• Title/Summary/Keyword: Oxidation and Reduction Products

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Effect of Doenjang (Korean Fermented Soybean Paste) on Lipid Oxidation and Cooking Properties of Pork Patties

  • Oh, Hyun-Ju;Kim, Chang-Soon
    • Food Science and Biotechnology
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    • v.18 no.5
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    • pp.1138-1144
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    • 2009
  • This study was carried out to investigate the cooking properties and lipid oxidation stability during storage at $4{\pm}1^{\circ}C$ when the various levels (5 to 20%) of doenjang (Korean fermented soybean paste) were added to pork patties cooked by pan frying (PF) and convection oven (CO). With increasing the addition of doenjang, cooking properties of pork patties revealed the improved cooking yield, less diameter reduction, and less thickness increase. Also, the shear force, hardness, and chewiness of pork patties were reduced. The PF cooking method showed better cooking properties than CO. Lipid oxidation expressed by the thiobarbituric acid reactive substances (TBARS) values was significantly reduced by the addition of more than 5% doenjang (p<0.05). The TBARS values of cooked pork patties by PF were significantly lower than CO during the 8 days of the storage (p<0.05). The development of warmed-over flavor (WOF) in cooked pork patties was delayed as the amount of the doenjang was increased. It was suggested that the addition of doenjang and PF favorably affected the cooking properties and stability of lipid oxidation in pork patties.

The Effects of Glass Color Tone by Oxidation Power Index (발화력지수(醱化力指數)가 유리색조(色調)에 미치는 영향(影響))

  • Park, Eun-Seong;Park, Byeong-Gi
    • Journal of Korean Society for Quality Management
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    • v.16 no.1
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    • pp.1-7
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    • 1988
  • The most important element upon the quality of family glass products is the color of glass, which is the first object of consumers concern in purchasing. Therefore, colorless and transparent color tone can level up the additional value of the products. But we have produced the glass products in a large quantity by using the automatic tank brazier, chronic problem has been left over the color tone. By compounding and analizing the management techniques applied by peculiar technique and design of experiments pertinently, and by adjusting the decoloring composition ratio, we can contribute to improvement of color tone as well as to the cost reduction by diminishing the unnecessary decoloring agent. Intangible effect was the securing the superiority of quality home and abroad with the improvement of color tone and was taking a triangular position the factors influencing the glass decoloring which had been an unexhausted field. Tangible effect was the reduction of decoloring cost by diminishing the unnecessary oxidant. We registered the optimal composition ratio condition which was searched by applicating the design of experiments. To maintain good color tone, we manage the degree of purity, the most important thing among the items of color tone, continuously by control chart and it has maintained steady state now.

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Characterization of Field-Aged Polymer Insulators for Distribution Power Systems (배전용 폴리머애자의 현장열화 특성평가)

  • 이병성;김찬영;한재홍
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.10
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    • pp.847-858
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    • 2000
  • The aging characteristics of 2 kinds of 3 years field-aged distribution polymer insulators which were dismounted from 5 regions have been investigated by electrical test and material characterization. Although the tan $\delta$of specimens prepared from weathershed was increased with surface aging, the tan $\delta$and leakage current of real products had no difference between virgin and dismounted ones. Due to the aging, all dismounted polymer insulators had micro-cracks on the surface of weathershed and only the products of manufacturer B showed the reduction of OIT(oxidation induction time). But, there were no differences between virgin and dismounted products in contact angle and chemical structure. Therefore, it can be considered that the aging is only limited on the surface of dismounted polymer insulators and that NMR technique are very useful to evaluate the aging of polymer materials.

