• Title/Summary/Keyword: Oxalate Content

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The Cause of Calcium Deficient leaf of Burley Tobacco (Nicotiana tabacum L.) (Burley종 연초의 칼슘결핍엽 발생원인)

  • Kim, Yong-Ok;Park, Soo-June;Lee, Chul-Hwan;Choi, Jung
    • Journal of the Korean Society of Tobacco Science
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    • v.11 no.1
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    • pp.3-9
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    • 1989
  • Field experiment was conducted to find out the cause of calcium deficiency of burley tobacco (Nicotiana tabacum L.), Liming materials and application rate were CaSO4 : Ca 35kg/10a, CaCO3 : 35kg/10a and agricultural lime : Ca 142kg/10a. The breakdown in tissues at tips and margins of upper leaves was developed at maximum growth stage. If complete breakdown and death does not occur and growth takes place later, giving the leaf a scalloped appearance. Upper leaves contained lower calcium content than other leaves. The stem and midvein of calcium deficient plants contained lower calcium and calcium minus oxalic acid, but higher oxalic acid contents than those of normal plant. Fresh leaves of limed plot contained higher calcium and oxalic acid, but not significant increment of calcium minus oxalic acid than those of unlimed plot. Since calcium oxalate is insoluble, it could precipitate within the culls if the calcium and oxalic acid are accessible to each other. It suggest that high level of oxalic acid in stem and midvein could be interfering with translocation of calcium to upper leaves.

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Fabrication of Nanowire by Electrospinning Process Using Nickel Oxide Particle Recovered from MLCC (MLCC에서 회수된 산화니켈 분말의 전기방사공정을 통한 나노와이어 제조)

  • Haein Shin;Jongwon Bae;Minsu Kang;Kun-Jae Lee
    • Journal of Powder Materials
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    • v.30 no.6
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    • pp.502-508
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    • 2023
  • With the increasing demand for electronic products, the amount of multilayer ceramic capacitor (MLCC) waste has also increased. Recycling technology has recently gained attention because it can simultaneously address raw material supply and waste disposal issues. However, research on recovering valuable metals from MLCCs and converting the recovered metals into high-value-added materials remains insufficient. Herein, we describe an electrospinning (E-spinning) process to recover nickel from MLCCs and modulate the morphology of the recovered nickel oxide particles. The nickel oxalate powder was recovered using organic acid leaching and precipitation. Nickel oxide nanoparticles were prepared via heat treatment and ultrasonic milling. A mixture of nickel oxide particles and polyvinylpyrrolidone (PVP) was used as the E-spinning solution. A PVP/NiO nanowire composite was fabricated via E-spinning, and a nickel oxide nanowire with a network structure was manufactured through calcination. The nanowire diameters and morphologies are discussed based on the nickel oxide content in the E-spinning solution.

Chemical Forms of Ca, Mg Compounds Occuring in Perilla Leaves and Their Changes after Harvest (깻잎에 있어 Ca, Mg의 존재형태와 수확후의 변화)

  • 최영희
    • Journal of the East Asian Society of Dietary Life
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    • v.11 no.4
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    • pp.274-280
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    • 2001
  • The chemical forms of calcium compounds in perilla leaves and their changes after harvest were investigated. The four types of calcium compounds extracted were as follows: water soluble calcium(F-I: mainly water soluble organic acid salts and calcium ion), IN-sodium chloride soluble calcium(F-II: calcium-pectate and calcium-carbonate), 2%-acetic acid soluble calcium(F-III: calcium-phosphate), and 5%-hydrochloric acid soluble calcium(F-IV: calcium-oxalate). The calcium content of perilla leaves was not found to vary with their age. Relatively high levels of F-l (28.4~39.5) and F-II (34.4~47.4) were found in young and mature leaves while the F-IV constituted 15.6~21.6% of the total calcium. The F-IV calcium contents of perilla. spinach and jaso were 16.8, 42.4 and 22.3%, respectively. In contrast to calcium. magnesium existed as water soluble magnesium at the highest content of 90.6% in spinach while 62.9% and 16.8% of the total magnesium existed as water soluble magnesium in perilla and jaso, repectively. The change in vitamin C and F-IV calcium content were examined for 7 days after harvest. Vitamin C content decreased slowly at the beginning but rapidly from the 4th day after harvest. On the other hand, the F-IV calcium content increased slowly at the beginning and rapidly from the 4th day of observation. This result suggests that the increase in F-IV calcium is related to the decrease in vitamin C content. This phenomena was more distinctly observed at 2$0^{\circ}C$ than 5$^{\circ}C$.

