• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 2001년도 학술발표회 논문집(Proceedings of the Korean Textile Conference)
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• pp.285-288
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• 2001

• 한국수소및신에너지학회논문집
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• 제32권5호
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• pp.308-314
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• 2021

Chemical durability issue in polymer electrolyte membranes has been a challenge for the commercialization of polymer electrolyte membrane fuel cells (PEMFCs). In this study, we proposed a manufacturing method of Nafion composite membrane containing a stable polyimide antioxidant to improve the chemical durability of the membrane. The thermal casting of the Nafion solution with poly (amic acid) induced polyimide reaction. We evaluated proton conductivity, oxidative stability with ex-situ Fenton's test, and fluoride ion emission to analyze the effect of polyimide antioxidants. We confirmed that incorporating the polyimide antioxidant improves the chemical durability of the Nafion membrane while maintaining inherent proton conductivity.

• 한국가스학회지
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• 제6권4호
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• pp.40-46
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• 2002

천연가스 수송배관은 매설환경에서의 방식 및 외부충격 등에 대비하여 배관을 보호할 목적으로 폴리에틸렌(polyethylene)으로 피복(coating)되어 있다. 국내 천연가스의 보급과 함께 배관피복 기술도 초기 사용하던 폴리에틸렌 테이프에서, 분말용착식의 1층(one-layer), 압출식의 2층 피복으로 발전되어 현재는 에폭시 층이 도입된 3층 피복 시스템을 적용한 배관들이 전국에 매설되고 있다. 그러나 강관에 적용된 폴리에틸렌 피복이 경우에 따라 장기간사용에 따른 자연균열이 발생하여 피복의 안정성에 문제를 일으키기도 하므로, 상업적인 배관 피복재들의 내구 물성의 분포를 확인하여 천연가스 수송용 배관의 신뢰성 확보에 기여하고자 하였다. 이를 위하여 선진외국에서 폴리에틸렌 배관의 내구성과 장기사용안정성 평가를 위해 오래 전부터 활용되고 있는 저속균열저항성(slow crack growth resistance: SCGR)과 배관 피복층의 산화유도시간(oxidative induction time: OIT)을 측정하여 국내 배관 피복재들의 내구성을 평가하고 이를 근거로 하여 적합한 폴리에틸렌 물성치의 목표값을 제안하였다.

• 한국수소및신에너지학회논문집
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• 제29권5호
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• pp.411-418
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• 2018

The polymer electrolyte membranes, CL-SPEEK/Cellulose composite membrane I, II, III with the improved electrochemical and mechanical properties were prepared and characterized. The engineering plastic polyether ether ketone (PEEK) and cellulose were sulfonated and cross-linked. The membranes were prepared by sol-gel casting method with different amount of cross-linking reagent. In conclusion, the composite membranes I, II, III showed improved thermostability, tensile strength and oxidative durability. Proton conductivity of the membranes was also improved and the composite membrane I showed 0.1312 S/cm at $80^{\circ}C$ which was the best of those composite membranes.

• 멤브레인
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• 제27권2호
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• pp.182-188
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• 2017

본 연구에서는 고분자 전해질 연료전지(PEFC)의 전해질막의 화학적 안정성의 향상을 위하여 3-mercaptopropyl silica gel (3MPTSG)과 poly(arylene ether sulfone)(SPAES)을 이용하여 복합막을 제조하였다. 일반적으로 방향족 탄화수소계 고분자막은 전극 부분에서 발생한 라디컬에 의한 고분자 산화가 일어나 내구성이 감소하게 되는데 이는 대부분 주쇄에 포함된 에테르 기 부분의 취약성으로 발생한다. 본 연구에서는 이러한 라디칼에 의한 고분자 주쇄의 산화를 방지하기 위해 친수성의 무기물 입자를 도입하여 이온전도도 감소율을 최소화하고 산화안정성을 높이고자 하였다. 복합막들의 물성 및 전기화학적 특성을 평가하기 위해 접촉각, FT-IR, 이온전도도, 이온교환용량(IEC), 함수율, 열안정성 등을 수행하였다. 실리카의 함량이 0에서 0.5%까지 증가함에 따라 이온전도도 및 함수율은 각각 10% 감소한 0.076 S cm-1 및 16% 감소한 24.6 wt%이었으나, 산화안정성은 10% 향상되었다.

• 한국결정성장학회지
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• 제16권3호
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• pp.121-126
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• 2006

HVOF thermal spray coating of Co-alloy T800 is progressively replacing the classical hard coatings such as chrome plating because of the very toxic $Cr^{6+}$ ion known as carcinogen causing lung cancer. For the study of the possibility of replacing of chrome plating, the wear properties of HVOF Co-alloy T800 coatings are investigated using the reciprocating sliding tester both at room and at an elevated temperature of $1000^{\circ}F\;(538^{\circ}C)$. The possibility as durability improvement coating is studied for the application to the high speed spindles vulnerable to frictional heat and wear. Wear mechanisms at the reciprocating sliding wear test are studied for the application to the systems similar to the sliding test such as high speed spindles. Wear debris and frictional coefficients of T800 coatings both at room and at an elevated temperature of $1000^{\circ}F\;(538^{\circ}C)$ are drastically reduced compared to those of non-coated surface of parent substrate Inconel 718. This study shows that the coating is recommendable for the durability improvement coatings on the surfaces vulnerable to frictional heat. The sliding surfaces are weared by the mixed mechanisms such as oxidative wear, abrasion by the sliding ball slurry erosion by the mixture of solid particles and small drops of the melts and semi-melts of the attrited particles cavitation by the relative motions among the coating, sliding ball, the melts and semi-melts. and corrosive wear. The oxide particles and the melts and semi-melts play roles as solid and liquid lubricant reducing the wear and friction coefficient.

