• Title/Summary/Keyword: Organic solvent

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Bioconversion of Cholesterol by Organic Solvent Tolerant Pseudomonas savastanoi BCNU 106

  • Gang, Jeong-Han;Jeong, Mi-Yeon;Kim, Mi-Rim;Park, Jeong-Uk;Ju, U-Hong
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.474-477
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    • 2000
  • An organic solvent-tolerant Pseudomonas savastanoi strain BCNU 106 was isolated.. This bacterium was gram negative rod, and showed oxidase positive, catalase positive, and decaboxylase positive reactions. The Pseudomonas strain oxidized cholesterol on the medium supplemented with an organic solvent. The strain BCNU 106 is able to grow in presence of organic solvents of which log $P_{ow}$ is between 1.5 to 7.0. The strain was well grown in a medium supplemented with a 10% volume of a organic solvent (toluene, p-xylene, cyclohexane, mesitlylene) containing $cholesterol(20mg/m{\ell)$. Major conversion compound were 7-dehydrocholesteryl dimethylphosphate, cholesta-4,7-dien-3-one, and cholesta-3,5-dieone.

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Biodegradation of Hydrocarbons by an Organic Solvent-Tolerant Fungus, Cladosporium resinae NK-1

  • Oh, Ki-Bong;Mar, Woong-Chon;Chang, Il-Moo
    • Journal of Microbiology and Biotechnology
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    • v.11 no.1
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    • pp.56-60
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    • 2001
  • A kerosene fungus of Cladosporium resinae NK-1 was examined for its ability to degrade individual n-alkanes and aromatic hydrocarbons by gas chromatography-mass spectrometry, and its organic solvent-tolerance was investigated by making use of the water-organic solvent suspension culture method. It grew on a wide range of solvents of varying hydrophobicities and it was found to have tolerance to various kinds of toxic organic solvents (10%, v/v) such as n-alkanes, cyclohexane, xylene, styrene, and toluene. A hydrocarbon degradation experiment indicated that NK-1 had a greater n-alkane degrading ability compared to that of the other selected strains. C. resinae NK-1, which could utilize 8-16 carbon chain-length n-alkanes of medium chain-length as a carbon source, could not assimilate the shorter chain-length n-alkanes and aromatic hydrocarbons tested so far. The n-alkane degrading enzyme activity was found in the mycelial extract of the organism.

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Stabilization of HRP Using Hsp90 in Water-miscible Organic Solvent (Hsp90을 이용한 유기용매에서의 과산화효소 안정화 연구)

  • Chung, Ja Hee;Choi, Yoo Seong;Song, Seung Hoon;Yoo, Young Je
    • Korean Chemical Engineering Research
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    • v.44 no.1
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    • pp.92-96
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    • 2006
  • Enzymes in organic media afford many advantages such as chiral synthesis and resolution, modification of fats and oils and production of biodegradable polymers. However, the nature of solvents influences the activity and stability of enzymes, and the presence of organic solvents always constitute a risk of enzyme inactivation. Heat-shock protein Hsp90, one of the molecular chaperone, was applied for understanding of enzyme inactivation and for increasing of enzyme stability in water-miscible organic solvent. Hsp90 showed stabilization effect on HRP in the 30% of DMSO, in the 30% and 50% of dioxane. Hsp90 also showed reactivation effect on the inactivated HRP by water-miscible organic solvent such as dioxane and DMSO. In addition, structural analysis using fluorescence spectrophotometry and circular dichroism showed that exposure of HRP in water-miscible organic solvent caused appreciable conformational changes and enzyme inactivation, and the unfolded HRP by water-miscible organic solvent was refolded by Hsp90.