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Electrical properties of La-doped BaTiO3 synthesized by homogeneous precipitation (균일침전법으로 제조된 란탄이 혼입된 $BaTiO_3$의 전기적 특성)

  • Huh, Woo-Young;Ryu, Kyoung-Youl;Kim, Seung-Won;Lee, Chul
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.5
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    • pp.498-503
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    • 1999
  • La-doped $BaTiO_3$ ceramics were prepared from BaTiO(C_2O_4)_2\;{\cdot}\;XH_2O(BTO)$, which was synthesized by homogeneous precipitation using dimethyl oxalate. The electrical properties of La-doped $BaTiO_3$ were investigated with variation of La-contents and particle size. It was found that a large PTCR (positive temperature coefficient of resistivity) effect was appeared in the conditions at the 0.6 mol% of La-content and at small particle size of BTO as 1.0$\mu\textrm{m}$. The plot of temperature vs. 1/$\varepsilon_m$(T) above Curie temperature $(T_c)$ was agreed with Curie-Weiss law. The potential barrier calculated from measured resistance and capacitance of specimen, also gave higher value at small particle size of BTO as 1.0 $\mu\textrm{m}$ and at La-content of 0.6 mol%.

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Distribution of Organic Matter and $Al_o+1/2Fe_o$ Contents in Soils Using Principal Component and Multiple Regression Analysis in Jeju Island (주성분분석 및 다중회귀분석에 의한 제주도 토양유기물 및 $Al_o+1/2Fe_o$ 함량 분포)

  • Moon, Kyung-Hwan;Lim, Han-Cheol;Hyun, Hae-Nam
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.5
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    • pp.748-754
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    • 2010
  • The contents of soil organic matter (SOM) and $Al_o+1/2Fe_o$ in soils are important criteria for the classification of new Andisols in Soil Taxonomy system. There are many soil types in Jeju Island with various soil forming environments. This paper was conducted to estimate the contents of soil organic matter and the content of ammonium oxalate extracted Al and Fe ($Al_o+1/2Fe_o$) using various environmental variables and to make soil property maps using a statistical analyses. The soil samples were collected from 321 locations and analyzed to measure the contents of SOM and $Al_o+1/2Fe_o$. It was analyzed the relationships among them and various environmental variables such as temperature, precipitation, net primary product, radiation, evapotranspiration, altitude, soil forming energy, topographic wetness index, elevation, difference surrounded area, and distances from the shore and the peak. We can exclude multi-collinearity among environmental variables with principal component analysis and reduce all the variables to 3 principal components. The contents of SOM and $Al_o+1/2Fe_o$ were estimated by multiple regression models and maps of them were made using the models.

Studies on the Utilization of Orange Peel in the Spirit Vinegar Brewing (식초양조(食醋釀造)에 있어 밀감과피즙(果皮汁) 이용(利用)에 관(關)한 연구(硏究))

  • Kim, Yong Ho;Park, Yoon Joong;Sohn, Cheon Bae
    • Korean Journal of Agricultural Science
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    • v.8 no.1
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    • pp.108-116
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    • 1981
  • A study was carried out to get the basic information about the brewing of spirit vineger from medium containing mandarin orange peel, and the results obtained were as follows. 1. The yield of peel to fruit was 29.0%. 2. The optimum concentration of peel extract for the acetic acid fermentation medium was about 25%. 3. Acetic fermentation was inhibited when the peel extract content of medium was over 70%. Also the maximum acidity of the medium which contained 90% of peel extract was declined up to 1% comparing to the medium contained 25% of peel extract. 4. In the acetic acid fermentation of medium containing 25% of orange peel extract under the aerobic condition, the average rate of acetic acid production was 0.062g/100ml. hr. and the rate of acetic acid production in log phase was 0.15g/100ml. hr. also the yield of product based on acetification was 91.4% 5. Oxalate, pyruvate, malate was detected in acetic acid fermentation medium. 6. The quality of vineger made from medium containing 25% of orange peel extract was good.

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A Study on the Cookery of Andong Sikhe(II) -Physicochemical Changes upon Fermentation Temperature and Time- (안동식혜의 조리법에 관한 연구(II) -발효온도와 시간에 따른 이화학적 변화-)

  • 윤숙경
    • Korean journal of food and cookery science
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    • v.4 no.2
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    • pp.21-30
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    • 1988
  • To study the optimum fermentation and aging conditions for preparation of Andong Sikhe which is consumed in the northern Kyungbuk province as a traditional beverage, Sikhe were fermented and aged at $12^{\circ}C$ for 48, 60 and 72hrs and fermented at 40, 50. and $60^{\circ}C$ for 2, 3, and 4hrs and then aged at $12^{\circ}C$ for 20 hrs, Non-volatile organic acids and free sugars were analyzed by GC and HPLC, respectively, and sensory test was performed. Sikhe fermented at $40^{\circ}C$ for 3hrs and aged at $12^{\circ}C$ for 20hrs was evaluated the most favorable one by sensory test. This Sikhe had the lowest pH 4.6~4.7 among sample and 14.6% of sugar. The sugar content was lower than those of Sikhe Fermented at $50^{\circ}C$ and $60^{\circ}C$. In organic acid analysis, the concentration of malate 67.53%/mg in this Sikhe was the highest. Lactate, succinate and maleate were produced more in this Sikhe than in any other ones. Oxalate which was existed before fermentation was not found in the Sikhe, and a small amounts of citrate and fumarate were produced. In sugar analysis, maltose was dominant 11.56%, glucose 1.25% and fructose 0.45%.

