• 제목/요약/키워드: Oxidation State

검색결과 586건 처리시간 0.031초

순수 타이타늄의 기계적 특성에 미치는 마찰 교반 용접 공정 조건의 영향 (Microstructure and Mechanical Properties of Pure Titanium Processed using Friction Stir Welding)

  • 이용재;최안드레;이승준;;신세은;이동근
    • 열처리공학회지
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    • 제32권3호
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    • pp.124-130
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    • 2019
  • Friction stir welding is one of the interesting welding methods for titanium and its alloy which proceeds with plastic flow due to thermo-mechanical stirring and friction heat. Solid-state welding can solve severe problems such as high-temperature oxidation, interstitial oxygen diffusion and grain coarsening by liquid-state welding. Dynamic recrystallization and grain refinement can vary significantly with the plunging load and rotational speed of tool during friction stir welding, and suitable process conditions must be optimized to obtain microstructure and better mechanical characteristics. Suitable FSW conditions were 1000 kg of plunging load and 200 rpm of rotational speed and it showed YS 270 MPa, UTS 332.1 MPa, and El 17.3%, which were very similar to those of wrought titanium sheet.

Panax ginseng and its ginsenosides: potential candidates for the prevention and treatment of chemotherapy-induced side effects

  • Wan, Yan;Wang, Jing;Xu, Jin-feng;Tang, Fei;Chen, Lu;Tan, Yu-zhu;Rao, Chao-long;Ao, Hui;Peng, Cheng
    • Journal of Ginseng Research
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    • 제45권6호
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    • pp.617-630
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    • 2021
  • Chemotherapy-induced side effects affect the quality of life and efficacy of treatment of cancer patients. Current approaches for treating the side effects of chemotherapy are poorly effective and may cause numerous harmful side effects. Therefore, developing new and effective drugs derived from natural nontoxic compounds for the treatment of chemotherapy-induced side effects is necessary. Experiments in vivo and in vitro indicate that Panax ginseng (PG) and its ginsenosides are undoubtedly non-toxic and effective options for the treatment of chemotherapy-induced side effects, such as nephrotoxicity, hepatotoxicity, cardiotoxicity, immunotoxicity, and hematopoietic inhibition. The mechanism focus on anti-oxidation, anti-inflammation, and anti-apoptosis, as well as the modulation of signaling pathways, such as nuclear factor erythroid-2 related factor 2 (Nrf2)/heme oxygenase-1 (HO-1), P62/keap1/Nrf2, c-jun Nterminal kinase (JNK)/P53/caspase 3, mitogen-activated protein kinase (MEK)/extracellular signal-regulated kinases (ERK), AMP-activated protein kinase (AMPK)/mammalian target of rapamycin (mTOR), mitogen-activated protein kinase kinase 4 (MKK4)/JNK, and phosphatidylinositol 3-kinase (PI3K)/AKT. Since a systemic review of the effect and mechanism of PG and its ginsenosides on chemotherapy-induced side effects has not yet been published, we provide a comprehensive summarization with this aim and shed light on the future research of PG.

Electrochemical Determination of 6-Benzylaminopurine (6-BAP) Using a Single-wall Carbon Nanotube-dicetyl Phosphate Film Coated Glassy Carbon Electrode

  • Li, Chunya
    • Bulletin of the Korean Chemical Society
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    • 제27권7호
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    • pp.991-994
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    • 2006
  • Herein, insoluble single-walled carbon nanotube (SWNT) was successfully dispersed into water in the presence of a special kind of surfactant-dicetyl phosphate (DCP), subsequently, a SWNT-DCP composite film coated glassy carbon electrode (GCE) was fabricated. The electrochemical behaviors of 6-benzylaminopurine (6-BAP) at the unmodified GCE and SWNT-DCP modified GCE were examined. It is found that the SWNT-DCP modified GCE remarkably enhances the oxidation peak current of 6-BAP, indicating great potential in the determination of trace level of 6-BAP. Finally, a sensitive and simple voltammetric method with a good linear relationship in the range of ${\times}5.0\;\;10^{-8}\sim 2.5\;{\times}\;10^{-6}$ mol/L, was developed for the determination of 6-BAP. The detection limit is as low as $2.0\;{\times}\;10^{-8}$ mol/L for 3-min accumulation. This newly-proposed method was successfully demonstrated with practical samples.

The Sintering Temperature Effect on Electrochemical Properties of LiMn2O4

  • Hwang, Jin-Tae;Park, Sung-Bin;Park, Chang-Kyoo;Jang, Ho
    • Bulletin of the Korean Chemical Society
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    • 제32권11호
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    • pp.3952-3958
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    • 2011
  • The effect of sintering temperature on the electrochemical property of $LiMn_2O_4$ was investigated. Results showed that the particle size was increased at higher sintering temperatures while the initial capacity was decreased after high temperature sintering. Capacity fading, on the other hand, was suppressed at lower sintering temperatures since the sintering at higher temperatures (${\geq}800^{\circ}C$) increased the Mn ions with a lower oxidation state ($Mn^{+3}$), which induced structural instability during cycling due to dissolution of Mn ions into the electrolyte. In particular, $LiMn_2O_4$ sintered above $830^{\circ}C$ showed severe capacity fading (capacity loss was 38% of initial capacity) by lower coulombic efficiency due to the abnormally increased particle size.

