• Title/Summary/Keyword: Oxygen Gas

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수산화가스 발생기의 모델링 및 특성해석 (A Study on Analysis of the Hydrogen-Oxygen Gas Generator)

  • 강병회;이정민;목형수;최규하
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2001년도 춘계학술대회 논문집 전기기기 및 에너지변환시스템부문
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    • pp.198-201
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    • 2001
  • The mixed gas of Hydrogen and Oxygen is gained from water electrolysis reaction. It has constant volume ratio 2 : 1 Hydrogen and Oxygen, and it is used as a source of thermal energy by combustion reaction. This gas has better characteristics in the field of economy, efficiency of energy, and environmental intimacy than acetylene gas and LPG used for gas welding machine. So several studies of this gas are actively in progress nowadays. The object of this study is the optimization of power condition in the side of electrical for the high efficiency of water electrolysis equipment. First, chemical analysis of electrolysis is conducted, and the relation of electrical energy and chemical energy is quantitatively investigated. For basic experiment, unit electrode of singular electrolysis electrode is manufactured and experimented, results are compared and analyzed with simulation, and the electrolysis is electrically equivalent.

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AC Impedance Study of the Electrochemical Behavior of Hydrogen/Oxygen Gas Mixture at Nafion/Catalyst Electrode Interface

  • Song, S.M.;Lee, W.M.
    • 한국수소및신에너지학회논문집
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    • 제11권4호
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    • pp.179-188
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    • 2000
  • The anodic reaction of hydrogen/oxygen gas mixture at platinum or palladium electrode interfacing with a solid polymer electrolyte was investigated using AC impedance method. The impedance spectrum of the electrode reactions of the mixture depends on the gas composition, electrode roughness, the mode of electrochemical operation and the cell potential. For electrolysis mode of operation, the spectrum taken for the reaction on a rough platinum electrode for the gas mixture revealed clearly that the local anodic reduction of oxygen gas takes place concurrently with the anodic oxidation of hydrogen gas.

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Prediction of Gas Permeability by Molecular Simulation

  • Yoo, Jae ik;Jiang, Yufei;Kim, Jin Kuk
    • Elastomers and Composites
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    • 제54권3호
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    • pp.175-181
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    • 2019
  • The research and development of high-performance polymer materials with excellent gas barrier properties has gained considerable attention from the viewpoint of expanding their applications in various fields, including tire automobile parts and the polymer film industry. Natural rubber (NR) has been widely used as a rubber material in real-life, but its application is limited owing to its poor gas barrier properties. In this paper, we study the gas barrier properties of NR, epoxidized natural rubber (ENR), and their blend compositions by using molecular simulation. The results show that ENR-50 has superior oxygen barrier properties than those of NR. Moreover, the oxygen barrier properties of a blend of NR/ENR-50 improve with increasing volume fraction of ENR-50. The trend of improved oxygen barrier properties of NR, ENR-50, and their blend is in good agreement with experimental observations.

LP가스의 폭발 현상 및 화염전파에 관한 연구 (A Study on the Explosion Phenomenon and Flame Propagation of LP Gas)

  • 최재욱;이동훈;김태근;민철웅;임우섭;최병식
    • 한국가스학회지
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    • 제11권2호통권35호
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    • pp.65-70
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    • 2007
  • LP 가스의 폭발현상 및 위험성을 평가하기 위하여, 산소농도변화와 LP 가스의 농도에 따른 혼합가스 조성을 변화시켜 실험을 행하였다. 산소농도 21%에서 LP 가스의 농도가 증가할수록 폭발하한계는 낮아졌으며, 최소산소농도(MOC, Minimum Oxygen Concentration)는 1.0 bar, 1.5 bar, 2.0 bar에서 각각 14.5%, 12.0%, 11.5%로 낮아졌다. 최대폭발압력은 압력이 증가할 경우 $6.46kg/cm^2,\;9.41kg/cm^2,\;13.49kg/cm^2$로 증가하였으며, LP 가스의 초기압력이 클수록 화염의 전파속도가 증가하였다.

