• 한국전기전자재료학회논문지
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• 제35권2호
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• pp.178-183
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• 2022

For enhancing the flame-retardant properties of wallpapers, we developed an organic-inorganic hybrid solution with ZrSiO₄ as a functional ceramic powder, coated on non-woven fabric using dip coating, spray coating, and slot-die coating methods. Their flame retardant properties were characterized by a 45° combustion tester, which is manufactured according to the flame-retardant performance standard (KOFEIS 1001 and KS F 2819). In organic-inorganic hybrid solution, with increasing the concentration of acid-catalyst (acetic acid), the precipitation of ZrSiO₄ powders increased, and the flame retardant properties decreased. The highest flame retardant result was obtained for the solution adding 5 wt% acetic acid. The optimization of the coating method and coating number resulted in the most excellent flame-retardant properties being obtained for the non-woven fabric coated for 5 or 7 times by dip coating method, and their flame-retardant properties corresponded to class 2 flame-retardant performance of wallpapers.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2007년도 추계학술발표대회 및
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• pp.49.2-49.2
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• 2007

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.391.2-391.2
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• 2014

Solution-processible hybrid bipolar field effect transistors (HBFETs) with balanced hole and electron mobilities were fabricated using a combination of the organic p-type poly (3-hexylthiophene) (P3HT) layer and inorganic n-type ZnO material. The hole and electron mobilities were first optimized in single layer devices by using acetonitrile as a solvent additive to process the P3HT and annealing to process the ZnO layer. The highest hole mobility of the P3HT-only-devices with 5% acetonitrile was 0.15 cm2V-1s-1, while the largest electron mobility was observed in the ZnO-only-devices annealed at $200^{\circ}C$ and found to be $7.2{\times}10-2cm2V-1s-1$. The inorganic-organic HBFETs consisting of P3HT with 5% acetonitrile and ZnO layer annealed at $200^{\circ}C$ exhibited balanced hole and electron mobilities of $4.0{\times}10-2$ and $3.9{\times}10-2cm2V-1s-1$, respectively. The effect on surface morphology and crystallinity by adding acetonitrile and thermal annealing were investigated through X-ray diffraction and atomic force microscopy (AFM). Our findings indicate that techniques demonstrated herein are of great utility in improving the performance of inorganic-organic hybrid devices

• 한국해양공학회지
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• 제29권6호
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• pp.475-480
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• 2015

In this study, we developed a Cr-free organic/inorganic hybrid solution and investigated its coating properties on degraded STS316L. Both the OIBD-1 solution and OIBD-2 solution had excellent corrosion resistance and adhesion ability. However, the solution had some problems in a boiling water environment. In addition, the flexibility was excellent, and the scratch resistance was relatively good.

• 공업화학
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• 제23권1호
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• pp.53-58
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• 2012

투명한 플라스틱 필름의 표면경도를 향상시키기 위하여 유-무기 하이브리드 코팅 용액을 졸-겔 공정을 이용하여 합성하였다. 무기성분으로 콜로이드 실리카와 유기성분으로 PMMA, 유-무기 성분 간의 결합력을 향상시켜 하이브리드 코팅 층의 특성을 더욱 향상시키기 위하여 실란커플링제로서 vinyl trimethoxy silane (VTMS)과 [3-(metha cryloyloxy)] propyl trimethoxy silane (MAPTMS)를 이용하였고, 알콕시 실란의 종류, 콜로이드 실리카/PMMA의 함량비 등의 반응조건에 따라 콜로이드 실리카/PMMA 졸을 합성하였다. 이러한 졸을 PET 필름에 바코팅시키고, 열경화 시켜 하드코팅막을 제조하여 물리적 화학적 특성을 조사하였다. PMMA에 비해서 하이브리드 형태에서 코팅 막의 연필경도와 기재와의 부착력이 우수하였다.

• 한국산업융합학회 논문집
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• 제26권4_2호
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• pp.591-598
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• 2023

In this study, the corrosion resistance by salt spray was evaluated using A6061-T6 for an electric vehicle battery pack case coated with an organic/inorganic hybrid solution. The lowest curing temperature of 190 ℃ resulted in significant corrosion and pitting. Meanwhile, no corrosion was observed in the coated specimens at 210 ℃ and 230 ℃ except at 210 ℃ - 6 min and 8 min. The surface of the as-received coating specimen observed by FE-SEM exhibited streaks and dents in the rolling direction, but the coating surface was clean. On the 190 ℃ - 6 min coating specimen, which had a lot of corrosion, rolling streaks spread, and dents were caused by corrosion. The 200 ℃ - 12 min coating specimen did not show corrosion, but it showed an etched surface. In the line profile, Si, the main component of the coating solution, was detected the most, and Ti was also detected. In the coating specimens with salt spray, O increased and Si decreased, regardless of corrosion. The peeling rate by adhesion evaluation was 26 - 87% for the 190 ℃ coating specimen, 4 - 83% for the 210 ℃ coating specimen, and 94 - 100% for the 230 ℃ coating specimen. The optimal curing conditions for the coating solution used in this study were 210 ℃ for 10 min.

