• Title/Summary/Keyword: Organic removal

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The Effects of Changing of Hydraulic Retention Time and Charging Media on the Removal of Nitrogen and Phosphorus in the Up-flow Anaerobic/Anoxic Reactor and Water-mill for Sewage Treatment (상향류식 혐기성조, 무산소조 및 수차호기조를 이용한 하수처리시 수리학적 체류시간의 변화와 메디아 충진이 질소 및 인 제거에 미치는 영향)

  • Shin, Myoung-Chul;Lee, Young-Shin
    • Journal of Environmental Health Sciences
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    • v.35 no.1
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    • pp.64-70
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    • 2009
  • The aims of this study is to examine the effects of the changes in HRT(Hydraulic Retention Time) and media charge in a water-mill, among other operation factors, on the nitrogen and phosphorus removal in order to use up-flow anaerobic reactors, anoxic reactors and water-mill aerobic reactors for sewage treatment. The extension of HRT improved the nitrogen removal efficiency, however the removal pattern was constant regardless of HRT. The removal of phosphorus was constant (80%-90%) regardless of the change in HRT. The removal rate with change in influx load varied such that at the OLR (Organic Load Rate) of 1-3 kg/d, the T-N removal efficiency was 80.7%-88.9% and the T-P removal efficiency was 82.9%-89.3% while at the NLR (Nitrogen Loading Rate) of 0.108-0.156 kg/d the removal efficiencies were 80.7-88.9% (T-N) and 82.9-89.3% (T-P). The analyses of the nitrogen and phosphorous removal characteristics with the C/N and C/P ratio showed that the mean T-N removal rate was 88% at the C/N ratio of 1.2-2.6, and that the mean T-P removal rate was 86% at the C/P ratio of 7.2-14.1. Also, the analysis of nitrogen and phosphorous removal characteristics were analyzed in relation to media charge. The comparison between with and without media charge in the water-mill showed that while the nitrogen removal efficiencies were 86-94% and 85-89% respectively, the difference of phosphorous removal efficiencies were between the two conditions was not significant, thus it suggested that the media charge has less effect on the removal efficiency of phosphorous compared to that of nitrogen.

Reduced Post-Chlorine Dosage Required for Disinfection: Improvement with Ozonation and GAC Process (오존 및 입상활성탄 도입시 후염소 주입량 저감효과 분석)

  • Baek, Young-Ae;Joe, Woo-Hyeun;Kim, Jong-Moon;Choi, Young-Jun
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.4
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    • pp.445-452
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    • 2007
  • This study was carried out to examine effect of post-chlorine dosage reduction by ozonation and GAC process in the field plant for 3years in the "G" water purification plant in Seoul. And it is to compare GAC with BAC process in removal effects of TOC, THMs, THMFP, $UV_{254}$. As a result, chlorine dosage of ozonation and GAC(=BAC) is less demand than GAC. Seasonal reduction of chlorine demand is from about 37% to 59% with BAC, and from 24 to 46% with GAC. Higher reduction in BAC could be achieved. The efficiency of chlorine demand reduction with ozonation was depending on the organic carbon removal. $UV_{254}$ concentration is less about 0.13~0.74L/mg.m in BAC than GAC. Therefore, the combination of ozonation and GAC was more effective in reducing post-chlorine than the single GAC. TOC was also monitored, and results show that a linear relationship between TOC and chlorine demand is appropriate under each treatment process. It means that removal of organic matter(TOC) from finished water is necessary to reduce post-chlorine dosage in clear well and to minimize order of chlorine in distribution systems.

Control of Excessive Biofilm for the Treatment of High Strength Organic Wastewater by Biofilm Process (생물막공법에 의한 고농도 유기폐수 처리시 생물막 과부착 제어)

  • 임재명;권재혁;한동준
    • Journal of environmental and Sanitary engineering
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    • v.10 no.3
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    • pp.67-77
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    • 1995
  • This study was performed for minimization of excessive biofilm effects at the high strength organic wastewater treatment. As a results of biofilm attachment experiment using piggery wastewater, aggravation of water quality due to excessive biofilm showed after 15 days of operating times.4 excessive biofilm phase, the equivalent biofilm thickness and VSS contents per unit aura were observed in the range of 1,100 to $1,200{\mu}m$ and 2.5 to 3.0mg $VSS/cm^{2}$, respectively. In the aerobic fixed biofilm reactor/anoxic fixed biofilm reactor(AFBR/ANFBR) process with endogenous respiration phase, the BOD removal efficiency was obtained more than 90 percentage at the surface loading rate and volumetric loading rate of the AFBR maintained less than 17 g $BOD/m^{2}{\cdot}$day and 1.7kg $BOD/m^{3}{\cdot}$day, respectively. The removal efficiency of TKN and $NH_{3}$-N at the loading rates below 5.60g $NH_{3}-N/m^{2}{\cdot}day$ and 0.56kg $NH_{3}-N/m^{3}{\cdot}$day were above 76 percentage and 82 percentage, respectively. In order to reduced sludge production rate and aggravation of water quality, endogenous respiration phase was accepted at first AFBR reactor. As a results of this operating condition, sludge production was minimized and removal efficiency was maintained stability.

