• 제목/요약/키워드: Oxygen Separation

검색결과 208건 처리시간 0.023초

산소/질소 분리를 위한 다층구조 제올라이트 5A를 함유한 탄소분자체 분리막 제조 (Hierarchical 5A Zeolite-Containing Carbon Molecular Sieve Membranes for O2/N2 Separation)

  • 리웬;추아총양;배태현
    • 멤브레인
    • /
    • 제30권4호
    • /
    • pp.260-268
    • /
    • 2020
  • 다층 구조를 가진 5A 제올라이트를 탄소 분자체 분리막에 첨가한 복합막을 제조하고 질소/산소의 분리 특성을 평가하였다. 제올라이트의 첨가는 선택도에는 미세한 영향을 주지만 투과도를 크게 증가시키는 방법으로 전체적인 탄소막의 질소/산소의 분리 성능을 상승시켰다. 특히 메조포어를 함유한 다층구조의 제올라이트 첨가제는 분리막의 투과도를 보다 효율적으로 상승시켜 아주 우수한 분리 성능에 도달하였다. 이 연구의 결과는 저렴한 탄소막 전구체와 제올라이트 소재를 활용하고도 고성능의 질소/산소 분리막을 손쉽게 제조할 수 있다는 것을 제시한다.

야금학적으로 Pre-Lithiation된 리튬이온전지 음극용 SiOx의 리튬소스가 미세구조에 미치는 영향 (Effects of Li-Sources on Microstructure of Metallurgically Pre-Lithiated SiOx for Li-Ion Battery's Anode)

  • 이재영;이보라;김낙원;장보윤;김준수;김성수
    • 한국전기전자재료학회논문지
    • /
    • 제32권1호
    • /
    • pp.78-85
    • /
    • 2019
  • The effect of various lithium sources such as LiCl, LiOH, and Li-metal on the microstructure and electrochemical properties of granulated $SiO_x$ powders were investigated. Various lithium sources were metallurgically added for a passive pre-lithiation of $SiO_x$ to improve its low initial coulombic efficiency. In spite of using the same amount of Li in various sources, as well as the same process conditions, different lithium silicates were obtained. Moreover, irreversible phases were formed without reduction of $SiO_x$, which might be from additional oxygen incorporation during the process. Accordingly, there were no noticeable electrochemical enhancements. Nevertheless, the $Li_4SiO_4$ phase changes the initial electrochemical reaction, and consequently the relationship between the microstructure and electrochemical properties of metallurgically pre-lithiated $SiO_x$ could provide a guideline for the optimization of the performance of lithium ion batteries.

Transmission Electron Microscopy Study of Stacking Fault Pyramids Formed in Multiple Oxygen Implanted Silicon-on-Insulator Material

  • Park, Ju-Cheol;Lee, June-Dong;Krause, Steve J.
    • Applied Microscopy
    • /
    • 제42권3호
    • /
    • pp.151-157
    • /
    • 2012
  • The microstructure of various shapes of stacking fault pyramids (SFPs) formed in multiple implant/anneal Separation by Implanted Oxygen (SIMOX) material were investigated by plan-view and cross-sectional transmission electron microscopy. In the multiple implant/anneal SIMOX, the defects in the top silicon layer are confined at the interface of the buried oxide layer at a density of ${\sim}10^6\;cm^{-2}$. The dominant defects are perfect and imperfect SFPs. The perfect SFPs were formed by the expansion and interaction of four dissociated dislocations on the {111} pyramidal planes. The imperfect SFPs show various shapes of SFPs, including I-, L-, and Y-shapes. The shape of imperfect SFPs may depend on the number of dissociated dislocations bounded to the top of the pyramid and the interaction of Shockley partial dislocations at each edge of {111} pyramidal planes.

Dairy wastewater treatment using microalgae for potential biodiesel application

  • Choi, Hee-Jeong
    • Environmental Engineering Research
    • /
    • 제21권4호
    • /
    • pp.393-400
    • /
    • 2016
  • The aim of this study was to evaluate the biomass production and dairy wastewater treatment using Chlorella vulgaris. The results indicated that the maximum percentages of biochemical oxygen demand, chemical oxygen demand, suspended solids, total nitrogen, and total phosphorus removed were 85.61%, 80.62%, 29.10%, 85.47%, and 65.96%, respectively, in dairy effluent at 10 d. A maximum of 1.23 g/L dry biomass was obtained in 7 d. The biomass productivity was strongly influenced by the nutrient reduction in the dairy effluent. The biodiesel produced by the C. vulgaris in the dairy effluent was in good agreement with the American Society of Testing and Materials-D6751 and European Standards 14214 standards. Therefore, using dairy effluent for microalgal cultures could be a useful and practical strategy for an advanced, environmentally friendly treatment process.

