
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    • 1994
  • For the measurement of the change of respiration rate caused by the gas content of storage atmosphere which furnishes important data for the interpretation of ULO storage, GC was used. It has been shown that the respiration rate and respiratory heat generation rate of Fuji apple is more than doubled in normal low temperature storage when compared with ULO storage, and that in ULO storage the respiration rate and respiratory heat generation rate directly proportional to the concentration of O2 in storage atmosphere as well as inversely proportional to that of CO2. It was possible to establish a functional formula for the respiratory heat generation rate of Fuji apple in all the storage conditions in terms of u=-0.7638+0.0003 O2-0.0007 log(CO2)+0.1369 log(Tb) concerning temperature and the concentration of O2 and CO2

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The Luminescence Property of Ba-Mg-Al-O:$Eu^2+$ Blue Phosphors (Ba-Mg-Al-O:$Eu^2+$ 청색형광체의 발광특성)

  • 김광복;천희곤;조동율;구경완
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.157-161
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    • 2000
  • Blue phosphor of Ba-Mg-Al-O:Eu$^{2+}$ phase was fabricated by conventional firing techniques under reducing atmosphere and its photoluminescence properties are studied with varying Eu concentration and phost-annealing temperature under air atmosphere. This phosphors were well crystallized with particle size in the range of 3~5um and emitted a blue light at a dominent wavelength 450nm for 254nm UV irradiation. The concentration quenching wit Eu$^{2+}$ was that with increasing Eu concentration the energy transfer between the activator ions steadily improves, so that the excitation energy is transported over larger distances through the lattice before luminescence can occur. Thermal quenching also occurred in this phosphor means that in a host lattice with the $\beta$-alumina structure the bond of an Eu$^{2+}$ ion with the nearest-neighbour oxygen ion is much stronger than in a lattice with the magnetoplumbite structure.cture.

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Synthesis of Ultrafine TiC-15%Co Powder by Thermochemical Method (열화학적 방법에 의한 초미립 TiC-15%Co 분말의 합성)

  • 홍성현;탁영우;김병기
    • Journal of Powder Materials
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    • v.10 no.4
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    • pp.281-287
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    • 2003
  • Ultrafine TiC-15%Co powders were synthesized by a thermochemical process, including spray drying, calcination, and carbothermal reaction. Ti-Co oxide powders were prepared by spray drying of aqueous solution of titanium chloride and $Ti(OH)_2$ slurry, both containing cobalt nitrate, fellowed by calcination. The oxide powders were mixed with carbon powder to reduce and carburize at 1100~125$0^{\circ}C$ under argon or hydrogen atmosphere. Ultrafine TiC particles were formed by carbothermal reaction at 1200~125$0^{\circ}C$, which is significantly lower than the formation temperature (~1$700^{\circ}C$) of TiC particles prepared by conventional method. The oxygen content of TiC-15%Co powder synthesized under hydrogen atmosphere was lower than that synthesized under argon, suggesting that hydrogen accelerates the reduction rate of Ti-Co oxides. The size of TiC-15%Co powder was evaluated by FE-SEM and TEM and Identified to be smaller than 300 nm.

A Thermal Decomposition Characteristics of Propellants for Safety Bag (에어백용 가스발생제의 열분해 특성)

  • 이내우
    • Journal of the Korean Society of Safety
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    • v.11 no.4
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    • pp.97-106
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    • 1996
  • Some of accidents are based on unstable chemical substances. These chemicals are easily decomposed or Ignited by heats or mechanical shocks like sodium azide. Sodium azide is commonly used as propellant for inflating automotive safety bags and the other chemical manufacturing purposes. The investigation of thermal hazard potential of sodium azide is very important because unexpected traffic accident can be occureed. The experiments were carried out by DSC, TG an ARC in air, oxygen, argon and nitrogen atmosphere. The decomposition temperatures were about $410^{\circ}C$~$420^{\circ}C$ by DSC and $330^{\circ}C$~$370^{\circ}C$ by ARC, this is very significant result for treatment of chemical. The heats of decomposition were about 81 kcal/mol in ai. and 10 kcal/mol in other atmosphere.

