• Title/Summary/Keyword: Organic substrates

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Low-Temperature Processable Charge Transporting Materials for the Flexible Perovskite Solar Cells

  • Jo, Jea Woong;Yoo, Yongseok;Jeong, Taehee;Ahn, SeJin;Ko, Min Jae
    • Electronic Materials Letters
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    • v.14 no.6
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    • pp.657-668
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    • 2018
  • Organic-inorganic hybrid lead halide perovskites have been extensively investigated for various optoelectronic applications. Particularly, owing to their ability to form highly crystalline and homogeneous films utilizing low-temperature solution processes (< $150^{\circ}C$), perovskites have become promising photoactive materials for realizing high-performance flexible solar cells. However, the current use of mesoporous $TiO_2$ scaff olds, which require high-temperature sintering processes (> $400^{\circ}C$), has limited the fabrication of perovskite solar cells on flexible substrates. Therefore, the development of a low-temperature processable charge-transporting layer has emerged as an urgent task for achieving flexible perovskite solar cells. This review summarizes the recent progress in low-temperature processable electron- and hole-transporting layer materials, which contribute to improved device performance in flexible perovskite solar cells.

First Record of the Marsh Fly Genus Ditaeniella (Diptera: Sciomyzidae) from Korea

  • Son, Yeongjin;Suh, Sang Jae
    • Animal Systematics, Evolution and Diversity
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    • v.35 no.2
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    • pp.73-75
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    • 2019
  • Members of this family Sciomyzidae are known as marsh flies and snail-killing flies because most of the known larvae are obligate predators of Mollusca, especially freshwater and terrestrial Gastropoda. Most species are found in the shallow ephemeral aquatic habitats with rich organic substrates, such as the hard-water streams, small ponds and lakes in mountain valleys. To date, a total of 8 marsh fly species in 4 genera have been known in Korea. During a taxonomic survey of the family Sciomyzidae in Korea, the authors have found the genus Ditaeniella Sack, 1939; thus, it was discovered for the first time in Korea. This genus can be distinguished by the other related taxa with hairs over much of the mesopleuri, hairs on the prosternum and one orbital seta. In addition, the nominate species, Ditaeniella grisescens Meigen, 1830 was also firstly recoded in the Korean fauna.

Effects of Supplemental Levels of Spent Mushroom (Flammulina velutipes) Substrates on Chemical Composition and Quality of Whole Crop Sorghum Silage (팽이버섯 수확 후 배지의 첨가수준이 수수 사일리지의 화학적 조성과 품질에 미치는 영향)

  • Moon, Yea-Hwang;Lee, Sung-Sill;Kang, Tae-Won;Cho, Soo-Jeong
    • Journal of Mushroom
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    • v.10 no.3
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    • pp.136-142
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    • 2012
  • This study was carried out to determine the supplemental level of spent mushroom (Flammulina velutipes) substrates as an energy source in manufacturing of high moisture sorghum whole crop silage. Whole crop sorghum was harvested at heading stage and ensiled with spent mushroom substrates of 20% (S-20), 40% (S-40) and 60% (S-60) as fresh matter basis. Each silage was manufactured in plastic buckets included vinyl bag by three replications and stored for 0, 3, 6 and 9 weeks, respectively. Fermentation characteristics and quality of sorghum silages manufactured by supplemental level of spent mushroom substrates were as follows. Moisture contents of whole crop sorghum and spent mushroom substrates were 83.85% and 54.3%, respectively, and that of silages was 78% for S-20, 71% for S-40 and 68% for S-60. Ether extracts content of silages was significantly (P<0.05) increased during the fermentation periods. The pH in silages fermented for 3 weeks and above ranged from 4.24 to 4.42, and the decrease of pH by fermentation was relatively greater in S-40 compare to the other treatments. The lactic acid content of silage inclined that the S-40 was higher compared to the other treatments and decreased with elongation of fermentation period of silage. The contents of acetic acid and propionic acid of silages were not influenced by treatments and fermentation period. Flieg's score for estimation of silage quality ranged from 60 to 83, and was relatively high quality in the S-40 fermented for 9 week, and was relatively low quality in the S-60 fermented for 9 week. From above results, we suggest that 40% supplementation of spent Flammulina velutipes mushroom substrates as an energy source is resonable level in manufacturing of high moisture sorghum whole crop silage.

