• Elastomers and Composites
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• 제43권4호
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• pp.281-287
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• 2008

고체상태 $^{13}C$ NMR을 이용하여 폴리부타디엔 고무(BR) 가황체의 정성 및 정량분석을 행하였다. TBBS로 촉진된 기존의 충진 BR 가황체에서는 올레핀성 이중결합에의 부가반응과 이중결합 옆의 $\alpha$ 위치에서의 치환반응이 동시에 일어났다. 또한 반응 초기에는 이중결합 옆의 $\alpha$ 위치에서의 치환반응은 이중결합에의 부가반응보다 빠르게 진행되었다. 한편 과가류(overcure) 시간 동안 이중결합-부가 폴리설파이드 구조는 5각형 및 6각형 고리 구조로 변형되는 것으로 추정되었다. 이러한 사슬 변형은 과가류 시간에 발생하는 화학적 가교 밀도와 상관되었다.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2005년도 춘계학술대회 논문집
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• pp.738-742
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• 2005

Rapid Prototype has been used to design and Production of part in a variety of fields ; Car, Electronic products, Aviation, Heavy industry etc. Moreover development of hardware gave rise to use the method of Rapid Prototype more and more at high precision and complicated shapes. Expecially, to be using process of products that shapes of Micro-hole ; Cellular phones, Antennas, Jewels, Semi conductor cases. In case of Micro-shape, precision of the shape turns on various condition ; Laser size, Laminate height, scanning speed, overcure, viscosity of resin, etc. Sometimes breaks out the case that interner hole of shape is blocked by viscosity of resin. The phenomenon has solved easily to reduce viscosity of resin. But, in case of the method brings about the problem that strength goes down in actuality products hardening. This study on verify to change of shape of Micro-hole and makes the semiconductor case which has shape of Micro-hole by using resin of higher viscosity, scanning speed and overcure

• 한국기계가공학회지
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• 제6권3호
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• pp.77-84
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• 2007

As a life cycle of product bas shortend, Rapid prototypiug has come into the spotlight to shortened the time of producint a prototype. But It followed in laminated directivity and of the prototype production which is decided the interference which Beccuase of invisible rough surface, some inferences have occured during an assembly hour. Consequently, This study on rapid prototyping has parameter to determine surface roughness and surface form precision of total shape. In order to improve Surface form precision, it can control parameters which are Laminate Height, Layer Hatch Overcue, Fill Cure Depth. In addition, we found the parameter which have a deep effect on surface roughness among various parameters, and then, tried to reduce the interference that can be occurred by surface roughness during assembly.