• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집D
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• pp.60-65
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• 2001

Bomb calorimeter was developed for measuring the calorific value of combustible matter such as wastes. The calorimeter consist of bomb, stirred-water type bucket, thermometer and ignition circuit. Operation and performance of the calorimeter have been tested experimentally. In the present study, calorific values of light oil, lamp oil and bunker C oil is measured using the bomb calorimeter. Mass of the sample is fixed at lg, and oxygen pressure in the bomb is used as an experimental parameter. Sample in the oxygen bomb is burned with electrically heated Ni-Cr wire of 100mm in length, and temperature of water in the bucket become increased by $5^{\circ}C$ during about 30min. Calorific value of the sample is calculated with the temperature difference of water. Combustion tests, such as the record of temperature history and the inspection of remnants, are performed at 4, 6, 8 and 10 atm of the oxygen pressure. From the test results, oxygen pressure in the bomb must be over 10atm for complete combustion.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2001년도 제22회 KOSCI SYMPOSIUM 논문집
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• pp.23-30
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• 2001

Bomb calorimeter was developed for measuring the calorific value of combustible matter such as wastes. The calorimeter consist of bomb, stirred-water type bucket, thermometer and ignition circuit. Operation and performance of the calorimeter have been tested experimentally. In the present study, calorific values of light oil, lamp oil, benzoic acid, ethyl alcohol and methyl alcohol is measured using the bomb calorimeter. Mass of the sample is fixed at 19, and oxygen pressure in the bomb is used as an experimental parameter. Sample in the oxygen bomb is burned with electrically heated Ni-Cr wire of 100mm in length, and temperature of water in the bucket become increased by $2{\sim}5^{\circ}C$ during about 30min. Calorific value of the sample is calculated with the temperature difference of water. Combustion tests, such as the record of temperature history and the inspection of remnants, are performed at 6, 8 and 10 atm of the oxygen pressure. From the test results, oxygen pressure in the bomb must be over 10atm for complete combustion.

• 분석과학
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• 제23권6호
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• pp.615-618
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• 2010

An oxygen bomb combustion procedure were studied for determination of heavy metal in polymer materials such as polyvinyl chloride and polypropylene by ICP-AES. This method is proposed as a rapid and simple sample preparation for decomposition of polymer containing certified contents of the analytes by teflon coated oxygen bomb combustion using different absorbing solution. The recoveries of metal were found to be 30~102% from absorbed solution by ICP-AES method using polypropylene certified reference material(PP CRM-As, Ba, Cd, Hg, Pb, Zn). The recoveries of metal using PVC CRM(Cd, Hg, Pb) was found to be 45 ~101% with same procedures.

• 한국결정성장학회지
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• 제21권6호
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• pp.274-279
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• 2011

연소 반응기를 이용하여 고분자 물질에 함유된 할로겐 원소인 브롬과 염소를 정량하기 위한 조건을 연구하였다. 염소농도 측정의 경우, Mohr법이나 전위차 적정법을 이용한 경우가 산-염기 적정법을 이용한 경우보다 분석 데이터 간 편차가 낮게 나타났다. 또한, 연소 반응기에서 단계별로 포집한 용액에 대한 염소와 브롬 측정 결과, 두 원소 모두 증류수를 흡수액으로 사용할 때, 0.3 M NaOH 수용액을 사용할 때보다 더 높은 회수율을 보였으며, 흡수액/세척액에서의 농도가 가스상의 형태로 배출되는 농도에 비해 높은 것으로 나타났다. 한편, 브롬 함량을 측정할 때, 연소 반응기를 이용한 경우가 XRF나 연소-이온크로마토그래피를 이용한 경우에 비해 농도가 상대적으로 낮게 평가되는 것으로 나타났다.