Polyesters Biosynthesis of Alcaligenes eutrophus H16(ATCC 17699) from Various Mono- and Dicarboxylic Acids and Diols

  • Song, Jae-Jun;Shin, Yong-Chul
    • Journal of Microbiology and Biotechnology
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    • v.3 no.2
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    • pp.123-128
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    • 1993
  • The polyesters (polyhydroxyalkanoates; PHAs) production capability in a two-step cultivation of Alcaligenes eutrophus H16(ATCC 17699) was investigated by using various organic carbon sources. The carbon sources used included linear $C_2~C_10$ monocarboxylic acids, $C_3~C_10$ dicarboxylic acids, crotonic acid, and several linear vicinal and $\omega$-diols. The polyesters synthesized were characterized by 500 MHz $^1 H-NMR$ spectroscopy, intrinsic viscosity$[\eta]$ measurement in chloroform and differential scanning calorimetry (DSC). The PHAs synthesis data showed that the use of C-odd ($C_3, C_5, and C_7$) monocarboxylic acids resulted in poly(3-hydroxybutyrate-co-3-hydroxyvalerate)(P(3HB-co-3HV) (3HV content ranging 40 to 70 mol%) while the use of $C_9$ substrate gave the copolyester containing only 4 mol% of 3HV. All culture products obtained on $C_3$~C$_{10}$ dicarboxylic acids gave exclusively P(3HB). 500 MHz $^1 H-NMR$ analysis showed that all polyesters synthesized generally contained 1~2 mol% 3HV even for the unrelated substrates such as the carboxylic acids with even number of carbon. When $\alpha, \omega$-diols with even number of carbon were used as substrates, 4-hydroxybutyrate(4HB) was inserted into the polyester chain composed of P(3HB-co-4HB). Vicinal diols were generally not utilized by the bacterium for polyester production.n.

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Deposition of Nanocrystals using Phase Separation on Flexible Substrates (유연기판위에 상분리를 이용한 반도체 나노입자 증착)

  • Oh, Seung-Kyun;Chung, Kook-Chae;Kim, Young-Kuk;Choi, Chul-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.284-284
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    • 2009
  • We have fabricated semiconductor nanocrystals using phase separation on flexible substrates for future application in QD-LEDs. The phase separation between the CdSe semiconductor nanocrystals and TPD organic underlayer can occur during the solvent drying, and the CdSe may rise towards the surface of the coated films, which is arranged into close packed array called self-assembly process. In this work, the polyethylene naphthalate (PEN) films of $200{\mu}m$ thickness was used as a flexible substrate, which was coated with indium tin oxide(ITO) as a transparent electrode of <$15{\Omega}/cm^2$. A number of solvents such as chloroform, toluene, and hexane was used and their coating properties were investigated using the spin coating process. The dispersion of both QD and TPD was rather poor in toluene and hexane and resulted in rougher surface and some aggregates. Meanwhile, the surface roughness of templates can be a very critical issue in the fabrication of QD-LED devices. Some experiments was performed to reduce the ~4nm surface roughness of the PEN films and It can be decreased to the minimum of ~0.7nm. Also discussed are the optical properties of semiconductor nanocrystals used in this phase separation and possible large area and continuous coating process for future application.

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Annealing under low oxygen partial pressure for crystal growth of BaTiO$_3 $thin films prepared by coating-pyrolysis process (코딩-열분해법에 의해 제조한 BaTiO$_3 $ 박막의 결정 성장을 위한 낮은 산소 분압에서의 열처리)

  • Kim, Seung-Won
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.2
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    • pp.111-115
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    • 2000
  • $BaTIO_3$ thin films were prepared on (100) $BaTIO_3$ substrates by coating- pyrolysis process using metal-organic compounds of Ba and Ti. The amorphous films prefired at $450^{\circ}C$were crystallized above $700^{\circ}C$ under oxygen partial pressure of $2\times 10^{-4}$. The lattice parameters of the perpendicular axis for the $BaTIO_3$ thin films heat-treated below $800^{\circ}C$ were closer to a value of cubic $BaTIO_3$, whereas those above $800^{\circ}C$ were closer to a value of tetragonal BaTiG. The results of XRD P scan and pole-figure analyses indicated that BaTiO, thin films have an epitaxial relationship with the $SrTiO_3$ substrates. The $BaTIO_3$thin films annealed at$800^{\circ}C$ showed the surface with island-like grains about 0.4$mu \textrm{m}$ and the cross section of 0.8 $mu \textrm{m}$ thickness with granular grains.