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Oxygen Permeability Measurement of $ZrO_2-TiO_2-YB_2O_3$ Mixed Conductor

  • Hitoshi Naito;Kim, Hitoshi ishima;Toru Takahashi;Hiroo Yugami
    • The Korean Journal of Ceramics
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    • 제6권2호
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    • pp.124-128
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    • 2000
  • Electrical properties of $ZrO_2-TiO_2Yb_2O_3$mixed conductor (Ti-YbSZ) were investigated. This mixed conductor can be applied as a membrane for gas separation at high temperatures. The total conductivity decreased with increasing the $TiO_2$concentration. At high temperatures, the rate of the conductivity degradation became smaller than that at low temperatures. From the oxygen partial pressure dependence of the total conductivity of Ti-YbSZ, the electronic conductivity increased with increasing $TiO_2$concentration at low oxygen partial pressures and at high temperatures. Both 15 and 20 mol% $TiO_2$doped YbSZ showed high oxygen permeability. Mixed conductors, which has high $TiO_2$concentration in YbSZ, are promising materials for using as a membrane for gas separation at high temperatures.

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Simulation of Inductively Coupled $Ar/O_2$ Plasma; Effects of Operating Conditions on Plasma Properties and Uniformity of Atomic Oxygen

  • Park, Seung-Kyu;Kim, Jin-Bae;Kim, Heon-Chang
    • 반도체디스플레이기술학회지
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    • 제8권4호
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    • pp.59-63
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    • 2009
  • This paper presents two dimensional simulation results of an inductively coupled $Ar/O_2$ plasma reactor. The effects of operating conditions on the plasma properties and the uniformity of atomic oxygen near the wafer were systematically investigated. The plasma density had the linear dependence on the chamber pressure, the flow rate of the feed gas and the power deposited into the plasma. On the other hand, the electron temperature decreased almost linearly with the chamber pressure and the flow rate of the feed gas. The power deposited into the plasma nearly unaffected the electron temperature. The simulation results showed that the uniformity of atomic oxygen near the wafer could be improved by lowering the chamber pressure and/or the flow rate of the feed gas. However, the power deposited into the plasma had an adverse effect on the uniformity.

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Mixed Hydrogen Gas Generator용 전력변환장치 개발 (Development of Mixed Hydrogen Gas Generator Power Conversion System)

  • 정장근;문상필;조길제;김창일
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2007년도 학술대회 논문집 전문대학교육위원
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    • pp.88-92
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    • 2007
  • In this paper, the basic experiment, electrolytic cell design and basic manufacturing have been made to interpret the characteristics of Hydrogen-Oxygen-Gas-Generator. As for the detailed matters, the data research on basic technology on Hydrogen-Oxygen-Gas and analysis on characteristics of Hydrogen-Oxygen-Gas from basic experiment. Also the experiment of characteristics and comparative evaluation between constant current source using IGBT converter from existing method and constant current source using new phase shift PWM control method converter. As results when it has injected constant DC current, we has compared Gas quantities by variable ripple frequencies using phase shift PWM control method converter. Therefore, in linear region, it has not different Gas quantities by constant DC current and by phase shift PWM control method converter. Also, it has increased Gas quantities wilder linear region when put ripple frequency at saturation region. Through, Gas quantities and input power, it has acquired higher input power per Gas quantities at put pulse curren. Therefore, when designing converter or inverter for electrolysis, which has ripple current.

