• Journal of the Korean Chemical Society
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• v.50 no.3
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• pp.196-202
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• 2006

The self diffusion distributions of viscoelastic molten polyurethanes were determined from the relationship between the relaxation spectra and the distribution of self diffusion. The relaxation spectra of ester, PCL and PCL dyed type molten polyurethanes were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Ree-Eyring and Maxwell non-Newtonian model(REM model) from computer calculation. The experiments were carried out at various temperatures using the physica rheometer with the temperature controller. The self diffusion and hole distance of amorphous region of polyurethane samples were investigated by experiments of stress relaxation. The diffusion coefficients and hole volumes were calculated from rheological parameters and crystallite size in order to study the diffusion of flow segments in amorphous region. It was observed that the relaxation spectra and self diffusions of these polymer samples are directly related to the distribution of molecular weights, viscosities, hole volumes and activation energies of flow segments.

• Journal of the Korean GEO-environmental Society
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• v.9 no.5
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• pp.83-89
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• 2008

This study is to figure out the speed of soil diffusion and shapes as well when landslide occurred. It was measured the speed and shapes of soil diffusion using installed indoor-simulation of a land slide. Standard sand was used to measure it and this measurement is following the moisture content of standard sand. The result of this experiment follows the moisture content; as the moisture content goes up, the area and speed of soil diffusion goes faster as well. As the average of records by the moisture content was analyzed, the area and speed of land slide are increased proportionally. The shape of diffusion is formed as fanwise. It depends on the moisture content as above; the speed was fast when the moisture content is high, and it was getting narrower and longer as the speed of diffusion was faster.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.4
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• pp.245-251
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• 2018

Recently, as the importance of structural maintenance has been increased, studies on self - healing concrete technology are being actively carried out. On the other hand, test for evaluating the self-healing performance is not standardized yet. Although visual test is used as a basic method for measuring crack widths, it is difficult to observe the crack width inside the specimen, and there is a disadvantage that only the local measurement of the surface can be measured due to the inhomogeneous cracking characteristics. Although permeability test has been widely used as an indirect method for measuring crack width, there is a problem due to the viscosity of water, and also a possibility that the internal material of the specimen may be eluted during the test. In this study, we propose a crack width evaluation method using gas diffusion characteristics. Idealized straight cracks were fabricated by acrylic and the diffusion coefficients of specimens were analyzed with respect to crack width and thickness. The experimental results show that the crack width and the diffusion coefficient are in a linear relationship and that the thickness and diffusion coefficient are inversely related.

• Nuclear Engineering and Technology
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• v.5 no.2
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• pp.115-131
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• 1973

L.S. Pontryagin's maximum principle is applied to the minimum critical mass problem without any restriction on the ranges of uranium enrichment. For the analysis, two group diffusion equation is adopted for a cylindrical reactor neglecting the vertical axis consideration. The result shows that the three-zoned reactor turns out to be most optimal: the inner and outer zones with the minimum enrichment ; whereas the middle 3one with the maximum enrichment. With the given three-zoned reactor, critical condition is derived, which leads to the calculation of the determinant. By finding the roots of the determinant the numerical calculation of the minimum critical mass is carried out for the case of Kori reactor geometry changing the minimum or the maximum enrichment. It is found from many computed values that the least possible critical mass turns out to be the case of 1.2% maximum enrichment for the middle zone and 0.65% minimum enrichment for the inner and out zones.

• Membrane Journal
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• v.12 no.1
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• pp.51-53
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• 2002

The hydrogen ions in poly (vinyl alcohol) (PVA)/sulfosuccinic acid (SSA) membranes substiuted with $Li^+, Na^+, and K^+/ $of monvoalent metal ions, $Mg^{2+}, Ca^{2+} and Ba^{2+}$ of divalent metal ions, and $Al^{3+}$ of trivalent metal ion. In addition, $Li^+ ions were exchanged with varing reaction time. The effects of metal ions exchanged were investigated in terms of methanol permeability -uling diffusion cell. The methanol permeabilies decreased in the sequence of $Na^+, Li^+ and K^+$ and this might be due to the 'Salting-out' effect while the methanol permeabilities for divalent and trivalent ion-substituted membranes were affected by the combined effects of salting-out, eletrostatic crosslinking and extent of metal ion substiution. As for $Li^+$ ions, methanol permeabilities of PVA/SSA membranes decreased in proportion to the degrees of subsituted $Li^+$ ions.

