• Journal of the Korean Chemical Society
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• v.23 no.1
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• pp.42-45
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• 1979

The experimental procedures of Beckmann rearrangement mostly involve the use of vigorous conditions such as strongly acidic reagents (conc. HCl, $H_2SO_4$, $PCl_5$, etc.) or elevated temperatures, which frequently cause isomerization of ketooximes prior to rearrangement.We have effected the Beckmann rearrangement on $5{\alpha}$-cholestan-3-one oxime using the carbon tetrachloride-triphenylphosphine reagent under mild, neutral conditions to give 3-aza-A-homo-$5{\alpha}$-cholestan-4-one. This new, mild, facile and rapid general method of Beckmann rearrangement is presented, and compared with the classical (more conventional) Beckmann reagent of polyphosphoric acid.

• Korean Journal of Food Science and Technology
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• v.47 no.1
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• pp.27-36
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• 2015

The improved analytical method with gas chromatography (GC) and GC-mass spectrometry was established to identify and quantify disaccharides and trisacchrides in honey. In this method, the analysis of trimethylsilyl (TMS), TMS-oxime and TMS-methoxime sugars takes into account the determination of a single peak of complete separation on the chromatogram. The number of possible peaks for the qualitative and quantitative determination of TMS, TMS-oxime, and TMS-methoxime sugars was 17, 22, and 25, respectively. This new analytical method allowed for the determination of diand trisaccharides in honey by TMS-oxime and TMS-methoxime derivatives. This study suggested that the improved method is more suitable and precise than the other analytical methods for the simultaneous determination of sugars in honey.

• Bulletin of the Korean Chemical Society
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• v.23 no.9
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• pp.1187-1188
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• 2002

• Proceedings of the Korean Society of Potoscience Conference
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• 2002.06a
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• pp.29-29
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• 2002

• Bulletin of the Korean Chemical Society
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• v.18 no.1
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• pp.3-5
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• 1997

• Bulletin of the Korean Chemical Society
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• v.6 no.6
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• pp.380-381
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• 1985

• Bulletin of the Korean Chemical Society
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• v.19 no.12
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• pp.1373-1375
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• 1998

• YAKHAK HOEJI
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• v.18 no.4
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• pp.255-258
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• 1974

The insecticidal activity of six lately synthesized carbamate derivatives of furfural oxime N-methylcarbamate (I), 5-methyljural oxime N-methylcarbamate (II), methyl p-(methylcarbamoyl) oxybenzoate (IV), ethyl p-(methylcarbamoyl) oxybenzoat(V), n-propyl p-(methyl carbamoyl)oxybenzoate(VI) and n-butyl p-(methyl carbamoyl)oxybenzoate examined using o.2w/v% acetone solutions of each compound. Among them, alkyl p-(methyl carbamoyl) oxybenzontes exerted slightly insecticidal effects on Sogata furcifera H$_{ORVATH}$, Delphacodes stria striatella FALLEN, wherease no significant effects were observed on Mil-aparvata Iugens Stal, Inazuma dorsolis Moischiulsky, and Naphotettix apicalis cincticeps U$_{HLER}$.

• Archives of Pharmacal Research
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• v.18 no.3
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• pp.195-202
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• 1995

The thio, thio acetyl, oxime, and several hydrazone and azine derivatives of the antitumor alkaloid acronycine (1) were prepared. NMR spectroscopy was used to study the configurations around the C=N double bond in these acronycine derivatives. In the hydrazones and azines of acronycine the N-N bond assumes a syn configuration to the $C_6-OCH_3$ group, while the NO bond in the oxime and the N-N bond in noracronycine hydrazone and azines assumes an anti configuration.

• Journal of Photoscience
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• v.6 no.3
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• pp.145-151
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• 1999

The use of O-carbamoyloximes as photobase generators was investigated. $\alpha$-Meth-ylbenzilydeneamino phenylcarbamate(2a) and $\alpha$-methyl benzilydeneamino cyclohexylcarbamate(2b) were prepared by the reaction of phenyl or cyclohexyl isocyanates with acetophenone oxime , respectively. Aniline, phenylhydrazine and N, N'-diphenylhydrazine were detected in thephotolysis of 2a and cyclohexylamine and cyclohexylhydrazine in the photolysis of 2b. A monomer having pendant carbamoyloxyimino groups (BGM) was prepared by the reaction fo methancryloyloxyethyl iocyanate with acetophenone oxime, and copolymerized with styrene. The BGM copolymer films turned insoluble on UV irradiation, and the degree of insolubilizationwas increased by post-baking. The photocrosslinking was thought to be due to coupling of resulting pendant aminyl radicals, and the thermal crosslinking was due to association of resulting amino and hydrazino groups by hydrogen bonding. The introduction of epoxy groups into polymer increased the degree of thermal crosslinking by post-baking.