• Title/Summary/Keyword: Oxidation resistant

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A Study on the Oxidation Resistance of Aluminum Cast Iron by Aluminum Content (알루미늄 함량에 따른 알루미늄 주철의 내산화성에 관한 연구)

  • Kim, Dong-Hyuk
    • Journal of Korea Foundry Society
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    • v.40 no.6
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    • pp.135-145
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    • 2020
  • Aluminum cast iron has excellent oxidation resistance, sulfurization resistance, and corrosion resistance. However, the ductility at room temperature is insufficient, and at temperatures above 600?, the strength drops sharply and practicality is limited. In the case of heat-resistant cast iron, high-temperature materials containing Cr and Ni account for 30 to 50% or more. However, these high-temperature materials are expensive. Aluminum heat-resistant cast iron is considered as a substitute for expensive heat-resistant materials. Oxidation due to the aging temperature and holding time conditions increases more in 0 wt.% Al-cast iron than in 2 and 4 wt.% Al-cast iron according to oxidized weight and gravimetric oxide layer thickness measurements. As a result of observing the cross-section of the oxide layer, it was found to contain 0 wt.% of Al-cast iron silicon oxide-containing SiO2 or Fe2SiO4 oxide film. In cast iron containing aluminum, the thickness of the internal oxide layer due to aluminum increases as the aging temperature and retention time increase, and the amount of the iron oxide layer generated on the surface decreases.

A Study on Improvement of Material Characteristics by Control of Ion Implantation (이온주입 제어에 의한 재료특성 개선에 관한 연구)

  • Yang, Young-Joon;Lee, Chi-Woo;Fujita, Kazuhisa
    • Journal of Advanced Marine Engineering and Technology
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    • v.32 no.8
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    • pp.1178-1184
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    • 2008
  • In this study, techniques of ion implantation were used in order to improve the characteristics of metal materials such as the oxidation and wear resistant. In particular it is necessary to develope their oxidation and wear resistant that could be used in severe environmental conditions. There are mainly two elementary technologies including ion implantation and/or thin film coating. Ion implantation method was performed for surface modification. As a result, it was found that some ion implantations methods such as Nb, high-temperature Nb ion implantation and Nb+C combined implantation are somewhat effective for improving the oxidation resistance of TiAl alloy. Furthermore, the fluorine PBII treatment is more effective for improving the oxidation resistance of the TiAl alloy with three-dimensional shapes. The implantation of boron ion into thin film of TiN was also effective for improving the properties of materials like high temperature wear resistance. TiCrN film was applied to the actual seal ring for steam turbines, and it was observed that its sliding property showed a successfully good performance.

Effects of Palladium Buffer Layer on the Oxidation Resistance of Inconel 738LC Oxidation Resistant Coating Layer by Pt Modified-pack Aluminizing (Inconel 738LC의 Pt Modified-pack Aluminizing 내산화 코팅의 산화저항성에 미치는 Palladium 완충층의 영향)

  • Han W. K.;Choi J. W.;Hong S. J.;Hwang G. H.;Kang S. G.
    • Korean Journal of Materials Research
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    • v.15 no.4
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    • pp.233-239
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    • 2005
  • In this study, the effects of Pd buffer layer on the oxidation resistance of Pt modified-pack aluminized Inconel 738LC, used for gas turbine, were investigated. Pd was electroplated on Inconel 738LC, and Pt was electroplated on the electroplated Pd surface. Thus, the thickness of electroplated Pt/Pd was $10\;{\mu}m$ and the atomic ratio of Pt : Pd was about 6 : 4. After Pt/Pd electroplating, Inconel 738LC was pack aluminized to form the oxidation resistant layer. To investigate the oxidation resistance of Pt/Pd modified-pack aluminized Inconel 738LC, iso-thermal oxidation and cyclic oxidation were performed. The iso-thermal oxdation and the cyclic oxidation data indicated that the Pt/Pd modified-pack aluminized Inconel 738LC was more oxidation resistant than the Pt modified-pack aluminized Inconel 738LC. It was thought that the difference of thermal expansion coefficient between Inconel 738LC and Pt was lowered by the Pd buffer layer.