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Effect of the Presence of Soil on the Ferrous Catalyzed Sodium Persulfate Oxidation of Naphthalene (과황산나트륨과 제일철 촉매를 이용한 나프탈렌 산화 시 토양이 미치는 영향 평가)

  • Han, Dai-Sung;Yun, Yeo-Bog;Ko, Seok-Oh
    • Journal of Soil and Groundwater Environment
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    • v.15 no.1
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    • pp.29-38
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    • 2010
  • Batch tests were carried out to examine the influence of the presence of soil and Fe(II) sorption capacity of soil on the ferrous catalyzed sodium persulfate oxidation for the destruction of organic pollutants in the application of in-situ chemical oxidation. Laboratory column tests were also conducted to investigate the transport of oxidant and catalyst in contaminated groundwater. Test results proved that Fe(II) was adsorbed on soil surface, and thus soil behaved as a heterogeneous catalyst, enhancing the naphthalene removal rate up to 50%. Column tests that were conducted with and without dissolved Fe(II) showed that naphthalene removal ratio were 24% and 25%, respectively. The removal efficiency was not enhanced with dissolved Fe(II), since the dissolved Fe(II) flew out of the column as the oxidant progressively injected into the column saturated with Fe(II). It indicates that the injected oxidant could not interact with dissolved Fe(II). But target organic pollutant was degraded in soil column system, implying that sulfate radical was produced by the reaction of dissolved persulfate with Fe(II) adsorbed on soil.

Efficiency Evaluation of Adsorbents for the Removal of VOC and NO2 in an Underground Subway Station

  • Son, Youn-Suk;Kang, Young-Hoon;Chung, Sang-Gwi;Park, Hyun-Ju;Kim, Jo-Chun
    • Asian Journal of Atmospheric Environment
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    • v.5 no.2
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    • pp.113-120
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    • 2011
  • Adsorbent combination studies have been carried out to remove nitrogen dioxide ($NO_2$) and volatile organic compounds (VOCs: BTEX) out of a subway environment characterized by high flow and low concentration. Optimal conditions for the high removal efficiency of the concerned target compounds were obtained through testing a series of control factors such as adsorbent sorts, thicknesses, and superficial velocity. It was found that the efficiencies increased as the specific surface area of activated carbon and its thickness increased, and external void fraction decreased. Furthermore, mixed activated carbon with granular and constructed contents was extensively tested to reduce pressure drop through the carbon bed. It was found that the performance of higher contents of granular activated carbon was better than that of higher contents of the constructed carbon. When the mixed carbon was applied to the subway ventilation system in order to eliminate $NO_2$ and VOC simultaneously, the removal efficiencies were found to be 75% and 85%, respectively.

Anaerobic/oxic Treatment of Slurry-type Swine Waste

  • Won, Chul-Hee;Rim, Jay-Myoung
    • Environmental Engineering Research
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    • v.13 no.4
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    • pp.203-209
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    • 2008
  • This paper presents the experimental results in five months operation from a combined anaerobic/oxic system treating swine waste with average concentrations in organic matter and nitrogen of 7,930 mgCOD/L and 671 mgTKN/L, respectively. The system was formed using an upflow anaerobic sludge blanket (UASB) reactor and oxic reactor connected in series with a recycling line of oxic effluents to UASB for its denitrification. The UASB reactor was operated at an organic volumetric loading rate (VLR) of $2.1{\sim}4.5\;kgTCOD/m^3$/day and the removal efficiency of TCOD was $66.3{\sim}85.4%$. The overall removal efficiency of TCOD was more than 99%. The oxic reactor was operated at a nitrogen VLR of $0.10{\sim}0.20\;kgTKN/m^3$/day and the nitrification efficiency was 75%. However, the complete denitrification was observed in the UASB reactor that was due to the optimal temperature and sufficient carbon source. The overall removal rate of TN was about 80%. About 76.2% of the influent COD mass was accountable in a COD mass balance at a level of VLR $3.64\;kgCOD/m^3$/day. The production rate of methane was $0.32\;LCH_4/gCOD_{removed}$ when influent organics, VLR, were recorded by $3.4{\sim}4.5\;kgCOD/m^3$/day.