목질분해효소에 의한 고지의 재활용 기술연구 (제1보) -목질분해균으로부터 조효소의 단리 (Studies on the Recycling Technology of the Waste Paper with Wood Degradable Enzyme(I) - Separation of Crude Enzyme from Wood Degradable fungi -)

  • 양재경;이중명;엄태진
    • 펄프종이기술
    • /
    • 제29권1호
    • /
    • pp.43-51
    • /
    • 1997
  • The various culture conditions of Trichoderma viride(ATCC 3454) and Phanerochaete chrysosporium(ATCC 26921) with glucose-pepton medium, Mandels medium, YMG medium for wood degradable enzyme were examined. Mycellium of the two species grew profusely on glucose-pepton medium. Maximum fungal growth was observed about 10days. But CMCase, Fpase, laccase activity in the culture medium with glucose-pepton was not detected. When grown in fermenter culture using Mandels medium, Trichoderma viride produced CMCase and Fpase. Its CMCase activity was 0.15 lU/ml and Fpase activity was 0.3 IU/ml within about 4-6days. Phanerochaete chrysosporium grown in a YMG medium gave the best enzyme activity when they were grown under stationary culture with an atmosphere of 100% oxygen. Levels of laccase activity of 3.0 mull were achieved in stationary culture under 100% oxygen. The enzyme condensation by ultrafiltration method caused a 2-fold(cellulase) and 6-fold(laccase) as compared to control activity.

  • PDF

Li+- and H+-Exchanged Low-Silica X Zeolite as Selective Nitrogen Adsorbent for Air Separation

  • Kim, Jin-Bae
    • Bulletin of the Korean Chemical Society
    • /
    • 제24권12호
    • /
    • pp.1814-1818
    • /
    • 2003
  • $Li^+$ and $H^+$ co-exchanged LSXs (Li-H-LSX) with various ratios of $Li^+$ and $H^+$ were prepared, and those adsorption characteristics of nitrogen and oxygen were compared with Li-Na-LSX and Li-Ca-LSX. Li-H-LSX showed higher nitrogen capacity and selectivity than that of Li-Na-LSX in the wide range of Li-exchanged ratio. The nitrogen capacity of Li-Ca-LSX was slightly higher than that of fully Li- or Ca-exchanged LSX (Li- LSX or Ca-LSX). However, Li-Ca-LSX showed low nitrogen/oxygen adsorption selectivity until the Li content reached about 80%, which was a tendency near that of Ca-LSX.

적조생물 Cochlodinium polykrikoides에 노출된 어류의 산소 소모량 및 조직 변화 (Response of Oxygen Consumption and Gill Tissue of Fish Exposed to Red Tide Organism Cochlodinium polykrikoides)

  • 심정민;이주;이용화;김봉석
    • 한국환경과학회지
    • /
    • 제18권11호
    • /
    • pp.1283-1289
    • /
    • 2009
  • Eco-physiological research and the control of Cochlodinium polykrikoides was carried out to elucidate eco-physiological characteristics of red tide organism through culture experiment depending on the condition of photon irradiance. Oxygen consumption of C. polykrikoides was high with a value of 1.12 mg/L/hr in the dark compared with that of 0.13 mg/L/hr at $100{\mu}mEm^{-2}s^{-1}$. DO values in a circular chamber with the lapse of time in seawater containing C. polykrikoides were declined in the dark period. DO values of seawater containing C. polykrikoides in the dark were declined from 7.01 mg/L to 2.65 mg/L in 30 cm depth and from 7.01 mg/L to 6.63 mg/L in 5 cm depth depending on the depth of circular culture vessel. Olive flounder, Paralichthys olivaceus and file fish, Stephanolepis cirrhifer exposed to Cochlodinium showed the separation of the lamella epithelium from gill filament, which disrupted the respiratory process at the gill level.

Effect of oxygen containing compounds in uranium tetrafluoride on its non-adiabatic calciothermic reduction characteristics

  • Gupta, Sonal;Kumar, Raj;Satpati, Santosh K.;Sahu, Manharan L.
    • Nuclear Engineering and Technology
    • /
    • 제53권6호
    • /
    • pp.1931-1938
    • /
    • 2021
  • Uranium ingot is produced by metallothermic reduction of uranium tetrafluoride using magnesium or calcium as reductant. Presence of oxygen containing compounds viz. uranyl fluoride and uranium oxide in the starting uranium fluoride has a significant effect on the firing time, final temperature of the charge, slag-metal separation and hence the metal recovery. As reported in the literature, the maximum tolerable limit for uranyl fluoride in the UF4 is 2.5 wt% and limit for uranium oxide content is in the range 2-3 wt%. No theoretical or experimental basis is available till date for these limits. Analyses have been carried out in this study to understand the effect of UO2F2 concentration in the starting fluoride on the final temperature of the products and thus the reduction characteristics. UF4 having uranyl fluoride concentration, less than as well as more than 2.5 wt%, have been investigated. Thermodynamic calculations have been carried out to arrive at a general expression for the final temperature attained by the products during calciothermic reduction of UF4. Finally, an upper limit for the oxygen containing impurities has been estimated using the CaO-CaF2 phase diagram.

Novel Polypyrrole composite membrane with high gas selectivity and permeability

  • Son, Won-Il;Kim, Byoung-Sik;Hong, Jae-Min
    • 한국막학회:학술대회논문집
    • /
    • 한국막학회 2004년도 춘계 총회 및 학술발표회
    • /
    • pp.147-152
    • /
    • 2004
  • Gas separation membrane technology is useful for a variety of applications [1, 2]. such as hydrogen recovery from reactor purge gas, nitrogen and oxygen enrichment, water vapor removal from air, stripping of carbon dioxide from natural gas. etc. Although membrane separations are attractive because of low energy costs and simple operation, low permeabilities and/or selectivity often limit membrane applications [3, 4].(omitted)

  • PDF