• 한국화재소방학회논문지
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• 제22권3호
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• pp.258-264
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• 2008

본 논문에서는 산불의 한 형태인 지표화의 체계적인 연구를 위해 열량분석과 연소특성에 관한 실험방법과 측정 시스템을 제안하여 향후 산불 관련 연구에 있어서 이를 활용하고자 한다. 또한 제안된 방법과 시스템의 효용성을 나타내고자 부분적인 결과를 논문에 제시 하였다. 이를 위하여 지표화의 대표적인 연소 물질인 침엽수종과 활엽수종 낙엽을 선정하여 밀도 및 시료의 용기 크기를 변화시켜 가며 실험하였다. 열량분석은 통상 사용되는 분석기기 중 열중량 분석기(TGA : Thermogravimetric Analyzer), 연소열 측정장치(Oxygen Bomb Calorimeter)를 이용하여 분석하였으며, 연소특성은 기존의 이론적 모델로 가장 잘 알려져 있는 Pool fire모델에 따른 모의 연소실험을 통하여 지표화 상부의 열 유체속도, 연소온도, 화염 높이에 따른 열방출 속도, 연소 질량감소 속도 둥을 측정하여 분석하였다. 언급된 변수들은 지표화의 위험성 및 산불확산 예측에 기초 자료로 사용할 수 있다.

• Journal of Microbiology and Biotechnology
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• 제20권11호
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• pp.1534-1538
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• 2010

Fed-batch cultures of Hansenula polymorpha were studied to develop an efficient biosystem to produce recombinant human serum albumin (HSA). To comply with this purpose, we used a high-purity oxygen-supplying strategy to increase the viable cell density in a bioreactor and enhance the production of target protein. A mutant strain, H. polymorpha GOT7, was utilized in this study as a host strain in both 5-l and 30-l scale fermentors. To supply high-purity oxygen into a bioreactor, nearly 100% high-purity oxygen from a commercial bomb or higher than 93% oxygen available in situ from a pressure swing adsorption (PSA) oxygen generator was employed. Under the optimal fermentation of H. polymorpha with highpurity oxygen, the final cell densities and produced HSA concentrations were 24.6 g/l and 5.1 g/l in the 5-l fermentor, and 24.8 g/l and 4.5 g/l in the 30-l fermentor, respectively. These were about 2-10 times higher than those obtained in air-based fed-batch fermentations. The discrepancies between the 5-l and 30-l fermentors with air supply were presumably due to the higher contribution of surface aeration over submerged aeration in the 5-l fermentor. This study, therefore, proved the positive effect of high-purity oxygen in enhancing viable cell density as well as target recombinant protein production in microbial fermentations.

• 한국근적외분광분석학회:학술대회논문집
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• 한국근적외분광분석학회 2001년도 NIR-2001
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• pp.1511-1511
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• 2001

Energy content, expressed as calories per gram, is an important part of the evaluation and marketing of foods in developed countries. Currently accepted methods of measurement of energy by U.S. food labeling legislation include measurement of gross calories by bomb calorimetry with an adjustment for undigested protein and by calculation using specific factors for the energy values of protein, carbohydrate less the amount of insoluble dietary fiber, and total fat. The ability of NIRS to predict the energy value of diverse, processed and unprocessed cereal food products was investigated. NIR spectra of cereal products were obtained with an NIR Systems monochromator and the wavelength range used for analysis was 1104-2494 nm. Gross energy of the foods was measured by oxygen bomb calorimetry (Parr Manual No. 120) and expressed as calories per gram (CPGI, range 4.05-5.49 cal/g). Energy value was adjusted for undigested protein (CPG2, range 3.99-5.38 cal/g) and undigested protein and insoluble dietary fiber (CPG3, range 2.42-5.35 cal/g). Using a multivariate analysis software package (ISI International, Inc.) partial least squares models were developed for the prediction of energy content. The standard error of cross validation and multiple coefficient of determination for CPGI using modified partial least squares regression (n=127) was 0.060 cal/g and 0.95, respectively, and the standard error of performance, coefficient of determination, bias and slope using an independent validation set (n=59) were 0.057 cal/g, 0.98, -0.027 cal/g and 1.05 respectively. The PLS loading for factor 1 (Pearson correlation coefficient 0.92) had significant absorption peaks correlated to C-H stretch groups in lipid at 1722/1764 nm and 2304/2346 nm and O-H groups in carbohydrate at 1434 and 2076 nm. Thus the model appeared to be predominantly influenced by lipid and carbohydrate. Models for CPG2 and CPG3 showed similar trends with standard errors of performance, using the independent validation set, of 0.058 and 0.088 cal/g, respectively, and coefficients of determination of 0.96. Thus NIRS provides a rapid and efficient method of predicting energy content of diverse cereal foods.

