• 제목/요약/키워드: Over-excitation

검색결과 295건 처리시간 0.024초

수열합성법에 의한 SrAl2O4:Eu 초미세 분말 합성공정 및 형광 특성 (Hydrothermal Synthesis of Ultra-fine SrAl2O4:Eu Powders and Investigation of their Photoluminescent Characteristics)

  • 박우식;김선재;김정식
    • 한국세라믹학회지
    • /
    • 제41권5호
    • /
    • pp.370-374
    • /
    • 2004
  • 본 연구에서는 수열합성법으로 SrAl$_2$O$_4$:Eu 형광체 분말을 합성하여 이들의 발광 특성과 장잔광 특성 등에 대해서 고찰하였다. 증류수에 Sr(NO$_3$)$_2$, Al(NO$_3$)$_3$ㆍ9$H_2O$, Eu(NO$_3$)$_3$$.$6$H_2O$ 등의 금속염을 용해시킨 용액을 NH$_4$OH 수용액으로 pH 률 적당히 조절하고 고온고압의 Autoclave 반응용기 내에서 반응시켰다. 이렇게 합성된 분말은 균일한 입도 분포를 나타내었으며, sub-micron 크기의 초미세 분말이었다. 합성된 SrAl$_2$O$_4$:Eu 초미세 분말을 Ar-H$_2$ 가스 환원분위기에서 1100 -140$0^{\circ}C$ 온도로 2시간동안 열처리시켜서 형광 특성을 나타내도록 만들었다. 분말의 여기 및 발광 특성을 측정한 결과, 발광파장을 520 nm 로 고정시켜 측정한 여기스펙트럼은 250 ∼ 450 nm 의 넓은 파장영역에 걸쳐 여기가 일어났고, 발광스펙트럼은 520 nm에서 최대 피크를 나타내었다. 또한 10분간 여기시킨 후 520 nm 파장에 대한 잔광 특성이 1000초 이상 지속되는 우수한 장잔광 특성을 나타내었다. 그 밖에 SEM, XRD를 이용하여 SrAl$_2$O$_4$:Eu 형광체 분말에 대한 미세구조 및 결정구조를 고찰하였다.

RSSCT를 이용한 GAC의 상수원수 내 용존유기물질 제거 (Removal of Dissolved Organic Matters in Drinking Water by GAC adsorption using RSSCT)

  • 김영일;배병욱
    • 상하수도학회지
    • /
    • 제20권5호
    • /
    • pp.727-736
    • /
    • 2006
  • Granular activated carbon (GAC) has been identified as a best available technology (BAT) by the United States Environmental Protection Agency (USEPA) for removal disinfection by-product (DBP) precursors, such as dissolved organic carbon (DOC) and dissolved organic nitrogen (DON). Rapid small-scale column test (RSSCT) were used to investigate four types of carbon (F400, Norit1240, Norit40S, and Aquasorb1500) for their affinity to absorb natural organic matter (NOM). DOC, $UV_{254}$, and Total dissolved nitrogen (TON) concentrations were measured in the column effluent to track GAC breakthrough. DOC and $UV_{254}$ breakthrough occurred at around 3500 bed volumes (BVs) of operation for all GACs investigated. The $UV_{254}$ breakthrough curves showed 33% to 48% at 8000 BVs, when the DOC was 48% to 65%. All GACs showed greater removal in DOC than $UV_{254}$. The NORIT1240 GAC was determined to have the highest adsorption capacity for DOC and $UV_{254}$. The removal of nitrate (NOTN) had not broken through over BVs. The initial TON breakthrough curves were started around 50%, when the DOC breakthrough was only 10 % at 500 BVs. The curves were gradually increased after 3500 BVs and approximately 69% through 81% of TON breakthrough occurred at 8000 BVs. All of the GACs were able to remove TON, in the case of this investigation the majority of the TON was present as DON. Because nitrate nitrogen was seldom removed and ammonium nitrogen ($NH_3-N$) was not detected in the effluent from RSSCTs even though raw water. The carbon usage rate of DOC was from 2 to 6 times less than that of TON. The NORIT1240 GAC demonstrated the best performance in terms of DOC removal, while the F400 GAC was best in terms of TON removal. Excitation emission matrix(EEM) analysis was used to show that GAC adsorption successfully removed most of Humic-like DOC and Fulvic-like DOCs. However, soluble microbial product(SMP)-like DOC in the absence of raw water were detected in the NORIT40S and Aquasorb1500 GAC. The authors assumed that this results is due probably to the part of GAC in the RSSCT which was converted into biological activated carbon(BAC). To compare with organics removal by GAC according to preloading, the virgin GACs had readily accessible sites that were adsorbed DOC more rapidly than preloaded GACs, but the TDN removal had not showed differences between those GACs.