Separation of Organic Pollutants by Nondispersive Membrane-Solvent Extraction (비분산 막-용매추출에 의한 유기오염물의 분리)

  • 유홍진;한성록
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.5 no.2
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    • pp.174-185
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    • 2004
  • Organic pollutants (Phenol, 2-Chlorophenol, Nitrobenzene) were separated from wastewater by nondispersive membrane solvent extraction, using a microporous hydrophobic hollow fiber module. The system was operated countercurrently and cocurrently with the aqueous phase flowing through the fiber lumens and the solvent flowing through the shell side. The distribution coefficients of several solvents (MIBK, IPAc, Hexane) were examined and MIBK was selected as an extracting solvent. Separation efficiency of countercurrent flow method was better than that of cocurrent flow method. Also, the overall mass transfer coefficients were determined.

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A Study on the Preparation of High Purity Silicic Acid by Solvent Extraction from Sodium Silicate (규산 나트륨으로부터 유기 용매 추출에 의한 고순도 규산 제조에 관한 연구)

  • Rho, Jae-Seong;Hong, Seong-Su;Chung, Hung-Ho
    • Applied Chemistry for Engineering
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    • v.7 no.4
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    • pp.802-808
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    • 1996
  • Silicic acid(SA) was extracted with organic solvents from aqueous sodium silicate solutions acidified with dilute sulfuric acid. Tetrahydrofuran(THF), isopropyl alcohol and acetone were used as organic solvents. The extraction degree of Si and the removal efficiency of Na is determined according to kinds of solvent and the mixing ratios of solvent, sodium chloride and $H_2O$. Optimum conditions for the preparation of high purity SA were THF as an organic solvent, volume ratio of organic solvent/SA : 1 (organic solvent 10ml/10ml SA) and the amount of NaCl addition 2.5g/10ml SA. The extraction degree of Si and the removal efficiency of Na at that point were 86.2% and 99.95% respectively and the purity of SA was 99.96%.

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Preparation and Characterization Study of PET Nanofiber-reinforced PEI Membrane, Investigation of the Application of Organic Solvent Nanofiltration Membrane (PET 나노섬유 강화 PEI 막의 제조 및 특성화 연구, 그에 따른 유기용매 나노여과막 가능성 검증)

  • Sung-Bae Hong;Kwangseop Im;Dong-Jun Kwon;Sang Yong Nam
    • Journal of Adhesion and Interface
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    • v.24 no.1
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    • pp.17-25
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    • 2023
  • In this study, waste polyethylene terephthalate (PET) was recycled to produce a support and then polyetherimide (PEI) was used for environmentally friendly organic solvent nanofiltration. The prepared composite membrane was first prepared by electrospinning a PET support, then casted on the support using PEI having excellent solvent resistance, and organic solvent nanoparticles using a Non-solvent Induced Phase Separation (NIPS) method. A filtration membrane was prepared. First, the fiber diameter and tensile strength of the PET scaffold prepared prior to membrane fabrication were identified through morphology analysis, and the optimal scaffold for the organic solvent nanofiltration membrane was identified. Afterward, the PET/PEI composite membrane prepared was checked for the DEA removal rate of Congo red having a molecular weight of 697 g/mol in ethanol to understand the performance as an organic solvent nanofiltration membrane according to the concentration of PEI. Finally, the removal rate of Congo red was 90% or more.

The Effect of Organic Solvents on the Activity for the Synthesis of 12wt% Co-based FT Catalyst (12wt% Co 담지 FT 촉매 제조시 유기용매가 촉매활성에 미치는 영향연구)

