• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2005년도 춘계학술발표대회 개요집
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• pp.370-376
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• 2005

Magnesium alloys are becoming important material for light weight car body, due to their low specific density but high specific strength. However they have a poor weldability, caused high oxidization tendency and low vapor temperature. In this study, the welding performance of magnesium alloys was investigated for automobile application. The materials were rolled magnesium alloy sheet contains Al and Zn such as AZ3l , AZ6l and AZ9l. Three types of welding process were studied, that were GTAW, Laser beam welding and FSW. To evaluate the weldability, we examined the appearance of welding bead. Also we checked bead shape and internal defects such as crack and porosity on cross section of welding bead. The mechanical property was measured for welded specimen by tensile test. For determination of the strength change by welding process, the hardness profile across the welding center was measured. For the results, the tensile properties of welded specimen were decreased obviously on all welding process. For the fusion welding process such as GTAW and laser beam welding, the surface of the welding bead was covered with oxidized magnesium dust but it was removed by simple cleaning work as wipe-out with tissue. Also under cut, that caused vaporization of base metal was occurred. for the friction stir welding, there was no oxidation, under-cut or internal defects. However it had poor weld performance, the reason was cleavage fracture occurred at plastic deformation zone. For welding of magnesium alloy, the laser beam welding process was recommended.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2000년도 하계학술대회 논문집 C
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• pp.2074-2076
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• 2000

In this paper, RFICP equipment is designed and manufactured with the aid of high frequency discharge to produce uniform plasma with high density and large diameter. And $SF_6$ gas is used to investigate plasma characteristics. The electron density and temperature, potential dependence of $SF_6$ plasma in accordance with its operating pressure, gas flux and input power are measured by the method of Langmuir probe. The etching characteristics of the plasma is researched in accordance with operating pressure, gas flux, input power to apply to Silicon Wafer which is used in the field of semiconductor process. The proposed RFICP equipment, in this paper, has relatively excellent etching characteristics, and is thought to be element of oxidization-sheath etching facility in semiconductor manufacturing process.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2004년도 제22회 춘계학술대회논문집
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• pp.385-390
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• 2004

An unique ceramic material produced through unidirectional solidification with eutectic composition of two-phase oxides was introduced recently. This composite material has the microstructure of coupled networks of two single crystals interpenetrate each other without grain boundaries. Depending on this microstructure this material, called Melt Growth Composite (MGC), can sustain its room temperature strength up to 1$700^{\circ}C$ (near its melting point) and offer strong oxidization-resistant ability, making its characteristics quite ideal for the gas turbine application. The research project on MGC started in 2001 with the objective of establishing component technologies for MGC application to the high temperature components of the gas turbine engine. MGC turbine nozzles are expected to improve efficiency of gas turbine. However, reduction of the thermal stress is required since high thermal stress is easily generated in MGC turbine nozzles due to temperature distribution. Firstly, the hollow nozzle shape was optimized to reduce thermal stress using numerical analysis. From the results of the first hot gas flow tests, the thermal stress due to span-wise temperature distribution was required to be reduced, and separated nozzle to three pieces was designed. This was tested in hot gas flow at 140$0^{\circ}C$ level, and temperature distributions on the nozzle surface were obtained and stress field was evaluated.

• 한국자동차공학회논문집
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• 제7권7호
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• pp.42-53
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• 1999

Two dimensional flame temperature and KL value distribution from the luminous flame containing soot in a DI diesel engine were measured by the tow-color method using tow different wavelengths of the flame image. The combustion chamber of a DI diesel engine was visualized by elongating the piston and cylinder and the flame in the combustion chamber was photographed on a nega-color film using a high speed camera. In this study, color CCD camera was used to digitize the three color density of the film exposed to the flame and standard lamp . The accuracy of the measuring method depends on the calibration line of film made from a high temperature standard tungsten lamp. The formation and oxidization of soot in the diesel engine were studied by observing measured time history of KL factor and flame temperature . Also , effects of various shapes of combustion chamber and fuel injection on flame temperature. Also, effects of various shapes of combustion chamber and fuel injection on flame temperature and KL value distribution were examined.

• Transactions on Electrical and Electronic Materials
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• 제9권5호
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• pp.209-212
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• 2008

We developed a simple and effective purification method to obtain high-purity single-walled carbon nanotubes (SWCNTs) with low surface damage. The purification process consists of oxidization at $430^{\circ}C$ for 1 h in a furnace system of air atmosphere and homogenization in dilute hydrochloric acid solution for extremely short time. The role of homogenizer was examined during purification process in terms of purity and quality of purified SWCNTs. High-purity and low surface damage of SWCNT products was obtained using homogenizer which was operated at 8500 rpm for 10 min in the environment of 7 % HCI solution. From XRD spectra, we observed that metal catalysts were thoroughly removed. Raman spectra showed that the intensity values of crystallization ($I_{G}/I_{D}$) of purified SWCNTs were very similar with that of pristine SWCNTs. Moreover, the structure damage of purified SWCNTs was hard to find from electron microscopy. Consequently, homogenizing, which is a quick and simple manner, can be promising method for obtaining final SWCNTs with clearly high purity and crystallinity.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2005년도 금형가공,미세가공,플라스틱가공 공동 심포지엄
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• pp.175-180
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• 2005

