• 제목/요약/키워드: Oxidation treatment

검색결과 1,920건 처리시간 0.031초

Oxidation and Isomerization of Lycopene under Thermal Treatment and Light Irradiation in Food Processing

  • John Shi;Ying Wu;Mike Bryan;Maguer, Le Marc
    • Preventive Nutrition and Food Science
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    • 제7권2호
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    • pp.179-183
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    • 2002
  • Lycopene as a natural antioxidant may provide protection against a broad range of epithelial cancers and chronic diseases. Lycopene concentrate extracted from tomatoes can be used as functional food. Lycopene would undergo degradation via isomerization and oxidation under different processing conditions, which impact its bioactivity and reduce the fuuctionality for health benefits. Heat and light induce lycopene oxidation and isomerization of all-trans form to cis form. The effects of thermal treatment and light irradiation on the stability of lycopene were determined. Results have shown that lycopene stability depends on the extent of oxidation and isomerization. Cir-isomers are less stable than trans-isomers. The level of cis-isomers increased as treatment time increased but only for a short period during the beginning of the treatment. The major effect of thermal treatment and light irradiation was a significant decrease in the total lycopene content. A true assessment of health benefits of lycopene concentrate depends on the lycopene content and the composition of all trans-isomers and cia-isomers.

Bioremediation of Phenolic Compounds Having Endocrine-disrupting Activity Using Ozone Oxidation and Activated Sludge Treatment

  • Nakamura, Yoshitoshi;Daidai, Masakazu;Kobayashi, Fumihisa
    • Biotechnology and Bioprocess Engineering:BBE
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    • 제9권3호
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    • pp.151-155
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    • 2004
  • The bioremediation of water system contaminated with phenolic compounds having endocrine-disrupting activity, i.e. 2,4-dichlorophenol, 2,4-dichlorophenoxy acetic acid (2,4-D), and 2,4,5-trichlorophenoxy acetic acid (2,4,5-T), was investigated by using ozone oxidation and activated sludge treatment. Ozone oxidation (ozonation time: 30 min) followed by activated sludge treatment (incubation time: 5 days) was an efficient treatment method for the conversion of phenolic compounds in water into carbon dioxide and decreased the value of total organic carbon (TOC) up to about 10% of initial value. Furthermore, 2,4-D was dissolved in water containing salt, i.e. artificial seawater (ASW), and this water was used as model coastal water contaminated with phenolic compounds. The activated sludge treatment (incubation time: 5 days) could consume significantly organic acids produced from 2,4-D in the model costal water by the ozone oxidation (ozonation time: 30min) and decrease the value of TOC up to about 35% of initial value.

GaN/Sapphire(0001) 기판위에 증착한 epitaxial Ni(111) 박막의 산화 과정 (Oxidation Process of Epitaxial Ni(111) Thin Films Deposited on GaN/Sapphire(0001) Substrates)

  • 서선희;강현철
    • 열처리공학회지
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    • 제22권6호
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    • pp.354-360
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    • 2009
  • This paper reports the oxidation mechanism of epitaxial Ni thin films grown on GaN/sapphire(0001) substrates, investigated by real-time x-ray diffraction and scanning electron microscopy. At the initial stage of oxidation process, a thin NiO layer with a thickness of ${\sim}50\;{\AA}$ was formed on top of the Ni films. The growth of such NiO layer was saturated and then served as a passive oxide layer for the further oxidation process. For the second oxidation stage, host Ni atoms diffused out to the surfaces of initially formed NiO layer through the defects running vertically to form NiO grains, while the sites that were occupied by host Ni, became voids. The crystallographic properties of resultant NiO films, such as grain size and mosaic distribution, rely highly on the oxidation temperatures.

상수처리에서 염소 및 오존산화를 이용한 색도제거 (Chromaticity removal by chlorine and ozone oxidation in water treatment)

  • 이정훈;김진근
    • 상하수도학회지
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    • 제31권4호
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    • pp.273-279
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    • 2017
  • Optimal processes to remove chromaticity at E water treatment plant(WTP) mainly caused by algae of E lake in Jeju island were investigated based on lab-tests of chlorine and ozone oxidation. 42.9% of chromaticity of filtered water was removed by chlorine oxidation under pH 7.0~8.0, dose of 1.0 mg/L with contact time of 30~60 min. On the other hand, chromaticity removal was 71.4% when post-ozone dose of 0.9~1.9 mg/L and pH 9.0, while it was increased to 86.7% under post-ozone dose of 3.1~7.3 mg/L and pH 9.0. However, there was no significant chromaticity removal efficiency increase when ozone doses were higher than 5.0 mg/L regardless of feeding point(i.e., pre-ozonation and post-ozonation) and pHs(i.e., 7.0 and 9.0.) under the experimental conditions. Based on the results, chlorine oxidation using existing chlorination facilities at the WTP is recommended for lower chromaticity while ozone oxidation is recommended for higher chromaticity by installing new ozone feeding facilities.