Li2SrSiO4-αNα에 첨가된 Eu2+의 광학적 특성 (Optical Properties of the Eu2+ Doped Li2SrSiO4-αNα)

  • 푸레둘람 남크하이;김태영;우현주;장기완;정중현
    • 새물리
    • /
    • 제68권11호
    • /
    • pp.1196-1202
    • /
    • 2018
  • 고상 반응법을 이용하여 처음으로 $Li_2SrSiO_{4-{\alpha}}N_{\alpha}:Eu^{2+}$ 형광체를 제조하고, 제조된 시료들에 대한 결정성 및 광학적 특성을 비교, 분석하였다. 제조된 시료들은 모두 230~530 nm의 넓은 영역에서 효율적인 여기 특성을 보이고 있다. 본 연구에 사용된 시료들 모두 568 nm에서 최대 발광 세기를 보이는데 이는 현재 상용 중인 $YAG:Ce^{3+}$에 비하여 최대 발광 세기가 약 18 nm 장파장 영역으로 이동함을 의미한다. 따라서 450 nm의 빛을 발하는 청색 LED와 결합하면, $YAG:Ce^{3+}$를 사용하여 상용화된 기존의 백색광보다 보다 따듯한 느낌의 백색광원용 형광체로 활용될 수 있으리라 판단한다. 또한 질소의 원료 물질로 사용된 $Si_3N_4$의 분말크기가 마이크론인 경우에 광활성 이온인 $Eu^{2+}$가 첨가되지 않아도 모체발광이 일어난다는 것을 처음으로 알게 되었다.

CELP 부호화기를 위한 양방향 패킷 손실 은닉 알고리즘 (BS-PLC(Both Side-Packet Loss Concealment) for CELP Coder)

  • 이인성;황정준;정규혁
    • 대한전자공학회논문지TC
    • /
    • 제42권12호
    • /
    • pp.127-134
    • /
    • 2005
  • VoIP에서 패킷의 손실은 음성의 품질에 영향을 주는 가장 중요한 요인이다. 따라서 수신된 정보로부터 손실된 패킷을 복구하는 것은 중요하다. 따라서 본 논문은 VoIP에서 가장 많이 사용되는 CELP 부호화기를 위한 수신측 기반의 손실 패킷 복구방법을 제안한다. 제안하는 WSOLA(Waveform Shift OverLab Add)기반의 BS-PLC (Both Side Packet Loss Concealment) 방법은 패킷 손실이 발생하였을 경우 미래 패킷을 이용할 수 있는 경우와 그렇지 않을 경우로 나누고, LP(Linear prediction) 파라미터와 여기 신호를 복구한다. 미래 패킷을 이용할 수 없는 경우에는 과거에 전송된 정상 패킷만을 가지고 복원을 하며, 미래 패킷을 이용할 수 있을 경우에는 과거의 정상 패킷과 미래의 정상 패킷을 동시에 이용하여 손실된 패킷을 복구한다. 연속 패킷 손실 환경은 Gilbert 모델로 설정하였고, 제안한 알고리즘을 VoIP에서 가장 많이 사용되는 CELP 음성부호화기인 G.729에 적용하여 성능을 비교한다. 성능 비교를 위해 손실율을 변화시키면서 SNR(Signal to Noise)와 MOS(Mean Opinion Score)측정하였고, 제안한 방법을 G.729의 패킷 손실 은닉 방법과 비교하였다. 실험 결과, 평균 손실률이 $20\%$에서도 SNR은 2dB, MOS값은 0.3정도로의 음질 개선을 보였다.

자기민감 고무를 이용한 구조물의 면진성능 연구 (A Study on Base Isolation Performance of Magneto-Sensitive Rubbers)

  • 황인호;임종혁;이종세
    • 한국지진공학회논문집
    • /
    • 제10권4호
    • /
    • pp.77-84
    • /
    • 2006
  • 최근 들어 지진발생 빈도의 증가와 더불어 초고층 빌딩, 장대교량 등과 같은 대형구조물의 경량화, 유연화로 인해 발생하는 구조물의 과도한 동적거동을 효과적으로 제어할 수 있는 제진시스템의 필요성이 증가하고 있다. 본 연구에서는 지진으로부터 구조물을 보다 효과적으로 보호하기 위해 자기장에 의해 역학적 성질을 변화시킬 수 있는 제어가 가능한 지능형재료인 자기민감 고무(Magneto-Sensitive Rubber)를 이용한 반 능동 기초격리 시스템을 제안하였다. 제안된 기초격리 시스템은 기존의 LRB(Lead-Rubber Bearing) 시스템과의 비교 분석을 통해 면진성능을 평가하였으며 이를 위해 몇 가지 역사적 지진들을 이용수치해석을 수행하였다. 제안된 자기민감 고무를 이용한 반 능동 기초격린 시스템은 기존의 수동 시스템보다 기초전단력이나 상부구조물에 가속도 전달을 차단함과 동시에 기초변위를 현저하게 감소시킬 수 있음을 보였다. 그러므로 자가민감 고무를 이용한 반 능동 기초격리 시스템은 지진으로부터 구조물을 효과적으로 보호할 수 있을 것으로 사료된다.