• 한국신재생에너지학회:학술대회논문집
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• 2007.06a
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• pp.13-19
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• 2007

To find out the optimum design of hydrogen storage and supply tank using Metal Hydride (briefly MH) and to make clear the performance characteristics under various conditions are our research purpose. In order to use the low-temperature exhaust heat, $LaNi_{4.7}Al_{0.3}$ which operates under the low pressure of 1 MPa is chosen, and we measure the basic properties, namely density, specific heat, PCT(Pressure-Concentration-Temperature) characteristics, and effective thermal conductivity. Then, a numerical calculation model of hydrogen storage using MH alloy is suggested and this thermal diffusion equation of model is solved by the backward difference method. This calculation results are compared with the experimental results of the systems which installed 1kg MH alloy and, it is found out that our calculation model can well predict the experimental results. By the experimental using MH alloy, it is recognized that the hydrogen flow rate can control by the step adjustment of brine temperature.

• Journal of Welding and Joining
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• v.15 no.2
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• pp.43-53
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• 1997

The complete joining method for dissimilar press punch materials and its real-time evaluation method is not available at present. Brazing method has been used for joining them, but it is known that the welded joint by the brazing has the lower bonding efficiency and reliability than the diffusion welding. The friction welding with a diffusion mechanism in bonding was applied in this study. This work was carried out to determine the proper friction welding conditions and to analyze mechanical properties of friction welded joints of sintered carbide tool materials (SKNM50 for the blade part of press punch) to alloy steel (SCM440 for the shank part of press punch) using aluminum (A6061 for the interlayer material) as an insert material between the sintered carbide tool materials and the alloy steel. In addition, acoustic emission test was carried out during friction welding to evaluate the weld quality.

• Journal of Power System Engineering
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• v.4 no.4
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• pp.54-58
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• 2000

The complete joining method for dissimilar hot die punch materials and its real-time evaluation method are not available at present. Brazing method has been used for joining them, but it is known that the welded joint by the brazing has the lower bonding efficiency and reliability than the diffusion welding. The friction welding with a diffusion mechanism in bonding was applied in this study. So, this work was carried out to determine the optimal friction welding conditions and to analyze mechanical properties of friction welded joints of hot die punch materials (STD61 for the blade part of hot die punch) to alloy steel (SCM440 for the shank part of hot die punch) such as plunger. In addition, acoustic emission test was carried out during friction welding to evaluate the weld quality.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.22 no.1
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• pp.142-147
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• 1998

Rotary bending fatigue tests were carried out on the nitrided titanium in order to investigate the effect of nitriding layer on fatigue limit. Main results obtained are as follows. (1) The fatigue limit of nitrided pure titanium is remarkably reduced because of enlargement of grain size at high heat treating temperature and high stress field created from the elastic interaction in the compound layer. (2) Further test using specimen which was removed nitrified layer gradually, were also conducted and it was found that by removing the compound layer the fatigue limit recovered as the level of basic material and rather increased by coming of a diffusion layer. Therefore it is concluded that the surface compound layer generated by nitriding treatment reduced the fatigue limit but diffusion layer increased it.

• Bulletin of the Korean Chemical Society
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• v.32 no.11
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• pp.3909-3913
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• 2011

In this paper we have carried out molecular dynamics simulations (MD) for model systems of liquid n-alkane oligomers ($C_{12}{\sim}C_{80}$) at high temperatures (~2300 K) in a canonical ensemble to calculate viscosity ${\eta}$, self-diffusion constants D, and monomeric friction constant ${\zeta}$. We found that the long chains of these n-alkanes at high temperatures show an abnormality in density and in monomeric friction constant. The behavior of both activation energies, $E_{\eta}$ and $E_D$, and the mass and temperature dependence of ${\eta}$, D, and ${\zeta}$ are discussed.