• Korean Chemical Engineering Research
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• 제46권2호
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• pp.310-315
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• 2008

실란커플링제인 glycidoxypropyl trimethoxysilane(GPTMS)과 vinyltriethoxysilane(VTES)을 출발물질로 하여 sol-gel 법에 의해 유-무기 혼성 용액을 제조하였다. 이 용액에 spiropyran계 광 변색 염료를 ethylacetate에 용해시킨 용액을 혼합하여 광 변색 코팅 용액을 제조하였다. 그 후 기재인 polycarbonate 시트에 스핀 코팅 시키고 $100^{\circ}C$에서 2 h 동안 열 경화시켜 광 변색성을 갖는 하드 코팅 막을 제조하였다. 코팅 막은 UV 광을 조사함에 의해 투명색으로부터 푸른색으로 변했다가 다시 투명색으로 변하는 가역적인 색변화를 보여주었다. 이때 코팅 막의 소색속도 및 연필경도는 코팅 용액 중의 GPTMS의 mol비가 증가됨에 따라 증가하였다.

• 한국해양공학회지
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• 제25권1호
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• pp.32-38
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• 2011

Galvanized steel has gone through a chemical process to keep it from corroding. The steel gets coated in layers of zinc because rust will not attack this protective metal. For countless outdoor, marine, or industrial applications, galvanized steel is an essential fabrication component. The reduction of the corrosion rate of zinc is an important topic. In the past, a very popular way to reduce the corrosion rate of zinc was to use chemical conversion layers based on $Cr^{+6}$. However, a significant problem that has arisen is that the use of chromium salts is now restricted because of environmental protection legislation. Therefore, it is very important to develop new zinc surface treatments that are environmentally friendly to improve the corrosion resistance of zinc and adhesion with a final organic protective layer. In this study, a Urethane solution (only Urethane 20 wt.%; S-700) and an organic/inorganic solution with Si (Si polysilicate 10 wt.% + Urethane 10 wt.%; LRO-317) are used. Based on the salt spray test of 72 h, S-700 and LRO-317 had a superior effect for the corrosion resistance on EGI and HDGI, respectively.

• 한국세라믹학회지
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• 제34권9호
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• pp.993-1001
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• 1997

The (0.8PPV+0.2DMPPV) copolymer and silica/borosilicate composites were synthesized by sol-gel process. The organic-inorganic hybrid solution was prepared by using of (0.8PPV+0.2DMPPV) copolymer precursor solution as a raw material for organic components and TEOS and TMB for glass components. Then by drying the solution in vacuum at 5$0^{\circ}C$ for 7days and subsequent heat treatment in vacuum at 15$0^{\circ}C$~30$0^{\circ}C$ for 2h~72h with heating rate of 0.2$^{\circ}C$/min and 1.8$^{\circ}C$/min, the organic-inorganic composites were synthesized. Microstructural evolution of the composites was characterized by DSC, IR spectrocopy, UV/VIS spectroscopy, and TEM. Elimination of the polymer precursor and degradation of the polymer were observed by DSC and Si-O and trans C=C absorption peaks were identified by IR spectra. The polymer was found to be successfully incorporated into the glass matrix and it was confirmed by the absorption peaks from the polymer in the UV/VIS spectra and the TEM results. The absorption peak of the composites was found to shift toward short wavelength side compared to that of the pure polymer and the amount of the blue shift increased with increasing the heat treatment temperature and heat treatment time and with decreasing the heating rate.

• 한국해양공학회:학술대회논문집
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• 한국해양공학회 2004년도 학술대회지
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• pp.7-12
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• 2004

Desalination system of revers osmosis(RO) membrane has been proven to be the most economical not only for the desalination of water containing salts, but also for the concentration of solute. RO membranes were traditionally made of inorganic polymers such. as cellulose acetate(CA), Polyamide(PA). To retain more minerals in deep ocean water, a new hybrid membrane composed of tourmaline film as organic material onto inorganic layer of CA polymer in asymmetric structure was developed for RO membrane process. The performance tests were carried out in the permeability of pure water and the rejection of NaCl solution to evaluate the adaptability for DOW desalination. The results of these basic tests show possibility to apply the new hybrid RO membrane for the desalination with function control.