  • LEE, JIYUN;HAN, JA-RYOUNG;CHUNG, JONGTAE;BAEK, YOUNGSOON
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.4
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    • pp.339-346
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    • 2015
  • The synthesis of Fischer-Tropsch (FT) oil is the catalytic hydrogenation of CO to give a range of products, which can be used for the production of high-quality diesel fuel, gasoline and linear chemicals. This studied catalyst was prepared Cobalt-supported alumina and silica by the incipient wet impregnation of the nitrates of cobalt, promoter and organic solvent with supports. Cobalt catalysts were calcined at $350^{\circ}C$ before being loaded into the FT reactors. After the reduction of catalyst has been carried out under $450^{\circ}C$ for 24h, FT reaction of the catalyst has been carried out at GHSV of 4,000/hr under $200^{\circ}C$ and 20atm. From these experimental results, we have obtained the results as following; In case of $SiO_2$ catalysts, the activity of 12wt% $Cobalt-SiO_2$ synthesized by organic solvent was about 2 or 3 times higher than the activity of 12wt% $Cobalt-SiO_2$ catalyst synthesized without organic solvent. In particular, the activity of the $Cobalt-SiO_2$ catalyst prepared in the presence of an organic solvent P was two to three times higher than that of the $Cobalt-SiO_2$ catalyst prepared without the organic solvent. Effect of Cr and Cu metal as a promoter was found little. 200 h long-term activity test was performed with a $Co/SiO_2$ catalyst prepared in the presence of an organic solvent of Glyoxal solution.

Removal of Organic Pollutants from Aqueous Solution by Hollow Fiber Module (중공사모듈에 의한 수용액으로부터 유기오염물의 제거)

  • 유홍진
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.4 no.2
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    • pp.114-119
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    • 2003
  • This study is to remove several organic pollutants from wastewater by non-dispersive membrane solvent extraction technique. The distribution coefficients of several solvents were determined and the experimental system was operated counter-currently and cocurrently with respect to the aqueous phase and solvent. In these experiments, as the flow rate of aqueous solution inclosed, due to being shortened contact time to solvent, the rate of removal of organic pollutants decreased and as the flow rate of solvent increased, the rate of removal increased. Meanwhile, the rate of removal of organic pollutants for the countercurrent flow system was higher than that for the occurrent flow system.

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Effect on Organic Solvent of Fabrication Processing in Epoxy Nanocomposites (나노복합재료에서의 유기용매의 영향)

  • Park, Jae-Jun;Ahn, Joon-Ho;Hwang, Byung-Joon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.206-206
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    • 2007
  • The nano-technology becomes a key technology in every field and it wasn't specialized any more. But nano-technology didn't applied every fields actively. Because It is difficult to fabricate the nanocomposites using nano-partie without aggregation of nano-size particles. So many researcher used organic solvent for dispersion in polymer nanocomposites. But organic solvent affected the electrical, mechanical, and thermal properties in the sample. We aimed this point that investigated the effect of organic solvent in the sample by evaporated temperature(60, 80, $100^{\circ}C$). In results, nano-particles affected to electrical properties of the sample due to decrease the energy gap. And at 120 Hz, impedance value of samples by varied evaporated temperature was decreased only at $60^{\circ}C$ dramatically. It's means that organic solvent role to impurities and decreased the activation energy. And these impurities contributed to the conductivity in the sample.

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Solvent Vapor Annealing Effects in Contact Resistances of Zone-cast Benzothienobenzothiophene (C8-BTBT) Transistors

  • Kim, Chaewon;Jo, Anjae;Kim, Heeju;Kim, Miso;Lee, Jaegab;Lee, Mi Jung
    • Journal of the Korean Ceramic Society
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    • v.53 no.4
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    • pp.411-416
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    • 2016
  • Benzothienobenzothiophene ($C_8-BTBT$) is a soluble organic small molecule material with high crystallinity resulting from its strong self-organizing properties. In addition, the high mobility and easy fabrication of $C_8-BTBT$ make it very attractive in terms of organic thin-film transistors. In this work, we made $C_8-BTBT$ thin films by using the zone-casting method; we also used an organic solvent to treat the devices with solvent vapor annealing to improve the electrical properties. As a result, we confirmed improved mobility, threshold voltage, and subthreshold swing after solvent vapor annealing. To prove the effect of solvent vapor annealing, we used the simultaneous extraction model to extract the contact resistance from the current-voltage curve. We confirmed that the electrical properties improved with decreasing contact resistance.