• Title/Summary/Keyword: Osmotic Pressure

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Ammonia Removal Characteristics in Membrane Contactor System Using Tubular PTFE Membrane (관형 PTFE 분리막을 이용한 막 접촉기(Membrane Contactor) 시스템에서 암모니아의 제거 특성)

  • Ahn, Yong-Tae;Hwang, Yu-Hoon;Shin, Hang-Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.5
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    • pp.353-358
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    • 2011
  • In this study, ammonia removal characteristics in membrane contactor system under various operating conditions were evaluated. The mass transfer coefficient was used to quantitatively compare the effect of various operation conditions on ammonia removal efficiency. Effective removal of ammonia was possible with the tubular PTFE membrane contactor system at all tested conditions. Among the various operation parameters, contact time and solution pH showed significant effect on ammonia removal mechanism. Overall ammonia removal rate was not significantly affected by influent suspended solution concentration unlike other pressure driven membrane filtration processes. Also the osmotic distillation phenomena which deteriorate the mass transfer efficiency can be minimized by preheating of strip solution. Membrane contactor system can be a possible alternative to treat high strength nitrogen wastewater by optimizing operation conditions such as stripping solution flow rate, influent wastewater temperature, and influent pH.

The Behavior of Electrolytes in Nonaqueous Solutions (IV). Relative Viscosities and Osmotic Coefficients of Alkaline Metal Iodides (물아닌 용액에서의 전해질의 행동에 관한 연구 (제4보). 요오드화알칼리금속의 상대점도와 삼투계수)

  • Si-Joong Kim;Jin-Ho Kim;Kyu-Seong Choi
    • Journal of the Korean Chemical Society
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    • v.28 no.6
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    • pp.349-354
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    • 1984
  • The relative viscosities and the osmotic coefficients of alkaline metal iodides (NaI, KI, RbI, CsI) in methanol, ethanol, dimethylsulfoxide (DMSO), and sulfolane (TMS) have been measured by Ubbelohde viscometer and vapor pressure osmometry at 45 ∼ $120^{\circ}C.$ The order of A and B coefficients in viscosity for alkaline metal iodides are MeOH > EtOH > TMS > DMSO, and TMS > EtOH > DMSO > MeOH. dB/dT values for the alkaline metal iodides are in the order of NaI > KI > RbI > CsI in the protic solvents, while those for the aprotic solvents are in the reverse order. The order of the osmotic coefficients for the alkaline metal iodides is EtOH > DMSO > MeOH > TMS.

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Angelica gigas Nakai 현탁세포 배양의 동결보존 연구

  • Jo, Ji-Suk;Lee, Song-Jae;Jeon, Su-Hwan;Kim, Ik-Hwan;Kim, Dong-Il
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.321-324
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    • 2000
  • Cell culture of Angelica gigas Nakai producing decursin and decursinol angelate as secondary metabolites were preserved in liquid nitrogen after pre-freezing in deep $freezer(-70^{\circ}C)$. The development of optimal procedure for cryopreservation was investigated by using cryoprotectant and pre-treatment before cooling. 0.7 M sucrose was found be the optimum osmotic pre-conditioning culture medium compared to mannitol, sorbitol and NaCl with the same osmotic pressure. In pre-culture medium, cells in exponential phase, supported the best growth after cryopreservation. Effective cryoprotectant was proved to be a mixture of sucrose, glycerol, DMSO. Higher concentration of cryoprotectant was better for cell viability. The highest relative cell viability established after the development of optimal procedure was 65%.

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Performance evaluation of forward osmosis (FO) hollow fiber module with various operating conditions (중공사막 모듈을 이용한 정삼투 공정에서의 운영조건 변화에 따른 성능평가)

  • Kim, Bongchul
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.4
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    • pp.357-361
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    • 2018
  • Forward osmosis (FO) process has been attracting attention for its potential applications such as industrial wastewater treatment, wastewater reclamation and seawater desalination. Particularly, in terms of fouling reversibility and operating energy consumption, the FO process is assumed to be preferable to the reverse osmosis (RO) process. Despite these advantages, there is a difficulty in the empirical step due to the lack of separation and recovery techniques of the draw solution. Therefore, rather than using FO alone, recent developments of the FO process have adapted a hybrid system without draw solution separation/recovery systems, such as the FO-RO osmotic dilution system. In this study, we investigated the performance of the hollow fiber FO module according to various operating conditions. The change of permeate flow rate according to the flow rates of the draw and feed solutions in the process operation is a factor that increases the permeate flow rate, one of the performance factors in the positive osmosis process. Our results reveal that flow rates of draw and feed solutions affect the membrane performance, such as the water flux and the reverse solute flux. Moreover, use of hydraulic pressure on the feed side was shown to yield slightly higher flux than the case without applied pressure. Thus, optimizing the operating conditions is important in the hollow fiber FO system.