• 멤브레인
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• 제33권6호
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• pp.279-304
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• 2023

폴리벤즈이미다졸(PBI) 기반의 막은 내구성이 우수한 네트워크 구조를 가지는 구조재료로서의 우수한 강성과 더불어서 고온에서의 우수한 내열성, 우수한 기계적 및 인장 특성, 높은 유리전이온도(T_g), 물이 없는 무수 환경에서의 이온 전도성능, 산화와 화학적 내구성으로 지난 20년 동안 다양한 용도의 대중적인 막 재료로 다양한 문헌에서 보고되어 왔다. 이온 전도성 PBI 기반 막은 고온용 양이온 교환막 연료 전지(HT-PEMFC)에서 광범위하게 사용되어왔다. 또한 PBI 기반 막은 독특한 특성으로 인해 기체분리막 및 유기용매나노여과(OSN) 막 개발에서 광범위하게 사용되어왔다. 이번 리뷰에서는 고온용 연료전지, 기체분리 및 OSN 적용을 위한 다양한 유형의 PBI 기반 막의 최근 연구동향 및 적용가능성에 대해 설명하고자 한다.

• 한국수소및신에너지학회논문집
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• 제22권1호
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• pp.1-12
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• 2011

To improve the mechanical properties, such as durabilities and antioxidative characteristics, the covalently cross-linked (CL-) SPEEK (sulfonated polyether ether ketone)/Cs-substituted HPA (heteropoly acid) organic-inorganic composite membranes (CL-SPEEK/Cs-HPAs), have been intensively investigated. The composite membrane were prepared by blending cesium-substituted HPAs (Cs-HPAs), including tungstophosphoric acid (TPA), molybdophosphoric acid (MoPA), and tungstosilicic acid (TSiA) with cross-linking agent content of 0.01 mL. And composite electrolytes composed of Cs-HPAs, prepared by immersion (imm.) and titration (titr.) methods to increase the stability of HPAs in water, were applied to polymer electrolyte membrane electrolysis (PEME). As a result, the proton conductivity of Cs-substituted composite membranes increased rapidly over $60^{\circ}C$ but mechanical properties, such as tensile strength, decreased in accordance with added Cs content. The bleeding-out of Cs-TPA membranes by titration method (50 vol.% Cs) decreased steadily to 2.15%. In the oxidative stability test by Fenton solution, the durability of membranes with Cs-HPA significantly increased. In case of CL-SPEEK/ Cs-TPA membrane, duration time increased more than 1200 hours. It is expected that even though CL-SPEEK/Cs-MoPA membrane shows the high proton conductivity, electrocatalytic activity and cell voltage of 1.80 V for water electrolysis, the CL-SPEEK/Cs-TPA (imm.) is more suitable as an alternative membrane in real system with the satisfactory proton conductivity, mechanical properties, anti-oxidative stability and cell voltage of 1.89 V.

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 2002년도 연료전지심포지움 2002논문집
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• pp.211-218
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• 2002

In this study, Pt/Pd (1.1), PtPd (2:1) and PtPd (3:1) binary catalysts and Pt/Ru/Pd (5:4:1) ternary catalyst were designed. The catalysts were synthesized by impregnation method using $NaBH_4$ as a reducing agent. A good catalyst for methanol oxidation requires low on-set potential, stable durability and low activation energy. In order to investigate the catalytic activity for the methanol oxidation, electrochemical measurements such as cyclic voltammetry and chronoamperometry were peformed in sulfuric acid with/without methanol solution. In order to calculate the activation energy of the reaction, electrochemical measurements were also tested at different temperatures. For investigation of the structural analysis such as particle size and alloying, X-ray diffraction and transmission electron microscopy analysis were used. In order to identify the role of the Pd and to determine the composition of the surface of the Pt/Pd nanoparticles, X-ray photoelectron spectroscopy (XPS) analysis was investigated. The XPS spectra of Pd showed that Pd appears only as a metallic state in the binary catalysts. The chemical states of Pt in PtPd catalysts are both metallic and oxidative. Polarization curves and power density data were obtained by testing the DMFC unit cell performance of PtPd and PtRuPd catalysts. These data showed that Pt/Pd (2:1) and Pt/Ru/Pd (5:4:1) have better performance than Pt and Pt/Ru, respectively.

• 한국표면공학회지
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• 제39권5호
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• pp.240-244
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• 2006

Tribaloy 800 (T800) powder is coated on the Inconel 718 substrate by the optimal High Velocity Oxy-Fuel (HVOF) thermal spray coating process developed by this laboratory. For the study of the possibility of replacing of the widely used classical chrome plating, friction, wear properties and sliding wear mechanism of coatings are investigated using reciprocating sliding tester both at room and at an elevated temperature of $1000^{\circ}F\;(538^{\circ}C). Both at room temperature and at $538^{\circ}C$, friction coefficients and wear debris of coatings are drastically reduced compared to those of non-coated surface of Inconel 718 substrate. Friction coefficients and wear traces of both coated and non-coated surfaces are drastically reduced at higher temperature of $538^{\circ}C$ compared with those at room temperature. At high temperature, the brittle oxides such as $CoO,\;Co_3O_4,\;MoO_2,\;MoO_3$ are formed rapidly on the sliding surfaces, and the brittle oxide phases are easily attrited by reciprocating slides at high temperature through complicated mixed wear mechanisms. The sliding surfaces are worn by the mixed mechanisms such as oxidative wear, abrasion, slurry erosion. The brittle oxide particles and melts and partial-melts play roles as solid and liquid lubricant reducing friction coefficient and wear. These show that the coating is highly recommendable for the durability improvement coating on the surfaces vulnerable to frictional heat and wear.