The $10-{\mu}m$ Noth-Polar Bightening of Juptier: A Dynamical Phenomenon?

  • Kim, Sang Joon;Seo, Haingja
    • 천문학회보
    • /
    • 제40권1호
    • /
    • pp.60.2-60.2
    • /
    • 2015
  • Since its detection in 1980, the $8-{\mu}m$ north-polar brightening of $CH_4$ on Juptier has not moved from $180^{\circ}$ (SysIII) longitude. The $8-{\mu}m$ $CH_4$ brightening is mostly thermal and very similar to that of $13-{\mu}m$ $C_2H_2$ emissions, but the morphology of these hydrocarbon north-polar brightenings are very different from that of the $3-{\mu}m$ $H_3{^+}$ auroral oval suggesting a significantly different excitation process yet unknown heating mechanism. Recently, Kim et al. (submitted to Icarus, 2015) found that that the center of the $3-{\mu}m$ $CH_4$ northern bright spot is located at ${\sim}200^{\circ}$ (SysIII) longitude, which is ${\sim}20^{\circ}$ west from the center of the $8-{\mu}m$ north-polar bright spot, and it does not coincide with the $3-{\mu}m$ $H_3{^+}$ bright spot. They found significantly high temperatures (500 ~ 850K) from $CH_4$ rotational lines on the $3-{\mu}m$ bright spot above the $1-{\mu}bar$ pressure level, while we find cooler temperatures (<350K) over the the $8-{\mu}m$ spot. They also found that the upper states of the $3-{\mu}m$ $CH_4$ bands are mostly populated by non-thermal excitations, such as auroral particle precipitations and/or Joule heatings in contrast to the $8-{\mu}m$ thermal emission. This finding indicates that the $10-{\mu}m$ hydrocarbon brightening is confined to low altitudes below the $1-{\mu}bar$ level eliminating the long-suggested possibility of direct auroral bombardments while opening a new possibility of dynamical origin for the $10-{\mu}m$ brightening.

  • PDF

제동시 발생하는 리어 드럼브레이크 Grunt(stick-slip) Noise 개선 (Rear Drum Brake Grunt(stick-slip) Noise Improvement on Braking During Nose-dive & Return Condition)

  • 홍일민;장명훈;김선호;최홍석
    • 한국소음진동공학회논문집
    • /
    • 제23권9호
    • /
    • pp.781-788
    • /
    • 2013
  • Grunt(stick-slip) noise happens between rear lining and drum on braking condition while vehicle is returning to steady position after nose-dive. The study presents a new testing and analysis methods for improving brake grunt noise on vehicle. Grunt noise is called a kind of stick slip noise with below 1 kHz frequency that is caused by the surfaces alternating between sticking to each other and sliding over each other with a corresponding change in friction force. This noise is typically come from that the static friction coefficient of surfaces is much higher than the kinetic friction coefficient. For the identification of the excitation mechanism and improvement of grunt noise, it is necessary to study variable parameters of rear drum brake systems on vehicle and to implement CAE analysis with stick slip model of drum brake. The aim of this study has been to find solution parameters throughout test result on vehicle and dynamo test. As a result of this study, it is generated from stick slip between rear lining and rear drum and it can be solved to reduce contact angle of lining with asymmetric and is effected not only brake drum strength but also rear brake size and brake factor.