Surface properties of Nb oxide thin films prepared by rf sputtering

  • 박주연;강용철
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.306.2-306.2
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    • 2016
  • Niobium oxide thin films were synthesized by reactive rf magnetron sputtering. The target was metallic niobium with 2 inch in diameter and the substrate was n-type Si wafer. To control the surface properties of the films, Nb oxide thin films were obtained at various mixing ratios of argon and oxygen gases. Nb oxide thin films were analyzed with alpha step, scanning electron microscopy (SEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The result of alpha step showed that the thickness of Nb oxide thin films were decreased with increasing the oxygen gas ratios. SEM images showed that the granular morphology was formed at 0% of oxygen gas ratio and then disappeared at 20 and 75% of oxygen gas ratio. The amorphous Nb oxide was observed by XRD at all films. The oxidation state of Nb and O were studied with high resolution Ni 2p and O 1s XPS spectra. And the change in the chemical environment of Nb oxide thin films was investigated by XPS with Ar+ sputtering.

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Characterization of Ni Oxide Nanofibers by Electrospinning

  • 박주연;고성위;강용철
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.379.2-379.2
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    • 2016
  • The Ni oxide/PVP nanofibers were synthesized by sol-gel and electrospinning technique. The obtained Ni oxide/PVP (polyvinylpyrrolidone) nanofibers were calcined to remove the PVP compound at 873 and 1173 K. The Ni oxide/PVP nanofibers were analyzed by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The SEM images showed that the mat form was prepared by calcination of Ni oxide/PVP nanofibers at 873 K. And the crystal structure of Ni oxide at 1173 K was also confirmed by SEM images. XRD results shows the crystallinity of metallic Ni and NiO. TEM images also verified the crystal phase of Ni and Ni oxide. XP spectra revealed that the oxidation state of Ni to conclude the chemical composition of Cu oxide nanofibers.

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Nanoscale NiO for transparent solid state devices

  • Patel, Malkeshkumar;Kim, Joondong;Park, Hyeong-Ho
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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    • pp.243.2-243.2
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    • 2015
  • We report a high-performing nanoscale NiO thin film grown by thermal oxidation of sputtered Ni film. The structural, physical, optical and electrical properties of nanoscale NiO were comprehensively investigated. A quality transparent heterojunction (NiO/ZnO) was formed by large-area applicable sputtering deposition method that has an extremely low saturation current of 0.1 nA. Considerable large rectification ratio of more than 1000 was obtained for transparent heterojunction device. Mott-Schottky analyses were applied to develop the interface of NiO and ZnO by establishing energy diagrams. Nanoscale NiO has the accepter carrier concentration of the order of 1018 cm-3. Nanoscale NiO Schottky junction device properties were comprehensively studied using room temperature impedance spectroscopy.

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고분자 연료전지의 전극 제조 및 성능 평가 (The fabrication of electrode and characterization of performance in the PEMFC)

  • 박인수;조용훈;최백범;정대식;조윤환;성영은
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2005년도 춘계학술대회
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    • pp.227-230
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    • 2005
  • There is a worldwide interest In the development and commercialization of PEMFCs for vehicular and stationary applications. The major problem in the practical use of PEMFCs is the deactivation of the Pt anode electrocatalyst by the adsorption of carbon monoxide. Therefore, intensive work has been devoted to finding electrocatalysts that are tolerant to CO in hydrogen at operating temperatures bellow $100^{\circ}C$. Also, DMFC is considered to be one of the most promising technologies for energy generation. But, the most important problem associated with the DMFC is the slow reaction rate of methanol oxidation and the second major problem is fuel crossover. So, the performance of a state-of-the-art DMFC is considerably lower than that of hydrogen-fuelled PEMFC. In this research, the preparation and characterization of electrode materials will be introduced. Also, some electrochemical techniques for the characterization of PEMFCs will be presented.

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MoSi$_2$의 초음파에 관한 기초적 연구 (A Study on Ultrasonic for MoSi$_2$)

  • 김유철;남궁재관
    • 한국안전학회지
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    • 제9권1호
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    • pp.28-30
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    • 1994
  • Ultrasonic for MoSi$_2$/Y. C. Kim, C. K. Namkoong/MoSi$_2$in the silicides has excellence in the oxidation and corrosion resistence. When the solid state bonding sintered-MoSi$_2$/metal or the thermal sprayed coating by powder-MoSi$_2$on the metal are carried out, the defects may be occured at the bonded surface. So, the method for evaluating the existence of the defects by non-destructive inspection is strongly desired. Here, the characteristics of ultrasonic for sintered-MoSi$_2$are elucidated and the possibility of the detection of defects using by ultrasonic is investigated.

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