Effect of Salt Level in the Feed on Performance of Red and Fallow Weaner Deer

  • Ru, Y.J.;Fischer, M.;Glatz, P.C.;Bao, Y.M.
    • Asian-Australasian Journal of Animal Sciences
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    • v.17 no.5
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    • pp.638-642
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    • 2004
  • In Australia, many cropping areas are affected by salt. In these regions, Chenopodiaceous plants, such as Atriplex, Kochia and Bassia spp have been planted to improve soil conditions. These plants have become invaluable feed resources for grazing animals in dry summers, but have a high sodium content. To assess the impact of high salt intake on grazing deer, two experiments were conducted. The first experiment used 30 fallow weaner deer to examine the effect of salt level in the diet on feed intake, water intake and body weight of fallow deer. Salt was added to lucerne chaff at 0, 1.5, 3.0, 4.5 and 6% and fresh water was offered all the time. Increasing the salt level in the diet from 0 to 6% didn't affect feed intake, osmotic pressure and mineral concentration in blood of fallow deer. However, water intake was significantly higher (p<0.05) in deer fed diets containing more than 3% salt. Body weight was lower (p${\leq}$0.056) for fallow deer in July and August when salt content was over 3%, suggesting they can ingest over 15 g sodium/day without significant depression in both feed intake and growth rate if the fresh water is available. In the second experiment, 18 red weaner deer were fed lucerne chaff diets containing 1.5, 4.5 and 6.0% salt with 6 deer/diet. The results revealed that feed intake and blood osmotic pressure were similar (p>0.05) for red deer fed different levels of salt although the feed intake declined from 1.91 to 1.67 kg with the increase of salt level from 1.5% to 6.0% in the diet. Water intake was significantly higher for deer fed diets containing over 4.5% salt, but there was no difference in body weight during the experiment. However, no recommendation can be made on the salt tolerance of red deer due to limited increment of salt level in the diet.

Temperature-Sensitive Polymers Adhered on FO Membrane as Drawing Agents (자극감응성 유도용질로서 정삼투막에 부착된 온도감응성 고분자)

  • Lee, Chong-Cheon;Lee, Jonghwi
    • Polymer(Korea)
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    • v.38 no.5
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    • pp.626-631
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    • 2014
  • Water purification requires a large amount of energy that can cause pollution problems. For this reason, forward osmosis (FO) has attracted intense interest that required a relatively low amount of energy for water purification. The forward osmosis has a serious problem that it needs drawing agents creating osmotic pressure to extract water from contaminated water. In this study, a copolymer of zwitterionic moiety and an interpenetrating polymer network (IPN) hydrogel based on thermo-responsive polymer hydrogel, poly(N-isopropylacrylamide) (PNIPAM) were prepared and attached on FO membranes, which successfully played the role of drawing agents. In the copolymer hydrogel, its swelling ratio was improved, but thermo-sensitivity was decreased. The swelling ratio and thermo-sensitivity of IPN hydrogel was lowered. We could confirm that swelling ratio is related to osmotic pressure.

Ecophysiological Interpretations on the Water Relations Parameters of Trees(V) -Seasonal Changes in Tissue-Water Relations on the Quercus grosseserrata and Quercus acutissima Leaves- (수목(樹木)의 수분특성(水分特性)에 관한 생리(生理)·생태학적(生態學的) 해석(解析)(V) -물참나무와 상수리나무 엽(葉)의 수분특성(水分特性)의 계절변화(季節變化)-)

  • Han, Sang Sup;Choi, Heung Seon
    • Journal of Korean Society of Forest Science
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    • v.72 no.1
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    • pp.37-44
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    • 1986
  • Seasonal changes of water relations parameters were obtained from p-v curves in leaves of Quercus grosseserrata and Quercus acutissima. The osmotic pressure at full hydration, ${\pi}_o$, and osmotic pressure at incipient plasmolysis, ${\pi}_p$, were high in newly emerged leaves but decreased with leaf development in each of the species. Water deficit at turgor loss was 10 to 20% in each of the species during the growing season. Maximum bulk elastic modulus in cell walls at full turgor, Emax, rises rapidly with leaf development before senescence in each of the species. Seasonal change of number of osmoles solute in symplasm per dry weight, Ns/DW, was higher in Quercus grosseserrata leaves than Quercus acutissima leaves, while relative water content (Vp/Vo, $RWC^*$, Vo/Vt) was relatively constant in each of the species.