Study on Antibiotic Resistant Enterobacteria in Pharmaceutical Effluent (제약회사 폐수처리장 방류수 중 항생제 내성 Enterobacteria에 관한 연구)

  • Kim, Jae-Gun;Kim, Young Jin
    • Journal of Environmental Health Sciences
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    • v.42 no.1
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    • pp.34-40
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    • 2016
  • Objectives: This study aims to examine the concentration, diversity, and antibiotic characteristics of penicillin G resistant enterobacteria present in pharmaceutical effluent. Methods: Water sampling was performed from a pharmaceutical company in Gyeonggi-do Province, Korea in March 2015. Water samples were plated in triplicate on tryptic soy agar plates with 32 mg/L of penicillin G. Penicillin G resistant enterobacteria were selected from the effluent and were subjected to 16S rRNA analysis for penicillin G resistant species determination. Identified resistant strains were tested for resistance to various antibiotics. Results: Penicillin G resistant enterobacteria were present at 6.2% as to culturable heterotrophic bacteria. Identified penicillin G resistant enterobacteria exhibited resistance to more than 10 of the antibiotics studied. These resistant bacteria are gram negative and are closely related to pathogenic species. Conclusion: Multi-antibiotic resistant bacteria in the effluent suggest a need for disinfection and advanced oxidation processes for pharmaceutical effluents.

Enhanced Flame Resistant Properties of Aluminum Hydroxide Addition on Electrospun Polyurethane Nanofibers (전기방사법에 의해 제조된 폴리우레탄 나노섬유의 수산화알루미늄 내첨에 의한 내염화 특성 향상)

  • Kim, Hyeong Gi
    • Fire Science and Engineering
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    • v.30 no.6
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    • pp.9-13
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    • 2016
  • Anti-oxidation and flame resistant polyurethane nanofibers were prepared by electrospinning and aluminum hydroxide addition. Electrospinning was carried out under the following procedure conditions; applied voltage, 20 kV; polymer solution feeding rate, 1.2 ml/h; collector rolling speed, 120 rpm; and tip to collector distance, 15 cm. Aluminum hydroxide was added to the prepared polymer solution for electrospinning to enhance the oxidation and flame resistant properties. The thermal properties were investigated by thermogravimetric analysis to determine the polymer decomposition temperature, integral procedure decomposition temperature, final decomposition temperature, and remaining amount after thermal decomposition. The activated energy for polymer degradation was also investigated using the Horowitz-Metzger equation. The activation energy increased to more than 50%. The thermal properties of the polyurethane nanofibers were improved by a hydration reaction during the thermal decomposition of aluminum hydroxide around $300{\sim}500^{\circ}C$.

Anodic Oxidation (양극 산화)

  • 노해용
    • Journal of the Korean Professional Engineers Association
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    • v.33 no.6
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    • pp.16-23
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    • 2000
  • Anodizing processes is the conversion of the aluminum surface to aluminum oxide while the part is the anode in an electrolytic cell. The object of the anodizing was increased corrosion resistant, paint adhesion and was provided unique, decorative colors. Many electrolytes, under different conditions, have been used for the anodic oxidation of alumminum and its alloys. This paper deals with the procedures used in the anodic oxidation of aluminum and its alloys, the nature and properties of the oxide films, their uses and anodizing equipment and process control.

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Study on Antibiotic Resistant Bacteria in Surface Water Receiving Pharmaceutical Complex Effluent (제약공단 방류수 유입 하천에서의 항생제 내성 bacteria에 관한 연구)

  • Kim, Young Jin;Kim, Young Gyu
    • Journal of Environmental Health Sciences
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    • v.42 no.6
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    • pp.409-418
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    • 2016
  • Objectives: The purpose of this study was to characterize penicillin G resistant bacteria in surface water from pharmaceutical complex effluent. Methods: Surface water was sampled from pharmaceutical complex effluent in Gyeonggi-do Province, Korea in March 2015. Water samples were plated in triplicate on tryptic soy agar plates with 32 mg/L of penicillin G. Penicillin G resistant bacteria were selected from the effluent and subjected to 16S rRNA analysis for the penicillin G resistant species determination. Identified resistant strains were tested for resistance to various antibiotics. Results: Penicillin G resistant bacteria were present at 8.0% in terms of culturable heterotrophic bacteria. Identified penicillin G resistant bacteria exhibited resistance to more than nine of the antibiotics studied. These resistant bacteria are gram negative and are closely related to pathogenic species. Conclusion: Multi-antibiotic resistant bacteria in the surface water of pharmaceutical complex effluent suggest the need for disinfection and advanced oxidation processed for pharmaceutical effluent.