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A Study on the Flavor Constituents of the Citron (Citrus junos) (유자의 향미성분에 관한 연구)

  • Kang Seong-Koo;Jang Mi-Jeong;Kim Yong-Doo
    • Food Science and Preservation
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    • v.13 no.2
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    • pp.204-210
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    • 2006
  • To accept basic data of utilizing of citron (Citrus junos) as a raw material of industrial produce, major chemical components of citron were investigated. Weight ration of poet flesh md seed of citron were 44.7, 42.9 and 12.4%, respectively. Comparing proximate composition of peel and flesh of citron, peel showed higher in crude protein crude fat and crude ash than flesh but lower in moisture, carbohydrate and soluble solid. The major free sugars of citron were fructose, glucose and sucrose. Peel contained higher in sucrose than flesh, but lower in fructose and glucose. The content of K md P were 309 and 15.9 mg% in peel and 175 and 22.4 mg% in fresh, respectively. The main organic acids of citron were citrate, malate and oxalate. Total organic acid content of flesh (6.6%) was higher than that of peel (4.6%). Total amino acid content of peel and flesh were 671.9 and 315.7 mg%, respectively. Free amino acid content of peel and flesh were 324.3 and 280.7 mg%, respectively, and the major ones were proline, serine, glutamic acid, aspartic acid, and histidine. Total 49 volatile compounds were detected and 26 of these ones were identified in cion. The major volatile component of citron was limonene, which consists of 80% among the total volatiles in peel by all extract methods.

Effect of Soil Salinity on Nitrate Accumulation of Lettuce (토양 염류집적이 상추의 Nitrate 축적에 미치는 영향)

  • Jin, Sun-Jae;Cho, Hyun-Jong;Chung, Jong-Bae
    • Korean Journal of Soil Science and Fertilizer
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    • v.37 no.2
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    • pp.91-96
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    • 2004
  • Accumulation of nitrate in edible crops is undesirable due to potential risks to human health. Since nitrate has a role in the osmotic regulation of plants, salt accumulation in soil is expected to stimulate nitrate accumulation in plants. Lettuce (Lactuca sativa L.) was grown in soils of different salinities, 9.69 and $4.49dS\;m^{-1}$, in a greenhouse, and the effect of soil salinity on nitrate accumulation in lettuce was investigated. Content of nitrate in the lettuce increased significantly as soil salinity increased under low light intensity and ample supply of nitrate in root media. Soluble sugar and oxalate contents in lettuce were also significantly higher in the soil of higher salinity. Phosphate, Cl, and $SO_4$ contents in lettuce were not significantly different in soils of different salinities. Among the cations, K content in lettuce was significantly higher in the soil of higher salinity, but Na, Ca, and Mg comtents were not much influenced. Comparing to the lettuce grown in low salinity soil, although the growth of lettuce was decreased by 9% in the soil of higher salinity, nitrate accumulation in the lettuce was increased by 18.6%. These results indicate that higher nitrate content in lettuce of higher salinity soil is a positive accumulation to adapt to the water stress condition. The nitrate accumulation of vegetables grown in plastic film houses is known to be due to the heavy fertilization and low light intensity, but salt accumulation in the soil, which can lower soil water potential, is expected to stimulate the nitrate accumulation further.

Molecular Properties of Excitation-Contraction Coupling Proteins in Infant and Adult Human Heart Tissues

  • Jung, Dai Hyun;Lee, Cheol Joo;Suh, Chang Kook;You, Hye Jin;Kim, Do Han
    • Molecules and Cells
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    • v.20 no.1
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    • pp.51-56
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    • 2005
  • Excitation-contraction coupling (ECC) proteins in the human heart were characterized using human atrial tissues from different age groups. The samples were classified into one infant group (Group A: 0.2-7 years old) and three adult groups (Group B: 21-30; Group C: 41-49; Group D: 60-66). Whole homogenates (WH) of atrial tissues were assayed for ligand binding, $^{45}Ca^{2+}$ uptake and content of ECC proteins by Western blotting. Equilibrium [$^3H$]ryanodine binding to characterize the ryanodine receptor (RyR) of the sarcoplasmic reticulum (SR) showed that the maximal [$^3H$]ryanodine binding ($B_{max}$) to RyR was similar in all the age groups, but the dissociation constant ($k_d$) of ryanodine was higher in the infant group than the adult groups. Oxalate-supported $^{45}Ca^{2+}$ uptake into the SR, a function of the SR SERCA2a activity, was lower in the infant group than in the adult groups. Similarly, [$^3H$]PN200-110 binding, an index of dihydropyridine receptor (DHPR) density, was lower in the infant group. Expression of calsequestrin and triadin assessed by Western blotting was similar in the infant and adult groups, but junctin expression was considerably higher in the adult groups. These differences in key ECC proteins could underlie the different $Ca^{2+}$ handling properties and contractility of infant hearts.