Progresses in membrane and advanced oxidation processes for water treatment

  • Khulbe, K.C.;Feng, C.Y.;Matsuura, T.;Ismail, A.F.
    • Membrane and Water Treatment
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    • 제3권3호
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    • pp.181-200
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    • 2012
  • At present water crisis is not an issue of scarcity, but of access. There is a growing recognition of the need for increased access to clean water (drinkable, agricultural, industrial use). An encouraging number of innovative technologies, systems, components, processes are emerging for water-treatment, including new filtration and disinfectant technologies, and removal of organics from water. In the past decade many methods have been developed. The most important membrane-based water technologies include reverse osmosis (RO), ultrafiltration (UF), microfiltration (MF), and nanofiltration. Beside membrane based water-treatment processes, other techniques such as advanced oxidation process (AOP) have also been developed. Some unconventional water treatment technology such as magnetic treatment is also being developed.

Effect of Packaging Method on the Lipid Oxidation, Protein Oxidation, and Color in Aged Top Round from Hanwoo (Korean Native Cattle) during Refrigerated Storage

  • Kang, Sun Moon;Kang, Geunho;Seong, Pilnam;Park, Beomyoung;Cho, Soohyun
    • 한국축산식품학회지
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    • 제34권3호
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    • pp.273-279
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    • 2014
  • The objective of this study was to investigate the effects of the packaging method on the lipid and protein oxidation, and color in aged top round from Hanwoo (Korean native cattle) for 14 d at $4^{\circ}C$. Catalase activity was the highest (p<0.05) in vacuum packaging (VP) treatment during storage, and was higher (p<0.05) in 50% Ox-MAP and 50% Ox-MAP+vacuum skin packaging (VSP) treatments than in other treatments at d 14. Superoxide dismutase activity was higher (p<0.05) in VP, 50% Ox-MAP, and 50% Ox-MAP+VSP treatments than in other treatments at d 14. During storage, total antioxidant activity was the highest (p<0.05) in VP treatment and was higher (p<0.05) in 50% Ox-MAP+VSP treatment than in 80% Ox-MAP treatment. TBARS value was the lowest (p<0.05) in VP treatment during storage and was lower (p<0.05) in 50% Ox-MAP and Ox-MAP+VSP treatments than in 80% Ox-MAP and Ox-MAP treatments, respectively. Carbonyl content was the lowest (p<0.05) in VP treatment from 10 d. From 7 d, the $a^*$ value was the highest (p<0.05) in VP treatment and was higher (p<0.05) in 50% Ox-MAP and 50% Ox-MAP+VSP treatments than in other treatments. The $b^*$ value was the highest (p<0.05) in VP treatment from 3 d, and was higher (p<0.05) in 80% Ox-MAP+VSP, 50% Ox-MAP, and 50% Ox-MAP+ VSP treatments than in 80% Ox-MAP treatment at d 14. Therefore, VP improved the oxidation and red color stabilities in stored-aged top round compared with Ox-MAP. In addition, 50% Ox-MAP improved the lipid oxidation and red color stabilities compared with 80% Ox-MAP, and its inhibitory effect on lipid oxidation was enhanced by combination with VSP.

유기성 폐수의 오존전해처리에 관한 연구 (A Study on the Treatment of Organic Wastewater by Ozone Electrolysis)

  • 정홍기;이태호
    • 환경위생공학
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    • 제11권2호
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    • pp.59-63
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    • 1996
  • To treat certain wastewater that has alcohol and phenol, we performed the ozone electrolysis by using the titanium electrode. In this experiment, we examined decomposition voltage of organics, time for electrolysis, and removal efficiency of organics. In addition we compared the ozone oxidation electrolysis. The followings are results; 1. When it comes to the alcohol treatment in wastewater, ozone electrolysis showed higher removal efficiency than ozone oxidation or electrolysis. 2. After comparing the decomposition rate of methylalcohol, ethylalcohol, and prophylalcohol in ozone electrolysis, we knew the fact that increasing carbon number made the decomposition rate slow. 3. According to the treatment of alcohol by ozone electrolysis, decomposition voltage was 50V, time for electrolysis was three hours, and treatment acidity was neutral (pH 6.5 - 8.1). 4. Ozone electrolysis was effective to the phenol treatment. When we treated phenol by using ozone electrolysis for three hours, TOC treatment efficiency was 95%. However, ozone oxidation just showed 45% treatment efficiency.