Improving Accident Tolerance of Nuclear Fuel with Coated Mo-alloy Cladding

  • Cheng, Bo;Kim, Young-Jin;Chou, Peter
    • Nuclear Engineering and Technology
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    • v.48 no.1
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    • pp.16-25
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    • 2016
  • In severe loss of coolant accidents (LOCA), similar to those experienced at Fukushima Daiichi and Three Mile Island Unit 1, the zirconiumalloy fuel claddingmaterials are rapidlyheateddue to nuclear decay heating and rapid exothermic oxidation of zirconium with steam. This heating causes the cladding to rapidly react with steam, lose strength, burst or collapse, and generate large quantities of hydrogen gas. Although maintaining core cooling remains the highest priority in accident management, an accident tolerant fuel (ATF) design may extend coping and recovery time for operators to restore emergency power, and cooling, and achieve safe shutdown. An ATF is required to possess high resistance to steam oxidation to reduce hydrogen generation and sufficient mechanical strength to maintain fuel rod integrity and core coolability. The initiative undertaken by Electric Power Research Institute (EPRI) is to demonstrate the feasibility of developing an ATF cladding with capability to maintain its integrity in $1,200-1,500^{\circ}C$ steam for at least 24 hours. This ATF cladding utilizes thin-walled Mo-alloys coated with oxidation-resistant surface layers. The basic design consists of a thin-walled Mo alloy structural tube with a metallurgically bonded, oxidation-resistant outer layer. Two options are being investigated: a commercially available iron, chromium, and aluminum alloy with excellent high temperature oxidation resistance, and a Zr alloy with demonstratedcorrosionresistance.Asthese composite claddings will incorporate either no Zr, or thin Zr outer layers, hydrogen generation under severe LOCA conditions will be greatly reduced. Key technical challenges and uncertainties specific to Moalloy fuel cladding include: economic core design, industrial scale fabricability, radiation embrittlement, and corrosion and oxidation resistance during normal operation, transients, and severe accidents. Progress in each aspect has been made and key results are discussed in this document. In addition to assisting plants in meeting Light Water Reactor (LWR) challenges, accident-tolerant Mo-based cladding technologies are expected to be applicable for use in high-temperature helium and molten salt reactor designs, as well as nonnuclear high temperature applications.

A Study on Development of Advanced Environmental-Resistant Materials Using Metal Ion Processing

  • Fujita Kazuhisa;Kim Hae-Ji
    • Journal of Mechanical Science and Technology
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    • v.20 no.10
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    • pp.1670-1679
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    • 2006
  • The development of the oxidation, wear and corrosion resistant materials that could be used in severe environmental conditions is needed. The elementary technologies for surface modification include ion implantation and/or thin film coating. Furthermore, in order to develop ion implantation technique to the specimens with three-dimensional shapes, plasma-based ion implantation (PBII) techniques were investigated. As a result, it was found that the ion implantation and/or thin film coating used in this study were/was effective for improving the properties of materials, which include implantations of various kinds of ions into TiAl alloy, TiN films formed on surface of base material and coatings in high-temperature steam. The techniques proposed in this study provide useful information for all of the material systems required to use at elevated temperature. For the practical applications, several results will be presented along with laboratory test results.

The Characteristic in Mg Alloy with Burning and Plasma Electrolyte Oxidation Surface Treatment (Mg Alloy의 Burning과 Plasma Electrolyte Oxidation 표면처리에 대한 연구)

  • Yu, Jae-In;Choi, Soon-Don;Jang, Ho-Kyeoung
    • Journal of the Korean Vacuum Society
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    • v.19 no.5
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    • pp.326-330
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    • 2010
  • The surface oxidation of magnesium was performed by burning and PEO treatment method. The scanning electron microscopy (SEM), EDS, and I-V characteristics have been applied to the study of the oxidation status. The sample formed by buring method shows weaker corrosion-resistant property than that by PEO method, but this shows more conducting property.