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Effect of dehydride atmosphere on Hydrogen concentration of Tantalum (탈수소화 분위기가 탄탈륨 분말 수소농도에 미치는 영향 연구)

  • Lee, Ji-eun;Yoon, Jin-Ho;Lee, Chan Gi
    • Journal of Industrial Technology
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    • v.41 no.1
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    • pp.25-30
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    • 2021
  • Hydride-dehydride process for efficient recycling of tantalum (Ta) is used for manufacturer of Ta powder. In case of metal powder, Impurities as like nitride, oxygen, hydrogen is decreased of physical properties. For manufacture of Ta powder, control of theses impurities is important. In this study, to decreased of impurities on Ta powder using HDH process optimize dehydride condition. Dehydration behavior of Ta is depended on temperature, time, and atmosphere. Phase transition of Ta hydride is analyzed by X-ray diffraction (XRD). Concentration of hydrogen is decreased with temperature increased. At high temperature, concentration of hydrogen in Ta is similar according to time increased. Size and morphology of powder is not observed after dehydride. Ta powder, which is less than 20 um, concentration of hydrogen under 800 ppm is obtain.

Separation characteristics of separation devices using inlet water mixed with exhalation gases without a compressor (날숨이 혼합된 물을 사용한 압축기없는 용존기체 분리기의 분리 특성)

  • Heo, Pil Woo
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.9
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    • pp.842-846
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    • 2016
  • It's possible for a human to breathe under water, but the amount of dissolved oxygen in the water is small and a large amount of water is necessary to obtain sufficient dissolved oxygen from water. So, large separation system with large water pumps, having large surface areas, and large battery sources are needed. Exhalation gases are used to solve this problem. Theses gases contain some oxygen, nitrogen, and carbon dioxide; they contain less oxygen and more carbon dioxide compared to air. Therefore, reduction of the amount of carbon dioxide is necessary. If exhalation gases are employed appropriately, the separation device can be made more compact. Inlet water mixed with exhalation gases is supplied into the separation device, and dissolved gases are separated from the mixed water as it passes through the device. The inlet part of a typical separation system with a water delivery pump before the membrane module has more than one atmosphere. Hence, a compressor is used to mix the exhalation gases. In this study, the pressure at the inlet due to the use of a suction pump after the membrane module was less than one atmosphere; hence, compressors were not required. Separation characteristics were studied using a separation device without a compressor. The use of exhalation gases led to an increase in the amount of dissolved gases being separated. As the amount of inlet exhalation gases was increased, the separation of dissolved gases was increased as well.

Different Oxygen Transmission Rate Packing Films During Modified Atmosphere Storage: Effects on Asparagus Spear Quality

  • Yoon, Hyuk Sung;Choi, In-Lee;Kang, Ho-Min
    • Horticultural Science & Technology
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    • v.35 no.3
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    • pp.314-322
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    • 2017
  • The aim of this study was to determine suitable oxygen transmission rate (OTR) films for modified atmosphere (MA) storage of asparagus spears (Asparagus officinalis L.), and to examine the related changes in asparagus spear quality. Asparagus spears were packed with 10,000, 20,000, 40,000, 70,000, and $100,000cc/m^2{\cdot}day{\cdot}atm$ OTR film treatments for MA storage, and perforated film (conventional storage) was used as the control. The fresh weight loss rate was less than 1% in all OTR film treatments but not in the control. In all OTR film treatments, ethylene content rapidly increased on the first day of storage, and gradually decreased thereafter to $2.0{\mu}L{\cdot}L^{-1}$ by the final storage day. In the 10,000 cc and 20,000 cc OTR film treatments, carbon dioxide content was maintained within the permissible range for asparagus spears under recommended controlled atmosphere (CA) and MA conditions (5-12%). The oxygen content was maintained between 12% and 20% in all OTR film treatments. Hue angles and total chlorophyll content were highest in the 10,000 cc OTR film treatment in both tips and stems. Visual quality was maintained at a saleable level only in the 10,000 cc OTR film treatment until the final storage day (25 days). Based on sensory evaluation, the least off-odor was detected in the 10,000 cc OTR film treatment, and the most in the control treatment. While the soluble solids content decreased with all film treatments, it was maintained at the highest level in the 10,000 cc OTR film treatment. Vitamin C content decreased with all film treatments during storage, but was maintained at higher levels in the 10,000, 20,000, and 40,000 cc OTR film treatments. The firmness of tips and stems increased with storage duration in all film treatments, stems were firmer under the perforated film, 10,000, and 20,000 cc OTR film treatments. Given these results, the 10,000 cc OTR film treatment is considered the most appropriate for MA asparagus spear storage since visual quality and soluble solids content were maintained, and fresh weight loss, vitamin C content, off-odor, and yellowing were suppressed during storage.