Anaerobic Hydrogen Fermentation and Membrane Bioreactor (MBR) for Decentralized Sanitation and Reuse-Organic Removal and Resource Recovery

  • Paudel, Sachin;Seong, Chung Yeol;Park, Da Rang;Seo, Gyu Tae
    • Environmental Engineering Research
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    • v.19 no.4
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    • pp.387-393
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    • 2014
  • The purpose of this study is to evaluate integrated anaerobic hydrogen fermentation and membrane bioreactor (MBR) for on-site domestic wastewater treatment and resource recovery. A synthetic wastewater (COD 17,000 mg/L) was used as artificial brown water which will be discharged from urine diversion toilet and fed into a continuous stirred tank reactor (CSTR) type anaerobic reactor with inclined plate. The effluent of anaerobic reactor mixed with real household grey water (COD 700 mg/L) was further treated by MBR for reuse. An optimum condition maintained in anaerobic reactor was HRT of 8 hrs, pH 5.5, SRT of 5 days and temperature of $37^{\circ}C$. COD removal of 98% was achieved from the overall system. Total gas production rate and hydrogen content was 4.6 L/day and 52.4% respectively. COD mass balance described the COD distribution in the system via reactor byproducts and effluent COD concentration. The results of this study asserts that, anaerobic hydrogen fermentation combined with MBR is a potent system in stabilizing waste strength and clean hydrogen recovery which could be implemented for onsite domestic wastewater treatment and reuse.

Excellent toluene removal via adsorption by honeycomb adsorbents under high temperature and humidity conditions

  • Cho, Min-Whee;Kim, Jongjin;Jeong, Jeong Min;Yim, Bongbeen;Lee, Hyun-Jae;Yoo, Yoonjong
    • Environmental Engineering Research
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    • v.25 no.2
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    • pp.171-177
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    • 2020
  • Removal through adsorption is the most widely used and effective treatment method for volatile organic compounds (VOCs) in exhaust gases. However, at high temperatures and humidity, adsorption is competitive due to the presence of moisture and unsmooth physical adsorption thereby deteriorating adsorption performance. Therefore, water adsorption honeycomb (WAH) and VOCs adsorption honeycomb (VAH) were prepared to improve VOCs adsorption at high temperatures and humidity. Adsorbed toluene amounts on single honeycomb (SH), containing only VAH, and combined honeycomb (CH), containing WAH and VAH, were determined. Further, the toluene adsorption rates of honeycomb adsorbents mounted on rotary systems, VAH-single rotor (SR) and WAH/VAH-dual rotor (DR) were determined. Toluene adsorption by WAH/VAH-CH (inlet temperature: 40-50℃; absolute humidity: 28-83 gH2O/kg-dry air) was 1.6 times that by VAH-SH, and the water adsorption efficiency of WAH/VAH-CH was 1.7 times that of VAH-SH. The adsorption/removal efficiency of the WAH/VAH-DR (inlet temperature: 45℃; absolute humidity: 37.5 gH2O/kg-dry air) was 3% higher than that of VAH-SR. This indicates that the WAH at the rotor inlet selectively removed water, thereby improving the adsorption efficiency of the VAH at the outlet.

Removal of heavy metal and Hydrogen sulfide/Nitrophenol using Mackban-stone (맥반석을 이용한 중금속과 악취물질/nitrophenol의 제거)

  • Quen, Zhe-Xue;Yin, Cheng-Ri;Jin, Yin-Shu;Seok, Mi-Soo;Lee, Sung-Taik
    • Journal of the Korea Organic Resources Recycling Association
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    • v.9 no.2
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    • pp.45-51
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    • 2001
  • Mackban-stone effectively removed heavy metals, such as Fe, Cu, Cd, and Zn, with best removal of Fe and Cu. And the removal of heavy merals related with ion exchange of Ca. Mackban-stone is also an efficient deodorant of hydrogen sulfide and ammonia and inhibited the growth of E coli. The degradation rare of 4-nitropheno1 by Nocardioides sp. PNP101 and 2,4-dinitrophenol by Strain CJ1 and Rhodococcus sp. DNP 505 are increased by Mackbane-srone.

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A Study on Heavy Metal Removal Using Alginic Acid (알긴산을 이용한 중금속 제거에 관한 연구)

  • Jeon, Choong;Choi, Suk Soon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.15 no.4
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    • pp.107-114
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    • 2007
  • A study on the removal of heavy metals using alginic acid, a kind of polysaccharides, was performed. Alginic acid adsorbed 480 mg Pb/g dry mass at pH 4, which was about twice as high as uptake capacity of other biosorbents. Isothermal adsorption curve for lead ions was described by the Langmuir model equation and the experimental data well fitted to model equation. The adsorption of lead ions was an endothermic process since binding strength increased with temperature. The effect of alkali metal ions ($Ca^{2+}$ and $Mg^{2+}$) on lead sorption capacity was negligible and most adsorption process was completed in 30min. The uptake capacity of other metals such as, copper, mercury, strontium, and cesium ions using alginic acid was also investigated.

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