• 약학회지
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• 제29권3호
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• pp.144-151
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• 1985

Cathodic stripping voltammetric determination of traces of selenium in plant samples was studied. Stripping peak of selenium (IV) from Cu-Se intermettalic deposit in acidic media containing copper (II) ion is specific, highly sensitive and well defined, is successfully used for the quantitative determination of selenuin down to the level of 1ng/ml. Sample is burnt in a calorimeter bomb under the oxygen pressure of 40atm. and the selenium is absorbed in 0.1M NaOH. After the solution is filtrated, concentrated and acidified with HCl, then passed through a column of cation exchange resin in the $H^{+}$ form(Dowex 50X-8). The column eluate is analyzed for selenium by differential pulse cathodic stripping voltammetric method. Analytical results of selenium for NBS SMR is well agreement with the certified values. Results are given for a series of plant materials.

• Tribology and Lubricants
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• 제12권1호
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• pp.36-41
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• 1996

The suitability of a pressure differential scanning calorimetry (PDSC) in monitoring the quality of synthetic base fluids has been investigated using polyalphaolefin (PAO) oils as an example. Induction period meassured at 170, 180 and 19$0^{\circ}C$, and 3.53 MPa oxygen pressure was applied to characterize their oxidation stability. The PDSC method has proven to be simple and repeatable and requires only small sample size for testing. More importantly, it can be applied in differentiating the oxidation performance quality of PAO oils and is versatile enough for use in studying kinetic aspects of PAO oil oxidation which include the effect of temperature and antioxidant concentration. Additionally, the method appears to correlate well with a rotary bomb oxidation test (RBOT).

• 한국화재소방학회논문지
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• 제22권5호
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• pp.72-78
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• 2008

본 연구에서는 EPS 샌드위치 패널 심재에 대한 일정한 외부 복사열에 의한 질량감소속도와 열방출특성을 분석하였다. 일정한 외부 복사열원에 노출된 EPS 샌드위치 패널 심재의 질량감소속도와 열방출특성을 분석하기 위해 3가지 Type의 시료를 사용하였으며, 연소열을 측정하기 위해 Oxygen bomb calorimeter를 질량감소속도와 열방출특성을 분석하기 위해 Mass loss calorimeter를 사용하였다. 질량감소속도와 열방출 특성을 분석하기 위해 $100mm{\times}100mm{\times}50mm$ 크기의 시료를 사용하였다. 연구결과 50 kW/$m^2$의 외부복사열원에서 평균질량감소속도는 Type A와 B의 경우 각각 2.7 g/$m^2s$, 2.8 g/$m^2s$로 비슷한 경향을 나타낸 반면, Type C는 2.3 g/$m^2s$로 상대적으로 낮게 나타났으며, 평균열방출속도는 Type B와 C의 경우 각각 47.19 kW/$m^2$, 50.06 kW/$m^2$으로 큰 차이가 없었으나, Type A는 58.23 kW/$m^2$으로 상대적으로 높게 나타났다. 열방출특성의 결과를 캐나다 분류체계에 적용할 경우 Type A와 C의 경우 C-3등급, Type B의 경우 C-2등급으로 분류되었다. 향후 콘칼로리미터법을 이용한 샌드위치 패널 심재에 대한 열방출율 특성과의 비교연구가 필요할 것으로 판단된다.