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소화탈리액 대상 오존 전처리와 Ultra Violet-Advanced Oxidation Process 연계 처리를 통한 유기물질 지표 개선 (Improvement of Organic Substances Indicators by Linked Ultra Violet-Advanced Oxidation Process After Ozonation for Anaerobic Digested Wastewater)

  • 이재엽;제스민아터;김일호
    • 상하수도학회지
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    • 제37권5호
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    • pp.253-259
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    • 2023
  • Bioreactors are devices used by sewage treatment plants to process sewage and which produce active sludge, and sediments separated by solid-liquid are treated in anaerobic digestion tanks. In anaerobic digestion tanks, the volume of active sludge deposits is reduced and biogas is produced. After dehydrating the digestive sludge generated after anaerobic digestion, anaerobic digested wastewater, which features a high concentration of organic matters, is generated. In this study, the decomposition of organic carbon and nitrogen was studied by advanced oxidation process. Ozone-microbubble flotation process was used for oxidation pretreatment. During ozonation, the TOC decreased by 11.6%. After ozone treatment, the TOC decreased and the removal rate reached 80.4% as a result of the Ultra Violet-Advanced Oxidation Process (UV-AOP). The results with regard to organic substances before and after treatment differed depending on the organic carbon index, such as CODMn, CODCr, and TOC. Those indexes did not change significantly in ozone treatment, but decreased significantly after the UV-AOP process as the linkage treatment, and were removed by up to 39.1%, 15.2%, and 80.4%, respectively. It was confirmed that biodegradability was improved according to the ratio of CODMn to TOC. As for the nitrogen component, the ammonia nitrogen component showed a level of 3.2×102 mg/L or more, and the content was maintained at 80% even after treatment. Since most of the contaminants are removed from the treated water and its transparency is high, this water can be utilized as a resource that contains high concentrations of nitrogen.

플라즈마 광촉매 복합 긍정을 이용한 악취물질 중 TEA, MEK의 분해처리 (Treatment of Odorous air pollutants by Plasma and Photocatalytic Process.)

  • 최금찬;정창훈
    • 한국환경과학회지
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    • 제12권12호
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    • pp.1255-1260
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    • 2003
  • Plasma-photocatalytic oxidation process was applied in the decomposition of Triethylamine(TEA) and Methyl ethyl ketone(MEK). Plasma reactor was made entirely of pyrex glass and consists of 24mm inner diameter, 1,800mm length and discharge electrode of 0.4mm stainless steel. And initial concentrations of TEA and MEK for plasma-photocatalytic oxidation are 100 ppm. Odor gas samples were taken by gas-tight syringe from a glass sampling bulb which was located at reactor inlet and outlet, and TEA and MEK were determined by GC-FID. For plasma process, the decomposition efficiency of TEA and MEK were evaluated by varying different flowrates and decomposition efficiency of TEA and MEK increased considerably with decreasing treatment flowrates. For photocatalytic oxidation process, also the decomposition efficiency of TEA and MEK increased considerably with decreasing treatment flowrates. The decomposition efficiency of MEK was 57.8%, 34.2%, 18.8% respectively and the decomposition efficiency of TEA was reached all 100%. This result is higher than that of plasma process only, From this study, the results indicate that plasma-photocatalytic oxidation process is ideal for treatment of TEA and MEK.

표면개질을 달리한 자동차 변속기어의 마멸특성 비교 (Comparision of Wear Characteristics of Automobile Transmission Gear on Surface Modification)

  • 류을현;조연상;김영희;박흥식
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2003년도 학술대회지
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    • pp.299-306
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    • 2003
  • The SCM420 used mainly to automobile transmission gear has problems that it costs transmission gear maker much money in carburizing treatment. For this, it needs to alternate the existing material and heat treatment to new gear material and surface modification. For this, friction and wear experiment according to sliding speed and applied load was carried out to evaluate the wear resistance of two transmission gear materials with oxidation nitrocarburising and non-oxidation nitrocarburising NT100, The presumed wear volume was calculated with the image processing for evaluation of wear resistance of two transmission gear materials. The results show that the oxidation nitrocarburising has a distinguished wear resistance than non-oxidation nitrocarburising.

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