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Synthesis of nickel fine powder in the mixed solvent of water and ethanol and ie oxidation behaviors (물과 에탄올의 혼합용매로부터 니켈 미분말의 합성 및 산화특성)

  • 이상근;최은영;이윤복;김광호;박희찬
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.3
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    • pp.139-144
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    • 2003
  • Nickel fine powders were prepared from nickel chloride aqueous solution containing ethanol as an organic solvent, and their oxidation behaviors were investigated. The reduction reaction by hydrazine from nickel chloride aqueous solution containing ethanol depend on reaction temperature. The reduction reaction time by hydrazine decreased with the increase of reaction temperature. By controlling reaction temperature, the products could be obtained spherical particles in the range of 0.1 $\mu\textrm{m}$~1.0 $\mu\textrm{m}$. Also, As reaction temperature increased from $40^{\circ}C$ to $80^{\circ}C$, the particle size slightly increased and had a broad size distribution owing to the presence of the coarse particles. The mean particle size and specific surface area of nickel powders prepared at $60^{\circ}C$ were 0.3 $\mu\textrm{m}$ and 31.8 $\m^2$/g, respectively. Weight loss of the powders at $300^{\circ}C$ was due to composition of $_Ni(OH)2$. In case of heat treatment at $200^{\circ}C$ in air, oxidation resistance of nickel powders was remarkable than that of as-synthesized.

Study on uranium metalization yield of spent pressurized water reactor fuels and oxidation behavior of fission products in uranium metals (사용후핵연료의 우라늄 금속 전환율 측정 및 전환체 내 핵분열생성물의 산화거동 연구)

  • Choi, Ke Chon;Lee, Chang Heon;Kim, Won Ho
    • Analytical Science and Technology
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    • v.16 no.6
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    • pp.431-437
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    • 2003
  • Metalization yield of uranium oxide to uranium metal from lithium reduction process of spent pressurized water reactor (PWR) fuels was measured using thermogravimetric analyzer. A reduced metal produced in the process was divided into a solid and a powder part, and each metalization yield was measured. Metalization yield of the solid part was 90.7~95.9 wt%, and the powder being 77.8~71.5 wt% individually. Oxidation behaviour of the quartemary alloy was investigated to take data on the thermal oxidation stability necessary for the study on dry storage of the reduced metal. At $600{\sim}700^{\circ}C$, weight increments of alloy of Mo, Ru, Rh and Pd was 0.40~0.55 wt%. Phase change on the surface of the alloy was started at $750^{\circ}C$. In particular, Mo was rapidly oxidized and then the alloy lost 0.76~25.22 wt% in weight.

A Novel Synthesis of 3,9-Dialkyl and 8-Aryl-3,9-dimethylxanthines

  • Youssif, Shaker;El-Kafrawy, Azza;Bayoumy, Besheer;El-Bahaie, Said
    • Bulletin of the Korean Chemical Society
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    • v.23 no.3
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    • pp.374-380
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    • 2002
  • Several compounds of 3,9-dialkylxanthines were prepared from 1-methyl-6-chlorouracil via nucleophillic reactions with different aliphatic amines, followed by nitrosation, reduction, formaylation and finally dehydrocyclization. On the other hands, a series of 8-aryl-3,9-dimethylxanthines were synthesized by dehydrocyclization of 5-arylamido-1-methyl-6-methylaminouracils either by fussion or oxidation of 5-arylidine-amino-1-methyl-6-methylaminouracils using sodium periodate. Phosphoryl chloride was found to be uneffective reagent for dehydrocyclization that, gave another products from 1,3-oxazolo[5,4-d] pyrimidines.

Storage Stability of Freeze Dried Loach for Instant Choo-o-tang (즉석 추어탕을 냉동 건조미꾸라지의 저장성)

  • 류홍수;문숙임;이수정;문갑순
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.28 no.1
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    • pp.153-160
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    • 1999
  • Storage stability of boiled and freeze dried loach and antioxidative effect of Zanthoxylum schinifolium were studied to confirm the possibility in development of instant choo o tang(Korean traditional loach soup). Packaging and storage temperature did not cause a measurable change in in vitro protein digestibility and trypsin indigestible substrate within 45 days of storage but remarkable quality changes were occurred in all samples stored after 60 days. Vacuum packaging and low temperature storage(4 oC) had some effect in retarding protein quality deterioration due to delaying polyunsaturated fatty acid oxidation. Maximum peroxide value and TBA value were reached in 15 days, and there were a slow(TBA value) and rapid reduction(POV) after peaks were reached. In contrast, increasing brown pigment development and fluorescence intensity continued until 90 days of storage. Treatment of ethanolic extracts from Zanthoxylum schinifolium prior to freeze drying could protect against lipid oxidation of freeze dried loach products.