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Surface Modification of Gold Electrode Using Nafion Polymer and Its Application as an Impedance Sensor for Measuring Osmotic Pressure (나피온 폴리머를 이용한 금 전극의 표면 개질 및 이의 삼투압 측정용 임피던스 센서 응용)

  • Min Sik, Kil;Min Jae, Kim;Jo Hee, Yoon;Jinwu, Jang;Kyoung G., Lee;Bong Gill, Choi
    • Applied Chemistry for Engineering
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    • v.34 no.1
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    • pp.9-14
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    • 2023
  • In this work, we developed a Nafion polymer-coated impedance sensor with two gold electrode configurations to measure the ion concentration in solution samples. The gold electrodes were fabricated through the sputtering process, followed by surface modification using Nafion polymer. The resulting sensors enable the prevention of the polarization phenomenon on the electrode surface, resulting in stable measurement of electrochemical signals. Spectroscopy and scanning electron microscopy measurements revealed that the thin film of Nafion was coated uniformly onto the surface of the gold electrode. The Nafion-coated sensor exhibited more stable impedance signals than the conventional gold electrode. It showed a highly reliable calibration curve (R2 = 0.983) of the impedance sensor using a standard sodium chloride solution. In addition, a comparison experiment between the impedance sensor and a commercial conductivity sensor was performed to measure the ion concentration of artificial tears, showing similar results for the two sensors.

Optimization of Ascorbic Acid Encapsulation in PLA Microcapsules Using Double Emulsion Process (이중유화법을 이용한 PLA 마이크로캡슐 내부로의 아스코르브산 캡슐화 공정 최적화)

  • Ji Won Yun;Young Mi Chung
    • Applied Chemistry for Engineering
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    • v.35 no.2
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    • pp.115-121
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    • 2024
  • This study analyzed the influence of process variables affecting the thermodynamic equilibrium and fluid dynamics of interfaces such as reverse micelle, salt concentration, interfacial tension, and viscosity of fluids to optimize the microencapsulation process using the W1/O/W2 double emulsion method. The process variable with the greatest impact on encapsulation efficiency was found to be the difference in osmotic pressure between the W1 and W2 phases. It was observed that increasing the salt concentration in the W2 phase or decreasing the ascorbic acid concentration in the W1 phase resulted in higher encapsulation efficiency. Additionally, a larger difference in osmotic pressure led to increased damage to the surface of the microparticles, as confirmed by SEM images. The introduction of reverse micelles, which was anticipated to increase encapsulation efficiency, either had a low contribution or even decreased encapsulation efficiency. The yield of microcapsules was expressed as a universal function, applicable to all process conditions or solution compositions. According to this universal function, no further increase in yield was observed beyond the Ca (capillary number) of approximately 20.

Transformation of Wheat Immature Embryos by Particle Bombardment

  • Wu Li-Min;Wei Yu-Ming;Zheng You-Liang
    • Journal of Plant Biotechnology
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    • v.7 no.2
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    • pp.113-121
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    • 2005
  • The objective of this study was to identify the major parameters controlling DNA delivery by particle bombardment to immature embryos of Chinese spring wheat (Triticum aestivum L.). Efficiency of DNA (uidA gene) delivery was assessed by transient GUS (${\beta}$-glucuronidase) expression in bombarded tissues. Of the parameters analyzed, acceleration pressure, bombardment distance, chamber vacuum pressure, bombardment times, osmotic conditioning of culture had a remarkable influence on transient gene expression. A bombardment procedure suitable for Chinese spring wheat cultivars was developed which allowed high-efficiency DNA delivery combined with reduced damage to target tissues. The high efficiency made the system practical for wheat genetic transformation research and accelerating wheat breeding programs.