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박용 디젤기관의 $NO_x$ 및 매연 배출물에 미치는 스크러버형 EGR 시스템 재순환배기의 영향에 관한 연구 (A Study on Effects of Recirculated Exhaust Gas upon $NO_x$ and Soot Emissions of a Marine Diesel Engine with Scrubber EGR System)

  • 배명환;하정호
    • Journal of Advanced Marine Engineering and Technology
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    • 제24권3호
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    • pp.70-78
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    • 2000
  • The effects of recirculated exhaust gas on the characteristics of ;$NO_x$ and soot emissions under a wide range of engine load have been experimentally investigated by a water-cooled, four-cylinder, indirect injection, four cycle and marine diesel engine operating at two kinds of engine speeds. The purpose of the present study is to develop the EGR control system for reducing $NO_x$ and soot emissions simultaneously in diesel engines. The EGR system is used to reduce NOx emissions, and a novel diesel soot removal apparatus with a cylinder-type scrubber for the experiment system which has 6 water injectors(A water injector is made up 144 nozzles with 1.0mm in diameter) is specially designed and manufactured to reduce the soot contents in the recirculated exhaust gas to intake system of the engines. The intake oxygen concentration obtained by the intake air flow and the oxygen concentration in the recirculated exhaust gas, and the exhaust oxygen concentration measured in exhaust manifold are used to analyse and discuss the influences of EGR on NOx and soot emissions. The experiments are performed at the fixed fuel injection timing of $15.3^{\circ}$ BTDC regardless of experimental conditions. It is found that $NO_x$ emissions decrease and soot emissions increase owing to the drop of intake oxygen concentration and exhaust oxygen concentration as EGR rate rises. Also, one can conclude that it is sufficient for the scrubber EGR system with a novel diesel soot removal apparatus to reduce $NO_x$ emissions, but not to reduce soot emissions.

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Hydrogen photoproduction by the synchronously grown marine unicellular cyanobacterium Synechococcus sp. Miami BG 043511 under extremely high oxygen concentration

  • Yih, Won-Ho;Takeyama, Haruko;Mitsui, Akira
    • Journal of the korean society of oceanography
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    • 제31권1호
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    • pp.18-22
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    • 1996
  • The effect of exogenous oxygen on hydrogen photoproduction was examined in the synchronously grown cells of marine Synechococcus sp. Miami BG 043511 under conditions of high cell density (0.6-0.8 mg chl-${\alpha}$ $ml^{-1}$) and high light intensity (1000 ${\mu}$E $m^{-2}$ $s^{-1}$). Hydrogen evolution after 20-h incubation did not decline under the initial oxygen concentrations up to 20%, but declined by half under 34% oxygen. 50% and 100% oxygen gas phase did not completely inhibit the hydrogen photoproduction during 40-h incubations. After 2-day pretreatment under 100% exogenous oxygen the hydrogen photoproduction capabilities were not irreversibly inhibited, which was demonstrated in the subsequent 9-day incubation under initial 0, 50 and even under 100% oxygen gas phase. This strain could be useful for developing a hydrogen photoproduction system under atmospheric oxygen concentration.

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XRD 분석에 의한 결정구조와 PL 분석에 의한 광학적 특성의 상관성 (Relationship between Optical Properties Analyzed by Photoluminance of Bonding Structure Analyzed by X-ray Diffractometer)

  • 오데레사
    • 반도체디스플레이기술학회지
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    • 제15권1호
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    • pp.70-75
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    • 2016
  • GZO films prepared on ITO glasses were annealed at various temperatures in a vacuum condition to research the relationship between oxygen vacancies and optical properties. GZO films after annealing in a vacuum showed the various optical-chemical properties depending on the annealing temperatures and oxygen gas flow rate during the deposition. The oxygen vacancy of GZO film prepared by oxygen gas flows of 22 sccm increased with increasing the annealing temperatures, because of the extraction of oxygen by the annealing. But the intensity of photoluminance of GZO with 22 sccm decreased in accordance with the annealing temperature, because of the reduction of ionized charge carriers. The oxygen vacancy by the extraction of oxygen enhanced a depletion, so the widen depletion had the strong Schottky barrier and the PL intensity due to the low carrier density decreased.