Point Defects and Photoluminescence of Green Phosphors Ca(1-1.5x)WO4:Tbx3+ and Ca(1-2x)WO4:Tbx3+, Nax+

  • Cho, Seon-Woog
    • 한국재료학회지
    • /
    • 제23권9호
    • /
    • pp.537-542
    • /
    • 2013
  • Two types of Tb- and Na-substituted green phosphors $Ca_{(1-1.5x)}WO_4:Tb_x^{3+}$: and $Ca_{(1-2x)}WO_4:Tb_x^{3+},Na_x^+$ were synthesized with various x values, using a solid-state reaction. The former phosphors contained both substitutional and vacancy point defects, while the later had only substitutional defects. X-ray diffraction results showed that the main diffraction peak, (112), was centered at $2{\theta}=28.72^{\circ}$ and indicated that there was no basic structural deformation caused by substitutions or vacancies. The photoluminescence emission and photoluminescence excitation spectra revealed the optical properties of trivalent terbium ions, $Tb^{3+}$. Typical transitions, $^5D_3{\rightarrow}^7F_6,\;^7F_5,\;^7F_4$ and $^5D_4{\rightarrow}^7F_6,\;^7F_5,\;^7F_4,\;^7F_3$, and cross relaxations were observed. Subtle differences in the photoluminescence of green phosphors were observed as a result of the point defects. The FT-IR spectra indicated that some of the ungerade vibrational modes had shifted positions and changed shapes, spreading out over a wide range of frequencies. This change can be attributed to the different masses of $Tb^{3+}$ and $Na^+$ ions and $V_{Ca}$" vacancies compared to $Ca^{2+}$ ions. The gerade normal modes of the Raman spectra exhibited subtle differences resulting from point defects in $Ca_{(1-1.5x)}Tb_xWO_4$ and $Ca_{(1-2x)}Tb_xNa_xWO_4$.

해양플랜트에 병렬 계류된 LNG 운반선의 거동에 슬로싱이 미치는 영향 (The Effects of Sloshing on the Responses of an LNG Carrier Moored in a Side-by-side Configuration with an Offshore Plant)

  • 이승재
    • 한국해양공학회지
    • /
    • 제24권5호
    • /
    • pp.16-21
    • /
    • 2010
  • During the loading/offloading operation of a liquefied natural gas carrier (LNGC) that is moored in a side-by-side configuration with an offshore plant, sloshing that occurs due to the partially filled LNG tank and the interactive effect between the two floating bodies are important factors that affect safety and operability. Therefore, a time-domain software program, called CHARM3D, was developed to consider the interactions between sloshing and the motion of a floating body, as well as the interactions between multiple bodies using the potential-viscous hybrid method. For the simulation of a floating body in the time domain, hydrodynamic coefficients and wave forces were calculated in the frequency domain using the 3D radiation/diffraction panel program based on potential theory. The calculated values were used for the simulation of a floating body in the time domain by convolution integrals. The liquid sloshing in the inner tanks is solved by the 3D-FDM Navier-Stokes solver that includes the consideration of free-surface non-linearity through the SURF scheme. The computed sloshing forces and moments were fed into the time integration of the ship's motion, and the updated motion was, in turn, used as the excitation force for liquid sloshing, which is repeated for the ensuing time steps. For comparison, a sloshing motion coupled analysis program based on linear potential theory in the frequency domain was developed. The computer programs that were developed were applied to the side-by-side offloading operation between the offshore plant and the LNGC. The frequency-domain results reproduced the coupling effects qualitatively, but, in general, the peaks were over-predicted compared to experimental and time-domain results. The interactive effects between the sloshing liquid and the motion of the vessel can be intensified further in the case of multiple floating bodies.

효율적인 주파수 변조된 초음파 파형 발생을 위한 최적화된 시그마 델타 변조 기법 (Optimized Sigma-Delta Modulation Methodology for an Effective FM Waveform Generation in the Ultrasound System)

  • 김학현;한호산;송태경
    • 대한의용생체공학회:의공학회지
    • /
    • 제28권3호
    • /
    • pp.429-440
    • /
    • 2007
  • A coded excitation has been studied to improve the performance for ultrasound imaging in term of SNR, imaging frame rate, contrast to tissue ratio, and so forth. However, it requires a complicated arbitrary waveform transmitter for each active channel that is typically composed of a multi-bit Digital-to-Analog Converter (DAC) and a linear power amplifier (LPA). Not only does the LPA increase the cost and size of a transmitter block, but it consumes much power, increasing the system complexity further and causing a heating-up problem. This paper proposes an optimized 1.5bit fourth order sigma-delta modulation technique applicable to design an efficient arbitrary waveform generator with greatly reduced power dissipation and hardware. The proposed SDM can provide a required SQNR with a low over-sampling ratio of 4. To this end, the loop coefficients are optimized to minimize the quantization noise power in signal band while maintaining system stability. In addition, the decision level for the 1.5 bit quantizer is optimized for a given input waveform, which results in the SQNR improvement of more than 5dB. Computer simulation results show that the SQNR of a FM(frequency modulated) signal generated by using the proposed method is about 26dB, and the peak side-lobe level (PSL) of its compressed waveform on receive is -48dB.