Synthesis of Titanium Hydride Powder Via Magnesiothermic Reduction of TiCl4 in H2 gas Atmosphere (수소분위기 내 사염화타이타늄의 마그네슘 열환원을 이용한 수소화타이타늄 분말 합성)

  • Sung-Hun Park;So-Yeong Lee;Ho-Seong Lee;Jungshin Kang;Ho-Sang Sohn
    • Resources Recycling
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    • v.32 no.2
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    • pp.19-32
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    • 2023
  • A novel method for the synthesis of titanium hydride powder from titanium tetrachloride via the magnesiothermic reduction in an hydrogen gas atmosphere was investigated. To examine the influence of temperature on the formation of titanium hydride, the reduction was conducted at 1023~1123 K under 1 atm of hydrogen gas atmosphere for approximately 30 min. Subsequently, the titanium hydride powder was sintered by maintaining the temperature for 0~120 min, and the decrease in the oxygen concentration of the powder was investigated. The experimental results showed that TiH1.924 was produced at 1023 K, whereas mixtures of TiH1.924 and TiH1.5 were produced at 1073 K and 1123 K. In addition, the hydrogen concentration in the powder decreased with increasing temperature. The concentration of oxygen in the powder decreased with increasing temperature and sintering time owing to the decrease in the specific surface area of the powder. The minimum concentration of oxygen was 0.246 mass% when the mixture of TiH1.924 and TiH1.5 was obtained at 1073 K and a sintering time of 120 min.

Effect of Oxygen Content on Shape Memory Characteristics of Ti-18Nb-6Zr-XO (X = 0~1.5at%) Alloys (생체용 Ti-18Nb-6Zr-XO (X = 0~1.5at%) 합금의 형상기억특성에 미치는 산소 농도의 영향)

  • Park, Young-Chul;Ock, Ji-Myeon;Oh, Jeong-Hwa;Park, Su-Ho;Lee, Jun-Hee;Kim, Jae-Il
    • Korean Journal of Materials Research
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    • v.21 no.11
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    • pp.617-622
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    • 2011
  • The effect of oxygen on the shape memory characteristics in Ti-18Nb-6Zr-XO (X = 0-1.5 at%) biomedical alloys was investigated by tensile tests. The alloys were fabricated by an arc melting method at Ar atmosphere. The ingots were cold-rolled to 0.45 mm with a reduction up to 95% in thickness. After severe cold-rolling, the plate was solution-treated at 1173 K for 1.8 ks. The fracture stress of the solution-treated specimens increased from 450 Mpa to 880 MPa with an increasing oxygen content up to 1.5%. The fracture stress increased by 287MPa with 1 at% increase of oxygen content. The critical stress for slip increased from 430 MPa to 695 MPa with an increasing oxygen content up to 1.5 at%. The maximum recovery strain of 4.1% was obtained in the Ti-18Nb-6Zr-0.5O (at%) alloy. The martensitic transformation temperature decreased by 140 K with a 1.0 at% increase in O content, which is lower than that of Ti-22Nb-(0-2.0)O (at%) by 20 K. This may have been caused by the effect of the addition of Zr. This study confirmed that addition of oxygen to the Ti-Nb-Zr alloy increases the critical stress for slip due to solid solution hardening without being detrimental to the maximum recovery strain.