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The Selection Proper Materials to Develop Specialized Root Substrate for Working with Bulb Onion Transplanter (양파 정식기용 전용 상토에 적합한 상토 재료 선발)

  • Min, Byeonggyu;ha, Injong;Lee, Jongtae;Choi, Silim;Lee, Sangdae
    • Journal of Bio-Environment Control
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    • v.25 no.2
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    • pp.100-105
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    • 2016
  • In this study we investigated the suitability of horticultural main organic root substrate materials (peatmoss, coir) for the development proper root substrate for working with bulb onion transplanter. We investigated seedling sprout ratio, growth and characteristics (bulk density, root substrate cohesion) those are suitable for mechanical transplanting by mixing with inorganic materials(red clay etc.). Although both seedling growth and root substrate bulk density were similar in peatmoss and coir based root substrates, we found that peatmoss mixing had higher root substrate cohesion compared to coir mixing. We assume that higher cohesion properties of peatmoss based root substrate will give more weight of root part during mechanical transplanting of young onion seedlings in the field. Because of this, we suggest that peatmoss is the appropriate ingredient for developing root substrates for working with bulb onion transplanter.

Solvent Sensing Properties of Thin Films Based on Zinc phthalocyanine (ZnPc) Compounds (Zinc phthalocyanine(ZnPc)화합물의 이용한 유기용제 센서)

  • Kim D.H.;Kang Y.G.;Kim J.H.;Roh S.C.;Kim H.J.
    • Journal of the Korean Institute of Gas
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    • v.9 no.4 s.29
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    • pp.26-29
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    • 2005
  • In this paper, the solvent sensing properties of the metallophthalocyanine macrocyclic compounds(ZnPc) have been deposited as thin films by the spin-coated method and evaporated methods onto alumina substrates and quartz substrates. And then the spin-coated materials of Zinc phthalocyanine solutions blended with $N,N'-diphenyl-N,N'-bis(1-naphthyl)-1,\;1-biphenyl-4,4'-diamine\;and/or\; Poly[2-methoxy-5-(2'-ethylhexyloxy)-1,4-phenylene-vinylene]$ solutions. The influences of the blended metallophthalocyanine macrocyclic compounds on the resistance have been measured and analysed in five different vapour organic compounds.

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A study on copper thin film growth by chemical vapor deposition onto silicon substrates (실리콘 기판 위에 화학적 방법으로 증착된 구리 박막의 특성 연구)

  • 조남인;박동일;김창교;김용석
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.3
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    • pp.318-326
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    • 1996
  • This study is to investigate a chemical vapor deposition technique of copper film which is expected to be more useful as metallizations of microcircuit fabrication. An experimental equipment was designed and set-up for this study, and a Cu-precursor used that is a metal-organic compound, named (hfac)Cu(I)VTMS ; (hevaflouoroacetylacetonate trimethyvinylsilane copper). Base pressure of the experimental system is in $10^{-6}$ Torr, and the chamber pressure and the substrate temperature can be controlled in the system. Before the deposition of copper thin film, tungsten or titanium nitride film was deposited onto the silicon wafer. Helium has been used as carrier gas to control the deposition rate. As a result, deposition rate was measured as $1,800\;{\AA}/min$ at $220^{\circ}C$ which is higher than the results of previous studies, and the average surface roughness was measured as about $200\;{\AA}$. A deposition selectivity was observed between W or TiN and $SiO_{2}$ substrates below $250^{\circ}C$, and optimum results are observed at $180^{\circ}C$ of substrate temperature and 0.8 Torr of chamber pressure.

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Thin Film Transistor Backplanes on Flexible Foils

  • Colaneri, Nick
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.529-529
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    • 2006
  • Several laboratories worldwide have demonstrated the feasibility of producing amorphous silicon thin film transistor (TFT) arrays at temperatures that are sufficiently low to be compatible with flexible foils such as stainless steel or high temperature polyester. These arrays can be used to fabricate flexible high information content display prototypes using a variety of different display technologies. However, several questions must be addressed before this technology can be used for the economic commercial production of displays. These include process optimization and scale-up to address intrinsic electrical instabilities exhibited by these kinds of transistor device, and the development of appropriate techniques for the handling of flexible substrate materials with large coefficients of thermal expansion. The Flexible Display Center at Arizona State University was established in 2004 as a collaboration among industry, a number of Universities, and US Government research laboratories to focus on these issues. The goal of the FDC is to investigate the manufacturing of flexible TFT technology in order to accelerate the commercialization of flexible displays. This presentation will give a brief outline of the FDC's organization and capabilities, and review the status of efforts to fabricate amorphous silicon TFT arrays on flexible foils using a low temperature process. Together with industrial partners, these arrays are being integrated with cholesteric liquid crystal panels, electrophoretic inks, or organic electroluminescent devices to make flexible display prototypes. In addition to an overview of device stability issues, the presentation will include a discussion of challenges peculiar to the use of flexible substrates. A technique has been developed for temporarily bonding flexible substrates to rigid carrier plates so that they may be processed using conventional flat panel display manufacturing equipment. In addition, custom photolithographic equipment has been developed which permits the dynamic compensation of substrate distortions which accumulate at various process steps.

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