In this study, we have developed a novel wire straightener which uses the direct heating method (DHM) fer straightening the micro wire. Also, we have developed a shearing device for cutting the micro wire. In order to avoid the surface oxidization, we supplied the inert gas(Ar) during the heating process and examined the effect of gas flow rate. The effects of the tension and the current applied to the tungsten micro wires were also thoroughly studied. From various experiments and analyses, we could obtain fine straightness $(\approx1\;{\mu}m/1000\;{\mu}m)$ and roundness $(<{\pm}2{\mu}m\;/100{\mu}m)$ when the tension is $500\~~600gf$ and the current is about 1.5A. for burrfree cutting, counter-punch method which two cutters moving contrary was used. The cutting blade has various U-groove angle where upper $10^{\circ}$, $mid:25^{\circ}$, lower $0^{\circ}$. After the shearing process, we confirmed the shearing section.

• Corrosion Science and Technology
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• 제20권4호
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• pp.175-182
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• 2021

Magnesium alloy is limited in the industrial field because its standard electrode potential is -2.363 V vs. NHE (Normal Hydrogen Electrode) at 25 ℃. This high electrochemical activity causes magnesium to quickly corrode with oxygen in air; chemical conversion coating prevents corrosion but causes surface defects like cracks and pores. We have examined the anti-corrosion effect of sol-gel coating sealed on the defected conversion coating layer. Sol-gel coatings produced higher voltage current and smaller pore than the chemical conversion coating layer. The conversion coating on magnesium alloy AZ31 was prepared using phosphate-permanganate solution. The sol-gel coating was designed using trimethoxymethylsilane (MTMS) and (3-Glycidyloxypropyl) trimethoxysilane (GPTMS) as precursors, and aluminum acetylacetonate as a ring-opening agent. The thermal shock resistance was tested by exposing specimens at 140 ℃ in a convection oven; the results showed changes in the magnesium alloy AZ31 surface, such as oxidization and cracking. Scanning electron microscope (FE-SEM) analysis confirmed a sealed sol-gel coating layer on magnesium alloy AZ31. Electrochemical impedance spectroscopy (EIS) measured the differences in corrosion protection properties by sol-gel and conversion coatings in 0.35 wt% NaCl solution, and the potentiodynamic polarization test and confirmed conversion coating with the sol-gel coating show significantly improved resistance by crack sealing.

• 대한금속재료학회지
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• 제49권7호
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• pp.557-564
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• 2011

This paper reports the relationship between the surface roughness and thermal emissivity of graphite (IG-11) in nuclear reactors. The roughness was controlled by changing the oxidization time, resulting in 0, 6, and 11% losses of mass. The levels of roughness were 0.40, 0.72 and 1.09${\mu}m$ for the weight loss of 0, 6 and 11%, respectively. The binders and graphite fillers were found to have sequentially oxidized with a higher thermal emission for the highly oxidized sample, but with a lower emission when measured at a higher temperature. Our study suggests a method for predicting the thermal emission rate of graphite in a nuclear reactor based on roughness measurement.

• 공업화학
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• 제18권3호
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• pp.255-261
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• 2007

망간계 금속산화물을 이용한 저온 선택적 촉매 환원 반응에 대하여 연구하였다. 망간계 금속산화물은 $200^{\circ}C$ 이하의 저온에서 우수한 탈질 특성을 보인다. 온도에 따른 $NH_3/NOx$ 몰비 변화 실험을 통하여 미반응 암모니아의 배출은 몰비가 증가하고 온도가 감소할수록 증가하였으며, $NO_2$의 발생은 반대의 현상을 보였다. $NO_2$는 NO가 촉매 표면에 흡착된 후 nitrate종으로 산화되어 생성되는 것으로 보인다. 촉매 표면에 생성된 nitrate종과 흡착된 암모니아가 반응하기 때문에 $NH_3/NOx$ 몰비 1.0 이상에서도 미반응 암모니아의 배출이 없었다. 담지된 금속산화물의 영향은 Zr은 산화상태를 증가시켜 $NO_2$의 배출이 증가하였으며, Ce를 첨가시킨 경우 $NO_2$ 발생량이 감소하였다. 그러나 금속산화물의 첨가는 전체적으로 NOx 전환율을 감소시켰다

• 한국전기전자재료학회논문지
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• 제23권8호
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• pp.655-659
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• 2010

Nanoporous titanium dioxide ($TiO_2$) is very attractive material for various applications due to the high surface to volume ratio. In this study, we have fabricated nanoporous $TiO_2$ thin films on Si by anodic oxidation. 500-nm-thick titanium (Ti) films were deposited on Si by using electron beam evaporation. Nanoporous structures in the Ti films were obtained by anodic oxidization using ethylene glycol electrolytes containing 0.3 wt% $NH_4F$ and 2 vol% $H_2O$ under an applied bias of 5 V. The diameter of nanopores in the Ti films linearly increased with anodization time and the whole Ti layer could become nanoporous after anodizing for 3 hours, resulting in vertically aligned nanotubes with the length of 200~300 nm and the diameter of 50~80 nm. Upon annealing at $600^{\circ}C$ in air, the anodized Ti films were fully crystallized to $TiO_2$ of rutile and anatase phases. We believe that our method to fabricate nanoporous $TiO_2$ films on Si is promising for applications to thin-film gas sensors and thin-film photovoltaics.