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'Studies on the Synthesis of Cyclitol derivatives' -Synthesis of Inositols, p-Hydroxybenzoates and thier Antimicrobial test for food industry ('Cyclitol 유도체(誘導體) 합성(合成)에 관(關)한 연구(硏究)' -Inositol stereomer 와 p-Hydroxybenzoate의 합성(合成)과 식품공업상(食品工業上) 응용(應用)을 위한 항균시험(抗菌試驗)-)

  • Sohn, Joo-Hwan
    • Applied Biological Chemistry
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    • v.13 no.3
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    • pp.197-205
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    • 1970
  • Inositols are cyclohexanehexol and they have been known to be nine stereomers. Scyllo-inositol, epi-inositol and muco-inositol could be synthesized from myo-inositol. Scyllo-inositol and epi-inositol were obtained by oxidation and reduction process from myo-inositol. Myo-inositol and epi-inositol were oxidized by treatment, in solution, with dilute hydrogen peroxide. In all cases, only axial hydroxyl groups were oxidized and monoketons were obtained. Reduction of myo-inosose-2 with sodium boron hydride was carried out in $pH2{\sim}3.$ The reduction products were equatorial alcohol but: reduction of DL-epi-inosose-2 by catalytic reduction produced axial alcohol obtained. Inositol could be esterified. Hexa-O-(p-hydroxy benzoyl)-esters of myo-inositol, scyllo-inositol, epi-inositol and muco-inositol were synthesized and their antimicrobial action on microbes were tested for application to food industry. As the results, it was found that the activities of muco-inositol ester was more vigorous than others.

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The effects of dietary photosensitizers on auto-oxidation of gallic and tannic acids (갈산과 타닌산의 자동산화에 미치는 식품 감광성분의 영향)

  • Lee, Eunbin;Lee, Hyowon;Hong, Jungil
    • Korean Journal of Food Science and Technology
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    • v.54 no.3
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    • pp.272-279
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    • 2022
  • Polyphenols are chemically unstable, and their bioactivities are reduced through oxidation. Photosensitizers (PS) induce photo-oxidation in various food systems. In this study, effects of dietary PS such as riboflavin (Rb), erythrosin B (EB), and zinc protoporphyrin on the auto-oxidation of polyphenols, gallic acid (GA) and tannic acid (TA) were evaluated under a fluorescent light. The formation of oxidation products from GA and TA increased in a PS concentration- and irradiation time-dependent manner. In addition, Rb and EB induced significant reduction in the polyphenols contents and ABTS radical scavenging activity of GA and TA under light. PS significantly enhanced the amount of reactive oxygen species generated from GA and TA. Therefore, the interaction of polyphenols with PS under light results in acceleration of polyphenol oxidation. This phenomenon should be carefully considered during food processing and storage.

Effect of Silica Coating on Particle Shape and Magnetic Properties of Iron Powder (II) (실리카 피착이 철분말의 입자형태 및 자기특성에 미치는 영향(제2보))

  • 오재희;김종식;류병환
    • Journal of the Korean Ceramic Society
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    • v.23 no.2
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    • pp.31-37
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    • 1986
  • The effect of dehydration temperature on the reduction process of silica-coated hematite was invest-igated The particle shape and magnetic properties of the products reduced from hematite at various conditions and the oxidation resistance of silica-coated iron powder were examined. It was revealed that single phase iron powder obtained over 45$0^{\circ}C$ had good magnetic properties. The iron powder manufactured between 45$0^{\circ}C$ and 50$0^{\circ}C$ displayed the maximum coercive force as a result of maintaining its acicular shaped. However the coercive force of iron powder reduced over 50$0^{\circ}C$ was decreased. The oxidation resistance of silica-coated iron powder in air was very good up to 11$0^{\circ}C$ and for 12 days.

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